CN101815682A - 玻璃-树脂复合物的制造方法 - Google Patents

玻璃-树脂复合物的制造方法 Download PDF

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Publication number
CN101815682A
CN101815682A CN200880110183A CN200880110183A CN101815682A CN 101815682 A CN101815682 A CN 101815682A CN 200880110183 A CN200880110183 A CN 200880110183A CN 200880110183 A CN200880110183 A CN 200880110183A CN 101815682 A CN101815682 A CN 101815682A
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CN
China
Prior art keywords
resin
glass
glass ribbon
layer
film
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Granted
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CN200880110183A
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CN101815682B (zh
Inventor
樋口俊彦
神庭基
杉本直树
近藤聪
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AGC Inc
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Asahi Glass Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/02—Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112—Single lapped joints
    • B29C66/1122—Single lap to lap joints, i.e. overlap joints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/45—Joining of substantially the whole surface of the articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7311—Thermal properties
    • B29C66/73117—Tg, i.e. glass transition temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74—Joining plastics material to non-plastics material
    • B29C66/746—Joining plastics material to non-plastics material to inorganic materials not provided for in groups B29C66/742 - B29C66/744
    • B29C66/7465—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/80—General aspects of machine operations or constructions and parts thereof
    • B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/834—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools moving with the parts to be joined
    • B29C66/8341—Roller, cylinder or drum types; Band or belt types; Ball types
    • B29C66/83411—Roller, cylinder or drum types
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/80—General aspects of machine operations or constructions and parts thereof
    • B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/834—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools moving with the parts to be joined
    • B29C66/8341—Roller, cylinder or drum types; Band or belt types; Ball types
    • B29C66/83411—Roller, cylinder or drum types
    • B29C66/83413—Roller, cylinder or drum types cooperating rollers, cylinders or drums
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/914—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux
    • B29C66/9141—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the temperature
    • B29C66/91411—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the temperature of the parts to be joined, e.g. the joining process taking the temperature of the parts to be joined into account
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/914—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux
    • B29C66/9161—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux
    • B29C66/91641—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux the heat or the thermal flux being non-constant over time
    • B29C66/91643—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux the heat or the thermal flux being non-constant over time following a heat-time profile
    • B29C66/91645—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the heat or the thermal flux, i.e. the heat flux the heat or the thermal flux being non-constant over time following a heat-time profile by steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • B29C66/9192—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams
    • B29C66/91921—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature
    • B29C66/91931—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • B29C66/9192—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams
    • B29C66/91921—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature
    • B29C66/91931—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined
    • B29C66/91933—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined higher than said fusion temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • B29C66/9192—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams
    • B29C66/91921—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature
    • B29C66/91931—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined
    • B29C66/91935—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined lower than said fusion temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • B29C66/9192—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams
    • B29C66/91921—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature
    • B29C66/91941—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to Tg, i.e. the glass transition temperature, of the material of one of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C66/90—Measuring or controlling the joining process
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    • B29C66/919—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
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    • B29C66/91921—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature
    • B29C66/91941—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to Tg, i.e. the glass transition temperature, of the material of one of the parts to be joined
    • B29C66/91943—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to Tg, i.e. the glass transition temperature, of the material of one of the parts to be joined higher than said glass transition temperature
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    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/20—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of continuous webs only
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    • B29B15/125—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by dipping
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    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
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    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
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    • B29B15/127—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by spraying
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    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
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Abstract

本发明的目的在于提供一种玻璃-树脂复合物的制造方法，所述方法不会损害玻璃所具有的良好特性，即使玻璃极薄也具备充分的搬运性、处理性及二次加工性。提供一种玻璃-树脂复合物的制造方法，其特征在于，将熔融玻璃成形为玻璃带后，在该玻璃带的至少一面上形成树脂层。所述树脂层优选通过对玻璃带进行粘贴、涂布热熔融树脂或涂布固化性树脂而形成。此外，还提供一种玻璃-树脂复合物的制造方法，所述方法在连续供给的树脂薄膜上粘贴被切断的玻璃基板。

Description

玻璃-树脂复合物的制造方法
技术领域
本发明涉及一种具有玻璃所具有的特性且处理性、搬运性及加工性优异的玻璃-树脂复合物的制造方法。
背景技术
近年来，在显示器用基板、传感器/元件罩等用途中使用的玻璃板厚度不断减小。然而，玻璃板的板厚越薄，玻璃原本所具有的“容易破裂”的缺点就越明显，搬运时和加工时的处理等越困难。
为了解决该问题，提出了在玻璃上层压树脂薄膜的方法(例如参照专利文献1～4)。然而存在如下问题：由于玻璃在层压树脂薄膜前的切断工序和搬运时在玻璃表面会产生物理性损伤，因此并不能说确保了充分的机械强度。
专利文献1：日本特开2003-337549号公报
专利文献2：日本特表2002-534305号公报
专利文献3：日本特开2001-113631号公报
专利文献4：日本特开2001-097733号公报
发明内容
发明要解决的问题
本发明是鉴于所述问题而进行的，目的在于提供一种玻璃-树脂复合物的制造方法，所述复合物即使玻璃极薄也具备充分的搬运性、处理性及加工性。
用于解决问题的方案
本发明提供一种玻璃-树脂复合物的制造方法，其特征在于，将熔融玻璃成形为玻璃带后，在该玻璃带的至少一面上形成树脂层。
所述成形的方法优选为浮法、熔融法、引下(Down Draw)法、流孔下引(Slot Down)法或重新引下(redraw)法，所述玻璃带的厚度优选为10～300μm。
所述树脂薄膜优选直接层压到玻璃带上或者通过夹置粘接剂层或粘合剂层而与玻璃带层压。
所述树脂层是通过夹置含有热熔融性树脂的热熔融层而层压到玻璃带上的，优选通过如下方法进行紧密粘贴：在所述热熔融性树脂具有熔点的情况下，设该熔点为Tm，在所述热熔融性树脂不具有熔点的情况下，设热熔融性树脂的玻璃化转变温度为Tg，在成形后的玻璃带的温度处于Tm-50℃～Tm+20℃(热熔融性树脂具有熔点的情况下)或者处于Tg～Tg+100℃(热熔融性树脂不具有熔点的情况下)的范围内的时刻，通过夹置热熔融层而将树脂薄膜紧密地粘贴在玻璃带上。
此外，所述树脂层是将含有热熔融性树脂的薄膜层压到玻璃带上而成的，优选通过如下方法进行紧密粘贴：设所述热熔融性树脂的熔点为Tm，在所述热熔融性树脂不具有熔点的情况下设热熔融性树脂的玻璃化转变温度为Tg，在成形后的玻璃带的温度处于Tm-50℃～Tm+20℃(热熔融性树脂具有熔点的情况下)或者Tg～Tg+100℃(热熔融性树脂不具有熔点的情况下)的范围内的时刻，将薄膜紧密地粘贴在玻璃带上。另外，本发明中，Tm、Tg用℃表示。
此外，本发明的树脂层优选通过以下方法形成：通过将实质上由固化性树脂构成的薄膜夹置粘接剂层或粘合剂层而层压到玻璃带上；或将部分固化的固化性树脂的片状物加压粘贴在玻璃带上，接着将所述固化性树脂固化。
进而，本发明提供一种玻璃-树脂复合物的制造方法，其特征在于，在连续供给的树脂薄膜的一部分面或整个面上涂布粘接剂或粘合剂，接着在所述树脂薄膜的粘接剂或粘合剂的涂布面上粘贴切断成规定尺寸的玻璃基板。
此外，本发明提供一种玻璃-树脂复合物的制造方法，其特征在于，该方法将切断成规定尺寸、且一侧的表面涂布有粘接剂或粘合剂的玻璃基板粘贴到连续供给的树脂薄膜上，所述玻璃基板的粘接剂或粘合剂的涂布面是面向树脂薄膜的面。
本发明中，所述玻璃基板的厚度优选为10～300μm。此外，本发明提供一种玻璃-树脂复合物的制造方法，其特征在于，通过所述方法获得复合物后，将该复合物卷绕成卷状。
发明的效果
根据本发明的制造方法，即根据在刚成形后的玻璃带上形成树脂层的制造方法，由于成形后的玻璃带在经历切断工序、搬运工序前玻璃表面已形成树脂层，因此玻璃表面物理性损伤的可能性低，能够获得具有很高机械强度的玻璃-树脂复合物。通过形成树脂层的工序，能够在熔融玻璃表面不与其它部件接触的状态下在其表面形成树脂层，原理上也能够显著降低玻璃表面的物理性损伤。
进而，由于在将厚度为10～300μm且具有挠性的玻璃带切断之前在其表面形成树脂层，因此也能够将玻璃-树脂复合物卷绕成卷状。
此外，根据本发明的制造方法，即根据将切断后的玻璃基板粘贴在连续供给的树脂薄膜上的制造方法，通过该方法获得的玻璃-树脂复合物，由于相邻的玻璃基板之间存在只有树脂薄膜的地方、即存在不是玻璃基板与树脂薄膜形成的多层结构的地方，因而发挥了该处能够容易地切断的效果。
附图说明
图1是表示本发明的实施例1的方法的概略模式图。
图2是表示本发明的实施例2的方法的概略模式图。
图3是表示本发明的实施例3的方法的概略模式图。
图4是表示本发明的实施例4的方法的概略模式图。
图5是表示本发明的实施例5的方法的概略模式图。
图6是表示本发明的实施例6的方法的概略模式图。
图7是表示本发明的实施例9的方法的概略模式图。
图8是表示本发明的实施例10的方法的概略模式图。
附图标记说明
1    玻璃带
2    退火部
3    树脂薄膜
4    夹持辊(nip roller)
5    玻璃-树脂复合物
6    口模涂布机
7    加热炉
8    浸渍涂布机
9    固化性树脂
10   紫外线照射装置
11   带有PET覆膜的聚酰胺酸生片
12   PET覆膜
13   带有PET覆膜的光固化型树脂薄膜
具体实施方式
以下，对本发明的玻璃-树脂复合物的制造方法进行说明。
本发明的玻璃-树脂复合物的制造方法的第1方案，是在连续成形的玻璃带的表面上形成树脂薄膜的方法。所述玻璃带可以使用钠钙玻璃、无碱玻璃等各种玻璃，但从强度、化学耐久性的方面出发，优选无碱玻璃。为了将熔融玻璃成形为玻璃带，可以选择浮法、熔融法、引下法、流孔下引法或重新引下法。
本发明中使用的玻璃带，优选具有10μm～300μm的厚度，特别优选具有50μm～150μm的厚度。玻璃带的厚度比10μm还薄时，难以形成树脂层，此外玻璃带的厚度比300μm还厚时，由于玻璃本身可确保强度，因而形成树脂层的必要性很小，而且玻璃自身的挠性丧失，因此难以获得卷状的玻璃-树脂复合物。
所述树脂层中使用的树脂，只要能够对玻璃赋予强韧性，则可以使用任何种类的树脂，但优选根据基于玻璃-树脂复合物的用途所要求的耐热性、耐化学药品性等进行选择。
作为所述树脂，可以列举例如聚酯树脂、聚碳酸酯树脂、聚醚砜树脂、聚烯烃树脂、聚乙烯醇树脂、硅酮树脂、聚酰胺树脂、丙烯酸树脂、聚苯乙烯树脂、三醋酸纤维素树脂、聚酰亚胺树脂、聚氯乙烯树脂、氟树脂等。此外，也可以是它们的共聚物、或含有填料等添加剂的树脂。
作为玻璃-树脂复合物的结构，可以形成玻璃/树脂层的二层结构，也可以形成两侧表面为树脂层即树脂层/玻璃/树脂层的三层结构。将玻璃-树脂复合物作为显示器基板使用时，由于对装置侧表面要求很高的平坦性，因而优选玻璃/树脂层的二层结构。
作为形成树脂层的方法，优选以下方法。
(1)通过夹置含有热熔融性树脂的热熔融层，而层压预先成形的薄膜状的树脂与玻璃带的方法。
(2)将含有热熔融性树脂的薄膜状的树脂直接与玻璃带层压的方法。
(3)将热熔融树脂直接或夹置粘接层或粘合层而涂布到玻璃带上以形成树脂层的方法。
(4)将固化性树脂直接或夹置粘接层或粘合层而涂布到玻璃带上后将其固化的方法。
另外，在所述热熔融性树脂具有熔点的情况下，设该熔点为Tm，在所述热熔融性树脂不具有熔点的情况下，设热熔融性树脂的玻璃化转变温度为Tg，在所述(1)的方法的情况下，优选在成形后的玻璃带的温度处于Tm-50℃～Tm+20℃(热熔融性树脂具有熔点的情况下)或Tg～Tg+100℃(热熔融性树脂不具有熔点的情况下)的范围内的时刻，夹置热熔融层将树脂薄膜与玻璃带紧密地粘贴。此外，在所述(2)的方法的情况下，优选在成形后的玻璃带的温度处于Tm-50℃～Tm+20℃(热熔融性树脂具有熔点的情况下)或Tg～Tg+100℃(热熔融性树脂不具有熔点的情况下)的范围内的时刻，夹置热熔融层将树脂薄膜紧密地粘贴在玻璃带上。这是因为，若玻璃带的温度低于Tm-50℃或Tg，则无法与树脂薄膜紧密地粘贴，若玻璃带的温度超过Tm+20℃或Tg+100℃，则热熔融层从界面流出，无法使玻璃带与树脂薄膜紧密地粘贴。在上述中，成形后的玻璃带的温度特别优选为Tm-30℃～Tm+5℃(热熔融性树脂具有熔点的情况下)或Tg～Tg+80℃(热熔融性树脂不具有熔点的情况下)的范围。
进而，作为形成树脂层的方法，除上述树脂层形成方法以外，也可以优选使用以下方法。
(5)将实质上由固化性树脂构成的薄膜夹置粘接剂层或粘合剂层而层压到玻璃带上的方法。
(6)将部分固化的固化性树脂的片状物加压粘贴在玻璃带上，接着将所述固化性树脂固化的方法。
作为将热熔融树脂、固化性树脂涂布到玻璃带表面的方法，可以采用喷涂法、口模涂布法、流涂法、浸涂法等。作为固化性树脂的固化方法，可以采用加热固化、紫外线固化、湿热固化等。
可以在玻璃带成形后经由退火工序冷却至常温左右后形成树脂层，也可以在退火工序前或退火工序中玻璃带处于加热状态的阶段形成树脂层。在退火工序前或退火工序中形成树脂层时，玻璃带所具有的热量可以被用于薄膜状树脂表面的熔融、粘接力的提高中。
此外，根据本发明的方法，在玻璃带表面形成树脂层后，使用卷绕装置能够获得卷绕成卷状的玻璃-树脂复合物。这样卷绕成卷状的玻璃-树脂复合物，可以应用于所谓卷对卷方式的显示器装置制造工序。将玻璃-树脂复合物卷绕成卷状时，可以根据需要将纸(衬纸)、树脂薄膜等夹置在复合物与复合物之间。
例如，边释放通过本发明的制造方法获得的卷状物，边连续供给玻璃-树脂复合物，并通过光刻工序在玻璃上形成薄膜晶体管(TFT)后，将玻璃-树脂复合物切断成所期望的长度，接着将树脂剥离除去，由此能够获得带有TFT的玻璃基板。
进而，对本发明的其它方案进行说明。本发明的制造方法的第2方案是如下的方法：在连续供给的树脂薄膜的一部分面或整个面上涂布粘接剂或粘合剂，接着在所述树脂薄膜中的粘接剂或粘合剂的涂布面上粘贴切断成规定尺寸的玻璃基板。
此外，本发明的制造方法的第3方案是将切断成规定尺寸的、且一侧的表面涂布有粘接剂或粘合剂的玻璃基板粘贴到连续供给的树脂薄膜上的方法。这种情况下，所述玻璃基板的粘接剂或粘合剂的涂布面是面向树脂薄膜的面。
第1方案是连续的树脂薄膜和连续的玻璃带的复合物的制造方法，与此相对，第2及第3方案是连续的树脂薄膜和不连续的玻璃基板的复合物的制造方法，在这一点上是不同的。
第2及第3方案中的树脂薄膜与第1方案同样可以使用聚酯树脂、聚碳酸酯树脂、聚醚砜树脂、聚烯烃树脂、聚乙烯醇树脂、硅酮树脂、聚酰胺树脂、丙烯酸树脂、聚苯乙烯树脂、三醋酸纤维素树脂、聚酰亚胺树脂、聚氯乙烯树脂或氟树脂，或者它们的共聚物、含有填料等添加剂的树脂。
第2方案的制造方法中，在将粘接剂或粘合剂涂布到树脂薄膜上时，可以使用口模涂布机、辊涂机。此外，第3方案的制造方法中，在将粘接剂或粘合剂涂布到玻璃基板上时，可以使用口模涂布机、辊涂机、丝网印刷机等。
接着，将通过所述方法涂布于树脂薄膜或玻璃基板上的粘接剂或粘合剂通过利用热、紫外线等的方法适当固化，将树脂薄膜及玻璃基板牢固地固定在一起。
通过这样的制造方法获得的玻璃-树脂复合物，与第1方案的制造方法的情况同样地，可以在树脂薄膜上粘贴玻璃基板后用卷绕装置卷成卷状。
通过第2及第3方案的制造方法获得的玻璃-树脂复合物的卷状物，与第1方案的情况同样可以应用于卷对卷方式的显示器装置制造工序中。
这里，在玻璃上形成薄膜晶体管(TFT)后，将玻璃-树脂复合物切断成所期望的长度时，优选将相邻的玻璃基板与玻璃基板之间(没有粘贴玻璃基板而只有树脂薄膜的地方)切断。这是因为，与将玻璃和树脂薄膜这两者同时切断的情况相比，仅将树脂薄膜切断比较容易。以下，用附图对本发明的实施例及比较例进行说明。但是，本发明不限于后述实施例的方式。
实施例
(实施例1)用图1对本实施例进行说明。通过已知的熔融法将线膨胀系数为38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，在退火部2退火至120℃左右。其后，夹置尿烷系热熔粘接剂层(厚度30μm，熔点120℃；未图示)，用调节至120℃的夹持辊4将厚度50μm的树脂薄膜(聚对苯二甲酸乙二醇酯薄膜)3层压到玻璃带1的两面上，由此得到玻璃-树脂复合物5。
(比较例1)通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带(旭硝子制AN100)成形为100μm的厚度，暂且退火至室温。其后，尝试在230℃(树脂辊的设定最高温度)下在所述玻璃带的单面热熔接厚度为50μm的热塑性聚酰亚胺树脂薄膜(三井化学公司制，AURUM薄膜，玻璃化转变温度：250℃)。
(比较例2)通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带(旭硝子制AN100)成形为100μm的厚度，退火至150℃左右，夹置尿烷系热熔粘接剂层(厚度30μm，熔点120℃)，用调节至150℃的夹持辊将厚度50μm的聚对苯二甲酸乙二醇酯薄膜层压到玻璃带的两面上。
(实施例2)用图2对本实施例进行说明。通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，退火至常温左右(约20℃，以下相同。)。然后，夹置丙烯酸系粘接剂层(未图示)，用夹持辊4将厚度50μm的树脂薄膜(聚对苯二甲酸乙二醇酯薄膜)3层压到玻璃带1的单面，由此得到玻璃-树脂复合物5。
(实施例3)用图3对本实施例进行说明。通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，在退火部2途中的、玻璃带1的表面温度为300℃的阶段，用夹持辊4将厚度50μm的热塑性聚酰亚胺树脂薄膜3(三井化学公司制AURUM薄膜，玻璃化转变温度＝250℃)热熔接于玻璃带1的单面上，由此得到玻璃-树脂复合物。
(实施例4)用图4对本实施例进行说明。通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，退火至常温左右。然后，用口模涂布机6，将熔融的热塑性丙烯酸树脂(未图示)涂布于玻璃带1的单面，并使其厚度为50μm。其后，使所述热塑性丙烯酸树脂冷却固化，获得玻璃-树脂复合物5。
(实施例5)用图5对本实施例进行说明。通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，退火至常温左右。然后，用口模涂布机6，将热固性硅酮树脂(未图示)涂布于玻璃带1的单面，并使厚度为20μm。其后，通过加热炉7将所述热固性硅酮树脂在100℃下加热固化10分钟，获得玻璃-树脂复合物5。
(实施例6)用图6对本实施例进行说明。通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，使其通过退火部2退火至常温左右。然后，用浸渍涂布机8，将固化性树脂(丙烯酸系紫外线固化性树脂)9加到玻璃带1的两面，并使其厚度为50μm。其后，通过用紫外线照射装置10照射紫外线，使所述丙烯酸系UV固化性树脂固化，获得玻璃-树脂复合物5。
(实施例7)通过已知的浮法将线膨胀系数38×10-7/℃的玻璃薄膜(旭硝子制AN100)成形为100μm的厚度，退火至常温左右，其后将所述玻璃薄膜切断成规定的尺寸(730×920mm)，获得平板状的玻璃基板。通过将该玻璃基板粘贴到连续供给的厚度50μm的聚对苯二甲酸乙二醇酯薄膜上，获得玻璃-树脂复合物。在将玻璃与树脂薄膜粘贴时，在聚对苯二甲酸乙二醇酯薄膜的表面涂布丙烯酸系粘接剂层。
(实施例8)通过已知的浮法将线膨胀系数38×10-7/℃的玻璃薄膜(旭硝子制AN100)成形为100μm的厚度，退火至常温左右，其后将所述玻璃薄膜切断成规定的尺寸(730×920mm)，获得平板状的玻璃基板。通过将该玻璃基板粘贴到连续供给的厚度50μm的聚对苯二甲酸乙二醇酯薄膜上，获得玻璃-树脂复合物。在将玻璃与树脂薄膜粘贴时，在玻璃基板的表面涂布丙烯酸系粘接剂层。
(实施例9)用图7对本实施例进行说明。将聚酰胺酸的N-甲基吡咯烷酮溶液(50质量％)通过口模涂布于连续输送的不锈钢片(表面为镜面加工，厚度300μm)上使其厚度为80μm，接着在设定为230℃的连续加热炉内通过10分钟，使所述聚酰胺酸的N-甲基吡咯烷酮溶液的浓度提高至85质量％，将该聚酰胺酸的生片(部分固化的固化性树脂的片状物)从不锈钢片上剥离，用厚度30μm的聚对苯二甲酸乙二醇酯薄膜夹着。这样获得厚度50μm的带有聚对苯二甲酸乙二醇酯(PET)覆膜的聚酰胺酸生片。
接下来，通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，使其通过退火部2退火至150℃左右。
然后，将所述带有PET覆膜的聚酰胺酸生片11的单面(与玻璃带1接触的面)的PET覆膜剥离，并用调整至150℃的夹持辊4在所述玻璃带1的两面加压粘贴带有PET覆膜的聚酰胺酸生片11。接着，将所述带有PET覆膜的聚酰胺酸生片11的外侧的PET覆膜12剥离，同时用60分钟通过设定为300℃的连续加热炉7内，结束酰亚胺化反应，获得玻璃-树脂复合物5。
(实施例10)用图8对本实施例进行说明。通过已知的熔融法将线膨胀系数38×10-7/℃的玻璃带1(旭硝子制AN100)成形为100μm的厚度，使其通过退火部2退火至50℃左右。其后，边将单面(内侧)的PET覆膜剥离，边将带有PET覆膜的光固化型树脂薄膜13(DuPont MRC DryFilm Ltd.制的光固化型干膜FX100；厚度50μm)用夹持辊4加压粘贴在所述玻璃带1的两面。然后，用紫外线照射装置10隔着最外层的PET覆膜照射紫外线，完成所述光固化型树脂薄膜的固化反应，获得玻璃-树脂复合物5。
通过上述实施例1～10获得的玻璃-树脂复合物的挠性优异，能够卷绕成卷状。因此，即使玻璃极薄，其搬运性、处理性及加工性也优异。另一方面，比较例1的方法中，热塑性聚酰亚胺树脂薄膜没有充分软化，不能获得玻璃-树脂复合物。此外，比较例2的方法中，尿烷系热熔粘接剂从粘接界面流出，不能获得玻璃-树脂复合物。
产业上的可利用性
通过本发明的制造方法获得的玻璃-树脂复合物，可以用于显示器用基板、传感器/元件罩。
另外，将2007年10月30日申请的日本专利申请2007-282293号的说明书、权利要求书、附图及摘要的全部内容援引于此，作为本发明的说明书的公开内容而并入。

Claims (15)

1.一种玻璃-树脂复合物的制造方法，其特征在于，将熔融玻璃成形为玻璃带后，在该玻璃带的至少一面上形成树脂层。
2.根据权利要求1所述的玻璃-树脂复合物的制造方法，其特征在于，所述成形的方法为浮法、熔融法、引下法、流孔下引法或重新引下法。
3.根据权利要求1或2所述的玻璃-树脂复合物的制造方法，其特征在于，所述玻璃带的厚度为10～300μm。
4.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，该方法通过夹置含有具有熔点的热熔融性树脂的热熔融层在玻璃带上层压树脂薄膜以形成树脂层，
设所述热熔融性树脂的熔点为Tm时，
在成形后的玻璃带的温度处于Tm-50℃～Tm+20℃的范围的时刻，夹置热熔融层将树脂薄膜紧密地粘贴在玻璃带上。
5.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，该方法通过夹置含有不具有熔点的热熔融性树脂的热熔融层在玻璃带上层压树脂薄膜以形成树脂层，
设所述热熔融性树脂的玻璃化转变温度为Tg时，
在成形后的玻璃带的温度处于Tg～Tg+100℃的范围的时刻，夹置热熔融层将树脂薄膜紧密地粘贴在玻璃带上。
6.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，该方法通过在玻璃带上层压含有具有熔点的热熔融性树脂的薄膜以形成树脂层，
设所述热熔融性树脂的熔点为Tm时，
在成形后的玻璃带的温度处于Tm-50℃～Tm+20℃的范围的时刻，将薄膜紧密地粘贴在玻璃带上。
7.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，该方法通过在玻璃带上层压含有不具有熔点的热熔融性树脂的薄膜以形成树脂层，
设所述热熔融性树脂的玻璃化转变温度为Tg时，
在成形后的玻璃带的温度处于Tg～Tg+100℃的范围的时刻，将薄膜紧密地粘贴在玻璃带上。
8.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，通过将热熔融树脂直接或者夹置粘接剂层或粘合剂层涂布到玻璃带上，从而形成树脂层。
9.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，通过将固化性树脂直接或者夹置粘接剂层或粘合剂层涂布到玻璃带上后，将所述固化性树脂固化，从而形成树脂层。
10.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，通过将实质上由固化性树脂构成的薄膜夹置粘接剂层或粘合剂层层压在玻璃带上，从而形成树脂层。
11.根据权利要求1～3的任一项所述的玻璃-树脂复合物的制造方法，其特征在于，通过将部分固化的固化性树脂的片状物加压粘贴在玻璃带上，接着将所述固化性树脂固化，从而形成树脂层。
12.一种玻璃-树脂复合物的制造方法，其特征在于，在连续供给的树脂薄膜的一部分面或整个面上涂布粘接剂或粘合剂，接着在所述树脂薄膜的粘接剂或粘合剂的涂布面上放置并粘贴切断成规定尺寸的玻璃基板。
13.一种玻璃-树脂复合物的制造方法，其特征在于，该方法将切断成规定尺寸、且一侧的表面涂布有粘接剂或粘合剂的玻璃基板粘贴到连续供给的树脂薄膜上，所述玻璃基板的粘接剂或粘合剂的涂布面是面向树脂薄膜的面。
14.根据权利要求12或13所述的玻璃-树脂复合物的制造方法，其特征在于，所述玻璃基板的厚度为10～300μm。
15.一种玻璃-树脂复合物的制造方法，其特征在于，通过权利要求1～14的任一项中所述的方法获得复合物后，将该复合物卷绕成卷状。
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Patentee before: Asahi Glass Co., Ltd.