DE2166543B2 - Plastische positive elektrode fuer galvanische elemente mit feststoffelektrolyten - Google Patents
Plastische positive elektrode fuer galvanische elemente mit feststoffelektrolytenInfo
- Publication number
- DE2166543B2 DE2166543B2 DE19712166543 DE2166543A DE2166543B2 DE 2166543 B2 DE2166543 B2 DE 2166543B2 DE 19712166543 DE19712166543 DE 19712166543 DE 2166543 A DE2166543 A DE 2166543A DE 2166543 B2 DE2166543 B2 DE 2166543B2
- Authority
- DE
- Germany
- Prior art keywords
- iodine
- cathode
- cells
- cell
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920003023 plastic Polymers 0.000 title claims description 21
- 239000004033 plastic Substances 0.000 title claims description 21
- 239000007784 solid electrolyte Substances 0.000 title claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 61
- 239000011630 iodine Substances 0.000 claims description 61
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 59
- 229910052744 lithium Inorganic materials 0.000 claims description 36
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 35
- 238000012546 transfer Methods 0.000 claims description 25
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 11
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 9
- XUGNJOCQALIQFG-UHFFFAOYSA-N 2-ethenylquinoline Chemical compound C1=CC=CC2=NC(C=C)=CC=C21 XUGNJOCQALIQFG-UHFFFAOYSA-N 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 6
- 210000004027 cell Anatomy 0.000 description 84
- 239000010406 cathode material Substances 0.000 description 21
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 229950000688 phenothiazine Drugs 0.000 description 11
- 238000005259 measurement Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 8
- -1 metal halide compound Chemical class 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229910052709 silver Inorganic materials 0.000 description 6
- 239000004332 silver Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 4
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 229910020486 P2VP Inorganic materials 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000003487 electrochemical reaction Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000011368 organic material Substances 0.000 description 4
- 230000010287 polarization Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000004382 potting Methods 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920005479 Lucite® Polymers 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 2
- 210000003850 cellular structure Anatomy 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- IINNWAYUJNWZRM-UHFFFAOYSA-L erythrosin B Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IINNWAYUJNWZRM-UHFFFAOYSA-L 0.000 description 2
- 239000004174 erythrosine Substances 0.000 description 2
- 229940011411 erythrosine Drugs 0.000 description 2
- 235000012732 erythrosine Nutrition 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920000128 polypyrrole Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- SZUVGFMDDVSKSI-WIFOCOSTSA-N (1s,2s,3s,5r)-1-(carboxymethyl)-3,5-bis[(4-phenoxyphenyl)methyl-propylcarbamoyl]cyclopentane-1,2-dicarboxylic acid Chemical compound O=C([C@@H]1[C@@H]([C@](CC(O)=O)([C@H](C(=O)N(CCC)CC=2C=CC(OC=3C=CC=CC=3)=CC=2)C1)C(O)=O)C(O)=O)N(CCC)CC(C=C1)=CC=C1OC1=CC=CC=C1 SZUVGFMDDVSKSI-WIFOCOSTSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- NUIURNJTPRWVAP-UHFFFAOYSA-N 3,3'-Dimethylbenzidine Chemical compound C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 description 1
- VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- LPSCRKGVODJZIB-UHFFFAOYSA-N [I].[C] Chemical compound [I].[C] LPSCRKGVODJZIB-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 241001233037 catfish Species 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940126543 compound 14 Drugs 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- JGUQDUKBUKFFRO-CIIODKQPSA-N dimethylglyoxime Chemical compound O/N=C(/C)\C(\C)=N\O JGUQDUKBUKFFRO-CIIODKQPSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920003228 poly(4-vinyl pyridine) Polymers 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 150000003220 pyrenes Chemical class 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- GVIJJXMXTUZIOD-UHFFFAOYSA-N thianthrene Chemical compound C1=CC=C2SC3=CC=CC=C3SC2=C1 GVIJJXMXTUZIOD-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/182—Cells with non-aqueous electrolyte with solid electrolyte with halogenide as solid electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Hybrid Cells (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4180170A | 1970-06-01 | 1970-06-01 | |
| US10665771A | 1971-01-15 | 1971-01-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2166543A1 DE2166543A1 (de) | 1974-09-05 |
| DE2166543B2 true DE2166543B2 (de) | 1977-08-18 |
Family
ID=26718545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712166543 Ceased DE2166543B2 (de) | 1970-06-01 | 1971-05-26 | Plastische positive elektrode fuer galvanische elemente mit feststoffelektrolyten |
Country Status (10)
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2909364A1 (de) * | 1978-03-13 | 1979-09-27 | Medtronic Inc | Elektrochemische zelle und verfahren zur herstellung einer solchen zelle |
| DE2912830A1 (de) * | 1978-04-03 | 1979-10-11 | Catalyst Research Corp | Batterie, depolarisator zur verwendung in dieser batterie und verfahren zur herstellung des depolarisators |
| DE3023969A1 (de) * | 1979-06-28 | 1981-01-08 | Union Carbide Corp | Ladungstransferkomplex-kathoden fuer festelektrolyt-elemente |
| DE3033432A1 (de) * | 1979-09-07 | 1981-04-02 | Catalyst Research Corp., Baltimore, Md. | Depolarisatoren fuer lithiumhalogenid-batterien |
| DE3111224A1 (de) * | 1980-03-28 | 1982-02-18 | Union Carbide Corp., 10017 New York, N.Y. | Positive ladungstransferkomplexelektroden fuer festelektrolytzellen |
| DE3111261A1 (de) * | 1980-03-28 | 1982-03-04 | Union Carbide Corp., 10017 New York, N.Y. | Positive ladungstransferkomplexelektroden fuer festelektrolytzellen |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3773557A (en) * | 1972-03-01 | 1973-11-20 | Wurlitzer Co | Solid state battery |
| US3895962A (en) * | 1972-03-01 | 1975-07-22 | Greatbatch W Ltd | Solid state battery and method of making the same |
| US3874929A (en) * | 1973-03-05 | 1975-04-01 | Wilson Greatback Ltd | Lithium-iodine battery |
| US3957533A (en) * | 1974-11-19 | 1976-05-18 | Wilson Greatbatch Ltd. | Lithium-iodine battery having coated anode |
| US3944433A (en) * | 1975-01-09 | 1976-03-16 | Wilson Greatbatch | Lithium iodine battery having improved energy density |
| US3937635A (en) * | 1975-01-09 | 1976-02-10 | Wilson Greatbatch | Lithium-iodine battery |
| US3969142A (en) * | 1975-03-10 | 1976-07-13 | Wilson Greatbatch Ltd. | Lithium iodine battery |
| US4049890A (en) * | 1975-04-03 | 1977-09-20 | Catalyst Research Corporation | Lithium-iodine cells and method for making same |
| US4072803A (en) * | 1976-08-20 | 1978-02-07 | Catalyst Research Corporation | Lithium halide cell |
| US3996066A (en) * | 1975-07-22 | 1976-12-07 | Eleanor & Wilson Greatbatch Foundation | Lithium-iodine battery |
| JPS536841A (en) * | 1976-07-09 | 1978-01-21 | Matsushita Electric Ind Co Ltd | Battery |
| US4182797A (en) * | 1975-09-17 | 1980-01-08 | Matsushita Electric Industrial Co., Ltd. | Primary battery utilizing iodine charge transfer complex having a quaternary ammonium group |
| US4058889A (en) * | 1975-09-29 | 1977-11-22 | Eleanor & Wilson Greatbatch Foundation | Method of making a lithium-bromine cell |
| DE2546585C3 (de) * | 1975-10-17 | 1981-04-16 | Varta Batterie Ag, 3000 Hannover | Verfahren zur Herstellung von galvanischen Elementenmit negativen Elektroden aus Lithium oder Kalzium |
| US4092464A (en) * | 1976-07-19 | 1978-05-30 | P. R. Mallory & Co. Inc. | Flexible cells and batteries formed therefrom |
| DE2829031C3 (de) * | 1977-07-07 | 1982-05-19 | Matsushita Electric Industrial Co., Ltd., Kadoma, Osaka | Galvanische Zelle mit einem festen Elektrolyten aus Lithiumjodid |
| US4117212A (en) * | 1977-11-02 | 1978-09-26 | Wilson Greatbatch Ltd. | Lithium-iodine battery |
| US4132836A (en) * | 1977-11-21 | 1979-01-02 | Eleanor & Wilson Greatbatch Foundation | Alkali metal-halogen cell having mixed halogen cathode |
| US4217403A (en) * | 1978-04-17 | 1980-08-12 | Catalyst Research Corporation | Lithium halide battery |
| US4147842A (en) * | 1978-06-14 | 1979-04-03 | Eleanor & Wilson Greatbatch Foundation | Lithium-bromine cell |
| US4166887A (en) * | 1978-06-19 | 1979-09-04 | Wilson Greatbatch Ltd. | Lithium halogen cell including activated charcoal |
| US4211832A (en) * | 1978-12-07 | 1980-07-08 | Wilson Greatbatch Ltd. | Lithium-halogen cell including monomer charge transfer complex |
| US4287319A (en) * | 1979-01-24 | 1981-09-01 | Medtronic, Inc. | Compositions of polyvinylpyridine and iodine |
| US4210706A (en) * | 1979-04-30 | 1980-07-01 | Medtronic, Inc. | Cathode materials for electrochemical cells |
| US4332865A (en) * | 1979-10-08 | 1982-06-01 | Matsushita Electric Industrial Co., Ltd. | Process for producing solid electrolyte primary cell |
| DE3039900C2 (de) * | 1979-10-29 | 1983-11-03 | Hitachi, Ltd., Tokyo | Trockenelektrolyt |
| US4278745A (en) * | 1980-02-25 | 1981-07-14 | Medtronic, Inc. | Cathode materials for electrochemical cells |
| US4442187A (en) * | 1980-03-11 | 1984-04-10 | University Patents, Inc. | Batteries having conjugated polymer electrodes |
| US4393125A (en) * | 1980-04-21 | 1983-07-12 | Medtronic, Inc. | Battery cathodes |
| US4314010A (en) * | 1980-09-29 | 1982-02-02 | Union Carbide Corporation | Solid state cell employing an electron donor-embedded anode |
| US4333996A (en) * | 1980-09-29 | 1982-06-08 | Union Carbide Corporation | Solid state cell in which an inert nonconductive material is dispersed in the cathode |
| US4292380A (en) * | 1980-10-23 | 1981-09-29 | Catalyst Research Corporation | Two-cell battery structure |
| US4340651A (en) * | 1980-11-12 | 1982-07-20 | Medtronic, Inc. | Cathode material and high capacity lithium-iodine cells |
| US4761355A (en) * | 1980-11-24 | 1988-08-02 | Medtronic, Inc. | Electrochemical cells and cathode materials |
| DE3118630A1 (de) * | 1981-05-11 | 1982-11-25 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von elektrisch leitfaehigen polymeren und deren verwendung in der elektrotechnik und zur antistatischen ausruestung von kunststoffen |
| US4430397A (en) | 1981-07-06 | 1984-02-07 | Medtronic, Inc. | Electrochemical cells |
| US4616167A (en) * | 1981-07-13 | 1986-10-07 | Karl Adler | Electronic apparatus |
| US4398346A (en) * | 1981-10-23 | 1983-08-16 | Medtronic, Inc. | Method for lithium anode and electrochemical cell fabrication |
| JPS58121569A (ja) * | 1982-01-14 | 1983-07-19 | Hitachi Ltd | プラスチツク２次電池 |
| FR2522158A1 (fr) * | 1982-02-23 | 1983-08-26 | Thomson Csf | Dispositif de detection de presence ou d'absence d'une quantite de charge, et de memorisation du resultat de cette detection |
| JPS58169769A (ja) * | 1982-03-30 | 1983-10-06 | Toshiba Corp | 固体電解質電池 |
| DE3227914A1 (de) * | 1982-07-27 | 1984-02-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zum verarbeiten von elektrisch leitfaehigen pyrrol-polymeren sowie nach diesem verfahren herstellbare mehrschichtenelemente |
| FR2534073A1 (fr) * | 1982-10-05 | 1984-04-06 | Commissariat Energie Atomique | Generateur electrochimique utilisable notamment comme batterie comportant du polypyrrole comme matiere active d'electrode |
| DE3244900A1 (de) * | 1982-12-04 | 1984-06-07 | Basf Ag, 6700 Ludwigshafen | Batterie oder elektrochemischer speicher auf basis von elektrochemisch oxidierbaren und/oder reduzierbaren polymeren |
| US4501876A (en) * | 1983-07-18 | 1985-02-26 | E. I. Du Pont De Nemours And Company | Film-forming poly(conjugated polymethine-type)dye |
| EP0161318B1 (en) * | 1983-08-30 | 1992-11-04 | MITSUI TOATSU CHEMICALS, Inc. | Iodine cell |
| US4584251A (en) * | 1983-12-23 | 1986-04-22 | Ciba-Geigy Corporation | Solid electrolyte cell and iodine-doped metal complexes as the cathode material |
| JPH079811B2 (ja) * | 1987-09-09 | 1995-02-01 | シャープ株式会社 | 電池の製造方法 |
| DE3838329A1 (de) * | 1987-11-11 | 1989-05-24 | Ricoh Kk | Negative elektrode fuer sekundaerbatterie |
| US5019468A (en) * | 1988-10-27 | 1991-05-28 | Brother Kogyo Kabushiki Kaisha | Sheet type storage battery and printed wiring board containing the same |
| US5124508A (en) * | 1990-08-14 | 1992-06-23 | The Scabbard Corp. | Application of sheet batteries as support base for electronic circuits |
| US5147985A (en) * | 1990-08-14 | 1992-09-15 | The Scabbard Corporation | Sheet batteries as substrate for electronic circuit |
| US5478667A (en) * | 1992-10-29 | 1995-12-26 | Shackle; Dale R. | Heat dissipating current collector for a battery |
| US5486680A (en) * | 1994-01-10 | 1996-01-23 | Lieberman; Mitchell J. | Warming system using a flexible battery |
| CN1174515C (zh) * | 1999-11-29 | 2004-11-03 | 松下电器产业株式会社 | 非水电解质电池 |
| US7335441B2 (en) * | 2001-08-20 | 2008-02-26 | Power Paper Ltd. | Thin layer electrochemical cell with self-formed separator |
| US7022431B2 (en) * | 2001-08-20 | 2006-04-04 | Power Paper Ltd. | Thin layer electrochemical cell with self-formed separator |
| DE102013017594A1 (de) * | 2013-09-27 | 2015-04-02 | Forschungszentrum Jülich GmbH | Herstellungsverfahren für elektrochemische Zellen einer Festkörperbatterie |
| CN104979534B (zh) * | 2015-06-01 | 2018-03-30 | 哈尔滨工业大学 | 一种碘‑硫/碳复合材料及其制备方法与应用 |
| US10790482B2 (en) | 2017-08-04 | 2020-09-29 | Greatbatch Ltd. | Lithium-iodine electrochemical cells exhibiting low discharge impedance |
| RU2722688C1 (ru) * | 2019-04-05 | 2020-06-03 | Общество с ограниченной ответственностью "Инэнерджи" | Гибкий тонкопленочный положительный электрод и способ его изготовления |
| RU2722687C1 (ru) * | 2019-04-05 | 2020-06-03 | Общество с ограниченной ответственностью "Инэнерджи" | Гибкий тонкопленочный положительный электрод и способ его изготовления |
| CN112234185B (zh) * | 2020-10-28 | 2022-08-30 | 珠海冠宇电池股份有限公司 | 一种正极极片及其应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2953620A (en) * | 1957-05-06 | 1960-09-20 | Sprague Electric Co | Battery cell structure |
| US2954417A (en) * | 1957-08-19 | 1960-09-27 | Sprague Electric Co | Solid electrolyte battery cell |
| US3073884A (en) * | 1959-08-03 | 1963-01-15 | Ethyl Corp | High energy batteries |
| US3057760A (en) * | 1960-07-05 | 1962-10-09 | Union Carbide Corp | Polyhalogen depolarizers |
| US3235408A (en) * | 1963-10-18 | 1966-02-15 | Corson G & W H | Ammonia electric current-producing cell |
| US3352720A (en) * | 1964-03-09 | 1967-11-14 | Glenn R Wilson | Polymeric depolarizers |
| US3455742A (en) * | 1966-02-10 | 1969-07-15 | Mallory & Co Inc P R | High energy density solid electrolyte cells |
| US3443997A (en) * | 1966-02-11 | 1969-05-13 | North American Rockwell | Solid state electrochemical devices |
| US3438813A (en) * | 1967-03-24 | 1969-04-15 | American Cyanamid Co | Battery cell depolarizers |
| US3463670A (en) * | 1967-05-26 | 1969-08-26 | Mallory & Co Inc P R | High energy density thermal cell |
| US3498843A (en) * | 1968-09-25 | 1970-03-03 | Us Navy | Electrochemical cells for thermal batteries having transition metal fluoride cathode and an alkali metal fluoride electrolyte |
-
1970
- 1970-06-01 US US41801A patent/US3660163A/en not_active Expired - Lifetime
-
1971
- 1971-01-15 US US106657A patent/US3674562A/en not_active Ceased
- 1971-05-20 GB GB5607471*A patent/GB1358999A/en not_active Expired
- 1971-05-20 GB GB1606771*[A patent/GB1358998A/en not_active Expired
- 1971-05-20 CA CA113,532,A patent/CA950530A/en not_active Expired
- 1971-05-26 DE DE19712166543 patent/DE2166543B2/de not_active Ceased
- 1971-05-27 SE SE7106847A patent/SE404464C/xx unknown
- 1971-05-28 FR FR7119597A patent/FR2095696A5/fr not_active Expired
- 1971-05-31 ES ES391808A patent/ES391808A1/es not_active Expired
- 1971-06-01 NL NLAANVRAGE7107526,A patent/NL170684C/xx not_active IP Right Cessation
- 1971-06-01 CH CH799971A patent/CH561467A5/xx not_active IP Right Cessation
-
1973
- 1973-08-22 ES ES418096A patent/ES418096A1/es not_active Expired
-
1977
- 1977-05-12 HK HK227/77A patent/HK22777A/xx unknown
- 1977-05-12 HK HK226/77A patent/HK22677A/xx unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2909364A1 (de) * | 1978-03-13 | 1979-09-27 | Medtronic Inc | Elektrochemische zelle und verfahren zur herstellung einer solchen zelle |
| DE2912830A1 (de) * | 1978-04-03 | 1979-10-11 | Catalyst Research Corp | Batterie, depolarisator zur verwendung in dieser batterie und verfahren zur herstellung des depolarisators |
| DE3023969A1 (de) * | 1979-06-28 | 1981-01-08 | Union Carbide Corp | Ladungstransferkomplex-kathoden fuer festelektrolyt-elemente |
| DE3033432A1 (de) * | 1979-09-07 | 1981-04-02 | Catalyst Research Corp., Baltimore, Md. | Depolarisatoren fuer lithiumhalogenid-batterien |
| DE3111224A1 (de) * | 1980-03-28 | 1982-02-18 | Union Carbide Corp., 10017 New York, N.Y. | Positive ladungstransferkomplexelektroden fuer festelektrolytzellen |
| DE3111261A1 (de) * | 1980-03-28 | 1982-03-04 | Union Carbide Corp., 10017 New York, N.Y. | Positive ladungstransferkomplexelektroden fuer festelektrolytzellen |
Also Published As
| Publication number | Publication date |
|---|---|
| HK22777A (en) | 1977-05-20 |
| DE2126055B2 (de) | 1974-04-11 |
| NL170684B (nl) | 1982-07-01 |
| FR2095696A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-02-11 |
| GB1358998A (en) | 1974-07-03 |
| HK22677A (en) | 1977-05-20 |
| US3674562A (en) | 1972-07-04 |
| US3660163A (en) | 1972-05-02 |
| SE404464C (sv) | 1983-02-21 |
| ES391808A1 (es) | 1975-09-16 |
| ES418096A1 (es) | 1976-02-16 |
| CA950530A (en) | 1974-07-02 |
| NL7107526A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1971-12-03 |
| CH561467A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-04-30 |
| NL170684C (nl) | 1982-12-01 |
| SE404464B (sv) | 1978-10-02 |
| DE2126055A1 (de) | 1971-12-09 |
| GB1358999A (en) | 1974-07-03 |
| DE2166543A1 (de) | 1974-09-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8235 | Patent refused |