BR9910956A - Catalisador, ligante fosfonito, processos para a preparação de uma mistura de c5-mononitrilas monoolefìnicas, para a isomerização catalìtica de monoalqueno-nitrilas alifáticas ramificadas, e para a preparação de adipodinitrila, e, uso de um catalisador. - Google Patents

Catalisador, ligante fosfonito, processos para a preparação de uma mistura de c5-mononitrilas monoolefìnicas, para a isomerização catalìtica de monoalqueno-nitrilas alifáticas ramificadas, e para a preparação de adipodinitrila, e, uso de um catalisador.

Info

Publication number
BR9910956A
BR9910956A BR9910956-5A BR9910956A BR9910956A BR 9910956 A BR9910956 A BR 9910956A BR 9910956 A BR9910956 A BR 9910956A BR 9910956 A BR9910956 A BR 9910956A
Authority
BR
Brazil
Prior art keywords
preparation
catalyst
adipodinitrile
monoalkylene
nitriles
Prior art date
Application number
BR9910956-5A
Other languages
English (en)
Other versions
BR9910956B1 (pt
Inventor
Jakob Fischer
Wolfgang Siegel
Dagmar Pascale Keitel
Lorenz Siggel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR9910956A publication Critical patent/BR9910956A/pt
Publication of BR9910956B1 publication Critical patent/BR9910956B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4866—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the ester moiety containing a substituent or structure which is considered as characteristic
    • C07F9/4875—Esters with hydroxy aryl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"CATALISADOR, LIGANTE FOSFONITO, PROCESSOS PARA A PREPARAçãO DE UMA MISTURA DE C~ 5~-MONONITRILAS MONOOLEFìNICAS, PARA A ISOMERIZAçãO CATALìTICA DE MONOALQUENO-NITRILAS ALIFáTICAS RAMIFICADAS, E PARA A PREPARAçãO DE ADIPODINITRILA, E, USO DE UM CATALISADOR". A invenção refere-se a um catalisador compreendendo pelo menos um metal do subgrupo VIII com pelo menos um ligante fosfonito bidentado de fórmula geral (I) ou seus sais ou suas misturas, a um processo para produção de misturas de C~ 5~-mononitrilas, a um processo para a isomerização catalítica de monoalqueno-nitrilas alifáticas ramificadas e a um processo para produção de adipodinitrila.
BRPI9910956-5A 1998-06-05 1999-06-04 catalisador, ligante fosfonito, processos para a preparação de uma mistura de c5-mononitrilas monoolefìnicas, para a isomerização catalìtica de monoalqueno-nitrilas alifáticas ramificadas, e para a preparação de adipodinitrila, e, uso de um catalisador. BR9910956B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19825212A DE19825212A1 (de) 1998-06-05 1998-06-05 Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
PCT/EP1999/003888 WO1999064155A1 (de) 1998-06-05 1999-06-04 Katalysator, umfassend einen komplex eines metalls der viii. nebengruppe auf basis eines zweizähnigen phosphonitliganden und verfahren zur herstellung von nitrilen

Publications (2)

Publication Number Publication Date
BR9910956A true BR9910956A (pt) 2001-03-13
BR9910956B1 BR9910956B1 (pt) 2010-11-16

Family

ID=7870052

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9910956-5A BR9910956B1 (pt) 1998-06-05 1999-06-04 catalisador, ligante fosfonito, processos para a preparação de uma mistura de c5-mononitrilas monoolefìnicas, para a isomerização catalìtica de monoalqueno-nitrilas alifáticas ramificadas, e para a preparação de adipodinitrila, e, uso de um catalisador.

Country Status (16)

Country Link
US (1) US6521778B1 (pt)
EP (1) EP1091804B1 (pt)
JP (1) JP4480058B2 (pt)
KR (1) KR100576667B1 (pt)
CN (1) CN1159106C (pt)
AR (1) AR018438A1 (pt)
BR (1) BR9910956B1 (pt)
CA (1) CA2334151C (pt)
DE (2) DE19825212A1 (pt)
ES (1) ES2173750T3 (pt)
ID (1) ID27071A (pt)
MY (1) MY120574A (pt)
RU (1) RU2223146C2 (pt)
TR (1) TR200003625T2 (pt)
TW (1) TW519496B (pt)
WO (1) WO1999064155A1 (pt)

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DE10150285A1 (de) * 2001-10-12 2003-04-17 Basf Ag Phosphonite
DE10156292A1 (de) * 2001-11-19 2003-05-28 Basf Ag Verfahren zur Herstellung von Organodiphosphoniten
US6660876B2 (en) 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
MY138064A (en) 2002-01-24 2009-04-30 Basf Ag Method for the separation of acids from chemical reaction mixtures by means of ionic fluids
US6660877B2 (en) 2002-03-07 2003-12-09 E. I. Du Pont De Nemours And Company Phosphonite ligands and their use in hydrocyanation
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE10350999A1 (de) 2003-10-30 2005-06-02 Basf Ag Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen
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WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
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FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
EP2257516A4 (en) * 2008-03-19 2012-12-12 Invista Tech Sarl METHOD FOR THE PRODUCTION OF CYCLODODECATRIOS AND METHOD FOR THE PRODUCTION OF LAUROLACTONE
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
EP2334624B1 (en) 2008-10-14 2014-10-01 Invista Technologies S.à.r.l. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
CN102471218B (zh) 2009-08-07 2014-11-05 因温斯特技术公司 用于形成二酯的氢化并酯化
CN103502206B (zh) 2010-07-07 2016-01-13 因温斯特技术公司 用于制备腈的方法
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Also Published As

Publication number Publication date
CA2334151C (en) 2007-10-23
CN1159106C (zh) 2004-07-28
AR018438A1 (es) 2001-11-14
BR9910956B1 (pt) 2010-11-16
EP1091804A1 (de) 2001-04-18
TR200003625T2 (tr) 2001-04-20
US6521778B1 (en) 2003-02-18
JP4480058B2 (ja) 2010-06-16
JP2002517473A (ja) 2002-06-18
TW519496B (en) 2003-02-01
RU2223146C2 (ru) 2004-02-10
WO1999064155A1 (de) 1999-12-16
EP1091804B1 (de) 2002-02-27
DE59900903D1 (de) 2002-04-04
ES2173750T3 (es) 2002-10-16
ID27071A (id) 2001-02-22
CA2334151A1 (en) 1999-12-16
DE19825212A1 (de) 1999-12-09
CN1304334A (zh) 2001-07-18
KR100576667B1 (ko) 2006-05-08
KR20010052561A (ko) 2001-06-25
MY120574A (en) 2005-11-30

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