CN1086918C - 以发酵液为原料的动物饲料添加剂的生产方法 - Google Patents
以发酵液为原料的动物饲料添加剂的生产方法 Download PDFInfo
- Publication number
- CN1086918C CN1086918C CN97113051A CN97113051A CN1086918C CN 1086918 C CN1086918 C CN 1086918C CN 97113051 A CN97113051 A CN 97113051A CN 97113051 A CN97113051 A CN 97113051A CN 1086918 C CN1086918 C CN 1086918C
- Authority
- CN
- China
- Prior art keywords
- animal feed
- particle
- feed additive
- zymotic fluid
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 69
- 238000000855 fermentation Methods 0.000 title abstract description 35
- 230000004151 fermentation Effects 0.000 title abstract description 35
- 241001465754 Metazoa Species 0.000 title abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 239000006052 feed supplement Substances 0.000 title abstract 2
- 239000002245 particle Substances 0.000 claims abstract description 60
- 239000000654 additive Substances 0.000 claims abstract description 26
- 239000012530 fluid Substances 0.000 claims description 110
- 235000019730 animal feed additive Nutrition 0.000 claims description 30
- 238000001035 drying Methods 0.000 claims description 28
- 235000011868 grain product Nutrition 0.000 claims description 27
- 238000007906 compression Methods 0.000 claims description 26
- 230000006835 compression Effects 0.000 claims description 26
- 230000000996 additive effect Effects 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 11
- 238000004381 surface treatment Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 abstract description 44
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 abstract description 35
- 239000004472 Lysine Substances 0.000 abstract description 23
- 239000000126 substance Substances 0.000 abstract description 14
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 abstract description 11
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 abstract description 7
- 239000004473 Threonine Substances 0.000 abstract description 6
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 abstract description 6
- 239000008187 granular material Substances 0.000 abstract description 6
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 abstract description 5
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000470 constituent Substances 0.000 abstract description 2
- 235000010633 broth Nutrition 0.000 abstract 4
- 239000013589 supplement Substances 0.000 abstract 1
- 229940024606 amino acid Drugs 0.000 description 29
- 239000012141 concentrate Substances 0.000 description 29
- 235000001014 amino acid Nutrition 0.000 description 28
- 150000001413 amino acids Chemical class 0.000 description 28
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- 230000002349 favourable effect Effects 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 235000019766 L-Lysine Nutrition 0.000 description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 description 12
- 239000011707 mineral Substances 0.000 description 12
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- 239000000243 solution Substances 0.000 description 12
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- 229930006000 Sucrose Natural products 0.000 description 8
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 8
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 235000005822 corn Nutrition 0.000 description 4
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- 241000186226 Corynebacterium glutamicum Species 0.000 description 3
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- 244000291564 Allium cepa Species 0.000 description 2
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
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- 238000002386 leaching Methods 0.000 description 2
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
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- 239000000843 powder Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000008174 sterile solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000186146 Brevibacterium Species 0.000 description 1
- 241000186216 Corynebacterium Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 108010068370 Glutens Proteins 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000001888 Peptone Substances 0.000 description 1
- 108010080698 Peptones Proteins 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- CYDMQBQPVICBEU-UHFFFAOYSA-N chlorotetracycline Natural products C1=CC(Cl)=C2C(O)(C)C3CC4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O CYDMQBQPVICBEU-UHFFFAOYSA-N 0.000 description 1
- CYDMQBQPVICBEU-XRNKAMNCSA-N chlortetracycline Chemical compound C1=CC(Cl)=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(O)=C(C(N)=O)C(=O)[C@@]4(O)C(O)=C3C(=O)C2=C1O CYDMQBQPVICBEU-XRNKAMNCSA-N 0.000 description 1
- 229960004475 chlortetracycline Drugs 0.000 description 1
- 235000019365 chlortetracycline Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
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- 238000009792 diffusion process Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000021312 gluten Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
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- 238000011081 inoculation Methods 0.000 description 1
- 229910001412 inorganic anion Inorganic materials 0.000 description 1
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- 238000009413 insulation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000003808 methanol extraction Methods 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
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- 238000003860 storage Methods 0.000 description 1
- WPLOVIFNBMNBPD-ATHMIXSHSA-N subtilin Chemical compound CC1SCC(NC2=O)C(=O)NC(CC(N)=O)C(=O)NC(C(=O)NC(CCCCN)C(=O)NC(C(C)CC)C(=O)NC(=C)C(=O)NC(CCCCN)C(O)=O)CSC(C)C2NC(=O)C(CC(C)C)NC(=O)C1NC(=O)C(CCC(N)=O)NC(=O)C(CC(C)C)NC(=O)C(NC(=O)C1NC(=O)C(=C/C)/NC(=O)C(CCC(N)=O)NC(=O)C(CC(C)C)NC(=O)C(C)NC(=O)CNC(=O)C(NC(=O)C(NC(=O)C2NC(=O)CNC(=O)C3CCCN3C(=O)C(NC(=O)C3NC(=O)C(CC(C)C)NC(=O)C(=C)NC(=O)C(CCC(O)=O)NC(=O)C(NC(=O)C(CCCCN)NC(=O)C(N)CC=4C5=CC=CC=C5NC=4)CSC3)C(C)SC2)C(C)C)C(C)SC1)CC1=CC=CC=C1 WPLOVIFNBMNBPD-ATHMIXSHSA-N 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
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- 125000000430 tryptophan group Chemical group [H]N([H])C(C(=O)O*)C([H])([H])C1=C([H])N([H])C2=C([H])C([H])=C([H])C([H])=C12 0.000 description 1
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Images
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
- A23K10/16—Addition of microorganisms or extracts thereof, e.g. single-cell proteins, to feeding-stuff compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/16—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
- A23K10/12—Animal feeding-stuffs obtained by microbiological or biochemical processes by fermentation of natural products, e.g. of vegetable material, animal waste material or biomass
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/10—Organic substances
- A23K20/142—Amino acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K30/00—Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs
- A23K30/20—Dehydration
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K40/00—Shaping or working-up of animal feeding-stuffs
- A23K40/10—Shaping or working-up of animal feeding-stuffs by agglomeration; by granulation, e.g. making powders
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Animal Husbandry (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Biomedical Technology (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Physiology (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Fodder In General (AREA)
- Feed For Specific Animals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19621930A DE19621930C1 (de) | 1996-05-31 | 1996-05-31 | Verfahren zur Herstellung eines Tierfuttermittel-Zusatzes auf Fermentationsbrühe-Basis |
DE19621930.2 | 1996-05-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1170515A CN1170515A (zh) | 1998-01-21 |
CN1086918C true CN1086918C (zh) | 2002-07-03 |
Family
ID=7795823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97113051A Expired - Lifetime CN1086918C (zh) | 1996-05-31 | 1997-05-29 | 以发酵液为原料的动物饲料添加剂的生产方法 |
Country Status (19)
Country | Link |
---|---|
US (1) | US5840358A (hu) |
EP (1) | EP0809940B2 (hu) |
JP (1) | JPH1042793A (hu) |
KR (1) | KR100433357B1 (hu) |
CN (1) | CN1086918C (hu) |
AT (1) | ATE220297T1 (hu) |
AU (1) | AU711473B2 (hu) |
BR (1) | BR9703417B1 (hu) |
CA (1) | CA2206587A1 (hu) |
DE (2) | DE19621930C1 (hu) |
DK (1) | DK0809940T4 (hu) |
ES (1) | ES2179978T5 (hu) |
HU (1) | HU219610B (hu) |
IL (1) | IL120949A (hu) |
MX (1) | MX9703665A (hu) |
RU (1) | RU2180175C2 (hu) |
SK (1) | SK283277B6 (hu) |
TW (1) | TW334342B (hu) |
ZA (1) | ZA974733B (hu) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105658080A (zh) * | 2013-10-24 | 2016-06-08 | 赢创德固赛有限公司 | 包含l-氨基酸的饲料添加剂 |
Families Citing this family (73)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19707380A1 (de) * | 1997-02-25 | 1998-08-27 | Degussa | Verfahren zur Herstellung eines rieselfähigen Tierfuttermittelsupplements auf Methioninsalzbasis und das so erhältliche Granulat |
CA2255130A1 (en) * | 1997-12-16 | 1999-06-16 | Archer Daniels Midland Company | Process for making granular l-lysine feed supplement |
US5990350A (en) * | 1997-12-16 | 1999-11-23 | Archer Midland Company | Process for making granular L-lysine |
US6844006B1 (en) * | 1999-07-09 | 2005-01-18 | Pennfield Oil Company | Process and apparatus for the preparation of chlortetracycline-containing animal feed compositions |
US6319528B1 (en) * | 1999-05-05 | 2001-11-20 | Degussa Aktiengesellschaft | Feedstuff additive which contains D-pantothenic acid and/or its salts and a process for the preparation thereof |
US6238714B1 (en) * | 1999-05-05 | 2001-05-29 | Degussa-Huls Ag | Feedstuff additive which contains D-pantothenic acid and/or its salts and a process for the preparation thereof |
JP2000333615A (ja) * | 1999-05-28 | 2000-12-05 | Ajinomoto Co Inc | アミノ酸で強化した混合飼料 |
EP1752543A1 (en) * | 2000-01-20 | 2007-02-14 | Archer-Daniels-Midland Company | Process for making a variety of l-lysine feed supplements |
ES2272240T3 (es) * | 2000-01-20 | 2007-05-01 | Archer Daniels Midland Company | Procedimiento de preparacion de diversos suplementos alimenticios con l-lisina. |
JP2001309751A (ja) * | 2000-05-02 | 2001-11-06 | Ajinomoto Co Inc | 飼料用添加物 |
DE10032349A1 (de) | 2000-07-04 | 2002-01-17 | Degussa | Rieselfähige D-Pantothensäure und/oder deren Salze enthaltende Futtermittel-Additive und Verfahren zu deren Herstellung |
JP4362959B2 (ja) * | 2000-08-24 | 2009-11-11 | 味の素株式会社 | 塩基性アミノ酸の製造方法 |
JP2003219807A (ja) | 2002-01-25 | 2003-08-05 | Ajinomoto Co Inc | L−リジンを主成分とする造粒乾燥物 |
US20040115304A1 (en) * | 2002-12-16 | 2004-06-17 | Frank Dubner | Feesdstuffs additives containing L-lysine with improved abrasion resistance, and process for their production |
ES2242121T3 (es) * | 2003-05-07 | 2005-11-01 | Degussa Ag | Granulados recubiertos de percarbonato sodico con estabilidad al almacenamiento mejorada. |
EP1656454A4 (en) * | 2003-07-08 | 2011-06-22 | Novus Int Inc | PROCESS FOR METHIONINAL RECOVERY |
DE10331366A1 (de) * | 2003-07-11 | 2005-01-27 | Degussa Ag | Verfahren zur Granulation eines Tierfuttermittel-Zusatzes |
DE10359668A1 (de) | 2003-12-18 | 2005-07-14 | Basf Ag | Verfahren zur Herstellung von Methionin |
KR101052573B1 (ko) * | 2004-04-02 | 2011-07-29 | 씨제이제일제당 (주) | 균일한 함량을 갖는 과립형 동물 사료 첨가제를 제조하는 방법 및 그에 의하여 제조되는 과립형 동물 사료 첨가제 |
DE102004026152A1 (de) * | 2004-05-28 | 2005-12-15 | Basf Ag | Fermentative Herstellung von Feinchemikalien |
JP2008502728A (ja) | 2004-06-10 | 2008-01-31 | ボード、オブ、トラスティーズ、オブ、ミシガン、ステイト、ユニバーシティ | リジンからのカプロラクタムの合成 |
CN100417334C (zh) * | 2004-06-24 | 2008-09-10 | 长春大成实业集团有限公司 | 复合饲料颗粒料的生产方法、设备及复合饲料颗粒料 |
ES2718638T3 (es) | 2004-10-07 | 2019-07-03 | Ajinomoto Kk | Procedimiento enzimático para producir aminoácidos básicos |
US20070082031A1 (en) * | 2005-10-08 | 2007-04-12 | Hermann Lotter | L-lysine-containing feed additives |
KR100838200B1 (ko) * | 2006-01-10 | 2008-06-13 | 씨제이제일제당 (주) | 과립화에 의한 라이신 발효액을 주성분으로 하는 동물 사료보충물 및 그 제조 방법 |
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- 1997-05-30 HU HU9700977A patent/HU219610B/hu unknown
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IL120949A (en) | 2000-06-01 |
SK68197A3 (en) | 1997-12-10 |
EP0809940A2 (de) | 1997-12-03 |
DE59707676D1 (de) | 2002-08-14 |
HUP9700977A3 (en) | 1999-08-30 |
IL120949A0 (en) | 1997-09-30 |
EP0809940A3 (de) | 1999-06-02 |
HU9700977D0 (en) | 1997-07-28 |
HU219610B (hu) | 2001-05-28 |
CA2206587A1 (en) | 1997-11-30 |
HUP9700977A2 (en) | 1997-12-29 |
EP0809940B2 (de) | 2013-03-27 |
EP0809940B1 (de) | 2002-07-10 |
DK0809940T3 (da) | 2003-04-14 |
ATE220297T1 (de) | 2002-07-15 |
ES2179978T5 (es) | 2013-07-26 |
BR9703417B1 (pt) | 2013-01-22 |
AU711473B2 (en) | 1999-10-14 |
KR100433357B1 (ko) | 2004-09-10 |
RU2180175C2 (ru) | 2002-03-10 |
KR970073368A (ko) | 1997-12-10 |
AU2372497A (en) | 1997-12-04 |
JPH1042793A (ja) | 1998-02-17 |
ZA974733B (en) | 1997-12-30 |
TW334342B (en) | 1998-06-21 |
DK0809940T4 (da) | 2013-04-29 |
MX9703665A (es) | 1998-04-30 |
ES2179978T3 (es) | 2003-02-01 |
BR9703417A (pt) | 1998-09-15 |
DE19621930C1 (de) | 1997-12-11 |
CN1170515A (zh) | 1998-01-21 |
US5840358A (en) | 1998-11-24 |
SK283277B6 (sk) | 2003-05-02 |
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