DE19654391A1 - Katalysator zur selektiven Herstellung von Propylen aus Propan - Google Patents

Katalysator zur selektiven Herstellung von Propylen aus Propan

Info

Publication number
DE19654391A1
DE19654391A1 DE19654391A DE19654391A DE19654391A1 DE 19654391 A1 DE19654391 A1 DE 19654391A1 DE 19654391 A DE19654391 A DE 19654391A DE 19654391 A DE19654391 A DE 19654391A DE 19654391 A1 DE19654391 A1 DE 19654391A1
Authority
DE
Germany
Prior art keywords
catalyst according
catalyst
compound
subgroup
propane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19654391A
Other languages
German (de)
English (en)
Inventor
Daniel Dr Heineke
Michael Dr Baier
Dirk Dr Demuth
Klaus Dr Harth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE19654391A priority Critical patent/DE19654391A1/de
Priority to PCT/EP1997/006858 priority patent/WO1998029365A1/de
Priority to KR10-1999-7005839A priority patent/KR100522986B1/ko
Priority to EP97953761A priority patent/EP0948475B1/de
Priority to DE59709647T priority patent/DE59709647D1/de
Priority to US09/331,052 priority patent/US6576804B1/en
Priority to JP52957298A priority patent/JP4287909B2/ja
Priority to AT97953761T priority patent/ATE235446T1/de
Priority to ES97953761T priority patent/ES2196390T3/es
Priority to MYPI97006337A priority patent/MY118017A/en
Publication of DE19654391A1 publication Critical patent/DE19654391A1/de
Priority to US10/340,282 priority patent/US6989346B2/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE19654391A 1996-12-27 1996-12-27 Katalysator zur selektiven Herstellung von Propylen aus Propan Withdrawn DE19654391A1 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
DE19654391A DE19654391A1 (de) 1996-12-27 1996-12-27 Katalysator zur selektiven Herstellung von Propylen aus Propan
US09/331,052 US6576804B1 (en) 1996-12-27 1997-12-09 Method and catalyst for producing olefins, in particular propylenes, by dehydrogenation
KR10-1999-7005839A KR100522986B1 (ko) 1996-12-27 1997-12-09 탈수소화에 의한 올레핀, 특히 프로필렌의 제조 방법
EP97953761A EP0948475B1 (de) 1996-12-27 1997-12-09 Verfahren zur herstellung von olefinen, insbesondere von propylen, durch dehydrierung
DE59709647T DE59709647D1 (de) 1996-12-27 1997-12-09 Verfahren zur herstellung von olefinen, insbesondere von propylen, durch dehydrierung
PCT/EP1997/006858 WO1998029365A1 (de) 1996-12-27 1997-12-09 Verfahren zur herstellung von olefinen, insbesondere von propylen, durch dehydrierung
JP52957298A JP4287909B2 (ja) 1996-12-27 1997-12-09 脱水素によるオレフィン、特にプロピレンの製造方法
AT97953761T ATE235446T1 (de) 1996-12-27 1997-12-09 Verfahren zur herstellung von olefinen, insbesondere von propylen, durch dehydrierung
ES97953761T ES2196390T3 (es) 1996-12-27 1997-12-09 Procedimiento para la obtencion de olefina, particularmente de propileno, mediante deshidrogenacion.
MYPI97006337A MY118017A (en) 1996-12-27 1997-12-27 Method for producing olefins, in particular propylenes by dehydrogenation
US10/340,282 US6989346B2 (en) 1996-12-27 2003-01-13 Preparation of olefins, particularly of propylene, by dehydrogenation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19654391A DE19654391A1 (de) 1996-12-27 1996-12-27 Katalysator zur selektiven Herstellung von Propylen aus Propan

Publications (1)

Publication Number Publication Date
DE19654391A1 true DE19654391A1 (de) 1998-07-02

Family

ID=7816238

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19654391A Withdrawn DE19654391A1 (de) 1996-12-27 1996-12-27 Katalysator zur selektiven Herstellung von Propylen aus Propan
DE59709647T Expired - Lifetime DE59709647D1 (de) 1996-12-27 1997-12-09 Verfahren zur herstellung von olefinen, insbesondere von propylen, durch dehydrierung

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE59709647T Expired - Lifetime DE59709647D1 (de) 1996-12-27 1997-12-09 Verfahren zur herstellung von olefinen, insbesondere von propylen, durch dehydrierung

Country Status (9)

Country Link
US (2) US6576804B1 (enExample)
EP (1) EP0948475B1 (enExample)
JP (1) JP4287909B2 (enExample)
KR (1) KR100522986B1 (enExample)
AT (1) ATE235446T1 (enExample)
DE (2) DE19654391A1 (enExample)
ES (1) ES2196390T3 (enExample)
MY (1) MY118017A (enExample)
WO (1) WO1998029365A1 (enExample)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7850842B2 (en) 2002-05-03 2010-12-14 Basf Aktiengesellschaft Zr02-base catalyst carrier and method for the production thereof
US8680005B2 (en) 2011-01-25 2014-03-25 Basf Se Catalyst from flame-spray pyrolysis and catalyst for autothermal propane dehydrogenation
DE102015112612A1 (de) 2015-07-31 2017-02-02 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock Verfahren zur Herstellung von Olefinen sowie Katalysator
WO2020069481A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020069480A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020236738A1 (en) * 2019-05-17 2020-11-26 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020236707A1 (en) * 2019-05-17 2020-11-26 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation

Families Citing this family (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19937106A1 (de) * 1999-08-06 2001-02-08 Basf Ag Multikomponenten-Katalysatoren
DE19937105A1 (de) * 1999-08-06 2001-02-08 Basf Ag Oxidkatalysatoren
US6696388B2 (en) * 2000-01-24 2004-02-24 E. I. Du Pont De Nemours And Company Gel catalysts and process for preparing thereof
RU2178398C1 (ru) * 2000-07-27 2002-01-20 Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" Способ получения олефиновых углеводородов
ES2290166T3 (es) 2000-09-08 2008-02-16 Alza Corporation Dispositivo transdermico.
DE10047642A1 (de) * 2000-09-26 2002-04-11 Basf Ag Verfahren zur Dehydrierung von Kohlenwasserstoffen
CA2425315C (en) 2000-10-13 2010-01-12 Alza Corporation Apparatus and method for piercing skin with microprotrusions
US7419481B2 (en) 2000-10-13 2008-09-02 Alza Corporation Apparatus and method for piercing skin with microprotrusions
MXPA03003301A (es) 2000-10-13 2004-12-13 Johnson & Johnson Aplicador de un conjunto de microsalientes mediante impacto.
ATE416692T1 (de) 2000-10-13 2008-12-15 Alza Corp Mikronadelelementhalter für schlagapplikator
RU2282468C2 (ru) 2000-10-26 2006-08-27 Алза Корпорейшн Устройство для трансдермальной доставки лекарственных средств, имеющее микровыступы с покрытием
EP1752189A3 (en) 2001-04-20 2007-02-21 Alza Corporation Microprojection array having a beneficial agent containing coating
CA2444883A1 (en) 2001-04-20 2002-10-31 Alza Corporation Microprojection array having a beneficial agent containing coating
DE10211275A1 (de) * 2002-03-13 2003-09-25 Basf Ag Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung
CN1193824C (zh) * 2001-10-19 2005-03-23 松下电器产业株式会社 纯化催化剂、其制备方法和气体纯化装置
ZA200209470B (en) * 2001-12-04 2003-06-03 Rohm & Haas Improved processes for the preparation of olefins, unsaturated carboxylic acids and unsaturated nitriles from alkanes.
US7390768B2 (en) * 2002-01-22 2008-06-24 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Stabilized tin-oxide-based oxidation/reduction catalysts
KR20060038407A (ko) 2003-06-30 2006-05-03 알자 코포레이션 비휘발성 반대이온을 포함하는 코팅된 미세돌출부용 제제
JP4562360B2 (ja) * 2003-07-18 2010-10-13 旭化成株式会社 多孔質結晶性ジルコニア材料、及びその製造方法
AU2004285484A1 (en) 2003-10-24 2005-05-12 Alza Corporation Pretreatment method and system for enhancing transdermal drug delivery
AU2004287412A1 (en) 2003-10-28 2005-05-19 Alza Corporation Method and apparatus for reducing the incidence of tobacco use
KR20060099523A (ko) 2003-10-31 2006-09-19 알자 코포레이션 미세 돌출부 어레이를 위한 자가 작동 어플리케이터
US7309480B2 (en) * 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
EP1744683B1 (en) 2004-05-13 2016-03-16 Alza Corporation Apparatus and method for transdermal delivery of parathyroid hormone agents
RU2271860C1 (ru) * 2005-03-15 2006-03-20 Татьяна Владимировна Борисова Катализатор для дегидрирования парафиновых углеводородов
WO2007033934A2 (de) * 2005-09-20 2007-03-29 Basf Se Verfahren zur ermittlung der tortuosität, katalysatorträger, katalysator und verfahren zur dehydrierung von kohlenwasserstoffen
JP2009167171A (ja) * 2008-01-11 2009-07-30 Rohm & Haas Co プロパンをプロペンに転化するための担持触媒およびその転化のためのプロセスにおけるその使用
US20090325791A1 (en) * 2008-06-27 2009-12-31 Wei Pan Hydrocarbon Dehydrogenation with Zirconia
US8404104B2 (en) * 2008-06-27 2013-03-26 Uop Llc Hydrocarbon dehydrogenation with zirconia
US8431761B2 (en) * 2008-06-27 2013-04-30 Uop Llc Hydrocarbon dehydrogenation with zirconia
US8101541B2 (en) * 2008-07-14 2012-01-24 Sud-Chemie Inc. Catalyst for dehydrogenation of hydrocarbons
US20100331590A1 (en) * 2009-06-25 2010-12-30 Debarshi Majumder Production of light olefins and aromatics
US8293670B2 (en) * 2009-12-09 2012-10-23 Uop Llc Process for the production of propylene
US8624074B2 (en) * 2010-03-22 2014-01-07 Uop Llc Reactor flowscheme for dehydrogenation of propane to propylene
WO2012101566A1 (de) * 2011-01-25 2012-08-02 Basf Se Katalysator aus der flammen-spraypyrolyse für die autotherme propandehydrierung
WO2012157578A1 (ja) * 2011-05-13 2012-11-22 国立大学法人東京工業大学 アルコール化合物およびオレフィン化合物の製造用触媒、並びにアルコール化合物およびオレフィン化合物の製造方法
EP2689843A1 (en) 2012-07-26 2014-01-29 Saudi Basic Industries Corporation Alkane dehydrogenation catalyst and process for its preparation
US20150038897A1 (en) 2013-07-30 2015-02-05 Zosano Pharma, Inc. Low-Profile Microneedle Patch Applicator
US10221110B2 (en) * 2016-12-08 2019-03-05 Evonik Degussa Gmbh Dehydrogenation of olefin-rich hydrocarbon mixtures
JP2018177750A (ja) * 2017-04-21 2018-11-15 Ｊｘｔｇエネルギー株式会社 不飽和炭化水素の製造方法及び脱水素触媒の再生方法
WO2020046978A1 (en) 2018-08-31 2020-03-05 Dow Global Technologies Llc Methods for dehydrogenating hydrocarbons
KR102725736B1 (ko) 2018-08-31 2024-11-06 다우 글로벌 테크놀로지스 엘엘씨 수소-선택적 산소 운반체 재료의 생산 방법
ZA201906807B (en) 2018-11-21 2020-07-29 Indian Oil Corp Ltd Highly active catalyst for dehydrogenation of alkanes and method of preparation thereof
US20220250049A1 (en) * 2019-03-21 2022-08-11 Kellogg Brown & Root Llc Processes for catalytic paraffin dehydrogenation and catalyst recovery
US11364482B2 (en) 2019-05-17 2022-06-21 Exelus, Inc. Mixed metal oxide catalyst useful for paraffin dehydrogenation
US11168039B2 (en) 2019-05-17 2021-11-09 Exelus, Inc. Mixed metal oxide catalyst useful for paraffin dehydrogenation
CN110237849A (zh) * 2019-07-03 2019-09-17 福州大学 一种用于丙烷脱氢制丙烯的铂基催化剂及其制备方法
CN110237840B (zh) * 2019-07-04 2020-09-15 中国科学院大连化学物理研究所 一种铂单原子催化剂的制备及其在丙烷脱氢制丙烯反应中的应用
US12330140B2 (en) * 2020-02-26 2025-06-17 Basf Corporation Catalyst compositions and methods of preparation and use thereof
BR112022017379A2 (pt) * 2020-03-06 2022-10-18 Exxonmobil Chemical Patents Inc Processos para melhorar alcanos e hidrocarbonetos aromáticos de alquila
EP4114812A1 (en) * 2020-03-06 2023-01-11 ExxonMobil Chemical Patents Inc. Processes for upgrading alkanes and alkyl aromatic hydrocarbons
US20240316544A1 (en) 2021-08-11 2024-09-26 Exxonmobil Chemical Patents Inc. Processes for Regenerating Catalysts and for Upgrading Alkanes and/or Alkyl Aromatic Hydrocarbons
EP4547630A1 (en) 2022-09-14 2025-05-07 Dow Global Technologies LLC Methods for dehydrogenating hydrocarbons utilizing combustion units
WO2024059551A1 (en) 2022-09-14 2024-03-21 Dow Global Technologies Llc Methods for dehydrogenating hydrocarbons utilizing countercurrent flow regenerators
EP4540210A1 (en) 2022-09-14 2025-04-23 Dow Global Technologies LLC Methods for dehydrogenating hydrocarbons utilizing regenerators
KR20250069852A (ko) 2022-09-14 2025-05-20 다우 글로벌 테크놀로지스 엘엘씨 탄화수소의 탈수소화 방법
WO2024141479A1 (en) * 2022-12-26 2024-07-04 Basf Se A method for preparation of an olefin from an alcohol
EP4667447A1 (en) 2024-06-21 2025-12-24 Basf Se Process for the preparation of polyisobutene from bio-based olefins from primary alcohol

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE421888A (enExample) *
US2098959A (en) * 1934-05-02 1937-11-16 Phillips Petroleum Co Processes for converting hydrocarbons
US2375021A (en) * 1939-03-25 1945-05-01 Universal Oil Prod Co Treatment of hydrocarbons
RO57356A2 (enExample) * 1972-05-03 1974-12-15
US4131628A (en) * 1977-02-22 1978-12-26 Uop Inc. Hydrocarbon dehydrogenation using nonacidic multimetallic catalyst
US4677237A (en) * 1984-11-29 1987-06-30 Uop Inc. Dehydrogenation catalyst compositions
JPS63139050A (ja) * 1986-11-28 1988-06-10 住友化学工業株式会社 ジルコニア質セラミツクス
DE3739002A1 (de) * 1987-11-17 1989-05-24 Veba Oel Ag Metallmischoxidpulver, deren mischungen, metalloxidpulver und deren verwendung bei der katalytischen dehydrierung von kohlenwasserstoffen
DE3803894A1 (de) * 1988-02-09 1989-08-10 Degussa Presslinge auf basis von pyrogen hergestelltem titandioxid, verfahren zu ihrer herstellung und ihre verwendung
US4891343A (en) * 1988-08-10 1990-01-02 W. R. Grace & Co.-Conn. Stabilized zirconia
DE3841800A1 (de) * 1988-12-12 1990-06-13 Linde Ag Verfahren und katalysator zur dehydrierung oder dehydrozyklisierung von kohlenwasserstoffen
ATE146451T1 (de) 1989-05-12 1997-01-15 Fina Research Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen
US5510553A (en) 1989-05-12 1996-04-23 Fina Research, S.A. Catalytic dehydrogenation of alkylaromatic hydrocarbons
US5089455A (en) * 1989-08-11 1992-02-18 Corning Incorporated Thin flexible sintered structures
JPH0380937A (ja) * 1989-08-25 1991-04-05 Tonen Corp 炭化水素の水蒸気改質触媒及びその製造方法
IT1238085B (it) * 1990-02-07 1993-07-05 Snam Progetti Composizione catalicica per la deidrogenazione di paraffine c2-c5
GB9026952D0 (en) * 1990-12-12 1991-01-30 Tioxide Group Services Ltd Stabilised metal oxides
US5243122A (en) * 1991-12-30 1993-09-07 Phillips Petroleum Company Dehydrogenation process control
FR2688000A1 (fr) * 1992-03-02 1993-09-03 Inst Francais Du Petrole Procede de deshydrogenation d'hydrocarbures aliphatiques satures en hydrocarbures olefiniques.
US5254787A (en) * 1992-09-08 1993-10-19 Mobil Oil Corp. Dehydrogenation and dehydrocyclization using a non-acidic NU-87 catalyst
US5447898A (en) * 1993-09-21 1995-09-05 Shell Oil Company Process for the preparation of zirconia
GB9322358D0 (en) * 1993-10-29 1993-12-15 Johnson Matthey Plc Pigmentary material
US5600046A (en) * 1993-12-16 1997-02-04 Uop Combination dehydrocyclodimerization and dehydrogenation process for producing aromatic and olefin products
US5401893A (en) * 1993-12-16 1995-03-28 Uop Combination dehydrocyclodimerization and dehydrogenation process for producing aromatic and olefin products
US5510557A (en) 1994-02-28 1996-04-23 Abb Lummus Crest Inc. Endothermic catalytic dehydrogenation process
KR970001064B1 (ko) * 1994-03-15 1997-01-25 한국과학기술연구원 고인성·내저온열화 정방정 지르코니아 복합체의 제조방법
AU3640195A (en) * 1994-09-23 1996-04-09 Alsimag Technical Ceramics, Inc. Improved stabilized zirconia
DE69603633T2 (de) * 1995-03-08 2000-03-09 Mitsubishi Chemical Corp. Verfahren für die selektive Oxidation von Wasserstoff und für die Dehydrierung von Kohlenwasserstoffen
US5786294A (en) * 1996-05-10 1998-07-28 Northwestern University Crystalline mesoporous zirconia catalysts having stable tetragonal pore wall structure
DE19646538A1 (de) * 1996-10-30 1998-05-07 Inst Angewandte Chemie Berlin Verfahren zur Herstellung von Alkenen, Alkadienen oder Alkenylaromaten durch Dehydrierung der entsprechenden Alkane, Alkene oder Alkylaromaten
US5977013A (en) * 1996-12-19 1999-11-02 Battelle Memorial Institute Catalyst and method for aqueous phase reactions
DE19653629A1 (de) * 1996-12-20 1998-06-25 Basf Ag Monoklines Zirconiumoxid mit hoher Oberfläche
IT1289934B1 (it) * 1997-02-20 1998-10-19 Eniricerche Spa Catalizzatore superacido per la idroisomerizzazione di n-paraffine e procedimento per la sua preparazione
US5877369A (en) * 1997-10-23 1999-03-02 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
DE19905837A1 (de) * 1999-02-12 2000-08-17 Basf Ag Verfahren zur Racemisierung von optisch aktiven Aminen
DE19807268A1 (de) * 1998-02-20 1999-08-26 Basf Ag Verfahren zur Herstellung von Alkoholen

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7850842B2 (en) 2002-05-03 2010-12-14 Basf Aktiengesellschaft Zr02-base catalyst carrier and method for the production thereof
US8680005B2 (en) 2011-01-25 2014-03-25 Basf Se Catalyst from flame-spray pyrolysis and catalyst for autothermal propane dehydrogenation
DE102015112612A1 (de) 2015-07-31 2017-02-02 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock Verfahren zur Herstellung von Olefinen sowie Katalysator
WO2017021195A1 (de) * 2015-07-31 2017-02-09 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock Verfahren zur herstellung von olefinen sowie katalysator
WO2020069481A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020069480A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020236738A1 (en) * 2019-05-17 2020-11-26 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation
WO2020236707A1 (en) * 2019-05-17 2020-11-26 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation

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US6989346B2 (en) 2006-01-24
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US20030163012A1 (en) 2003-08-28
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