IT1265049B1 - Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi - Google Patents

Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi

Info

Publication number
IT1265049B1
IT1265049B1 IT93MI001794A ITMI931794A IT1265049B1 IT 1265049 B1 IT1265049 B1 IT 1265049B1 IT 93MI001794 A IT93MI001794 A IT 93MI001794A IT MI931794 A ITMI931794 A IT MI931794A IT 1265049 B1 IT1265049 B1 IT 1265049B1
Authority
IT
Italy
Prior art keywords
unsaturated monomers
polymerization
complexes
lantanides
carbon atoms
Prior art date
Application number
IT93MI001794A
Other languages
English (en)
Inventor
Paolo Biagini
Gabriele Lugli
Fabio Garbassi
Piero Andreussi
Original Assignee
Eniricerche Spa
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa, Enichem Spa filed Critical Eniricerche Spa
Publication of ITMI931794A0 publication Critical patent/ITMI931794A0/it
Priority to IT93MI001794A priority Critical patent/IT1265049B1/it
Priority to US08/283,258 priority patent/US5633353A/en
Priority to KR1019940019054A priority patent/KR100292790B1/ko
Priority to CA002129485A priority patent/CA2129485C/en
Priority to EP94112279A priority patent/EP0637589B1/en
Priority to CN94116194A priority patent/CN1117102C/zh
Priority to DE69414657T priority patent/DE69414657T2/de
Priority to RU94028655A priority patent/RU2144035C1/ru
Priority to AT94112279T priority patent/ATE173477T1/de
Priority to JP20291494A priority patent/JP3605680B2/ja
Publication of ITMI931794A1 publication Critical patent/ITMI931794A1/it
Priority to US08/607,432 priority patent/US5728816A/en
Application granted granted Critical
Publication of IT1265049B1 publication Critical patent/IT1265049B1/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/064—Aluminium compounds with C-aluminium linkage compounds with an Al-Halogen linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Complessi metallorganici dei lantanidi a stechiometria ben definita ed utilizzabili nella polimerizazione stereospecifica di monomeri insaturi, sono rappresentabili dalla formula generale,Me (Ar) (ALX, R), (1)in cui: Me rappresenta un metallo con numero atomico 21, 39, oppure numero atomico compreso tra 57 e 71; Ar rappresenta il benzene oppure un benzene sostituito con da 1 a 3 gruppi alchilici contenenti da 1 a 10 atomi di carbonio, X è un atomo di alogeno, mentre R è un radicale alchilico lineare, ciclico o ramificato contenente da 1 a 12 atomi di carbonio.Viene descritta la preparazione dei complessi ed il loro impiego nella polimerizzazione stereospecifica di monomeri insaturi.
IT93MI001794A 1993-08-06 1993-08-06 Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi IT1265049B1 (it)

Priority Applications (11)

Application Number Priority Date Filing Date Title
IT93MI001794A IT1265049B1 (it) 1993-08-06 1993-08-06 Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi
US08/283,258 US5633353A (en) 1993-08-06 1994-08-01 Halogenated organometallic complexes and their use in the polymerization of unsaturated monomers
KR1019940019054A KR100292790B1 (ko) 1993-08-06 1994-08-02 란타노이드계의 할로겐화 착염과 불포화 단량체의 중합반응에서 이들의 용도
CA002129485A CA2129485C (en) 1993-08-06 1994-08-04 Halogenated complexes of lanthanides and their use in the polymerization of unsaturated monomers
DE69414657T DE69414657T2 (de) 1993-08-06 1994-08-05 Neue halogenierte Komplexe von Lanthaniden und deren Verwendung für die Polymerisation von ungesättigten Monomeren
CN94116194A CN1117102C (zh) 1993-08-06 1994-08-05 镧系元素卤代络合物及其制备方法和不饱和单体聚合方法
EP94112279A EP0637589B1 (en) 1993-08-06 1994-08-05 New halogenated complexes of lanthanides and their use in the polymerization of unsaturated monomers
RU94028655A RU2144035C1 (ru) 1993-08-06 1994-08-05 МЕТАЛЛООРГАНИЧЕСКИЙ КОМПЛЕКС ЛАНТАНИДОВ, СПОСОБ ЕГО ПОЛУЧЕНИЯ И СПОСОБ ПОЛИМЕРИЗАЦИИ α-ОЛЕФИНОВ И ДИОЛЕФИНОВ
AT94112279T ATE173477T1 (de) 1993-08-06 1994-08-05 Neue halogenierte komplexe von lanthaniden und deren verwendung für die polymerisation von ungesättigten monomeren
JP20291494A JP3605680B2 (ja) 1993-08-06 1994-08-05 ランタニドの有機金属錯体
US08/607,432 US5728816A (en) 1993-08-06 1996-02-27 Method for polymerization of unsaturated monomers using halogenated complexes of group IIIA metals

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001794A IT1265049B1 (it) 1993-08-06 1993-08-06 Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi

Publications (3)

Publication Number Publication Date
ITMI931794A0 ITMI931794A0 (it) 1993-08-06
ITMI931794A1 ITMI931794A1 (it) 1995-02-06
IT1265049B1 true IT1265049B1 (it) 1996-10-28

Family

ID=11366794

Family Applications (1)

Application Number Title Priority Date Filing Date
IT93MI001794A IT1265049B1 (it) 1993-08-06 1993-08-06 Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi

Country Status (10)

Country Link
US (2) US5633353A (it)
EP (1) EP0637589B1 (it)
JP (1) JP3605680B2 (it)
KR (1) KR100292790B1 (it)
CN (1) CN1117102C (it)
AT (1) ATE173477T1 (it)
CA (1) CA2129485C (it)
DE (1) DE69414657T2 (it)
IT (1) IT1265049B1 (it)
RU (1) RU2144035C1 (it)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5854166A (en) * 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
US6130302A (en) 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
DE19746266A1 (de) 1997-10-20 1999-04-22 Bayer Ag Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen
FR2799394A1 (fr) * 1999-10-11 2001-04-13 Michelin Soc Tech Catalyseur solide supporte utilisable pour la polymerisation de dienes conjugues, son procede de preparation et procede de polymerisation de dienes conjugues utilisant ce catalyseur
DE10115106A1 (de) 2001-03-27 2002-10-10 Bayer Ag Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren
IT1403289B1 (it) * 2010-12-27 2013-10-17 Polimeri Europa Spa Metallo alchil-areni e procedimenti per la loro preparazione
KR101631396B1 (ko) 2012-01-31 2016-06-16 아사히 가세이 케미칼즈 가부시키가이샤 공역 디엔계 모노머의 중합 촉매 조성물
CN105121477B (zh) * 2013-03-13 2017-03-15 宇部兴产株式会社 共轭二烯聚合用催化剂及使用该催化剂的共轭二烯聚合物、改性共轭二烯聚合物、其制造方法、轮胎用橡胶组合物、及橡胶皮带用橡胶组合物

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4384982A (en) * 1981-05-18 1983-05-24 Phillips Petroleum Company Process and catalyst for olefin polymerization
IT1140452B (it) * 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1151543B (it) * 1982-04-15 1986-12-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
US4603185A (en) * 1983-12-27 1986-07-29 The Standard Oil Company Catalytic process for the polymerization of acetylene
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
IT1186730B (it) * 1985-06-05 1987-12-16 Enichem Elastomers Procedimento per la polimerizzazione di isoprene
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
GB8915531D0 (en) * 1989-07-06 1989-08-23 Ass Octel Alkaline earth,transition and lanthanide metal inorganic salt complexes
US5218064A (en) * 1990-02-14 1993-06-08 Showa Denko K.K. Process for preparing narrow molecular weight distribution syndiotactic polymers or copolymers of unsaturated carboxylic acid esters
GB9107378D0 (en) * 1991-04-08 1991-05-22 Ici Plc Olefin polymerisation
IT1265048B1 (it) * 1993-08-06 1996-10-28 Eniricerche Spa Complessi metallorganici dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi

Also Published As

Publication number Publication date
ITMI931794A0 (it) 1993-08-06
CA2129485A1 (en) 1995-02-07
JP3605680B2 (ja) 2004-12-22
JPH07112989A (ja) 1995-05-02
US5728816A (en) 1998-03-17
CA2129485C (en) 2005-10-18
KR950005833A (ko) 1995-03-20
CN1117102C (zh) 2003-08-06
CN1103869A (zh) 1995-06-21
DE69414657T2 (de) 1999-07-29
RU2144035C1 (ru) 2000-01-10
KR100292790B1 (ko) 2001-06-15
ITMI931794A1 (it) 1995-02-06
DE69414657D1 (de) 1998-12-24
ATE173477T1 (de) 1998-12-15
RU94028655A (ru) 1996-06-27
US5633353A (en) 1997-05-27
EP0637589B1 (en) 1998-11-18
EP0637589A1 (en) 1995-02-08

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