BR0212966A - Fosfonita, uso da mesma, complexo de metal de transição, processo para a preparação e uso do mesmo, e, processos para a adição de ácido cianìdrico a uma ligação dupla olefìnica na presença de um catalisador, e para a isomerização de nitrilas orgânicas na presença de um catalisador - Google Patents

Fosfonita, uso da mesma, complexo de metal de transição, processo para a preparação e uso do mesmo, e, processos para a adição de ácido cianìdrico a uma ligação dupla olefìnica na presença de um catalisador, e para a isomerização de nitrilas orgânicas na presença de um catalisador

Info

Publication number
BR0212966A
BR0212966A BR0212966-3A BR0212966A BR0212966A BR 0212966 A BR0212966 A BR 0212966A BR 0212966 A BR0212966 A BR 0212966A BR 0212966 A BR0212966 A BR 0212966A
Authority
BR
Brazil
Prior art keywords
catalyst
phosphonite
processes
preparation
transition metal
Prior art date
Application number
BR0212966-3A
Other languages
English (en)
Other versions
BR0212966B1 (pt
Inventor
Michael Bartsch
Robert Baumann
Dagmar Pascale Kunsmann-Keitel
Gerd Haderlein
Tim Jungkamp
Marco Altmayer
Wolfgang Siegel
Ferenc Molnar
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR0212966A publication Critical patent/BR0212966A/pt
Publication of BR0212966B1 publication Critical patent/BR0212966B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4866—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the ester moiety containing a substituent or structure which is considered as characteristic
    • C07F9/4875—Esters with hydroxy aryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"FOSFONITA, USO DA MESMA, COMPLEXO DE METAL DE TRANSIçãO, PROCESSO PARA A PREPARAçãO E USO DO MESMO, E, PROCESSOS PARA A ADIçãO DE áCIDO CIANìDRICO A UMA LIGAçãO DUPLA OLEFìNICA NA PRESENçA DE UM CATALISADOR, E PARA A ISOMERIZAçãO DE NITRILAS ORGâNICAS NA PRESENçA DE UM CATALISADOR". Fosfonita da fórmula 1 ou 2, em que R1 e R2, independentemente um do outro, representam hidrogênio, um grupo alquila ou alquileno com de 1 a 8 átomos de carbono, ou um grupo alcóxi com de 1 a 8 átomos de carbono com a condição de que R1 e R2 não sejam simultaneamente H, R3 seja H ou metila, R4 seja t-butila, R5, R6, R7, R8, R9, independentemente um do outro, sejam H ou um grupo alquila ou alquileno com de 1 a 8 átomos de carbono.
BRPI0212966-3A 2001-10-12 2002-10-01 fosfonita, uso da mesma, complexo de metal de transição, processo para a preparação e uso do mesmo, e, processos para a adição de ácido cianìdrico a uma ligação dupla olefìnica na presença de um catalisador, e para a isomerização de nitrilas orgánicas na presença de um catalisador. BR0212966B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10150285A DE10150285A1 (de) 2001-10-12 2001-10-12 Phosphonite
DE10150285.0 2001-10-12
PCT/EP2002/010985 WO2003033141A1 (de) 2001-10-12 2002-10-01 Phosphonite

Publications (2)

Publication Number Publication Date
BR0212966A true BR0212966A (pt) 2004-10-13
BR0212966B1 BR0212966B1 (pt) 2012-11-27

Family

ID=7702231

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0212966-3A BR0212966B1 (pt) 2001-10-12 2002-10-01 fosfonita, uso da mesma, complexo de metal de transição, processo para a preparação e uso do mesmo, e, processos para a adição de ácido cianìdrico a uma ligação dupla olefìnica na presença de um catalisador, e para a isomerização de nitrilas orgánicas na presença de um catalisador.

Country Status (14)

Country Link
US (1) US7022866B2 (pt)
EP (1) EP1438132B1 (pt)
JP (1) JP4128141B2 (pt)
KR (1) KR100899463B1 (pt)
CN (1) CN1260009C (pt)
AR (1) AR036637A1 (pt)
AT (1) ATE360481T1 (pt)
BR (1) BR0212966B1 (pt)
CA (1) CA2462719A1 (pt)
DE (2) DE10150285A1 (pt)
ES (1) ES2284977T3 (pt)
MX (1) MXPA04002437A (pt)
MY (1) MY128709A (pt)
WO (1) WO2003033141A1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10136488A1 (de) * 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
MY138064A (en) 2002-01-24 2009-04-30 Basf Ag Method for the separation of acids from chemical reaction mixtures by means of ionic fluids
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE102004004718A1 (de) 2004-01-29 2005-08-18 Basf Ag Verfahren zur Hydrocyanierung
WO2007046799A1 (en) 2005-10-18 2007-04-26 Invista Technologies S.A R.L. Process of making 3-aminopentanenitrile
EP1996598B1 (en) 2006-03-17 2013-10-16 Invista Technologies S.à.r.l. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US8906334B2 (en) 2007-05-14 2014-12-09 Invista North America S.A R.L. High efficiency reactor and process
EP2164587B1 (en) 2007-06-13 2018-04-04 INVISTA Textiles (U.K.) Limited Process for improving adiponitrile quality
EP2229353B1 (en) 2008-01-15 2018-01-03 INVISTA Textiles (U.K.) Limited Hydrocyanation of pentenenitriles
EP2229354B1 (en) 2008-01-15 2013-03-20 Invista Technologies S.à.r.l. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
WO2009117498A2 (en) * 2008-03-19 2009-09-24 Invista Technologies S.A R.L. Methods of making cyclododecatriene and methods of making laurolactone
JP5619753B2 (ja) 2008-10-14 2014-11-05 インヴィスタテクノロジーズ エスアエルエル ２−第二級−アルキル−４，５−ジ−（直鎖−アルキル）フェノール類を製造する方法
EP2462103A4 (en) 2009-08-07 2014-01-08 Invista Tech Sarl HYDROGENATION AND ESTERIFICATION TO FORM DIESTERS
EP2574190B1 (en) 2010-07-07 2014-01-22 Invista Technologies S.à.r.l. Process for making nitriles
US9024049B2 (en) 2010-09-07 2015-05-05 Invista North America S.A.R.L. Nickel compositions for preparing nickel metal and nickel complexes
CN104662029A (zh) * 2012-06-01 2015-05-27 因温斯特技术公司 稳定的氢氰化配体组合物

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GB1112539A (en) 1965-11-26 1968-05-08 Du Pont Preparation of organic nitriles
US3496217A (en) 1967-05-23 1970-02-17 Du Pont Hydrocyanation of olefins
US3798256A (en) 1971-08-02 1974-03-19 Du Pont Hydrocyanation of olefins
US3766237A (en) 1972-01-25 1973-10-16 Du Pont Hydrocyanation of olefins
US3903120A (en) 1973-06-19 1975-09-02 Du Pont Preparation of zerovalent nickel complexes from elemental nickel
US3850973A (en) 1973-09-26 1974-11-26 Du Pont Hydrocyanation of conjugated diolefins
US4493906A (en) 1983-03-08 1985-01-15 The Dow Chemical Company Catalyst for the selective hydrogenation of acetylenes
FR2553760B1 (fr) 1983-10-25 1986-05-02 Inst Francais Du Petrole Procede d'hydrogenation selective en presence de solvant des composes acetyleniques d'une coupe d'hydrocarbures c4 riche en butadiene
US4774353A (en) 1986-06-05 1988-09-27 E. I. Du Pont De Nemours And Company Triorganotin catalyst promoters for hydrocyanation
US4704492A (en) 1986-12-24 1987-11-03 Mobil Oil Corporation Selective hydrogenation of acetylenic impurities in crude butadiene
US4874884A (en) 1988-03-31 1989-10-17 E. I. Du Pont De Nemours And Company Promoter synergism in pentenenitrile hydrocyanation
US5523453A (en) 1995-03-22 1996-06-04 E. I. Du Pont De Nemours And Company Process for hydrocyanation
US5693843A (en) 1995-12-22 1997-12-02 E. I. Du Pont De Nemours And Company Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles
US6171966B1 (en) 1996-08-15 2001-01-09 Applied Materials, Inc. Delineation pattern for epitaxial depositions
ZA986369B (en) 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
MY124170A (en) 1997-07-29 2006-06-30 Invista Tech Sarl Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor
DE19825212A1 (de) 1998-06-05 1999-12-09 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
EP0983945A1 (de) 1998-09-03 2000-03-08 Crown Cork & Seal Technologies Corporation Verfahren zum Herstellen einer Verschlusskappe und Verschlusskappe

Also Published As

Publication number Publication date
US20040235648A1 (en) 2004-11-25
MY128709A (en) 2007-02-28
KR100899463B1 (ko) 2009-05-26
MXPA04002437A (es) 2004-06-29
CA2462719A1 (en) 2003-04-24
EP1438132A1 (de) 2004-07-21
CN1260009C (zh) 2006-06-21
DE50210044D1 (de) 2007-06-06
CN1568226A (zh) 2005-01-19
JP2005505610A (ja) 2005-02-24
US7022866B2 (en) 2006-04-04
BR0212966B1 (pt) 2012-11-27
JP4128141B2 (ja) 2008-07-30
ATE360481T1 (de) 2007-05-15
EP1438132B1 (de) 2007-04-25
KR20040048947A (ko) 2004-06-10
WO2003033141A1 (de) 2003-04-24
DE10150285A1 (de) 2003-04-17
ES2284977T3 (es) 2007-11-16
AR036637A1 (es) 2004-09-22

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B15K Others concerning applications: alteration of classification

Free format text: PARA:INT.CI. B01J 31/18, B01J 31/22, C07C 253/10, C07C 253/30, C07F 9/18

Ipc: B01J 31/18 (2006.01), B01J 31/22 (2006.01), C07C 2

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 27/11/2012, MEDIANTE O RECOLHIMENTO DA TAXA QUINQUENAL DE MANUTENCAO (ARTIGOS 119 E 120 DA LPI) E OBSERVADAS AS DEMAIS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)