CN105175149B - A kind of plants and flowers cultivation matrix and the preparation method and application thereof - Google Patents
A kind of plants and flowers cultivation matrix and the preparation method and application thereof Download PDFInfo
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Abstract
The present invention relates to a kind of plants and flowers cultivation matrixes, including organic base composition particle, inorganic matrix composition grain, sustained release control fertilizer efficiency particulate matter and plant-based medicine.Wherein, plant-based medicine is the composition of light-activated toxin and pyrethrin；Organic substrate composition grain is using air-dried cow dung, tealeaves and the decomposed material of needles of pinus massoniana and chitosan, plant ash, fertile soil through mixed composition；Inorganic matrix composition grain uses the composition of perlite, diatomite, rare earth and Titanium Citrate；Sustained release control fertilizer efficiency particulate matter is using potassium acrylate or the copolymer of polyglutamic acid potassium and trace element compound, plant modifying agent in chelating amino acids.The present invention has green insect prevention and sustained release control fertilizer efficiency, meet the needs of plants and flowers growing nutrient element, promote photosynthesis, have to the taking root of plant, survival rate and remarkably promotes effect, blooming period prolonging, earning rate is improved, for developing water-saving planting and improving the ecological environment, is had a very important significance.
Description
Technical field
The present invention relates to technical field of agricultural cultivation, in particular to a kind of plants and flowers cultivation matrix and preparation method thereof with
Using.
Background technique
With the continuous social and economic development, the people's material and cultural life level is continuously improved, and plant, flowers are extensive
Ground enters family, by people's potting on indoor or Around the house or balcony.However, living in skyscraper in city
Crowd is more and more, and for the fan of indoor flower-growing, maximum problem is that the ground in one side living area has green
Change band, on the other hand it is that the selected soil building waste got is more that the source for soil of raising flowers is fewer, poor quality,
It should not be used to raise flowers.In order to solve this problem, just there is the Nutrition Soil of inner wrapping to sell on flowers market, still, these
The Nutrition Soil of inner wrapping, contained nutritional ingredient is relatively simple, while giving out the different smell in soil, is not particularly suited for interior
It raises flowers.It can be seen that being stepped up as the development and people of horticultural industry beautify to living environment and afforest requirement, gardening
Is constantly present some problems during plantation and landscaping greening, such as exist potting medium specific gravity of soil is high, permeability is poor,
The content of organic matter is low, and water conservation, the problems such as fertilizer-preserving ability is poor seriously affect the growth and development of plant, flowers.
Along with agrotechnical development, the development of Floristry and level of application have become countries in the world agricultural
The cultivation technique without soil of one of important indicator of modernization level, especially plants and flowers obtains since the 1980s
Development at full speed, application of the cultivation technique without soil in terms of flowers promotes the large-scale production of flowers, so that 21 century becomes
The epoch of industry of flowers and plants high development.In terms of plants and flowers plantation, substrate culture is just playing increasingly in horticultural gardening
Important role, compared to soil cultivation, it has many advantages, such as water-saving, saves fertilizer, avoids soil pollution, and can be to avoid continuous cropping
Obstacle needs to adjust matrix physicochemical character according to different plant growths.However, current soilless culture substrate be with peat,
Vermiculite and perlite use after mixing according to a certain percentage, but peat makes for a long time as a kind of resource non-renewable in a short time
With being restricted, and domestic peat largely belongs to turf, and resolution is big, compared to external moss peat, physics and chemistry
Shape has certain difference, less desirable for substrate culture effect, it is accordingly required in particular to be pointed out that since peat is substantially free of
Nutrient is especially a lack of microelement, therefore, needs artificially to add nutrient, but nutrient in the course of cultivation
It controls and improper easily causes plants and flowers nutrient deficiency or nosotoxicosis.It is, thus, sought for a kind of cheap, source is steady
Fixed, the preferable matrix of cultivation effect partially or completely to replace peat, to reduce the dependence to peat.
To solve the problems, such as plants and flowers cultivation matrix, domestic and international industry technology personnel have made in-depth study to it.
Application No. is 201310528221.1 patents of invention to disclose a kind of sweet osmanthus potting media, belongs to agricultural substrate cultivation
Train technical field, it is characterised in that cultivation matrix include the biogas residue of 35%-45%, the vermiculite of 20%-30%, 30%-40% rural area soil,
35kg/m3Macromolecule water-keeping slow release composite fertilizer, 0.6kg/m3Microelement, wherein biogas residue: vermiculite: rural area soil=3:2:3, tool
There is abundance, it is at low cost, good growth substrate environment is provided to sweet osmanthus, there is high cultivation survival rate.
Authorization Notice No. provides a kind of flower cultivation medium and preparation method thereof for the patent of invention of CN101548639B,
Flower cultivation medium includes major ingredient and additive, and wherein major ingredient includes peat and perlite, and additive includes water supply in media conditioning
Agent, pH adjusting agent and Nutrient germinant, peat, perlite particle size range be 1-3mm, have nutritional ingredient high, physical property
Stablize, water supply in media conditioner can reduce the surface tension of matrix, improve the wetting ability and homogeneity of stromal surface, change
The appearance stability of peat, prevents moisture quickly to scatter and disappear, and improves moisture infiltration rate in actual use, improves the suction of peat growing medium
It is aqueous, delay the efflorescence of peat, the trophic structure of flower cultivation medium is reasonable, and it is easy for plant to absorpt, meet plant growth
It needs.
Authorization Notice No. provides a kind of biological disease-preventing, the dedicated cultivation of anti-insect type flowers for the patent of invention of CN102643148B
Matrix and preparation method thereof is trained, raw material is scarp, furfural dregs, microbial fermentation inoculum, calcium superphosphate, trichoderma bacteria agent, gemma
Bacillus microbial inoculum, composting add expanded perlite to obtain the final product after a certain period of time, which is utilized active Trichoderma and bacillus
And its metabolite significantly inhibits floral crops diseases, scarp and its decomposition product have the pest being also easy to produce in matrix
Lethal effect is expelled, environment can be protected for flower planting, be conducive to the health of people.
Application No. is 201410199426.4 patents of invention to disclose a kind of high-efficiency sustained-release composite base of one-time use
Fertilizer, the fertilizer are made by the raw material of following parts by weight, i.e. diatomite 10-15, cow dung do 15-18, paddy bran 8-10, urea 20-
22, monoammonium phosphate 15-18, calcium superphosphate 8-10, natural plant gum 2-3, animal glue 1-3, basalt powder 1-2, potassium chloride 10-12,
Black earth 6-8, zinc sulfate 2-4, needles of pinus massoniana 4-5, pre-gelatinized tapioca 12-15, polyvinyl alcohol 6-8, glycerol 4-5, high activity
Zinc oxide 0.1-0.2, magnesium sulfate 3-5, egg shell 1-2,4-5 parts of auxiliary agent, above-mentioned raw materials are from a wealth of sources, and but fertility low in cost is rich
Foot, be utilized diatomite in manufacture craft and a variety of easy film forming raw materials be prepared for efficient slow release coating agent nutrient is formed it is double
It coats again, so that fertilizer efficiency is more lasting, avoids the loss of nutrient.
Authorization Notice No. is that the patent of invention of CN101023734B discloses botanical seedling culturing matrix, which contains
Volume after having acrylates-acrylamide cross-linked copolymer, every gram of cross-linked copolymer to absorb is 100-120 cubes li
Rice, the density of the cross-linked copolymer are 0.8 ton/cubic metre, the molar ratio of acrylates and acrylamide in the copolymer
For 1-4:9-6.Compared with conventional cigarette seedling medium, which, which has, promotes tobacco seedling growth, realizes without germ, without weeds matrix
Feature.
Authorization Notice No. is that the patent of invention of CN102276315B discloses a kind of production of organic environmental-protection gardening humus
Method, specially every 1000kg oil tea shell add oleander clast 10kg to be stirred stock, are measured by potassium bichromate titrimetric method
Total carbon content in material, micro kelvin nethod of measuring nitrogen measure total nitrogen content, and fermenting microbe 1kg is added, and purity nitrogen 3kg is stirred evenly,
Reach the production purpose of gardens increased surface covering and soilless culture substrate by the regulation of compost time, compost 25-60 days, dries
It does or dries to water content less than 30%, simple process, raw material sources are stablized, and environmental requirement is met.
Application No. is 201410667788.1 patents of invention to disclose a kind of flower culturing soil, including following parts by weight
Raw material, 35-40 parts of leaf mould, 10-20 parts of minishanny, 15-25 parts of garden mould, 5-10 parts of chicken manure, 2-6 parts of raising agent, preservative 2-7
Part, 15-20 parts of activated sludge, 15-20 parts of sawdust, 3-8 parts of active microorganism, 15-25 parts of plant ash, 1-5 parts of ammonium sulfate, swelling
20-30 parts native, the Flower nutrient soil nutriment is abundant, and fermentation time is short, and preservation capacity of water and fertility is good, at low cost.
It can be seen that the prior art is carried out mainly around Nutrition Soil and its bacteria agent and the slow release fertilizer aspect of flowers
A large amount of research, but there is following deficiency in currently available technology, it shows:
(1) in terms of cultivation matrix, it is full that the prior art, which mainly passes through addition multi mineral nutritional ingredient or biological bacteria,
The Nutrition Soil of sufficient seedling development and the multi mineral nutrition of particular formulation, but surface layer is easy when the fatal defects of Nutrition Soil are dry
In hardened, and it is wet when ventilating permeable it is poor, cannot be used alone；
(2) in terms of sustained release controls fertilizer efficiency, the prior art mainly using hydrophobic membrane material coating technology or uses polypropylene
Acid sodium-salt high polymer carries base fertilizer nutrient such as N, P, K substance as carrier, and therefore, the prior art uses polyacrylic acid
Sodium is as carrier, though provide water sucking and water-retaining function, existing sodium salt has aggravated the hardened degree of soil again,
It is fresh to use polyacrylic acid potassium less, and as the sustained release control carrier material of amino acid trace element chelated compound in.
In addition, different from common plant, soilless culture of flowers is generally used for the beautification dress of park, street and home environment
Decorations, it is desirable that it is more environmentally-friendly, toxic pesticides are not used as far as possible, but flowers are sick infested to be inevitable thing.Therefore, it is seeking
During seeking safely and effectively control measure, botanical pesticide prevention and treatment is paid more and more attention.Botanical pesticide is because have extensive
Adaptability, to the good antagonistic activity of plants and flowers pathogen, it is safe to non-target organism and free from environmental pollution the advantages that,
Having become most has one of plant disease-proof measure of potentiality to be exploited, according to the purposes feature of flowers, utilizes the active element of plant
Natural anthelmintic action preparation floriculture substrate is also rarely reported at present.
Based on problems of the prior art, the present invention provides a kind of plants and flowers cultivation matrix, not only has insect prevention
Effect, meet beautifying and decorating and the environmental requirement of home environment, and there is the function of sustained release control Meso- and micro-nutrients fertilizer efficiency
Can, internal nutrient is slowly discharged into soil, constantly nutrient is supplied to crops, effectively improves the benefit of fertilizer
Therefore, it the advantage is that plants and flowers robust growth, leaf color is dark green, flowers so that the fertilizer efficiency time of nutrient is long with rate
Flower is big and more, and bright in colour, the florescence is long, saves nutrient, moisture and labour, clear keep free of weeds can be to avoid soil continuous cropping
Obstacle is not limited by soil condition, greatly expansion agricultural production space, convenient for the factorial production etc..
Summary of the invention
The object of the present invention is to provide a kind of plants and flowers cultivation matrix that fertilizer efficiency is controlled with green insect prevention and sustained release, the bases
Matter can provide microelement and Fertilizer Efficiency of Amino Acids in necessary to growth for plants and flowers, and fertilizer efficiency composition is coated on to environment
And soil close friend polyacrylic acid potassium or polyglutamic acid potassium carrier in, fertilizer efficiency element, nutrient are released slowly into soil, mentioned
The utilization rate and duration of high fertilizer efficiency, meanwhile, the invasion of pest and disease damage can be effectively reduced；Rare earth element, lemon contained in matrix
Sour titanium elements can increase the photosynthesis of plants and flowers, promote plants and flowers robust growth, and leaf color is dark green, the flower of flowers it is big and
It is more, bright in colour, blooming period prolonging.
In order to achieve the above objectives, the technical solution adopted by the present invention are as follows: a kind of plants and flowers cultivation matrix includes organic
Substrate combination composition granule, inorganic matrix composition grain, sustained release control fertilizer efficiency particulate matter and plant-based medicine, according to parts by weight,
The cultivation matrix proportion are as follows:
Organic substrate composition grain is 30-60 parts；
Sustained release control fertilizer efficiency particulate matter is 25-35 parts；
Inorganic matrix composition grain is 15-25 parts；
Plant-based medicine is 0.5-10 parts.
The organic substrate composition grain is used in the mixed powder by air-drying cow dung, tealeaves and needles of pinus massoniana are constituted
In bottom material made of sterilizing again after fermented bacteria fermentation is decomposed, addition chitosan, plant ash, fertile soil through it is mixed, be granulated and
Composition prepared by drying process, parts by weight proportion are as follows:
Air-drying cow dung is 15-30 parts；
Chitosan is 10-15 parts；
Fertile soil is 22-25 parts；
Plant ash is 18-20 parts；
Tealeaves powder is 12-15 parts；
Needles of pinus massoniana powder is 8-10 parts；
Fermenting agent is 0.2-3 parts.
The fermenting agent is that 5 sections such as photosynthetic bacteria group, yeast flora, lactobacillus, bacillus group, mycorhiza flora are several
A kind of ten kinds of microorganisms sizing microbial inoculum made of compound criteria in same state, is market sale commodity.
The inorganic matrix composition grain is using perlite, diatomite, rare earth and Titanium Citrate according to following weight parts
Number proportion is through composition prepared by homogeneous blend granulation and drying process:
Perlite is 30-58 parts；
Diatomite is 35-40 parts；
Rare earth is 5-15 parts；
Titanium Citrate is 2-15 parts.
The sustained release control fertilizer efficiency particulate matter uses the three-dimensional net structure in cross-linking type polyacrylic acid potassium or polyglutamic acid potassium
It is interior, it is combined with trace element compound and plant modifying agent in chelating amino acids, each component is relative to cross-linking type polyacrylic acid potassium
Or the parts by weight proportion of polyglutamic acid potassium are as follows:
Cross-linking type polyacrylic acid potassium or polyglutamic acid potassium are 100 parts；
Trace element compound is 15-50 parts in chelating amino acids；
Plant modifying agent is 0.1-4 parts.
Wherein, trace element compound uses parts by weight for 50-60 parts of compound amino acid in the chelating amino acids
Aqueous solution, 25-30 parts of moderate-element compound, 15-20 parts of trace element compounds and 0.5-2.5 parts of auxiliary agent are by chelating
Technique forms.
The compound amino acid using aspartic acid, threonine, serine, glutamic acid, glycine, propylhomoserin, phenylalanine,
Lysine, arginine, histidine, methionine combination liquid；The moderate-element compound is using calcium chloride, magnesium chloride, anhydrous
One or more combinations of magnesium sulfate, ammonium sulfate；The trace element compound is sub- using boric acid, zinc sulfate, copper sulphate, sulfuric acid
One or more combinations of iron, ammonium molybdate tetrahydrate, manganese sulfate；The auxiliary agent includes emulsifier and cosolvent, and the emulsifier is adopted
With one or two kinds of combinations of lauryl sodium sulfate salt, calcium dodecyl benzene sulfonate, alkyl phenol polyoxyethylene ether, the hydrotropy
Agent is formic acid.
In the aminoacid chelating microelement solution, can also it be added including nitrogen, phosphorus (P2O5), the basic fertilizer of potassium.
The tealeaves can be substituted using the tea polyphenol extract object in tealeaves.
Wherein, one kind or more of the plant modifying agent selection brassin lactones, gibberellin, the basic element of cell division, methyl α-naphthyl acetate
Kind combination.
Wherein, the rare earth selects nitric acid rare earth, and the nitric acid rare earth is by two in light rare earth elements lanthanum, cerium, praseodymium, neodymium
The inorganic mixture of kind or two or more nitrate composition.
Rare earth can activate crop enzyme system, adjust the growth function of crop, can promote plant vital activity, promote chlorophyll
It is formed, the germination of crops takes root and optimizes chlorophyll tissue, increases organic synthesis, and therefore, rare earth is as a kind of containing micro
The compound of element has certain facilitation to plant growth；Rare earth, which also has, promotes plant generative organ to absorb organic nutriment
Effect, promote absorption of the excitation crops to nutrients such as nitrogen, phosphorus, potassium, increase the accumulation of dry matter, rare earth concentration is being suitable for
Within the scope of, it can significantly extend the time of flowering.
Wherein, titanium can promote photosynthesis and the growth and development of plant, improve the content of chlorophyll, increase yield and improvement
The effects of product quality, has apparent physiological activity, and the substantially nontoxic or toxicity of the citrate (Ti-Ci) of titanium category is atomic
Substance (similar edible salt), titanium has in matrix promotes plants and flowers development, maintains plants and flowers cauline leaf under low-light
Photosynthesis, the effects of increasing dry-matter accumulation and keep blade bud green tall and straight.
One kind of phytotoxin of the plant-based medicine selection with insecticidal action, the phytotoxin with bactericidal effect
Or two kinds of combinations.Wherein, the phytotoxin with insecticidal action uses pyrethrin, rotenone, nicotine, pepper amide chemical combination
Object, ryania and the like, tetrahydrofuran fatty acid compound, Glutamic Acid analog, dihydroagarofuran class compound,
One or more combinations of three thiophene and acetylene compound；The phytotoxin with bactericidal effect uses allicin；It is described
Plant-based medicine use with photoreactivation three thiophene toxin and pyrethrin composition, the three thiophene toxin with remove
Worm chrysanthemum element allocation ratio is 0.5-1:0.4-0.8.
Application of the plants and flowers cultivation matrix in succulent, decorative flower, foliage plant and herbaceous plant.
The preparation method of the plants and flowers cultivation matrix, includes the following steps:
1) compound amino acid: being formulated as the solution of free aminoacid content >=30% with deionized water by chelatropic reaction, heating
To 65 DEG C -70 DEG C, surfactant, cosolvent and after mixing evenly, addition moderate-element compound, microelement chemical combination is added
After object reacts 60-120min at 65 DEG C of -70 DEG C of temperature and stirring condition, mixed liquor is filtered or suction filtration is handled, is obtained
Trace element compound in chelating amino acids, it is spare.
2) acrylic acid or glutamic acid monomer the preparation of sustained release control fertilizer efficiency particulate matter: are formulated as mass concentration with deionized water
For 30% ~ 50% solution, it is 60%~80% that potassium hydroxide, which is added, and adjusts degree of neutralization, is warming up to 40 DEG C -60 DEG C, step 1) system is added
Trace element compound, plant modifying agent in the chelating amino acids obtained, add 0.1-1.0 parts of crosslinking agent, initiator after stirring
0.05-0.5 parts of progress polymerization reactions simultaneously continue to stir, and gel high polymer is made, after carrying out broken granulation processing to high polymer,
Heat cross-linking table is carried out to gained granulated polymer using spray-on process at a temperature of 80-180 DEG C with 0.5-1.8 parts of crosslinking agent again
Sustained release control fertilizer efficiency particulate matter can be obtained, wherein the crosslinking agent uses N, N- di-2-ethylhexylphosphine oxide third in surface treatment after heated drying
Acrylamide, initiator are redox initiation system, and reducing agent is sulphite, and oxidant is hydrogen peroxide.
3) preparation of organic substrate composition grain: tealeaves and needles of pinus massoniana are crushed as powder, and by its with through air-drying
The cow dung of processing, which is poured into, is mixing uniformly to form mixture in fermentation vat, mixture is divided in fermentation vat, and presses mixture
The 60%-70% of weight calculates the additional amount of moisture, and the dosage of fermenting agent is calculated in 1 ‰ -3 ‰ ratios of mixture weight, will
Fermenting agent is sprayed on the surface of mixture, is then covered in surface with plastic foil, and material temperature degree is higher than 60 DEG C during the fermentation
Shi Bixu carries out stirring processing, sterilization treatment is carried out after 30-60 days fermentation maturities, and chitosan, plant ash, fertile soil are added
Enter in decomposed material after mixing evenly, be granulated and be dried using pelletizer, organic substrate composition grain is made.
4) perlite, diatomite, rare earth, Titanium Citrate the preparation of inorganic matrix composition grain: are pressed into certain part by weight
Number mixes and is modulated to paste with ratio, it is granulated and is dried using pelletizer, and inorganic matrix combination is made
Composition granule.
5) be blended: will sustained release control fertilizer efficiency particulate matter made from step 2, organic substrate composition grain made from step 3),
Inorganic matrix composition grain made from step 4) carries out being mixed and stirred for uniformly, i.e., according to a certain percentage with plant-based medicine
Plants and flowers cultivation matrix is made.
It is that the present invention realizes the utility model has the advantages that the invention belongs to have the composite plant flower of green insect prevention and sustained release control fertilizer efficiency
Grass cultivation matrix can be not only middle microelement and Fertilizer Efficiency of Amino Acids necessary to the growth of plants and flowers slow release, improve fertilizer
The utilization rate and duration of effect, and the effect of expelling parasite, insect prevention can be provided for plants and flowers, the invasion of pest and disease damage are effectively reduced,
Meanwhile matrix can increase the photosynthesis of plants and flowers, promote plants and flowers robust growth, hestening rooting improves survival rate, makes
The leaf color for obtaining plants and flowers is dark green, bright in colour, and flower is big and more, and blooming period prolonging, the compound matrix are answered to the maximum extent
With production cost can be reduced, the earning rate of flower crop is improved, the modernization operation and industrialized scale for improving plants and flowers are transported
Battalion is horizontal, has huge economic benefit, social benefit and environmental benefit, for developing water-saving planting and improving the ecological environment,
It has a very important significance.
Specific embodiment
In order to make it easy to understand, being first described further to relational language involved in the present invention or mechanism of action.
Term " fertile soil ": being the Nutrition Soil that plant leaf is formed after microorganism decomposition is fermented in the soil, by
During multiple-microorganism alternating activity makes plant leaf decomposition, the advantages of being much different from natural soils, performance are formd
: first is that light loose, permeable venting capability is good, and retain water and nutrients ability is strong；Second is that porous, chronic administration is not hardened, easily
It is absorbed by plants, it is mixed with other soil, soil can be improved, is increase soil fertility；Third is that rich in organic matter, humic acid and a small amount of
Vitamin, auxin, microelement etc. can promote the growth and development of plant；Fourth is that the high temperature in decomposing and fermenting can kill wherein
Germ, worm's ovum and weed seed etc., reduce disease pest, Weed infestation.When using leaf mould, can according to the variety classes of potted flower,
Other type soil and suitable chemical fertilizer such as garden mould, clay, sandy soil is added in the requirement of root growth by a certain percentage, mixes
It is configured to compost after even and plants flowers again.
Term " trace element compound in chelating amino acids ": refer to using chelating amino acids plant nutrient, so that nothing
Machine element becomes organic chelated state element, so that the absorption rate of nutrient further increases, shows as with strong points, fertilizer
Effect is fast, and dosage is few, increase yield significantly, and can avoid fixed function of the soil to certain nutrients, economical and efficient.Plants and flowers is to metal
Chelate is particularly easy to the reason of absorbing, mainly since metallo-chelate is quite stable, some coordination atom in multidentate ligand
After in conjunction with central metal atom, remaining coordination atom reduces at a distance from central atom, they are in conjunction with central atom
Probability just increases.If wherein there is coordinate bond destruction, since other coordination atoms are still bonded with central atom in multidentate ligand,
It is easier to restore so that the coordination that is destroyed is strong, the more, in ligand available coordination atom is just for the coordination atom in multidentate ligand
The more, chela ring is formed just the more, it is strong just the more that same ligand and central atom are formed by coordination, ligand off center atom
Chance it is just smaller, chelate is just more stable, therefore, plants and flowers be particularly easy to absorb metallo-chelate.
Light-activated toxin mechanism of action: light-activated toxin (thiophenes) is one be largely present in compositae plant
Class secondary substance all has good light toxic effect living to the sick mosquito of a variety of biographies, nematode, mite class etc..Light-activated toxin is because right
The harmful organisms such as virus, pathogenic microorganism, nematode, insect have extensive and effective toxicity, and to safety of human and livestock, and in environment
In be easy to degrade, show huge potentiality as a kind of novel public nuisance-free agricultural chemicals.
The mechanism of action of photoactivation element mainly includes two kinds of I type and II type, and in I type mechanism, light-activated toxin absorbs light
Photon excited, rise to sharp singlet state first, then intersystem crossing, which drops to, is excited triplet, and substrate is (by photoactivation oxygen
The compound of change) it is reacted with the light-sensitive compound of excitation state (singlet state or triplet), by the transfer of hydrogen atom or electronics, divide
Not Sheng Cheng free radical or radical ion, free radical reacts the product for generating oxidation with oxygen, and light-sensitive compound rises in II type mechanism
It is just the same with I type mechanism, it absorbs in the same manner and excites generation excitation state, the light-sensitive compound of excitation state transfers the energy to
Ground state oxygen generate creating singlet oxygen, then, creating singlet oxygen or with substrate reactions generate oxide, or because not can be carried out reaction due to decay
Return ground state.
Botanical pesticide is one important in biological pesticide, is the deficiency for solving chemical pesticide, guarantees that high crop yield is excellent
Matter meets the needs of people are to non-harmful product and splendid selection free from environmental pollution, utilizes plant roots cauline leaf flowers fruit seed
Or separation to the pesticidal preparations that are processed into of active constituent, there is, low-residual low to people and animals' toxicity, being compatible with the environment property
It is good, nuisanceless, there is preferable activity to disease pest, do not injure the spy that natural enemy, the mode of action are unique, pest is not likely to produce drug resistance
Point.
Natural pyrethrum Dalmatian chrysanthemum (Chrysanthemum cineriaefolium) it is perennial catananche,
The nervous system for mainly acting on insect is a kind of ideal insecticide, is widely applied in control of insect.
Light-activated toxin (furocoumarin, three thiophene and polyacetylene class etc.), it is (photodynamic action, photo-induced under light illumination
Toxicity) there is very strong insecticidal activity to insect, very low to mammal activity, structure is simple, is readily synthesized, and has very big open
Send out potentiality.
Plants and flowers cultivation matrix of the present invention includes organic base composition particle, inorganic matrix composition
Grain, sustained release control fertilizer efficiency particulate matter and plant-based medicine, according to parts by weight, the cultivation matrix proportion are as follows:
Organic substrate composition grain is 30-60 parts；
Sustained release control fertilizer efficiency particulate matter is 25-35 parts；
Inorganic matrix composition grain is 15-25 parts；
Plant-based medicine is 0.5-10 parts.
One kind of phytotoxin of the plant-based medicine selection with insecticidal action, the phytotoxin with bactericidal effect
Or two kinds of combinations.Wherein, the phytotoxin with insecticidal action uses pyrethrin, rotenone, nicotine, pepper amide chemical combination
Object, ryania and the like, tetrahydrofuran fatty acid compound, Glutamic Acid analog, dihydroagarofuran class compound,
One or more combinations of three thiophene and acetylene compound；The phytotoxin with bactericidal effect uses allicin；It is described
Plant-based medicine preferably has the composition of three thiophene toxin and pyrethrin of photoreactivation.
The plant-based medicine is the composition that light-activated toxin and pyrethrin press 0.5-1:0.4-0.8 proportional arrangement,
It is preferably in a proportion of 0.55:0.45.Pyrethrin is used by " the west of the processing of Xi'an Jin Lv biotechnology Co., Ltd, sale
Peace gold is green " board pyrethrin extract；Tri- thiophene of light-activated toxin a- (a-terthienyl, abbreviation a-T) is SIGMA company
Product.
The organic substrate composition grain is used in the mixed powder by air-drying cow dung, tealeaves and needles of pinus massoniana are constituted
In bottom material made of sterilizing again after fermented bacteria fermentation is decomposed, addition chitosan, plant ash, fertile soil through it is mixed, be granulated and
Composition prepared by drying process, wherein fertile soil is used by " the Three Gorges corruption of the processing of Badong County Three Gorges nursery stock center, sale
Grow soil ", other components are also commercial goods.
The fermenting agent is that 5 sections such as photosynthetic bacteria group, yeast flora, lactobacillus, bacillus group, mycorhiza flora are several
A kind of ten kinds of microorganisms sizing microbial inoculum made of compound criteria in same state.The fermenting agent that the present invention uses is by Baoding day
Element fertilizer Research Institute, " agreeing green " the composite fermentation microbial inoculum sold.
The inorganic matrix composition grain is matched according to parts by weight using perlite, diatomite, rare earth and Titanium Citrate
Than through composition prepared by homogeneous blend granulation and drying process.Wherein, the rare earth selects nitric acid rare earth, and the nitric acid is dilute
The inorganic mixture that soil is made of two or more nitrate in light rare earth elements lanthanum, cerium, praseodymium, neodymium.The present invention adopts
Rare earth is entitled " obtain rare earth " rare earth commodity by the green precious rare-earth fertilizer industry Co., Ltd production and sales in Baotou more.
The sustained release control fertilizer efficiency particulate matter uses in the aqueous solution of potassium acrylate or potassium glutamate, adds chelating amino acids
Middle trace element compound is copolymerized with plant modifying agent, is crosslinked, be granulated, dry prepared by functional material.
Wherein, trace element compound uses parts by weight for 50-60 parts of compound amino acid in the chelating amino acids
Aqueous solution, 25-30 parts of moderate-element compound, 15-20 parts of trace element compounds and 0.5-2.5 parts of auxiliary agent are by chelating
Technique forms.The auxiliary agent includes emulsifier and cosolvent, and wherein emulsifier uses lauryl sodium sulfate salt, detergent alkylate
One or two kinds of combinations of sulfoacid calcium, alkyl phenol polyoxyethylene ether, cosolvent is formic acid.
The compound amino acid using aspartic acid, threonine, serine, glutamic acid, glycine, propylhomoserin, phenylalanine,
Lysine, arginine, histidine, methionine combination liquid, unit content is as shown in table 1.
1 compound amino acid unit content of table
| Amino acid | Aspartic acid | Threonine | Serine | Glutamic acid | Glycine | Propylhomoserin |
| Content (mg/L) | ≥1750 | ≥540 | ≥630 | ≥2120 | ≥570 | ≥650 |
| Amino acid | Phenylalanine | Lysine | Arginine | Histidine | Methionine | Total amino acid content |
| Content (mg/L) | ≥860 | ≥690 | ≥440 | ≥360 | ≥550 | ≥12540 |
The moderate-element compound is using calcium chloride, magnesium chloride, anhydrous magnesium sulfate, one or more groups of ammonium sulfate
It closes；
The trace element compound is using boric acid, zinc sulfate, copper sulphate, ferrous sulfate, ammonium molybdate tetrahydrate, manganese sulfate
One or more combinations.
Wherein, one kind or more of the plant modifying agent selection brassin lactones, gibberellin, the basic element of cell division, methyl α-naphthyl acetate
Kind combination.
Further, plants and flowers cultivation matrix, in parts by weight, component are as follows:
Organic substrate composition grain is 30 parts；
Sustained release control fertilizer efficiency particulate matter is 35 parts；
Inorganic matrix composition grain is 25 parts；
Plant-based medicine is 10 parts；
Further, plants and flowers cultivation matrix, in parts by weight, component are as follows:
Organic substrate composition grain is 60 parts；
Sustained release control fertilizer efficiency particulate matter is 25 parts；
Inorganic matrix composition grain is 14.5 parts；
Plant-based medicine is 0.5 part；
Further, plants and flowers cultivation matrix, in parts by weight, component are as follows:
Organic substrate composition grain is 50 parts；
Sustained release control fertilizer efficiency particulate matter is 30 parts；
Inorganic matrix composition grain is 19.5 parts；
Plant-based medicine is 0.5 part.
Embodiment 1
The total amino acid content of the present embodiment is >=13500mg/L, and number is 60 parts, and middle microelement adds number such as table
Shown in 2:
Microelement adds number in table 2
| Moderate-element | Calcium chloride | Magnesium chloride | Ammonium sulfate |
| Match number | 15 | 5 | 5 |
| Microelement | Boric acid | Zinc sulfate | Manganese sulfate |
| Match number | 7 | 4 | 5 |
The organic substrate composition grain of the present embodiment, the component of inorganic matrix composition grain are shown in table 3:
The addition component of the organic and inorganic substrate combination composition granule of table 3
| Organic substrate composition | Air-dry cow dung | Chitosan | Fertile soil | Plant ash | Tealeaves | Needles of pinus massoniana |
| Component | 15 | 15 | 25 | 20 | 15 | 10 |
| Inorganic matrix composition | Perlite | Diatomite | Rare earth | Titanium Citrate | ||
| Component | 58 | 35 | 5 | 2 |
Plants and flowers cultivation matrix of the present invention, preparation method include the following steps:
1) chelatropic reaction:
Compound amino acid is formulated as to the solution of free aminoacid content 30% with deionized water, is warming up to 65 DEG C -70 DEG C,
0.4 part of lauryl sodium sulfate salt of addition, 0.2 part of alkyl phenol polyoxyethylene ether, 0.2 part of formic acid, and after mixing evenly, in addition
25 parts of secondary element compound, 16 parts of trace element compound, after reacting 120min at 65 DEG C of -70 DEG C of temperature and stirring condition,
Mixed liquor is filtered or suction filtration is handled, obtains trace element compound in chelating amino acids, it is spare.
2) 100 parts of acrylic monomers the preparation of sustained release control fertilizer efficiency particulate matter: is formulated as mass concentration with deionized water
For 30% ~ 50% solution, it is 60%~80% that potassium hydroxide, which is added, and adjusts degree of neutralization, is warming up to 40 DEG C -60 DEG C, step 1) system is added
30 parts of trace element compound, 0.2 part of brassin lactones, 0.1 part of gibberellin, the basic element of cell division 0.2 in the chelating amino acids obtained
Part, add N after stirring, 0.2 part of N- methylene-bisacrylamide, 0.01 part of sodium sulfite .01 parts of hydrogen peroxidase 10 gathered
It closes and reacts and continue to stir, gel high polymer is made, after carrying out broken granulation processing to high polymer, use N, N- methylene again
The solution of 0.5 part of bisacrylamide configuration carries out heat cross-linking to gained granulated polymer using spray-on process at a temperature of 160 DEG C
Sustained release control fertilizer efficiency particulate matter can be obtained in surface treatment after heated drying.
3) preparation of organic substrate composition grain: tealeaves, needles of pinus massoniana are crushed as powder, and by itself and air-dried cow dung
It pours into and is mixing uniformly to form mixture in fermentation vat, mixture is divided in fermentation vat, and based on the 60% of mixture weight
The additional amount of moisture is calculated, 0.2 part of composite fermentation microbial inoculum is added, the surface of mixture is sprayed on after fermenting agent is diluted, then
It is covered in surface with plastic foil, stirring processing must be carried out when material temperature degree is higher than 60 DEG C during the fermentation, was fermented through 30-60 days
High temperature or sterilization treatment of being exposed to the sun are carried out after decomposed, and chitosan, plant ash, fertile soil are added in decomposed material after mixing evenly,
It is granulated and is dried using pelletizer, organic substrate composition grain is made；
4) preparation of inorganic matrix composition grain: perlite, diatomite, rare earth, Titanium Citrate are mixed, and with water tune
It is made as paste, it is granulated and is dried using pelletizer, inorganic matrix composition grain is made.
5) it is blended: sustained release control 35 parts of fertilizer efficiency particulate matter, 30 parts of organic substrate composition grain, inorganic matrix composition grain
25 parts, 10 parts of plant-based medicine be mixed and stirred for uniformly, obtaining plants and flowers cultivation matrix.
Embodiment 2
The total amino acid content of the present embodiment is >=14500, and number is 50 parts, and middle microelement adds number such as 4 institute of table
Show:
Microelement adds number in table 4
| Moderate-element | Calcium chloride | Magnesium chloride | Anhydrous magnesium sulfate | |
| Match number | 10 | 15 | 3 | |
| Microelement | Boric acid | Ferrous sulfate | Manganese sulfate | Zinc sulfate |
| Match number | 4 | 3 | 5 | 5 |
The organic substrate composition grain, the component of inorganic matrix composition grain of the present embodiment are as shown in table 5:
The organic and inorganic substrate combination composition granule of table 5 adds component
| Organic substrate composition | Air-dry cow dung | Chitosan | Fertile soil | Plant ash | Tealeaves | Needles of pinus massoniana |
| Component | 30 | 10 | 22 | 18 | 12 | 8 |
| Inorganic matrix composition | Perlite | Diatomite | Rare earth | Titanium Citrate | ||
| Component | 30 | 40 | 15 | 15 |
Plants and flowers cultivation matrix of the present invention, preparation method include the following steps:
1) 28 parts of moderate-element compound are added, 17 parts of trace element compound, is made by (1) the step of embodiment 1
It is standby, trace element compound in chelating amino acids is obtained, it is spare.
2) trace element compound 40 part are used in chelating amino acids, 0.2 part of methyl α-naphthyl acetate, 0.1 part of gibberellin, cell division
0.2 part of element, is prepared by (2) the step of embodiment 1, obtains sustained release control fertilizer efficiency particulate matter.
3) proportion raw material is added, is prepared by (3), (4) the step of embodiment 1, obtained organic substrate composition grain,
Inorganic matrix composition grain.
4) it is blended: sustained release control 25 parts of fertilizer efficiency particulate matter, 60 parts of organic substrate composition grain, inorganic matrix composition grain
14.5 parts, 0.5 part of plant-based medicine be mixed and stirred for uniformly, obtaining plants and flowers cultivation matrix.
Embodiment 3
The total amino acid content of the present embodiment is >=14000, and number is 55 parts, and middle microelement adds number such as 6 institute of table
Show:
Microelement adds number in table 6
| Moderate-element | Calcium chloride | Magnesium chloride | Ammonium sulfate | Anhydrous magnesium sulfate |
| Match number | 15 | 3 | 3 | 4 |
| Microelement | Boric acid | Zinc sulfate | Manganese sulfate | Ammonium molybdate tetrahydrate |
| Match number | 8 | 4 | 5 | 3 |
The organic substrate composition grain, the component of inorganic matrix composition grain of the present embodiment are as shown in table 7:
The organic and inorganic substrate combination composition granule of table 7 adds component
| Organic substrate composition | Air-dry cow dung | Chitosan | Fertile soil | Plant ash | Tealeaves | Needles of pinus massoniana |
| Component | 25 | 10 | 24 | 19 | 13 | 9 |
| Inorganic matrix composition | Perlite | Diatomite | Rare earth | Titanium Citrate | ||
| Component | 45 | 36 | 10 | 9 |
Plants and flowers cultivation matrix of the present invention, preparation method include the following steps:
1) 25 parts of moderate-element compound are added, 20 parts of trace element compound, is made by (1) the step of embodiment 1
It is standby, trace element compound in chelating amino acids is obtained, it is spare.
2) trace element compound 35 part are used in chelating amino acids, 0.2 part of brassin lactones, 0.1 part of gibberellin, cell
0.2 part of mitogen, 0.1 part of methyl α-naphthyl acetate, are prepared by (2) the step of embodiment 1, obtain sustained release control fertilizer efficiency particulate matter.
3) proportion raw material is added, is prepared by (3), (4) the step of embodiment 1, obtained organic substrate composition grain,
Inorganic matrix composition grain.
4) it is blended: sustained release control 30 parts of fertilizer efficiency particulate matter, 50 parts of organic substrate composition grain, inorganic matrix composition grain
19.5 parts, 0.5 part of plant-based medicine be mixed and stirred for uniformly, obtaining plants and flowers cultivation matrix.
Embodiment 4
Plants and flowers cultivation matrix made from the embodiment of the present invention 1-3 and common cultivation matrix are subjected to potting respectively
Rose test, each 30 plants of processing are cultivated, test carries out in company's flower planting base.
Test method:
1) the raw excellent rose plant of 3-5 that test material is selected from base plantation is elite stand, robust growth, nothing on clip maternal plant
The current year of pest and disease damage, raw lignifying branch was tested material.The acquisition selection of branch carries out in the morning, cuts rear branch and is immersed in immediately
In water, while moisturizing of spraying water on branch.When clip cuttings indoors or shady place, the branch chosen is cut into the left side 10 cm
Inclined-plane at 45 ° is cut in right cuttings, top straight snips, lower part, and compound leaf 2-3 piece in part in reservation, every compound leaf stays 2-4 leaflet, often
30 plants roll into a bundle, are put into the liquor potassic permanganate of 800 times of carbendazim solutions or 1%-2% and impregnate 3min progress bottoming disinfection.
2) matrix in the basin of cave is sprinkled profoundly water before cuttage, is then placed under on the spot spray head for 3 one group of basin, guarantee spraying model
The each cave basin of covering is enclosed, rolls hole with the waddy slightly thicker than cuttings, hole depth is about the half of matrix depth, and cuttings is then carried out skewer
It inserts, cuttage depth is about 4cm, is compacted after inserting with finger, so that matrix and cuttings close proximity, starting is set by spraying while cuttings
It is standby, guarantee that cuttings blade is wet.
Spray timings and spray time adjust in time according to different times and weather conditions, the leaf water taken root, unified
Watering.General cuttage initial stage relatively frequently, after callus formation is suitably reduced spraying by spraying under fair weather, as long as leaf
Piece has droplet, blade wilting does not occur, just reduces amount of water sprayed to the greatest extent, to improve ground temperature, is conducive to root growth.
3) day temperature control is at 25 DEG C, and night temperature control is at 18 DEG C or so, relative humidity 70%-80%.It investigates 30 days after planting and plants
Train influence of the matrix to the branches and leaves color of flowers, growth rate, survival rate etc..Test result is shown in Table 8:
8 based assays result of table
| Classification | Embodiment 1 | Embodiment 2 | Embodiment 3 | Common cultivation matrix |
| Branches and leaves color | It is dark green | It is dark green | It is dark green | It is yellowish green |
| Plant height (cm) | 34.5 | 35.2 | 37.5 | 25.3 |
| Root (root) | 4.4 | 4.2 | 4.6 | 2.4 |
| Average root long (cm) | 4.8 | 4.2 | 5.3 | 2.1 |
| Survival rate (%) | 98.8% | 99.4% | 97.6% | 72.3% |
| Insect prevention, anthelminthic effect | Without insect pest | Without insect pest | Without insect pest | Flower, leaf have worm |
Test result is shown, using plants and flowers cultivation matrix cuttage flowers of the invention, plant big and bright-coloured with leaf
Object flowers plant height advantage, cutting plantation is high, and with common cultivation discrete phase ratio, survival rate is significantly improved.
Although the present invention describes specific case study on implementation, the scope of the invention is not limited to above-mentioned specific realities
Example is applied, without departing from the case in the spirit of the invention, guarantor of the invention is each fallen within to various modifications of the invention, variations and alternatives
Protect range.
Claims (8)
1. a kind of plants and flowers cultivation matrix, it is characterised in that: the cultivation matrix includes organic base composition particle, inorganic
Substrate combination composition granule, sustained release control fertilizer efficiency particulate matter and plant-based medicine, according to parts by weight, proportion are as follows:
Organic substrate composition grain is 30-60 parts；
Sustained release control fertilizer efficiency particulate matter is 25-35 parts；
Inorganic matrix composition grain is 15-25 parts；
Plant-based medicine is 0.5-10 parts；
The organic substrate composition grain is used in the mixed powder being made of air-dried cow dung, tealeaves and needles of pinus massoniana through sending out
In bottom material made of sterilizing again after yeast-like fungi agent fermentation maturity, addition chitosan, plant ash, fertile soil are through mixed, granulation and drying
Composition prepared by processing, parts by weight proportion are as follows:
Air-drying cow dung is 15-30 parts；
Chitosan is 10-15 parts；
Fertile soil is 22-25 parts；
Plant ash is 18-20 parts；
Tealeaves powder is 12-15 parts；
Needles of pinus massoniana powder is 8-10 parts；
Fermenting agent is 0.2-3 parts；
The inorganic matrix composition grain is matched using perlite, diatomite, rare earth and Titanium Citrate according to following portions by weight
Than through composition prepared by homogeneous blend granulation and drying process:
Perlite is 30-58 parts；
Diatomite is 35-40 parts；
Rare earth is 5-15 parts；
Titanium Citrate is 2-15 parts；
The sustained release control fertilizer efficiency particulate matter uses in the three-dimensional net structure of cross-linking type polyacrylic acid potassium or polyglutamic acid potassium, knot
Conjunction has trace element compound and plant modifying agent in chelating amino acids, and each component is relative to cross-linking type polyacrylic acid potassium or poly- paddy
The parts by weight of propylhomoserin potassium match are as follows:
Cross-linking type polyacrylic acid potassium or polyglutamic acid potassium are 100 parts；
Trace element compound is 15-50 parts in chelating amino acids；
Plant modifying agent is 0.1-4 parts.
2. a kind of plants and flowers cultivation matrix according to claim 1, it is characterised in that: the plant modifying agent selects rue
One or more combinations of tongue fur element lactone, gibberellin, the basic element of cell division, methyl α-naphthyl acetate.
3. a kind of plants and flowers cultivation matrix according to claim 1, it is characterised in that: the rare earth selection nitric acid is dilute
Soil, the nitric acid rare earth are made of inorganic mixed two or more nitrate in light rare earth elements lanthanum, cerium, praseodymium, neodymium
Close object.
4. a kind of plants and flowers cultivation matrix according to claim 1, it is characterised in that: the plant-based medicine selection tool
There are the phytotoxin of insecticidal action, the one or two kinds of of phytotoxin with bactericidal effect to combine.
5. a kind of plants and flowers cultivation matrix according to claim 4, it is characterised in that: the plant with insecticidal action
Object toxin is using pyrethrin, rotenone, nicotine, pepper amide compound, ryania and the like, tetrahydrofuran fat
Acid compounds, Glutamic Acid analog, dihydroagarofuran class compound, one or more groups of three thiophene and acetylene compound
It closes；The phytotoxin with bactericidal effect uses allicin.
6. a kind of according to claim 1, plants and flowers cultivation matrix described in 4 or 5, it is characterised in that: the plant-based medicine
Using the composition of the three thiophene toxin and pyrethrin with photoreactivation, the three thiophene toxin and pyrethrin are configured
Ratio is 0.5-1:0.4-0.8.
7. the preparation method of plants and flowers cultivation matrix described in any right of claim 1-6, includes the following steps:
1) chelatropic reaction: compound amino acid is formulated as to the solution of free aminoacid content >=30% with deionized water, is warming up to 65
DEG C -70 DEG C, be added surfactant, cosolvent and after mixing evenly, addition moderate-element compound, trace element compound in
After reacting 60-120min at 65 DEG C of -70 DEG C of temperature and stirring condition, mixed liquor is filtered or suction filtration is handled, obtains amino
Trace element compound in acid chelating, it is spare；
2) preparation of sustained release control fertilizer efficiency particulate matter: acrylic acid or glutamic acid monomer, which are formulated as mass concentration, with deionized water is
30% ~ 50% solution, it is 60%~80% that potassium hydroxide, which is added, and adjusts degree of neutralization, is warming up to 40 DEG C -60 DEG C, step 1) is added and is made
Chelating amino acids in trace element compound, plant modifying agent, added after stirring crosslinking agent, initiator carry out polymerization reaction
And continue to stir, gel high polymer is made, after carrying out broken granulation processing to high polymer, again with crosslinking agent at 80-180 DEG C
At a temperature of using spray-on process to gained granulated polymer carry out heat cross-linking surface treatment, sustained release can be obtained after heated drying
Control fertilizer efficiency particulate matter, wherein the crosslinking agent uses N, N- methylene-bisacrylamide, and initiator is Redox Initiator body
System, reducing agent is sulphite, and oxidant is hydrogen peroxide；
3) preparation of organic substrate composition grain: tealeaves and needles of pinus massoniana are crushed as powder, and by it and through air-drying processing
Cow dung pour into and be mixing uniformly to form mixture in fermentation vat, mixture is divided in fermentation vat, and press mixture weight
60%-70% calculate moisture additional amount, in mixture weight 1 ‰ -3 ‰ ratios calculate fermenting agent dosage, will ferment
Microbial inoculum is sprayed on the surface of mixture, is then covered in surface with plastic foil, must when material temperature degree is higher than 60 DEG C during the fermentation
Stirring processing must be carried out, sterilization treatment is carried out after 30-60 days fermentation maturities, and corruption is added in chitosan, plant ash, fertile soil
In clinker after mixing evenly, it is granulated and is dried using pelletizer, organic substrate composition grain is made；
4) preparation of inorganic matrix composition grain: perlite, diatomite, rare earth, Titanium Citrate are matched by constant weight number
Ratio mixes and is modulated to paste, it is granulated and is dried using pelletizer, and inorganic matrix composition is made
Grain；
5) it is blended: by organic substrate composition grain, step made from sustained release control fertilizer efficiency particulate matter made from step 2, step 3)
4) inorganic matrix composition grain made from carries out being mixed and stirred for according to a certain percentage with plant-based medicine uniformly, obtaining
Plants and flowers cultivation matrix.
8. a kind of plants and flowers cultivation matrix as described in claim 1 is in succulent, decorative flower, foliage plant and draft
Application in plant.
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| CN114868750B (en) * | 2022-06-21 | 2023-03-24 | 中国农业大学 | Application of allicin in production of cow dung recycled padding, bactericide and preparation method thereof, and production method of cow dung recycled padding |
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| CN101023734A (en) * | 2007-04-05 | 2007-08-29 | 石俊雄 | Plant seedling-culturing substrate |
| CN101379943A (en) * | 2008-09-25 | 2009-03-11 | 天津滨海大顺花卉科技发展股份有限公司 | Arrowroot soilless culture ground mass and use thereof |
| CN101548639A (en) * | 2009-01-15 | 2009-10-07 | 孙向阳 | Flower cultivation medium and preparing method thereof |
| CN102668955A (en) * | 2012-05-25 | 2012-09-19 | 北京林大林业科技股份有限公司 | Production method of novel flower environment-friendly medium |
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