CN104080817B - 共轭二烯系单体的聚合催化剂组合物 - Google Patents

共轭二烯系单体的聚合催化剂组合物 Download PDF

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CN104080817B
CN104080817B CN201380006928.4A CN201380006928A CN104080817B CN 104080817 B CN104080817 B CN 104080817B CN 201380006928 A CN201380006928 A CN 201380006928A CN 104080817 B CN104080817 B CN 104080817B
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CN104080817A (zh
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岩濑胜弘
小杉裕士
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Asahi Kasei Corp
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Asahi Kasei Kogyo KK
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/603—Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/605—Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/602 or C08F4/603
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201380006928.4A 2012-01-31 2013-01-30 共轭二烯系单体的聚合催化剂组合物 Active CN104080817B (zh)

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JP2012019082 2012-01-31
JP2012-019085 2012-01-31
JP2012-019082 2012-01-31
JP2012019085 2012-01-31
PCT/JP2013/052028 WO2013115242A1 (ja) 2012-01-31 2013-01-30 共役ジエン系モノマーの重合触媒組成物

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CN104080817A CN104080817A (zh) 2014-10-01
CN104080817B true CN104080817B (zh) 2017-06-13

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US (1) US9556285B2 (enExample)
EP (1) EP2810960B1 (enExample)
JP (1) JP5942172B2 (enExample)
KR (1) KR101631396B1 (enExample)
CN (1) CN104080817B (enExample)
BR (1) BR112014018646B1 (enExample)
IN (1) IN2014DN06202A (enExample)
MY (1) MY169857A (enExample)
RU (1) RU2621683C2 (enExample)
SG (1) SG11201404288QA (enExample)
TW (1) TWI565723B (enExample)
WO (1) WO2013115242A1 (enExample)

Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
JP6468700B2 (ja) * 2013-11-11 2019-02-13 宇部興産株式会社 共役ジエン重合体およびその製造方法
WO2016027401A1 (ja) * 2014-08-20 2016-02-25 株式会社ブリヂストン 末端変性共役ジエン重合体の製造方法、末端変性共役ジエン重合体、ゴム組成物及びタイヤ
TWI671323B (zh) * 2014-09-12 2019-09-11 日商宇部興產股份有限公司 聚丁二烯及橡膠組成物
KR101796360B1 (ko) 2014-11-20 2017-11-09 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
KR101781699B1 (ko) * 2014-11-20 2017-09-25 주식회사 엘지화학 공액 디엔의 중합용 촉매 조성물
KR102156108B1 (ko) * 2015-12-23 2020-09-15 주식회사 엘지화학 공액디엔계 중합체의 제조방법 및 이로부터 제조된 공액디엔계 중합체
CN109153737A (zh) * 2016-05-24 2019-01-04 株式会社普利司通 末端改性的共轭二烯聚合物、橡胶组合物、橡胶产品和末端改性的共轭二烯聚合物的制造方法
KR102295653B1 (ko) 2017-11-22 2021-08-31 주식회사 엘지화학 공액디엔계 중합체 및 이의 제조방법
WO2022035132A1 (ko) 2020-08-12 2022-02-17 주식회사 엘지화학 메탈로센 담지 촉매의 제조 방법, 메탈로센 담지 촉매 및 이를 이용한 폴리올레핀의 제조 방법
CN119708301A (zh) * 2024-12-13 2025-03-28 浙江工业大学 一种基于Co-CFA-1的丁二烯聚合催化剂及其制备和应用
CN121402121A (zh) * 2025-12-30 2026-01-27 西安华大骄阳绿色科技有限公司 一种分子筛加氢脱硫催化剂和制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101180345A (zh) * 2005-03-18 2008-05-14 Jsr株式会社 制造改性聚合物的方法、由该方法获得的改性聚合物及其橡胶组合物
CN101384659A (zh) * 2006-02-15 2009-03-11 株式会社普利司通 轮胎胎侧用橡胶组合物和轮胎
CN101600736A (zh) * 2006-12-27 2009-12-09 Jsr株式会社 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2830080A1 (de) 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
IT1140452B (it) 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1265048B1 (it) 1993-08-06 1996-10-28 Eniricerche Spa Complessi metallorganici dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi
IT1265049B1 (it) 1993-08-06 1996-10-28 Eniricerche Spa Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi
RU2141382C1 (ru) * 1998-06-08 1999-11-20 Государственное унитарное предприятие Научно-исследовательский институт синтетического каучука им.акад.С.В.Лебедева Способ получения катализатора полимеризации и сополимеризации ненасыщенных углеводородов
KR100674760B1 (ko) 1999-03-04 2007-01-25 리가가쿠 겐큐쇼 촉매 조성물
JP3422733B2 (ja) 1999-03-04 2003-06-30 理化学研究所 触媒組成物
JP2003292513A (ja) 2002-03-29 2003-10-15 Inst Of Physical & Chemical Res 触媒組成物
JP2004027103A (ja) 2002-06-27 2004-01-29 Inst Of Physical & Chemical Res 触媒組成物
JP4030473B2 (ja) * 2003-06-25 2008-01-09 三井化学株式会社 希土類金属含有化合物、これを含むオレフィン重合触媒、及び該重合触媒を用いるオレフィンの重合方法
JP5035864B2 (ja) 2005-09-02 2012-09-26 独立行政法人理化学研究所 メタロセン錯体、およびそれを含む重合触媒組成物
ES2359516T3 (es) * 2005-12-05 2011-05-24 Jsr Corporation Procedimiento para producir polímero diénico conjugado, el polímero diénico conjugado y composición de caucho.
JP2007191611A (ja) * 2006-01-20 2007-08-02 Bridgestone Corp 変性ポリブタジエンゴム配合ゴム組成物及びタイヤ
JP2008291096A (ja) 2007-05-23 2008-12-04 Bridgestone Corp ポリブタジエン、並びにそれを用いたゴム組成物及びタイヤ
TWI458747B (zh) 2008-12-25 2014-11-01 Ube Industries Preparation of conjugated diene polymers
KR101685232B1 (ko) * 2009-08-24 2016-12-09 가부시키가이샤 브리지스톤 폴리디엔 제조를 위한 방법 및 촉매 시스템
TWI555574B (zh) * 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101180345A (zh) * 2005-03-18 2008-05-14 Jsr株式会社 制造改性聚合物的方法、由该方法获得的改性聚合物及其橡胶组合物
CN101384659A (zh) * 2006-02-15 2009-03-11 株式会社普利司通 轮胎胎侧用橡胶组合物和轮胎
CN101600736A (zh) * 2006-12-27 2009-12-09 Jsr株式会社 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物

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EP2810960B1 (en) 2017-08-09
US20140378620A1 (en) 2014-12-25
RU2014135420A (ru) 2016-03-20
JP5942172B2 (ja) 2016-06-29
WO2013115242A1 (ja) 2013-08-08
BR112014018646A8 (pt) 2017-07-11
US9556285B2 (en) 2017-01-31
KR101631396B1 (ko) 2016-06-16
EP2810960A1 (en) 2014-12-10
CN104080817A (zh) 2014-10-01
TWI565723B (zh) 2017-01-11
IN2014DN06202A (enExample) 2015-10-23
KR20140107647A (ko) 2014-09-04
EP2810960A4 (en) 2014-12-10
MY169857A (en) 2019-05-23
JPWO2013115242A1 (ja) 2015-05-11
RU2621683C2 (ru) 2017-06-07
BR112014018646A2 (enExample) 2017-06-20
TW201336881A (zh) 2013-09-16
SG11201404288QA (en) 2014-09-26
BR112014018646B1 (pt) 2020-12-15

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