CA2802893C - Novel catalyst mixtures - Google Patents

Novel catalyst mixtures Download PDF

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Publication number
CA2802893C
CA2802893C CA2802893A CA2802893A CA2802893C CA 2802893 C CA2802893 C CA 2802893C CA 2802893 A CA2802893 A CA 2802893A CA 2802893 A CA2802893 A CA 2802893A CA 2802893 C CA2802893 C CA 2802893C
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Prior art keywords
electrochemical cell
group
hydrogen
reaction
catalyst
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CA2802893A
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English (en)
French (fr)
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CA2802893A1 (en
Inventor
Richard I. Masel
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Dioxide Materials Inc
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Dioxide Materials Inc
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Priority claimed from US12/830,338 external-priority patent/US20110237830A1/en
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
    • B01J31/0288—Phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
    • B01J31/0291—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre also containing elements or functional groups covered by B01J31/0201 - B01J31/0274
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/004—CO or CO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/921—Alloys or mixtures with metallic elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04186—Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Analytical Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Inert Electrodes (AREA)
  • Catalysts (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Hybrid Cells (AREA)
CA2802893A 2010-07-04 2011-07-01 Novel catalyst mixtures Active CA2802893C (en)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US12/830,338 2010-07-04
US12/830,338 US20110237830A1 (en) 2010-03-26 2010-07-04 Novel catalyst mixtures
USPCT/US2011/030098 2011-03-25
PCT/US2011/030098 WO2011120021A1 (en) 2010-03-26 2011-03-25 Novel catalyst mixtures
US201161484072P 2011-05-09 2011-05-09
US61/484,072 2011-05-09
US13/174,365 2011-06-30
US13/174,365 US9566574B2 (en) 2010-07-04 2011-06-30 Catalyst mixtures
PCT/US2011/042809 WO2012006240A1 (en) 2010-07-04 2011-07-01 Novel catalyst mixtures

Publications (2)

Publication Number Publication Date
CA2802893A1 CA2802893A1 (en) 2012-01-12
CA2802893C true CA2802893C (en) 2018-08-28

Family

ID=47261920

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2802893A Active CA2802893C (en) 2010-07-04 2011-07-01 Novel catalyst mixtures

Country Status (8)

Country Link
US (1) US9566574B2 (enExample)
JP (2) JP6059140B2 (enExample)
KR (1) KR101801659B1 (enExample)
CN (1) CN102971451B (enExample)
AU (1) AU2011276362B2 (enExample)
BR (1) BR112013000261A2 (enExample)
CA (1) CA2802893C (enExample)
WO (1) WO2012006240A1 (enExample)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10173169B2 (en) 2010-03-26 2019-01-08 Dioxide Materials, Inc Devices for electrocatalytic conversion of carbon dioxide
US8956990B2 (en) 2010-03-26 2015-02-17 Dioxide Materials, Inc. Catalyst mixtures
US9012345B2 (en) * 2010-03-26 2015-04-21 Dioxide Materials, Inc. Electrocatalysts for carbon dioxide conversion
US9957624B2 (en) 2010-03-26 2018-05-01 Dioxide Materials, Inc. Electrochemical devices comprising novel catalyst mixtures
US9790161B2 (en) 2010-03-26 2017-10-17 Dioxide Materials, Inc Process for the sustainable production of acrylic acid
US20110237830A1 (en) 2010-03-26 2011-09-29 Dioxide Materials Inc Novel catalyst mixtures
US9815021B2 (en) * 2010-03-26 2017-11-14 Dioxide Materials, Inc. Electrocatalytic process for carbon dioxide conversion
CN104822861B (zh) * 2012-09-24 2017-03-08 二氧化碳材料公司 用于将二氧化碳转化为有用燃料和化学品的装置和方法
ITMI20121909A1 (it) * 2012-11-09 2014-05-10 Industrie De Nora Spa Cella elettrolitica dotata di microelettrodi
US10647652B2 (en) 2013-02-24 2020-05-12 Dioxide Materials, Inc. Process for the sustainable production of acrylic acid
AU2014271702A1 (en) 2013-05-29 2015-12-17 Kabushiki Kaisha Toshiba Reduction catalyst and chemical reactor
CN105493340B (zh) * 2013-06-27 2020-06-16 伊利诺伊大学董事会 用于二氧化碳转化的催化剂
RU2016106910A (ru) * 2013-07-31 2017-08-31 Аквахайдрекс Пти Лтд Композитные трехмерные электроды и способы их изготовления
US10570524B2 (en) 2014-09-08 2020-02-25 3M Innovative Properties Company Ionic polymer membrane for a carbon dioxide electrolyzer
US10724142B2 (en) 2014-10-21 2020-07-28 Dioxide Materials, Inc. Water electrolyzers employing anion exchange membranes
US10774431B2 (en) 2014-10-21 2020-09-15 Dioxide Materials, Inc. Ion-conducting membranes
US10975480B2 (en) 2015-02-03 2021-04-13 Dioxide Materials, Inc. Electrocatalytic process for carbon dioxide conversion
JP6548954B2 (ja) 2015-05-21 2019-07-24 株式会社東芝 還元触媒及び化学反応装置
AR106069A1 (es) * 2015-09-25 2017-12-06 Akzo Nobel Chemicals Int Bv Electrodo y proceso para su manufactura
US12286714B2 (en) * 2015-10-09 2025-04-29 Rutgers, The State University Of New Jersey Nickel phosphide catalysts for direct electrochemical CO2 reduction to hydrocarbons
WO2017176600A1 (en) 2016-04-04 2017-10-12 Dioxide Materials, Inc. Electrocatalytic process for carbon dioxide conversion
AU2016401931B2 (en) * 2016-04-04 2019-03-07 Dioxide Materials, Inc. Catalyst layers and electrolyzers
CN115198294A (zh) 2016-05-03 2022-10-18 欧普斯12公司 用于二氧化碳、一氧化碳和其他化学化合物的电化学反应的具有先进架构的反应器
US12359325B2 (en) 2016-05-03 2025-07-15 Twelve Benefit Corporation Membrane electrode assembly for COx reduction
US11680328B2 (en) 2019-11-25 2023-06-20 Twelve Benefit Corporation Membrane electrode assembly for COx reduction
JP6758586B2 (ja) * 2016-06-09 2020-09-23 国立大学法人秋田大学 大規模な二酸化炭素排出源（火力発電所等）で貯留した二酸化炭素の電解還元・メタノール同時合成のための二酸化炭素電解処理システム
DE102016217730A1 (de) 2016-09-16 2018-03-22 Siemens Aktiengesellschaft CO2-Elektrolyseverfahren
CN107871875B (zh) * 2016-09-26 2021-05-07 中国科学院大连化学物理研究所 一种析氧反应电催化剂、其制备方法及应用
US10774430B2 (en) 2016-10-04 2020-09-15 Johna Leddy Carbon dioxide reduction and carbon compound electrochemistry in the presence of lanthanides
JP6649293B2 (ja) 2017-01-25 2020-02-19 株式会社東芝 還元触媒、ならびにそれを用いた化学反応装置、還元方法、および還元物生産システム
JP6949641B2 (ja) * 2017-09-27 2021-10-13 積水化学工業株式会社 二酸化炭素還元装置
CN117926298A (zh) 2018-01-22 2024-04-26 十二益公司 用于二氧化碳反应器控制的系统和方法
US12320022B2 (en) 2018-01-22 2025-06-03 Twelve Benefit Corporation System and method for carbon dioxide reactor control
CN110055556B (zh) * 2018-04-28 2021-03-30 南方科技大学 析氢反应催化剂及其制备方法和应用
EP3887578A1 (en) 2018-11-28 2021-10-06 Opus 12 Incorporated Electrolyzer and method of use
WO2020132064A1 (en) 2018-12-18 2020-06-25 Opus 12 Inc. Electrolyzer and method of use
CN109860638B (zh) * 2019-01-07 2021-12-03 湖南大学 一种纳米多孔Ag2Al材料、制备方法及应用
KR20210132024A (ko) 2019-01-07 2021-11-03 오푸스-12 인코포레이티드 메탄 제조를 위한 시스템 및 방법
US11746426B2 (en) 2019-07-10 2023-09-05 California Institute Of Technology Stabilization of a co-bound intermediate via molecular tuning promotes CO2-to-ethylene conversion
CN111389459B (zh) * 2020-02-20 2021-04-13 嘉兴学院 一种用于催化还原二氧化碳或碳水化合物的组合物、及方法
KR20230010203A (ko) 2020-05-14 2023-01-18 닛토덴코 가부시키가이샤 이산화탄소 포착 처리 시스템 및 co2 네거티브 이미션 공장
KR20230092977A (ko) 2020-10-20 2023-06-26 트웰브 베네핏 코포레이션 이온성 중합체 및 공중합체
CA3196179A1 (en) 2020-10-20 2022-04-28 Lihui Wang Semi-interpenetrating and crosslinked polymers and membranes thereof
CN113737217B (zh) * 2021-09-29 2024-06-11 天津理工大学 一种高负载量金属Co单原子催化剂及其制备方法和应用
EP4569156A1 (en) 2022-08-12 2025-06-18 Twelve Benefit Corporation Acetic acid production
US12463265B2 (en) * 2022-12-01 2025-11-04 GM Global Technology Operations LLC Battery monitoring system for measuring carbon dioxide to detect imbalance in a group of parallel lithium-ion battery cells
JPWO2024135202A1 (enExample) * 2022-12-22 2024-06-27
US12460310B2 (en) 2023-04-04 2025-11-04 Twelve Benefit Corporation Integrated systems employing carbon oxide electrolysis in aluminum production

Family Cites Families (115)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE183856C (enExample)
US1919850A (en) 1933-07-25 Emil luscher
US2511198A (en) 1948-01-02 1950-06-13 Allied Chem & Dye Corp Preparation of concentrated formic acid
US2996359A (en) 1957-11-26 1961-08-15 Matheson Company Inc Method for continuous manufacture of carbon monoxide
JPS4848409A (enExample) * 1971-10-18 1973-07-09
BE791653A (fr) * 1971-12-28 1973-05-21 Texaco Development Corp Procede electrolytique de preparation de l'acide
US4299891A (en) 1972-10-27 1981-11-10 The Richardson Company Method for forming battery terminals and terminals produced thereby
US3959094A (en) 1975-03-13 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Electrolytic synthesis of methanol from CO2
US4207151A (en) 1976-06-04 1980-06-10 Monsanto Company Electrohydrodimerization process improvement and improved electrolyte recovery process
US4115433A (en) * 1977-10-11 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives
JPS54138502A (en) * 1978-04-17 1979-10-27 Toyo Soda Mfg Co Ltd Electrolytic reduction of organic and inorganic compounds
DE2849065A1 (de) 1978-11-11 1980-05-22 Basf Ag Verwendung von quartaeren ammoniumsalzen als leitsalze
US4240882A (en) 1979-11-08 1980-12-23 Institute Of Gas Technology Gas fixation solar cell using gas diffusion semiconductor electrode
US4315753A (en) 1980-08-14 1982-02-16 The United States Of America As Represented By The Secretary Of The Interior Electrochemical apparatus for simultaneously monitoring two gases
DE81982T1 (de) 1981-12-11 1983-09-29 The British Petroleum Co. P.L.C., Sunbury-On-Thames, Middlesex Elektrochemische organische synthese.
JPS59219485A (ja) 1983-05-26 1984-12-10 Asahi Chem Ind Co Ltd ２，５−ジメチルヘキサンジニトリルの製法
GB8401005D0 (en) 1984-01-14 1984-02-15 Bp Chem Int Ltd Formate salts
US4523981A (en) * 1984-03-27 1985-06-18 Texaco Inc. Means and method for reducing carbon dioxide to provide a product
US4545872A (en) 1984-03-27 1985-10-08 Texaco Inc. Method for reducing carbon dioxide to provide a product
US4609451A (en) 1984-03-27 1986-09-02 Texaco Inc. Means for reducing carbon dioxide to provide a product
DE3417790A1 (de) 1984-05-14 1985-11-14 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von ameisensaeure
US4595465A (en) 1984-12-24 1986-06-17 Texaco Inc. Means and method for reducing carbn dioxide to provide an oxalate product
US4620906A (en) 1985-01-31 1986-11-04 Texaco Inc. Means and method for reducing carbon dioxide to provide formic acid
US4673473A (en) 1985-06-06 1987-06-16 Peter G. Pa Ang Means and method for reducing carbon dioxide to a product
US4608132A (en) 1985-06-06 1986-08-26 Texaco Inc. Means and method for the electrochemical reduction of carbon dioxide to provide a product
US4608133A (en) 1985-06-10 1986-08-26 Texaco Inc. Means and method for the electrochemical reduction of carbon dioxide to provide a product
US4609440A (en) 1985-12-18 1986-09-02 Gas Research Institute Electrochemical synthesis of methane
US4609441A (en) 1985-12-18 1986-09-02 Gas Research Institute Electrochemical reduction of aqueous carbon dioxide to methanol
CA1272180A (fr) 1986-03-20 1990-07-31 Andre Mortreux Systeme catalytique, son procede de preparation et son application a la fabrication d'aldehydes
US4756807A (en) 1986-10-09 1988-07-12 Gas Research Institute Chemically modified electrodes for the catalytic reduction of CO2
US4711708A (en) 1986-10-09 1987-12-08 Gas Research Institute Chemically modified electrodes for the catalytic reduction of CO2
US4668349A (en) 1986-10-24 1987-05-26 The Standard Oil Company Acid promoted electrocatalytic reduction of carbon dioxide by square planar transition metal complexes
JPS63111193A (ja) 1986-10-30 1988-05-16 Asahi Chem Ind Co Ltd アジポニトリルの製法
IT1216929B (it) 1987-04-16 1990-03-14 Enichem Sintesi Procedimento per la sintesi di acidi 2-aril-propionici.
GB8712582D0 (en) * 1987-05-28 1987-07-01 Neotronics Ltd Acidic gas sensors
US4818353A (en) 1987-07-07 1989-04-04 Langer Stanley H Method for modifying electrocatalyst material, electrochemical cells and electrodes containing this modified material, and synthesis methods utilizing the cells
FR2624884B1 (fr) 1987-12-18 1990-04-20 Poudres & Explosifs Ste Nale Procede de synthese electrochimique de cetones alpha saturees
US4771708A (en) 1988-01-11 1988-09-20 Douglass Jr Edward T Incinerator and heat recovery system for drying wood poles
US4968393A (en) * 1988-04-18 1990-11-06 A. L. Sandpiper Corporation Membrane divided aqueous-nonaqueous system for electrochemical cells
FR2646441B1 (fr) 1989-04-28 1991-07-12 Poudres & Explosifs Ste Nale Procede d'electrosynthese d'un ester beta gamma insature
US5064733A (en) 1989-09-27 1991-11-12 Gas Research Institute Electrochemical conversion of CO2 and CH4 to C2 hydrocarbons in a single cell
JP3009703B2 (ja) 1990-05-02 2000-02-14 正道 藤平 二酸化炭素ガス還元用電極触媒
DE4016063A1 (de) 1990-05-18 1991-11-21 Hoechst Ag Verfahren zur teilweisen elektrolytischen enthalogenierung von di- und trichloressigsaeure sowie elektrolyseloesung
DE4211141A1 (de) 1992-04-03 1993-10-07 Basf Ag Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten
DE4227394A1 (de) 1992-08-19 1994-02-24 Basf Ag Verfahren zur Herstellung von Ameisensäure aus Kohlenmonoxid und Wasser
JP3360850B2 (ja) 1992-09-21 2003-01-07 株式会社日立製作所 銅系酸化触媒とその用途
EP0652202B1 (en) 1993-11-04 1997-06-04 Research Development Corporation Of Japan A method for producing formic acid or its derivatives
KR0169188B1 (ko) 1995-07-31 1999-03-20 강박광 탄화수소의 제조방법
DE19544671A1 (de) 1995-11-30 1997-06-05 Bayer Ag Urethan(meth)acrylate mit cyclischen Carbonatgruppen
GB9603754D0 (en) * 1996-02-22 1996-04-24 Bp Chem Int Ltd Lubricating oils
FR2745297B1 (fr) 1996-02-26 1998-05-22 Lesaffre Dev Utilisation d'une souche bacterienne pour la fabrication de l'acide formique ou du formiate et procede de fermentation utilisant cette souche
FR2747694B1 (fr) 1996-04-18 1998-06-05 France Etat Cathode pour la reduction de dioxyde de carbone et procede de fabrication d'une telle cathode
US5709789A (en) 1996-10-23 1998-01-20 Sachem, Inc. Electrochemical conversion of nitrogen containing gas to hydroxylamine and hydroxylammonium salts
US6660680B1 (en) 1997-02-24 2003-12-09 Superior Micropowders, Llc Electrocatalyst powders, methods for producing powders and devices fabricated from same
US5928806A (en) 1997-05-07 1999-07-27 Olah; George A. Recycling of carbon dioxide into methyl alcohol and related oxygenates for hydrocarbons
US6024855A (en) 1997-08-15 2000-02-15 Sachem, Inc. Electrosynthesis of hydroxylammonium salts and hydroxylamine using a mediator
DE19754304A1 (de) * 1997-12-08 1999-06-10 Hoechst Ag Polybetain-stabilisierte Platin-Nanopartikel, Verfahren zu ihrer Herstellung und Verwendung für Elektrokatalysatoren in Brennstoffzellen
US6099990A (en) * 1998-03-26 2000-08-08 Motorola, Inc. Carbon electrode material for electrochemical cells and method of making same
FI107528B (fi) 1998-12-23 2001-08-31 Kemira Chemicals Oy Menetelmä muurahaishapon valmistamiseksi
DE19953832A1 (de) 1999-11-09 2001-05-10 Basf Ag Verfahren zur Herstellung von Ameisensäure
KR100351625B1 (ko) 1999-11-11 2002-09-11 한국화학연구원 탄화수소 제조용 촉매
DE10002794A1 (de) 2000-01-24 2001-07-26 Basf Ag Abwasserreinigung beim Verfahren zur Herstellung von wasserfreier Ameisensäure
DE10002795A1 (de) 2000-01-24 2001-08-02 Basf Ag Werkstoff für eine Anlage zur Herstellung von wasserfreier Ameisensäure
DE10002791A1 (de) 2000-01-24 2001-07-26 Basf Ag Verfahren zur Gewinnung von wasserfreier Ameisensäure
FR2804622B1 (fr) 2000-02-04 2002-04-05 Inst Francais Du Petrole Composition catalytique pour la dimerisation, la codimerisation et l'oligomerisation des olefines
CN1275915C (zh) 2000-02-25 2006-09-20 新日本制铁株式会社 甲酸酯或甲醇的生产方法及其合成催化剂
FI117633B (fi) 2000-12-29 2006-12-29 Chempolis Oy Kemikaalien talteenotto ja valmistus massan valmistuksen yhteydessä
US6963909B1 (en) 2001-07-24 2005-11-08 Cisco Technology, Inc. Controlling the response domain of a bootP/DHCP server by using network physical topology information
DE10138778A1 (de) 2001-08-07 2003-02-20 Basf Ag Flexibles Verfahren zur gemeinsamen Herstellung von Ameisensäure sowie einer Carbonsäure mit mindestens zwei Kohlenstoffatomen und/oder deren Derivaten
WO2003043967A1 (en) 2001-11-08 2003-05-30 Mks Marmara Entegre Kimya San. A.S. Production of potassium formate
CA2464762A1 (en) 2001-11-09 2003-05-15 Basf Aktiengesellschaft Method for production of formic acid formates
DE60301288T2 (de) * 2002-03-22 2006-06-01 Haldor Topsoe A/S Verfahren zur Paraffinisomerisierung und dafür geeignete katalytische Zusammensetzung, enthaltend eine ionische Flüssigkeit und ein Metallsalz-Additiv
GB0215384D0 (en) 2002-07-04 2002-08-14 Johnson Matthey Plc Improvements in metal salts
DE10237379A1 (de) 2002-08-12 2004-02-19 Basf Ag Verfahren und Vorrichtung zur Herstellung von ameisensauren Formiaten und deren Verwendung
DE10237380A1 (de) 2002-08-12 2004-02-19 Basf Ag Verfahren und Vorrichtung zur Herstellung von ameisensauren Formlaten und deren Verwendung
US6939453B2 (en) 2002-08-14 2005-09-06 Large Scale Proteomics Corporation Electrophoresis process using ionic liquids
DE10249928A1 (de) 2002-10-26 2004-05-06 Basf Ag Flexibles Verfahren zur gemeinsamen Herstellung von (i) Ameisensäure, (ii) einer Carbonsäure mit mindestens zwei Kohlenstoffatomen und/oder deren Derivate und (iii) eines -Carbonsäureanhydrids
CA2539174C (en) 2003-09-17 2009-12-08 Japan Science And Technology Agency Process for reduction of carbon dioxide with organometallic complex
US6987134B1 (en) 2004-07-01 2006-01-17 Robert Gagnon How to convert carbon dioxide into synthetic hydrocarbon through a process of catalytic hydrogenation called CO2hydrocarbonation
CN1290215C (zh) * 2004-08-06 2006-12-13 重庆大学 电沉积法制备质子交换膜燃料电池电极时抑制析氢的方法
DE102004040789A1 (de) 2004-08-23 2006-03-02 Basf Ag Verfahren zur Herstellung von Ameisensäure
ES2263346B1 (es) 2004-08-25 2007-12-16 Consejo Superior De Investigaciones Cientificas Uso de una composicion catalitica en la insercion de dioxido de carbo no en acetales, ortoesteres y epoxidos.
US7618725B2 (en) 2004-09-21 2009-11-17 The Board Of Trustees Of The University Of Illinois Low contaminant formic acid fuel for direct liquid fuel cell
US7811433B2 (en) 2004-10-15 2010-10-12 Giner, Inc. Electrochemical carbon dioxide sensor
US7748976B2 (en) 2005-03-17 2010-07-06 Southwest Research Institute Use of recirculated exhaust gas in a burner-based exhaust generation system for reduced fuel consumption and for cooling
US7608743B2 (en) 2005-04-15 2009-10-27 University Of Southern California Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products
EP1871731B1 (en) 2005-04-15 2012-12-26 University Of Southern California Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products
DE102005020890A1 (de) 2005-05-04 2006-11-09 Basf Ag Herstellung von Natriumformiat
US20070187247A1 (en) 2005-07-20 2007-08-16 Lackner Klaus S Electrochemical methods and processes for carbon dioxide recovery from alkaline solvents for carbon dioxide capture from air
JP2009506213A (ja) 2005-08-25 2009-02-12 セラマテック・インク 空気および水を使用して合成ガスを製造するための電気化学的セル
JPWO2007037337A1 (ja) 2005-09-29 2009-04-09 三洋化成工業株式会社 電気化学素子用電解液及びこれを用いた電気化学素子
WO2007041872A1 (en) 2005-10-13 2007-04-19 Mantra Energy Alternatives Ltd. Continuous co-current electrochemical reduction of carbon dioxide
US7378561B2 (en) 2006-08-10 2008-05-27 University Of Southern California Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material
GB0704972D0 (en) * 2007-03-15 2007-04-25 Varney Mark S Neoteric room temperature ionic liquid gas sensor
JP2008288079A (ja) * 2007-05-18 2008-11-27 Panasonic Corp 無水銀アルカリ乾電池
US20090016948A1 (en) 2007-07-12 2009-01-15 Young Edgar D Carbon and fuel production from atmospheric CO2 and H2O by artificial photosynthesis and method of operation thereof
US8138380B2 (en) 2007-07-13 2012-03-20 University Of Southern California Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol
WO2009012154A2 (en) 2007-07-13 2009-01-22 University Of Southern California Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol
NZ564691A (en) 2007-12-21 2010-03-26 Nz Inst Plant & Food Res Ltd Glycosyltransferases, polynucleotides encoding these and methods of use
WO2009086460A1 (en) 2007-12-28 2009-07-09 Calera Corporation Methods of sequestering co2
US20100137457A1 (en) 2008-07-01 2010-06-03 Kaplan Thomas Proger Method for conversion of atmospheric carbon dioxide into useful materials
WO2010007602A1 (en) 2008-07-18 2010-01-21 Ffgf Limited The production of hydrogen, oxygen and hydrocarbons
CA2730712A1 (en) * 2008-07-30 2010-02-04 Blacklight Power, Inc. Heterogeneous hydrogen-catalyst reactor
CN102227629B (zh) * 2008-12-01 2015-09-23 Msa奥尔有限责任公司 具有离子液体电解质系统的电化学气体传感器
EP2382174A4 (en) 2009-01-29 2013-10-30 Trustees Of The University Of Princeton CONVERSION OF CARBON DIOXIDE IN ORGANIC PRODUCTS
US8366894B2 (en) 2009-02-20 2013-02-05 Giner, Inc. Multi-gas microsensor assembly
US20110114502A1 (en) 2009-12-21 2011-05-19 Emily Barton Cole Reducing carbon dioxide to products
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US20110237830A1 (en) * 2010-03-26 2011-09-29 Dioxide Materials Inc Novel catalyst mixtures
JP5591606B2 (ja) 2010-07-08 2014-09-17 三井造船株式会社 二酸化炭素の還元，固定方法
US8524066B2 (en) 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
EP2655310B1 (de) 2010-12-21 2014-11-05 Basf Se Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff
WO2013006711A1 (en) 2011-07-06 2013-01-10 Liquid Light, Inc. Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates

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