CN1322225A - 具有改进的熔体流动性的阻燃聚碳酸酯树脂组合物 - Google Patents
具有改进的熔体流动性的阻燃聚碳酸酯树脂组合物 Download PDFInfo
- Publication number
- CN1322225A CN1322225A CN99811885A CN99811885A CN1322225A CN 1322225 A CN1322225 A CN 1322225A CN 99811885 A CN99811885 A CN 99811885A CN 99811885 A CN99811885 A CN 99811885A CN 1322225 A CN1322225 A CN 1322225A
- Authority
- CN
- China
- Prior art keywords
- weight
- resin composition
- component
- compounded rubber
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 229920005668 polycarbonate resin Polymers 0.000 title claims abstract description 44
- 239000004431 polycarbonate resin Substances 0.000 title claims abstract description 44
- 239000003063 flame retardant Substances 0.000 title abstract description 42
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 36
- 229920001971 elastomer Polymers 0.000 claims abstract description 98
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 42
- 239000004417 polycarbonate Substances 0.000 claims abstract description 37
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 37
- 125000003118 aryl group Chemical group 0.000 claims abstract description 29
- -1 ester compound Chemical class 0.000 claims abstract description 28
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 24
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims description 44
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 31
- 238000010559 graft polymerization reaction Methods 0.000 claims description 25
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 18
- 229920001296 polysiloxane Polymers 0.000 claims description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
- 229920000573 polyethylene Polymers 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- NKKMVIVFRUYPLQ-UHFFFAOYSA-N but-2-enenitrile Chemical compound CC=CC#N NKKMVIVFRUYPLQ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 6
- 239000011541 reaction mixture Substances 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 239000000178 monomer Substances 0.000 abstract description 16
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 15
- 229920000642 polymer Polymers 0.000 abstract description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011342 resin composition Substances 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 90
- 239000011347 resin Substances 0.000 description 90
- 230000000052 comparative effect Effects 0.000 description 26
- 229910052799 carbon Inorganic materials 0.000 description 25
- 150000001721 carbon Chemical group 0.000 description 23
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 11
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 9
- 239000004810 polytetrafluoroethylene Substances 0.000 description 9
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 229920007019 PC/ABS Polymers 0.000 description 5
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 5
- 238000011088 calibration curve Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- 125000005375 organosiloxane group Chemical group 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005809 transesterification reaction Methods 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005185 salting out Methods 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000005910 alkyl carbonate group Chemical group 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- BQTPKSBXMONSJI-UHFFFAOYSA-N 1-cyclohexylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCCCC1 BQTPKSBXMONSJI-UHFFFAOYSA-N 0.000 description 1
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 1
- IRVZFACCNZRHSJ-UHFFFAOYSA-N 2,4,6,8-tetramethyl-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 IRVZFACCNZRHSJ-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229920006172 Tetrafluoroethylene propylene Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 150000004646 arylidenes Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- HAURRGANAANPSQ-UHFFFAOYSA-N cis-2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 HAURRGANAANPSQ-UHFFFAOYSA-N 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
配方 | 实施例1 | 实施例2 | 比较例1 | 比较例2 | 比较例3 | 比较例4 | 比较例5 | 比较例6 | 比较例7 | |
组分(A) | PC-1 | 80 | 80 | 80 | 80 | 80 | 95 | |||
PC-2 | 80 | |||||||||
PC-3 | 80 | |||||||||
PC-4 | 80 | |||||||||
PC-5 | ||||||||||
组分(B) | BAAS-1 | 20 | 20 | 20 | 20 | 5 | ||||
BAAS-2 | 20 | |||||||||
BAAS-3 | 20 | |||||||||
BAAS-4 | ||||||||||
AS-1 | 20 | 20 | ||||||||
组分(C) | 橡胶-1 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | ||
橡胶-2 | 10 | 5 | ||||||||
组分(D) | 阻燃剂-1 | 13 | 13 | 13 | 13 | 13 | 13 | 13 | 13 | 13 |
阻燃剂-2 | ||||||||||
组分(E) | PTFE | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
性能评估结果 | 悬臂梁式冲击强度42(kg.cm/cm) | 42 | 41 | 5 | 65 | 15 | 15 | 35 | 31 | 47 |
阻燃性 | 5VB | 5VB | V-2 | 5VB | 5VB | 5VB | V-1 | 5VB | 5VB | |
MI(g/10分钟) | 42 | 40 | >120 | 21 | 34 | 33 | 69 | 28 | 19 | |
挠曲模量(Kg/cm.cm) | 28,800 | 28,700 | 25,100 | 28,600 | 27,200 | 27,300 | 23,900 | 25,200 | 26,300 |
配方 | 比较例8 | 比较例9 | 比较例10 | 比较例11 | 比较例12 | 比较例13 | 比较例14 | 比较例15 | 比较例16 | 比较例17 | |
组分(A) | PC-1 | 80 | 80 | 80 | 80 | 80 | 90 | 90 | |||
PC-2 | |||||||||||
PC-3 | |||||||||||
PC-4 | |||||||||||
PC-5 | 70 | 70 | 70 | ||||||||
组分(B) | BAAS-1 | 15 | 15 | 15 | 5 | 5 | 5 | ||||
BAAS-2 | |||||||||||
BAAS-3 | |||||||||||
BAAS-4 | 20 | 20 | 10 | 10 | |||||||
AS-1 | |||||||||||
组分(C) | 橡胶-1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | ||||
橡胶-2 | 15 | 15 | 15 | 15 | 15 | 15 | |||||
组分(D) | 阻燃剂-1 | 15 | 15 | 20 | 13 | 20 | 20 | ||||
阻燃剂-2 | 10 | 15 | 10 | 15 | |||||||
组分(E) | PTFE | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |||
性能评估结果 | 悬臂梁式冲击强度(kg.cm/cm) | 17 | 18 | 10 | 40 | 10 | 9 | 37 | 18 | 50 | 19 |
阻燃性 | V-0 | V-0 | 5VB | V-0 | V-0 | 5VB | V-1 | 5VB | V-0 | 5VB | |
MI(g/10分钟) | 52 | 51 | 65 | 38 | 66 | 63 | 28 | 39 | 25 | 23 | |
挠曲模量(Kg/cm.cm) | 28,500 | 28,500 | 29,000 | 28,300 | 28,800 | 28,800 | 22,000 | 22,300 | 24,200 | 24,700 |
配方 | 比较例18 | 比较例19 | 比较例20 | |
组分(A)组分(B) | PC-1 | 50 | 80 | 80 |
PC-2 | ||||
PC-3 | ||||
PC-4 | ||||
BAAS-1 | 50 | 20 | 20 | |
BAAS-2 | ||||
BAAS-3 | ||||
AS-1 | ||||
组分(C) | 橡胶-1 | |||
橡胶-2 | 5 | 0.4 | 25 | |
组分(D) | 阻燃剂阻燃剂 | 13 | 13 | 13 |
组分(E) | PTFE | 0.5 | 0.5 | 0.5 |
性能评估结果 | 悬臂梁式冲击强度(kg.cm/cm) | 38 | 6 | 未断裂 |
阻燃性 | HB* | 5VB | V-2 | |
MI(g/10分钟) | 65 | 53 | 28 | |
挠曲模量(Kg/cm.cm) | 28,300 | 29,600 | 23,000 |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP35784098 | 1998-12-16 | ||
JP357840/1998 | 1998-12-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1322225A true CN1322225A (zh) | 2001-11-14 |
CN1142217C CN1142217C (zh) | 2004-03-17 |
Family
ID=18456202
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB998118850A Expired - Lifetime CN1142217C (zh) | 1998-12-16 | 1999-12-15 | 具有改进的熔体流动性的阻燃聚碳酸酯树脂组合物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6417319B1 (zh) |
JP (2) | JP3583718B2 (zh) |
KR (1) | KR100437929B1 (zh) |
CN (1) | CN1142217C (zh) |
DE (1) | DE19983615B4 (zh) |
ES (1) | ES2187304B2 (zh) |
HK (1) | HK1043142B (zh) |
MY (1) | MY119696A (zh) |
TW (1) | TWI224127B (zh) |
WO (1) | WO2000036016A1 (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101068881B (zh) * | 2004-12-06 | 2010-08-18 | 出光兴产株式会社 | 聚碳酸酯树脂组合物及其成型体 |
CN101372551B (zh) * | 2002-08-26 | 2011-05-25 | 出光兴产株式会社 | 聚碳酸酯树脂组合物和模塑制品 |
CN101646978B (zh) * | 2007-04-04 | 2011-11-02 | 旭化成电子材料株式会社 | 感光性树脂组合物 |
CN101263199B (zh) * | 2005-09-14 | 2011-12-14 | 拜尔材料科学股份公司 | 热塑性模塑组合物及其热成形制品 |
CN102532841A (zh) * | 2010-12-28 | 2012-07-04 | 奇美实业股份有限公司 | 聚碳酸酯组成物及其应用 |
CN104987691A (zh) * | 2015-06-09 | 2015-10-21 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6384114B1 (en) * | 1998-12-11 | 2002-05-07 | Idemitsu Petrochemical Co., Ltd. | Flame-retardant polycarbonate resin composition and its moldings |
KR100372568B1 (ko) * | 2000-11-01 | 2003-02-19 | 제일모직주식회사 | 열가소성 수지조성물 |
JP2003192919A (ja) * | 2001-10-17 | 2003-07-09 | Asahi Denka Kogyo Kk | 難燃性合成樹脂組成物 |
JP2003238793A (ja) * | 2002-02-19 | 2003-08-27 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
CN100526354C (zh) * | 2002-02-28 | 2009-08-12 | 三菱丽阳株式会社 | 热塑性树脂组合物及工程塑料组合物 |
WO2003078522A1 (en) * | 2002-03-19 | 2003-09-25 | Songwon Industrial Co., Ltd. | Oligomer-type flame-retardant compound and flame-retardant resin composition comprising same |
KR100462531B1 (ko) * | 2002-07-08 | 2004-12-17 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
JP4212928B2 (ja) * | 2003-03-05 | 2009-01-21 | テクノポリマー株式会社 | 難燃性樹脂組成物及び成形品 |
ES2221800B2 (es) * | 2003-06-16 | 2005-07-01 | Unex Aparellaje Electrico S.L. | Composicion extrusionable de resina sintetica. |
US20050250905A1 (en) * | 2004-05-04 | 2005-11-10 | Chang Moh-Ching O | Impact-modified polycarbonate molding compositions |
DE102005058847A1 (de) * | 2005-12-09 | 2007-06-14 | Bayer Materialscience Ag | Polycarbonat-Formmassen |
DE102007002925A1 (de) * | 2007-01-19 | 2008-07-24 | Bayer Materialscience Ag | Schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
KR100873986B1 (ko) | 2007-06-07 | 2008-12-17 | 한국화학연구원 | 방향족 아크릴계 화합물 및 이의 제조방법, 이를 포함하는중합성 수지 조성물 |
JP4737236B2 (ja) * | 2008-06-10 | 2011-07-27 | ソニー株式会社 | 難燃性ポリカーボネート樹脂組成物 |
KR20120086582A (ko) * | 2011-01-26 | 2012-08-03 | 송원산업 주식회사 | 고 내열성 올리고머형 포스파이트계 산화방지제 및 그를 포함하는 고분자 수지 조성물 |
JP6081321B2 (ja) * | 2013-09-02 | 2017-02-15 | 三菱エンジニアリングプラスチックス株式会社 | 薄肉成形品およびその製造方法 |
CN109071951B (zh) * | 2016-05-27 | 2022-02-18 | 三菱化学株式会社 | 树脂组合物及其成形体 |
EP3632938B1 (en) * | 2018-10-05 | 2023-05-03 | Trinseo Europe GmbH | Vinylidene substituted aromatic monomer and cyclic (meth)acrylate ester polymers |
KR102197617B1 (ko) * | 2018-11-22 | 2020-12-31 | 롯데케미칼 주식회사 | 내화학성이 개선된 폴리카보네이트 수지 조성물 |
EP3910001A1 (en) | 2020-05-13 | 2021-11-17 | SHPP Global Technologies B.V. | Polycarbonate copolymer and associated film extrusion composition, extruded film, and capacitor |
EP4089132B1 (en) | 2020-05-13 | 2024-03-27 | SHPP Global Technologies B.V. | Polycarbonate copolymer and associated film extrusion composition, extruded film, and capacitor |
WO2023149409A1 (ja) * | 2022-02-01 | 2023-08-10 | 株式会社カネカ | ポリカーボネート系樹脂組成物及び成形体 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0307963B1 (en) * | 1987-09-21 | 1995-02-15 | Mitsubishi Rayon Co., Ltd. | Polycarbonate resin composition |
JP2558126B2 (ja) | 1987-09-21 | 1996-11-27 | 三菱レイヨン株式会社 | 熱可塑性樹脂組成物 |
DE3922103A1 (de) * | 1989-07-05 | 1991-01-17 | Bayer Ag | Mischungen thermoplastischer polymerisate in pulverform |
JP2986672B2 (ja) * | 1994-02-16 | 1999-12-06 | 帝人化成株式会社 | 難燃性樹脂組成物 |
JPH08259791A (ja) * | 1995-01-23 | 1996-10-08 | Mitsubishi Rayon Co Ltd | 難燃性樹脂組成物 |
JP3500391B2 (ja) | 1995-06-14 | 2004-02-23 | 旭化成ケミカルズ株式会社 | 難燃性樹脂組成物 |
DE19600902A1 (de) * | 1996-01-12 | 1997-07-17 | Bayer Ag | Massen vom ABS-Typ für die Extrusions- und Tiefziehverarbeitung |
JP3218192B2 (ja) | 1996-10-14 | 2001-10-15 | 三菱レイヨン株式会社 | 難燃性樹脂組成物 |
KR20010009104A (ko) * | 1998-07-10 | 2001-02-05 | 유현식 | 난연성 열가소성 수지조성물 |
-
1999
- 1999-12-15 CN CNB998118850A patent/CN1142217C/zh not_active Expired - Lifetime
- 1999-12-15 DE DE19983615T patent/DE19983615B4/de not_active Expired - Lifetime
- 1999-12-15 ES ES200150025A patent/ES2187304B2/es not_active Expired - Fee Related
- 1999-12-15 WO PCT/JP1999/007045 patent/WO2000036016A1/ja active IP Right Grant
- 1999-12-15 KR KR10-2001-7004256A patent/KR100437929B1/ko active IP Right Grant
- 1999-12-15 US US09/830,832 patent/US6417319B1/en not_active Expired - Lifetime
- 1999-12-15 JP JP2000588270A patent/JP3583718B2/ja not_active Expired - Lifetime
- 1999-12-16 MY MYPI99005484A patent/MY119696A/en unknown
- 1999-12-16 TW TW088122168A patent/TWI224127B/zh not_active IP Right Cessation
- 1999-12-16 JP JP11356785A patent/JP2000234053A/ja active Pending
-
2002
- 2002-05-14 HK HK02103618.4A patent/HK1043142B/zh not_active IP Right Cessation
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101372551B (zh) * | 2002-08-26 | 2011-05-25 | 出光兴产株式会社 | 聚碳酸酯树脂组合物和模塑制品 |
CN101068881B (zh) * | 2004-12-06 | 2010-08-18 | 出光兴产株式会社 | 聚碳酸酯树脂组合物及其成型体 |
CN101263199B (zh) * | 2005-09-14 | 2011-12-14 | 拜尔材料科学股份公司 | 热塑性模塑组合物及其热成形制品 |
CN101646978B (zh) * | 2007-04-04 | 2011-11-02 | 旭化成电子材料株式会社 | 感光性树脂组合物 |
CN102532841A (zh) * | 2010-12-28 | 2012-07-04 | 奇美实业股份有限公司 | 聚碳酸酯组成物及其应用 |
CN102532841B (zh) * | 2010-12-28 | 2013-10-16 | 奇美实业股份有限公司 | 聚碳酸酯组成物及其应用 |
CN104987691A (zh) * | 2015-06-09 | 2015-10-21 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
JP2000234053A (ja) | 2000-08-29 |
TWI224127B (en) | 2004-11-21 |
ES2187304A1 (es) | 2003-05-16 |
MY119696A (en) | 2005-06-30 |
HK1043142A1 (en) | 2002-09-06 |
KR20010075578A (ko) | 2001-08-09 |
KR100437929B1 (ko) | 2004-06-30 |
ES2187304B2 (es) | 2005-06-16 |
US6417319B1 (en) | 2002-07-09 |
WO2000036016A1 (fr) | 2000-06-22 |
DE19983615B4 (de) | 2006-05-04 |
JP3583718B2 (ja) | 2004-11-04 |
DE19983615T1 (de) | 2001-11-22 |
HK1043142B (zh) | 2004-08-20 |
CN1142217C (zh) | 2004-03-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1142217C (zh) | 具有改进的熔体流动性的阻燃聚碳酸酯树脂组合物 | |
CN1071360C (zh) | 阻燃性热塑性聚碳酸酯模塑组合物 | |
CN1174038C (zh) | 阻燃的、耐冲击改性的聚碳酸酯模塑组合物 | |
CN1221441A (zh) | 阻燃热塑性树脂组合物 | |
CN1685011A (zh) | 阻燃的聚碳酸酯模塑组合物 | |
CN1153811C (zh) | 具有改进的性能稳定性的聚合物组合物 | |
CN1930243A (zh) | 聚碳酸酯树脂组合物及其模塑制品 | |
CN1234758C (zh) | 不燃性树脂组合物及其模制品 | |
CN1346386A (zh) | 聚碳酸酯基阻燃树脂组合物 | |
CN1198870C (zh) | 含聚碳酸酯及接枝聚合物的防燃模塑组合物 | |
CN1310747A (zh) | 具有金属外观的阻燃聚碳酸酯/橡胶改性的接枝共聚物树脂共混物 | |
CN1745131A (zh) | 耐火聚碳酸酯共混物 | |
JP2003049076A (ja) | 酸化チタン含有難燃性樹脂組成物および製法 | |
CN1404506A (zh) | 具有改良的可加工性和高光泽度的abs-模塑组合物 | |
KR101316581B1 (ko) | 폴리카보네이트 수지 조성물 및 이의 성형품 | |
CN1085997C (zh) | 聚碳酸酯树脂组合物 | |
CN1345352A (zh) | 阻燃的、接枝聚合物改性的聚碳酸酯模塑组合物 | |
JP3474251B2 (ja) | 繊維強化熱可塑性樹脂組成物 | |
CN1494572A (zh) | 化学稳定性增强的耐火聚碳酸酯组合物 | |
CN1146629C (zh) | 防燃聚碳酸酯/abs模塑组合物 | |
JP5008224B2 (ja) | ポリカーボネート系着色難燃樹脂組成物からなるハウジング材料及びその製法 | |
CN1382189A (zh) | 阻燃性聚碳酸酯共混物 | |
JPH07228764A (ja) | 難燃性樹脂組成物 | |
CN1039822A (zh) | 一种已改善刚性的聚苯乙烯树脂组合物 | |
JP2005263909A (ja) | 難燃性ポリカーボネート樹脂組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: ASAHI CHEMICAL CORP. Free format text: FORMER OWNER: ASAHI KASEI CORPORATION Effective date: 20050121 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20050121 Address after: Tokyo, Japan Patentee after: Asahi Kasei Chemical K. K. Address before: Japan Osaka Patentee before: Asahi Kasei Kogyo K. K. |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160425 Address after: Tokyo, Japan Patentee after: Asahi Kasei Kogyo K. K. Address before: Tokyo, Japan Patentee before: Asahi Kasei Chemical K. K. |
|
CX01 | Expiry of patent term |
Granted publication date: 20040317 |
|
CX01 | Expiry of patent term |