CN1051340C - 一种稳定的聚丙烯纤维 - Google Patents
一种稳定的聚丙烯纤维 Download PDFInfo
- Publication number
- CN1051340C CN1051340C CN94191786A CN94191786A CN1051340C CN 1051340 C CN1051340 C CN 1051340C CN 94191786 A CN94191786 A CN 94191786A CN 94191786 A CN94191786 A CN 94191786A CN 1051340 C CN1051340 C CN 1051340C
- Authority
- CN
- China
- Prior art keywords
- amino
- tetramethyl piperidine
- fiber
- tetramethyl
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 101
- -1 polypropylene Polymers 0.000 title claims abstract description 89
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 66
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 66
- 239000004611 light stabiliser Substances 0.000 title description 2
- 239000012760 heat stabilizer Substances 0.000 title 1
- 239000002530 phenolic antioxidant Substances 0.000 claims abstract description 44
- 150000001412 amines Chemical class 0.000 claims abstract description 39
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 230000007774 longterm Effects 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims description 76
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 30
- 239000007789 gas Substances 0.000 claims description 30
- 150000008301 phosphite esters Chemical class 0.000 claims description 29
- 238000006068 polycondensation reaction Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims description 22
- KTNPVRSKFWZJEZ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-1-amine Chemical compound CC1(C)CCCC(C)(C)N1N KTNPVRSKFWZJEZ-UHFFFAOYSA-N 0.000 claims description 18
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 18
- 230000002708 enhancing effect Effects 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 13
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 10
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 10
- 229960005137 succinic acid Drugs 0.000 claims description 9
- LUPBEAVDFFJJCT-UHFFFAOYSA-N 4-(4-chloro-1,3,5-triazin-2-yl)morpholine Chemical class ClC1=NC=NC(N2CCOCC2)=N1 LUPBEAVDFFJJCT-UHFFFAOYSA-N 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- KCZIUKYAJJEIQG-UHFFFAOYSA-N 1,3,5-triazin-2-amine Chemical compound NC1=NC=NC=N1 KCZIUKYAJJEIQG-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- OLLFLQZPZHRLPT-UHFFFAOYSA-N 4-chloro-6-cyclohexyl-1,3,5-triazin-2-amine Chemical class NC1=NC(Cl)=NC(C2CCCCC2)=N1 OLLFLQZPZHRLPT-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- TWHQPVYYDWEGRT-UHFFFAOYSA-N n-octadecylhydroxylamine Chemical class CCCCCCCCCCCCCCCCCCNO TWHQPVYYDWEGRT-UHFFFAOYSA-N 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- XYOVOXDWRFGKEX-UHFFFAOYSA-N azepine Chemical compound N1C=CC=CC=C1 XYOVOXDWRFGKEX-UHFFFAOYSA-N 0.000 claims description 2
- IFVTZJHWGZSXFD-UHFFFAOYSA-N biphenylene Chemical group C1=CC=C2C3=CC=CC=C3C2=C1 IFVTZJHWGZSXFD-UHFFFAOYSA-N 0.000 claims description 2
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 2
- 230000032683 aging Effects 0.000 abstract description 7
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 abstract 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 33
- GKHRLTCUMXVTAV-UHFFFAOYSA-N dimoracin Chemical compound C1=C(O)C=C2OC(C3=CC(O)=C(C(=C3)O)C3C4C(C5=C(O)C=C(C=C5O3)C=3OC5=CC(O)=CC=C5C=3)C=C(CC4(C)C)C)=CC2=C1 GKHRLTCUMXVTAV-UHFFFAOYSA-N 0.000 description 33
- 238000009987 spinning Methods 0.000 description 21
- 238000012360 testing method Methods 0.000 description 11
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 239000000155 melt Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 230000003796 beauty Effects 0.000 description 4
- 238000009954 braiding Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000003019 stabilising effect Effects 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- ZIMMJVAHXMONDY-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperazin-1-amine Chemical compound NN1C(CNCC1(C)C)(C)C ZIMMJVAHXMONDY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VVHOOGHYUMSEBF-UHFFFAOYSA-N CCCNCCNCCC.NNC(NN)=O Chemical compound CCCNCCNCCC.NNC(NN)=O VVHOOGHYUMSEBF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 125000002648 azanetriyl group Chemical group *N(*)* 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- QVTVDJWJGGEOGX-UHFFFAOYSA-N urea;cyanide Chemical compound N#[C-].NC(N)=O QVTVDJWJGGEOGX-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4808693A | 1993-04-15 | 1993-04-15 | |
| US08/048,086 | 1993-04-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1121362A CN1121362A (zh) | 1996-04-24 |
| CN1051340C true CN1051340C (zh) | 2000-04-12 |
Family
ID=21952660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94191786A Expired - Lifetime CN1051340C (zh) | 1993-04-15 | 1994-04-06 | 一种稳定的聚丙烯纤维 |
Country Status (20)
| Country | Link |
|---|---|
| JP (1) | JP3424080B2 (pt) |
| KR (1) | KR100282620B1 (pt) |
| CN (1) | CN1051340C (pt) |
| AT (1) | AT405412B (pt) |
| AU (1) | AU6263294A (pt) |
| BE (1) | BE1006850A3 (pt) |
| BR (1) | BR9406876A (pt) |
| CA (1) | CA2160574C (pt) |
| DE (2) | DE4492361T1 (pt) |
| DK (1) | DK175151B1 (pt) |
| FR (1) | FR2704009B1 (pt) |
| GB (1) | GB2292944B (pt) |
| HK (1) | HK1005489A1 (pt) |
| IT (1) | IT1269313B (pt) |
| NL (1) | NL9420023A (pt) |
| NO (1) | NO309683B1 (pt) |
| RU (1) | RU2126065C1 (pt) |
| SK (1) | SK284817B6 (pt) |
| TW (1) | TW268052B (pt) |
| WO (1) | WO1994024344A1 (pt) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2705679B1 (fr) * | 1993-05-24 | 1998-07-10 | Sandoz Sa | Nouvelles compositions stabilisantes des matières polymères, à base de phosphonites ou phosphites et d'un stabilisant contre l'hydrolyse. |
| EP0710677A3 (de) * | 1994-11-03 | 1998-02-04 | Ciba SC Holding AG | Verfahren zur Herstellung von stabilisierten Olefinpolymeren |
| TW401437B (en) | 1995-02-10 | 2000-08-11 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
| DK0880610T3 (da) | 1996-02-12 | 2001-11-19 | Fibervisions As | Partikelholdige fibre |
| CN1064416C (zh) * | 1996-05-02 | 2001-04-11 | 上海石油化工股份有限公司 | 可染细旦聚丙烯纤维的制造方法 |
| KR100227221B1 (ko) * | 1997-04-01 | 1999-11-01 | 이정국 | 발수성이 향상된 폴리프로필렌 섬유용 수지 조성물 및 이를 이용한 직물 |
| US5834541A (en) * | 1997-05-02 | 1998-11-10 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber and film prepared therefrom |
| US5994436A (en) * | 1997-12-18 | 1999-11-30 | Montell North America Inc. | Ductile gamma radiation resistant polyolefin composition and articles produced therefrom |
| US6172153B1 (en) * | 1998-06-12 | 2001-01-09 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber, film and fabric prepared therefrom |
| WO2000012605A1 (en) * | 1998-08-26 | 2000-03-09 | Union Carbide Chemicals & Plastics Technology Corporation | Novel polypropylene compositions |
| US6214915B1 (en) * | 1998-12-10 | 2001-04-10 | General Electric Company | Stabilized thermoplastic compositions |
| US6444733B1 (en) * | 1999-03-01 | 2002-09-03 | Ciba Specialty Chemicals Corporation | Stabilizer combination for the rotomolding process |
| NL1014465C2 (nl) * | 1999-03-01 | 2002-01-29 | Ciba Sc Holding Ag | Stabilisatorcombinatie voor het rotomoldingproces. |
| JP2002097322A (ja) * | 2000-09-25 | 2002-04-02 | Grand Polymer Co Ltd | ポリプロピレン系樹脂組成物およびその成形品 |
| JP4785135B2 (ja) * | 2006-07-31 | 2011-10-05 | 三菱レイヨン株式会社 | ポリプロピレン系難燃繊維 |
| CN101195944B (zh) * | 2007-12-11 | 2011-09-07 | 卢宗广 | 无石棉环保节能型隔膜布及其织造方法 |
| KR101062997B1 (ko) | 2009-05-29 | 2011-09-07 | 코오롱글로텍주식회사 | 고내열성 및 내광성을 지닌 폴리프로필렌 단섬유 및 이의 제조방법, 이로 만들어진 부직포 |
| DE102010006364B4 (de) * | 2010-01-29 | 2015-07-23 | Carl Freudenberg Kg | Verwendung von sterisch gehinderten Aminen für oxidationsstabilisierte Polyolefine |
| CN106319665A (zh) * | 2015-06-15 | 2017-01-11 | 东丽纤维研究所（中国）有限公司 | 一种有色聚丙烯纤维及其制备方法 |
| WO2018087077A1 (en) * | 2016-11-09 | 2018-05-17 | Borealis Ag | Polypropylene composition |
| GB2584305B (en) | 2019-05-30 | 2022-07-13 | Si Group Switzerland Chaa Gmbh | Antidegradant blend |
| CN110229421B (zh) * | 2019-07-02 | 2021-11-09 | 中广核俊尔(浙江)新材料有限公司 | 一种耐高温注塑聚丙烯材料及其制备方法和应用 |
| CN111057288A (zh) * | 2019-12-12 | 2020-04-24 | 宿迁联盛科技股份有限公司 | 一种防聚烯烃共聚物光老化、防聚烯烃红变的组合物 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101828A (zh) * | 1984-03-13 | 1987-01-10 | 三井东压化学有限公司 | 辐射稳定的聚丙烯树脂组合物 |
| JPS63182358A (ja) * | 1987-01-23 | 1988-07-27 | Tonen Sekiyukagaku Kk | ポリオレフイン組成物 |
| JPH01252644A (ja) * | 1987-12-30 | 1989-10-09 | Ciba Geigy Ag | 長鎖ｎ，ｎ―ジアルキルヒドロキシルアミンで安定化されたポリオレフィン組成物 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4590231A (en) * | 1983-10-11 | 1986-05-20 | Ciba-Geigy Corporation | Polyolefin compositions stabilized against degradation using hydroxylamine derivatives |
-
1994
- 1994-03-26 TW TW083102663A patent/TW268052B/zh not_active IP Right Cessation
- 1994-04-06 GB GB9520527A patent/GB2292944B/en not_active Expired - Lifetime
- 1994-04-06 CN CN94191786A patent/CN1051340C/zh not_active Expired - Lifetime
- 1994-04-06 DE DE4492361T patent/DE4492361T1/de active Granted
- 1994-04-06 AU AU62632/94A patent/AU6263294A/en not_active Abandoned
- 1994-04-06 DE DE4492361A patent/DE4492361C2/de not_active Expired - Lifetime
- 1994-04-06 AT AT0903394A patent/AT405412B/de not_active IP Right Cessation
- 1994-04-06 WO PCT/IB1994/000056 patent/WO1994024344A1/en active Application Filing
- 1994-04-06 KR KR1019950704499A patent/KR100282620B1/ko not_active IP Right Cessation
- 1994-04-06 RU RU95120604A patent/RU2126065C1/ru active
- 1994-04-06 NL NL9420023A patent/NL9420023A/nl active Search and Examination
- 1994-04-06 SK SK1272-95A patent/SK284817B6/sk not_active IP Right Cessation
- 1994-04-06 CA CA002160574A patent/CA2160574C/en not_active Expired - Lifetime
- 1994-04-06 JP JP52295194A patent/JP3424080B2/ja not_active Expired - Lifetime
- 1994-04-06 BR BR9406876A patent/BR9406876A/pt not_active IP Right Cessation
- 1994-04-14 BE BE9400382A patent/BE1006850A3/fr not_active IP Right Cessation
- 1994-04-14 IT ITMI940706A patent/IT1269313B/it active IP Right Grant
- 1994-04-14 FR FR9404431A patent/FR2704009B1/fr not_active Expired - Lifetime
-
1995
- 1995-10-03 NO NO953932A patent/NO309683B1/no not_active IP Right Cessation
- 1995-10-04 DK DK199501109A patent/DK175151B1/da not_active IP Right Cessation
-
1998
- 1998-05-28 HK HK98104631A patent/HK1005489A1/xx not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101828A (zh) * | 1984-03-13 | 1987-01-10 | 三井东压化学有限公司 | 辐射稳定的聚丙烯树脂组合物 |
| JPS63182358A (ja) * | 1987-01-23 | 1988-07-27 | Tonen Sekiyukagaku Kk | ポリオレフイン組成物 |
| JPH01252644A (ja) * | 1987-12-30 | 1989-10-09 | Ciba Geigy Ag | 長鎖ｎ，ｎ―ジアルキルヒドロキシルアミンで安定化されたポリオレフィン組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI940706A0 (it) | 1994-04-14 |
| ITMI940706A1 (it) | 1995-10-14 |
| FR2704009A1 (fr) | 1994-10-21 |
| BR9406876A (pt) | 1996-04-02 |
| SK127295A3 (en) | 1996-11-06 |
| DE4492361C2 (de) | 2003-10-16 |
| DK175151B1 (da) | 2004-06-21 |
| JPH08509031A (ja) | 1996-09-24 |
| KR960702018A (ko) | 1996-03-28 |
| TW268052B (pt) | 1996-01-11 |
| ATA903394A (de) | 1998-12-15 |
| RU2126065C1 (ru) | 1999-02-10 |
| IT1269313B (it) | 1997-03-26 |
| NL9420023A (nl) | 1996-01-02 |
| CN1121362A (zh) | 1996-04-24 |
| SK284817B6 (sk) | 2005-12-01 |
| FR2704009B1 (fr) | 1995-06-30 |
| BE1006850A3 (fr) | 1995-01-03 |
| GB2292944B (en) | 1997-12-10 |
| JP3424080B2 (ja) | 2003-07-07 |
| CA2160574C (en) | 2004-02-03 |
| GB9520527D0 (en) | 1995-12-13 |
| KR100282620B1 (ko) | 2001-02-15 |
| CA2160574A1 (en) | 1994-10-27 |
| DE4492361T1 (de) | 1997-08-21 |
| AU6263294A (en) | 1994-11-08 |
| GB2292944A (en) | 1996-03-13 |
| HK1005489A1 (en) | 1999-01-08 |
| NO953932L (no) | 1995-10-03 |
| NO953932D0 (no) | 1995-10-03 |
| NO309683B1 (no) | 2001-03-12 |
| DK110995A (da) | 1995-10-04 |
| WO1994024344A1 (en) | 1994-10-27 |
| AT405412B (de) | 1999-08-25 |
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