BR0314856A - Complexos de rutênio como (pré) catalisadores para reações de metátese - Google Patents

Complexos de rutênio como (pré) catalisadores para reações de metátese

Info

Publication number
BR0314856A
BR0314856A BR0314856-4A BR0314856A BR0314856A BR 0314856 A BR0314856 A BR 0314856A BR 0314856 A BR0314856 A BR 0314856A BR 0314856 A BR0314856 A BR 0314856A
Authority
BR
Brazil
Prior art keywords
catalysts
ruthenium complexes
metathesis reactions
formula
metathesis
Prior art date
Application number
BR0314856-4A
Other languages
English (en)
Other versions
BR0314856B1 (pt
Inventor
Karol Grela
Original Assignee
Boehringer Ingelheim Int
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehringer Ingelheim Int filed Critical Boehringer Ingelheim Int
Publication of BR0314856A publication Critical patent/BR0314856A/pt
Publication of BR0314856B1 publication Critical patent/BR0314856B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0046Ruthenium compounds

Abstract

"COMPLEXOS DE RUTêNIO COMO (PRé)CATALISADORES PARA REAçõES DE METáTESE". A invenção refere-se a novos (pré)catalisadores de complexos de rutênio de fórmula 1, em que L^ 1^, X, X<39>, R^ 1^, R^ 2^, R^ 3 e n são definidos aqui. Os novos complexos de rutênio de fórmula 1 são (pré)catalisadores convenientes para reações de metátese e podem ser aplicados, isto é, para reações de metátese com fechamento de anéis, metátese cruzada ou metátese eno-ino. Um outro aspecto da invenção são os novos intermediários de fórmula 2
BRPI0314856-4A 2002-10-15 2003-10-10 Complexos de rutênio como (pré) catalisadores para reações de metátese, bem como processos para sua preparação e de seus intermediários BR0314856B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PLP-356652 2002-10-15
PL356652A PL199412B1 (pl) 2002-10-15 2002-10-15 Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
PCT/EP2003/011222 WO2004035596A1 (en) 2002-10-15 2003-10-10 Ruthenium complexes as (pre)catalysts for metathesis reactions

Publications (2)

Publication Number Publication Date
BR0314856A true BR0314856A (pt) 2005-08-02
BR0314856B1 BR0314856B1 (pt) 2014-05-27

Family

ID=32105755

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0314856-4A BR0314856B1 (pt) 2002-10-15 2003-10-10 Complexos de rutênio como (pré) catalisadores para reações de metátese, bem como processos para sua preparação e de seus intermediários

Country Status (32)

Country Link
US (1) US6867303B2 (pt)
EP (1) EP1554294B1 (pt)
JP (1) JP4264418B2 (pt)
KR (1) KR101057963B1 (pt)
CN (1) CN1291996C (pt)
AR (1) AR041620A1 (pt)
AT (1) ATE332906T1 (pt)
AU (1) AU2003271713B2 (pt)
BR (1) BR0314856B1 (pt)
CA (1) CA2502342C (pt)
CO (1) CO5560614A2 (pt)
DE (2) DE60306795T2 (pt)
DK (1) DK1554294T3 (pt)
EA (1) EA008352B1 (pt)
EC (1) ECSP055653A (pt)
ES (1) ES2268412T3 (pt)
HK (1) HK1070076A1 (pt)
HR (1) HRP20050339B1 (pt)
IL (1) IL168002A (pt)
ME (1) ME00345B (pt)
MX (1) MXPA05003647A (pt)
MY (1) MY127285A (pt)
NO (1) NO335760B1 (pt)
NZ (1) NZ539944A (pt)
PE (1) PE20040510A1 (pt)
PL (2) PL199412B1 (pt)
RS (1) RS50334B (pt)
TW (1) TWI310768B (pt)
UA (1) UA79018C2 (pt)
UY (1) UY28020A1 (pt)
WO (1) WO2004035596A1 (pt)
ZA (1) ZA200501533B (pt)

Families Citing this family (108)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003007697A (ja) * 2001-06-21 2003-01-10 Hitachi Kokusai Electric Inc 半導体装置の製造方法、基板処理方法および基板処理装置
EP1455937B1 (en) 2001-11-15 2018-04-11 Materia, Inc. Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts
WO2004112951A2 (en) * 2003-06-19 2004-12-29 University Of New Orleans Research & Technology Foundation, Inc. Preparation of ruthenium-based olefin metathesis catalysts
US7241898B2 (en) 2003-08-02 2007-07-10 Boehringer Ingelheim International Gmbh Metathesis catalysts
US7491794B2 (en) * 2003-10-14 2009-02-17 Intermune, Inc. Macrocyclic compounds as inhibitors of viral replication
US7109344B2 (en) * 2003-12-04 2006-09-19 Boehringer Ingelheim International Gmbh Ruthenium catalyst
EP1543875A1 (en) * 2003-12-04 2005-06-22 Boehringer Ingelheim Pharma GmbH & Co. KG Novel metathesis ruthenium catalyst
DE102004033312A1 (de) * 2004-07-08 2006-01-26 Boehringer Ingelheim Pharma Gmbh & Co. Kg Kontinuierliches Metatheseverfahren mit Ruthenium-Katalysatoren
DE102005002336A1 (de) * 2005-01-17 2006-07-20 Boehringer Ingelheim Pharma Gmbh & Co. Kg Verfahren zur Durchführung von kontinuierlichen Olefin-Ringschluss-Metathesen in komprimiertem Kohlendioxid
JP5406525B2 (ja) * 2005-07-04 2014-02-05 ツァナン・サイテック・カンパニー・リミテッド ルテニウム錯体配位子、ルテニウム錯体、固定化ルテニウム錯体触媒及びその調製方法と用途
JP5249028B2 (ja) * 2005-07-25 2013-07-31 インターミューン・インコーポレーテッド C型肝炎ウイルス複製の新規大環状阻害剤
DE602006019323D1 (de) 2005-10-11 2011-02-10 Intermune Inc Verbindungen und verfahren zur inhibierung der replikation des hepatitis-c-virus
WO2007054483A1 (en) * 2005-11-09 2007-05-18 Boehringer Ingelheim International Gmbh Preparation of catalysts
EP1815838B1 (en) 2006-02-02 2010-09-08 3M Innovative Properties Company Solid materials obtainable by the ring-opening methathesis polymerization
CN100491326C (zh) * 2006-02-13 2009-05-27 中国科学院化学研究所 一种3-羟基烯酸衍生物及其制备方法与应用
DE102006008521A1 (de) 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese
DE102006008520A1 (de) 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Neue Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
PL379879A1 (pl) * 2006-06-07 2007-12-10 Umicore Ag & Co.Kg. Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy
CN101479283B (zh) 2006-06-30 2012-07-04 弗·哈夫曼-拉罗切有限公司 作为复分解反应催化剂的钌络合物
KR20090024834A (ko) * 2006-07-05 2009-03-09 인터뮨, 인크. C형 간염 바이러스 복제의 신규 억제제
US20090253904A1 (en) * 2006-07-18 2009-10-08 Boehringer Ingelheim Pharma Gmbh & Co. Kg Process for the Preparation of a Tetrahydro-1H-Azepines
RU2311231C1 (ru) * 2006-08-15 2007-11-27 ООО "Объединенный центр исследований и разработок" Катализатор для получения эфиров акриловой кислоты по реакции метатезиса диалкилмалеатов (варианты) и каталитическая композиция на его основе
DE102006040569A1 (de) 2006-08-30 2008-03-06 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuken
FR2909382B1 (fr) * 2006-11-30 2009-01-23 Enscr Complexes catalytiques a base de ruthenium et utilisation de tels complexes pour la metathese d'olefines
EP1942125A1 (en) 2006-12-20 2008-07-09 3M Innovative Properties Company Compositions curable by ring opening metathesis polymerarization at low temperatures and their application in the dental field
AR066191A1 (es) 2007-03-22 2009-08-05 Schering Corp Proceso e intermediarios para la sintesis de compuestos 8- [ ( 1- (3,5- bis- ( trifluorometil) fenil) - etoxi ) - metil]- 8 fenil - 1,7- diaza - espiro (4, 5) decan -2 ona
EP2177523A1 (en) * 2007-05-03 2010-04-21 Intermune, Inc. Novel macrocyclic inhibitors of hepatitis c virus replication
JP2010526834A (ja) * 2007-05-10 2010-08-05 インターミューン・インコーポレーテッド C型肝炎ウイルス複製の新規ペプチド阻害剤
US20080306230A1 (en) * 2007-06-07 2008-12-11 General Electric Company Composition and Associated Method
JP5358566B2 (ja) 2007-06-21 2013-12-04 アムジエン・インコーポレーテツド シナカルセトおよびその塩を合成する方法
DE102007039527A1 (de) 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Katalysatoren für Metathese-Reaktionen
DE102007039525A1 (de) 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuk
DE102007039695A1 (de) 2007-08-22 2009-02-26 Lanxess Deutschland Gmbh Katalysatoren für Metathese-Reaktionen
DE102007039526A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2027920B1 (de) 2007-08-21 2014-10-08 LANXESS Deutschland GmbH Katalysatoren für Metathese-Reaktionen
US8419332B2 (en) * 2007-10-19 2013-04-16 Atlas Bolt & Screw Company Llc Non-dimpling fastener
SG175692A1 (en) 2008-04-15 2011-11-28 Intermune Inc Novel macrocyclic inhibitors of hepatitis c virus replication
EP2143489A1 (de) * 2008-07-08 2010-01-13 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2147721A1 (de) 2008-07-08 2010-01-27 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
JP5736313B2 (ja) 2008-09-05 2015-06-17 オプコ ヘルス, インコーポレイテッド 8−[{1−(3,5−ビス−(トリフルオロメチル)フェニル)−エトキシ}−メチル]−8−フェニル−1,7−ジアザ−スピロ[4.5]デカン−2−オン化合物の合成のためのプロセスおよび中間体
DE102009005951A1 (de) 2009-01-23 2010-07-29 Evonik Degussa Gmbh Aldehydfunktionale Verbindungen
EP2210870A1 (de) 2009-01-23 2010-07-28 Evonik Degussa GmbH Hydroxy- und aldehydfunktionale Verbindungen
EP2393822B1 (en) 2009-02-03 2014-07-16 IDENIX Pharmaceuticals, Inc. Phosphinate ruthenium complexes
AR075584A1 (es) * 2009-02-27 2011-04-20 Intermune Inc COMPOSICIONES TERAPEUTICAS QUE COMPRENDEN beta-D-2'-DESOXI-2'-FLUORO-2'-C-METILCITIDINA Y UN DERIVADO DE ACIDO ISOINDOL CARBOXILICO Y SUS USOS. COMPUESTO.
EP2408557B1 (en) * 2009-03-17 2017-03-15 Johnson Matthey Public Limited Company Process for making Ru (II) catalysts
EP2255877B1 (en) 2009-05-07 2014-09-24 Umicore AG & Co. KG Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands
SG175334A1 (en) * 2009-05-07 2011-11-28 Hoffmann La Roche Process for the preparation of ruthenium metathesis complex catalysts
EP2473279B1 (en) 2009-08-31 2014-04-02 LANXESS Deutschland GmbH Metathesis of a nitrile rubber in the presence of a transition metal catalyst
EP2289621A1 (en) 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Process for the preparation of low molecular weight hydrogenated nitrile rubber
EP2289623A1 (en) 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Metathesis of nitrile rubbers in the presence of transition metal catalysts
CA2775697A1 (en) * 2009-09-28 2011-03-31 Intermune, Inc. Cyclic peptide inhibitors of hepatitis c virus replication
WO2011079439A1 (en) * 2009-12-30 2011-07-07 Zannan Scitech Co., Ltd. Highly active metathesis catalysts selective for romp and rcm reactions
US8592618B2 (en) * 2010-01-08 2013-11-26 Zannan Scitech Co., Ltd. Highly active metathesis catalysts selective for ROMP and RCM reactions
EP2361683A1 (en) * 2010-01-29 2011-08-31 Umicore AG & Co. KG Process for preparation of ruthenium-based carbene catalysts with chelating alkylidene ligands
EP2395034A1 (de) 2010-06-14 2011-12-14 LANXESS Deutschland GmbH Blends aus teilhydriertem Nitrilkautschuk und Silikonkautschuk, darauf basierende vulkanisierbaren Mischungen und Vulkanisate
EP2598511B1 (en) 2010-07-30 2018-07-04 Ecole Nationale Superieure de Chimie de Rennes Novel stable and highly tunable metathesis catalysts
EP2418225A1 (de) 2010-08-09 2012-02-15 LANXESS Deutschland GmbH Teilhydrierte Nitrilkautschuke
EP2484700B1 (de) 2011-02-04 2013-10-09 LANXESS Deutschland GmbH Funktionalisierte Nitrilkautschuke und ihre Herstellung
US8633280B2 (en) * 2011-03-30 2014-01-21 Zannan Scitech Co., Ltd Methods of modifying polymers with highly active and selective metathesis catalysts
PL216649B1 (pl) 2011-06-06 2014-04-30 Univ Warszawski Nowe kompleksy rutenu, sposób ich wytwarzania oraz zastosowanie w reakcji metatezy olefin
PL220408B1 (pl) * 2011-09-26 2015-10-30 Inst Chemii Organicznej Polskiej Akademii Nauk Kompleks rutentu, sposób jego wytwarzania oraz zastosowanie
US8975414B2 (en) * 2011-10-13 2015-03-10 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes
WO2013056400A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056461A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056463A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013098052A2 (en) 2011-12-28 2013-07-04 Lanxess Deutschland Gmbh Metathesis of nitrile rubbers in the presence of transition metal complex catalysts
WO2013098056A1 (en) 2011-12-28 2013-07-04 Lanxess Deutschland Gmbh Purification of optionally hydrogenated nitrile rubber
PL230302B1 (pl) 2012-02-27 2018-10-31 Apeiron Synthesis Spolka Z Ograniczona Odpowiedzialnoscia Katalizatory metatezy zawierające grupy oniowe
EP2639219B1 (en) * 2012-03-14 2016-08-10 Umicore AG & Co. KG Ruthenium-based metathesis catalysts and precursors for their preparation
HUE028176T2 (en) 2012-06-29 2016-12-28 Apeiron Synthesis Sa Metal complexes, their use, and methods for performing metathesis reactions
PL400162A1 (pl) * 2012-07-27 2014-02-03 Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy
CN103936793B (zh) 2013-01-10 2017-02-08 光明创新(武汉)有限公司 含卡宾配体的催化剂及其制备方法与其在复分解反应中的应用
US9938253B2 (en) 2013-06-12 2018-04-10 Trustees Of Boston College Catalysts for efficient Z-selective metathesis
EP2835381A1 (en) 2013-08-09 2015-02-11 Lanxess Elastomers B.V. Functionalized olefinic copolymers
WO2015157736A1 (en) 2014-04-10 2015-10-15 California Institute Of Technology Reactions in the presence of ruthenium complexes
US9441078B2 (en) 2014-05-30 2016-09-13 Pall Corporation Self-assembling polymers—I
US9593217B2 (en) 2014-05-30 2017-03-14 Pall Corporation Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (Va)
US9469733B2 (en) 2014-05-30 2016-10-18 Pall Corporation Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (IVa)
US9193835B1 (en) 2014-05-30 2015-11-24 Pall Corporation Self-assembling polymers—IV
US9765171B2 (en) 2014-05-30 2017-09-19 Pall Corporation Self-assembling polymers—V
US9616395B2 (en) 2014-05-30 2017-04-11 Pall Corportaion Membrane comprising self-assembled block copolymer and process for producing the same by spray coating (Ic)
US9163122B1 (en) 2014-05-30 2015-10-20 Pall Corporation Self-assembling polymers—II
US9169361B1 (en) 2014-05-30 2015-10-27 Pall Corporation Self-assembling polymers—VI
US9604181B2 (en) 2014-05-30 2017-03-28 Pall Corporation Membrane comprising self-assembled block copolymer and process for producing the same by spray coating (IIc)
US9592477B2 (en) 2014-05-30 2017-03-14 Pall Corporation Membrane comprising self-assembled block copolymer and process for producing the same by hybrid casting (Ib)
US9593219B2 (en) 2014-05-30 2017-03-14 Pall Corporation Membrane comprising self-assembled block copolymer and process for producing the same by spin coating (IIa)
US9598543B2 (en) 2014-05-30 2017-03-21 Pall Corporation Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (VIa)
US9162189B1 (en) 2014-05-30 2015-10-20 Pall Corporation Membrane comprising self-assembled block copolymer and process for producing the same by spin coating (Ia)
US9328206B2 (en) 2014-05-30 2016-05-03 Pall Corporation Self-assembling polymers—III
US9592476B2 (en) 2014-05-30 2017-03-14 Pall Corporation Membrane comprising self-assembled block copolymer and process for producing the same by hybrid casting (IIb)
US9593218B2 (en) 2014-05-30 2017-03-14 Pall Corporation Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (IIIa)
US9303133B2 (en) 2014-06-30 2016-04-05 Pall Corporation Hydrophilic membranes and method of preparation thereof (IV)
US9260569B2 (en) 2014-06-30 2016-02-16 Pall Corporation Hydrophilic block copolymers and method of preparation thereof (III)
US9962662B2 (en) 2014-06-30 2018-05-08 Pall Corporation Fluorinated polymer and use thereof in the preparation of hydrophilic membranes (vi)
US9309367B2 (en) 2014-06-30 2016-04-12 Pall Corporation Membranes comprising cellulosic material and hydrophilic block copolymer (V)
US9254466B2 (en) 2014-06-30 2016-02-09 Pall Corporation Crosslinked cellulosic membranes
US9394407B2 (en) 2014-06-30 2016-07-19 Pall Corporation Hydrophilic block copolymers and membranes prepared therefrom (I)
US9718924B2 (en) 2014-06-30 2017-08-01 Pall Corporation Hydrophilic block copolymers and membranes prepared therefrom (II)
EP3164409B1 (en) * 2014-07-03 2021-09-01 Guang Ming Innovation Company (Wuhan) Group 8 transition metal catalysts and method for making same and process for use of same in metathesis reaction
EP3034486A1 (de) 2014-12-16 2016-06-22 LANXESS Deutschland GmbH 1,3-Butadien-Synthese
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
HUE054859T2 (hu) 2016-11-09 2021-10-28 Verbio Ver Bioenergie Ag Cserebomlási reakcióhoz alkalmazható ruténium komplexek
WO2019110658A1 (de) 2017-12-08 2019-06-13 Arlanxeo Deutschland Gmbh Verfahren zur herstellung von nitrilkautschuken mit ruthenium-komplexkatalysatoren
EP3728337B1 (en) 2017-12-18 2022-02-09 ARLANXEO Deutschland GmbH Hydrogenation of nitrile butadiene rubber latex
US11203679B2 (en) 2018-04-27 2021-12-21 Arlanxeo Deutschland Gmbh Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber
CN112469738B (zh) 2018-07-23 2023-03-10 阿朗新科德国有限责任公司 催化剂用于丁腈橡胶的复分解的用途
US11673130B2 (en) 2018-12-12 2023-06-13 Arlanxeo Deutschland Gmbh Catalyst system containing a metathesis catalyst and at least one phenolic compound and a process for metathesis of nitrile-butadiene rubber (NBR) using the catalyst system
EP3898706A1 (en) 2018-12-17 2021-10-27 ARLANXEO Deutschland GmbH Process for preparing hnbr solutions with alternative solvents

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60140455D1 (de) 2000-08-10 2009-12-24 Trustees Boston College Wiederverwendbare methathese-katalysatoren

Also Published As

Publication number Publication date
UY28020A1 (es) 2004-05-31
ZA200501533B (en) 2006-11-29
PL356652A1 (en) 2004-04-19
MEP51508A (en) 2011-02-10
US20040127350A1 (en) 2004-07-01
MXPA05003647A (es) 2005-06-08
PE20040510A1 (es) 2004-09-14
HRP20050339B1 (hr) 2013-07-31
HRP20050339A2 (en) 2006-05-31
JP4264418B2 (ja) 2009-05-20
CA2502342C (en) 2012-06-19
AU2003271713B2 (en) 2010-04-29
IL168002A (en) 2009-11-18
DK1554294T3 (da) 2006-11-06
MY127285A (en) 2006-11-30
JP2006503085A (ja) 2006-01-26
CA2502342A1 (en) 2004-04-29
EP1554294A1 (en) 2005-07-20
BR0314856B1 (pt) 2014-05-27
KR101057963B1 (ko) 2011-08-22
DE60306795T2 (de) 2006-11-16
NZ539944A (en) 2007-05-31
ECSP055653A (es) 2005-07-06
HK1070076A1 (en) 2005-06-10
DE60306795D1 (de) 2006-08-24
TW200420569A (en) 2004-10-16
ES2268412T3 (es) 2007-03-16
AU2003271713A1 (en) 2004-05-04
UA79018C2 (en) 2007-05-10
EP1554294B1 (en) 2006-07-12
DE20320324U1 (de) 2004-05-27
NO20051052L (no) 2005-05-11
KR20050061539A (ko) 2005-06-22
AR041620A1 (es) 2005-05-26
PL207783B1 (pl) 2011-02-28
CO5560614A2 (es) 2005-09-30
WO2004035596A1 (en) 2004-04-29
CN1571791A (zh) 2005-01-26
PL199412B1 (pl) 2008-09-30
US6867303B2 (en) 2005-03-15
ATE332906T1 (de) 2006-08-15
EA008352B1 (ru) 2007-04-27
NO335760B1 (no) 2015-02-09
RS20050287A (en) 2007-06-04
ME00345B (me) 2011-05-10
RS50334B (sr) 2009-11-10
PL374739A1 (en) 2005-10-31
TWI310768B (en) 2009-06-11
CN1291996C (zh) 2006-12-27
EA200500607A1 (ru) 2005-10-27

Similar Documents

Publication Publication Date Title
BR0314856A (pt) Complexos de rutênio como (pré) catalisadores para reações de metátese
BR9714925A (pt) Método para preparação de citalopran, composto e composição farmacêutica antidepressiva
ATE272066T1 (de) Metallkomplexe als hyrdosilylierungskatalysatoren
DE69610422T2 (de) Assymetrische synthese von (-) 6-chloro-4-cyclopropyl-ethynyl-4-trifluoromethyl-1,4-dihydro-2h-3,1-benzoxazin-2-on
DE60019381D1 (de) Katalysator verwendbar für die Oxidierung von Alkanen
BR9810341A (pt) Catalisadores de carbeno de rutênio e ósmio
PT1140956E (pt) Ligantes e complexos para a hidrogenacao enantiosselectiva
TW200716534A (en) Novel resorcinol derivatives
DE60205241D1 (de) Synthese von cannabinoiden
DE69808619D1 (de) Prostaglandin-pharmazeutische-zusammensetzungen
DE60034802D1 (de) Hydrierung von benzol zu cyclohexan
BR0212966A (pt) Fosfonita, uso da mesma, complexo de metal de transição, processo para a preparação e uso do mesmo, e, processos para a adição de ácido cianìdrico a uma ligação dupla olefìnica na presença de um catalisador, e para a isomerização de nitrilas orgânicas na presença de um catalisador
ATE517857T1 (de) Herstellung von 4-phenylbutansäure
CY1105526T1 (el) Διαδικασια συνθεσης και ενδιαμεσα της πυριδιν-2-υλ-μεθυναμινης
BR9804757A (pt) Processo para a hidrogenação de (co) polímetos de dienos
DE50214495D1 (de) Neue übergangsmetall-komplexe und deren einsatz in übergangsmetall-katalysierten reaktionen
DE69817282D1 (de) Neue Katalysatoren für die Umwandlungsreaktionen von organischen Verbindungen
BR0013292A (pt) Derivados de benzenamina como anti-coagulantes
ATE253026T1 (de) Verfahren zur oligomerisierung von c6-olefinen
DE602006017249D1 (de) Herstellung von katalysatoren
BR9803274A (pt) Composto metaloceno.
EA199900277A2 (ru) Способ алкилирования затрудненных сульфонамидов
BRPI0412656A (pt) flucorcombretastatina e derivados da mesma
ATE512155T1 (de) Derivate von 4,6-disubstituiertem 1,2,4-triazolo- 1,3,4-thiadiazol, ein verfahren und anwendungen davon
BR0008824A (pt) Processo para a oxidação em fase gasosa de um propano a acroleìna e/ou a ácido acrìlico sob catálise, heterogênea

Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 27/05/2014, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 18A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2640 DE 10-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.