BR9812207A - Catalisador, processos para preparar um catalisador, misturas de mononitrilas c5 monoolefìnicas e adiponitrila, e, uso de catalisadores - Google Patents
Catalisador, processos para preparar um catalisador, misturas de mononitrilas c5 monoolefìnicas e adiponitrila, e, uso de catalisadoresInfo
- Publication number
- BR9812207A BR9812207A BR9812207-0A BR9812207A BR9812207A BR 9812207 A BR9812207 A BR 9812207A BR 9812207 A BR9812207 A BR 9812207A BR 9812207 A BR9812207 A BR 9812207A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- catalysts
- mixtures
- monoolefins
- processes
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 150000005673 monoalkenes Chemical class 0.000 title abstract 2
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 238000005669 hydrocyanation reaction Methods 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
- C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/65719—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and, at least, one ring oxygen atom being part of a (thio)phosphonous acid derivative
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"CATALISADOR, PROCESSOS PARA PREPARAR UM CATALISADOR, MISTURAS DE MONONITRILAS C~ 5~ MONOOLEFìNICAS E ADIPONITRILA, E, USO DE CATALISADORES". A invenção refere-se a um catalisador compreendendo pelo menos um complexo de níquel (O) contendo pelo menos um ligando de fosfonito monodentado, bidentado ou multidentado de fórmula geral (I) ou seus sais ou misturas. A invenção também refere-se a um processo para produzir ditos catalisadores e a um processo para produzir mononitrilas-C~ 5~ monoolefínicas com uma ligação C=C e C<154>N, por hidrocianação catalítica de butadieno ou uma mistura hidrocarbonada contendo 1,3-butadieno, caracterizado pelo fato de que a hidrocianação ocorre na presença de um tal catalisador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19740180A DE19740180A1 (de) | 1997-09-12 | 1997-09-12 | Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
PCT/EP1998/005733 WO1999013983A1 (de) | 1997-09-12 | 1998-09-09 | Katalysator, umfassend wenigstens einen nickel(o)komplex auf basis eines phosphonitliganden und verfahren zur herstellung von nitrilen |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9812207A true BR9812207A (pt) | 2000-07-18 |
Family
ID=7842178
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9812207-0A BR9812207A (pt) | 1997-09-12 | 1998-09-09 | Catalisador, processos para preparar um catalisador, misturas de mononitrilas c5 monoolefìnicas e adiponitrila, e, uso de catalisadores |
Country Status (15)
Country | Link |
---|---|
US (2) | US6242633B1 (pt) |
EP (1) | EP1019190B1 (pt) |
JP (1) | JP2001516640A (pt) |
KR (1) | KR100555259B1 (pt) |
CN (1) | CN1222358C (pt) |
AR (1) | AR017076A1 (pt) |
AU (1) | AU9538598A (pt) |
BR (1) | BR9812207A (pt) |
CA (1) | CA2303776A1 (pt) |
DE (2) | DE19740180A1 (pt) |
ES (1) | ES2234158T3 (pt) |
ID (1) | ID24451A (pt) |
MY (1) | MY118720A (pt) |
TW (1) | TW400249B (pt) |
WO (1) | WO1999013983A1 (pt) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19810794A1 (de) * | 1998-03-12 | 1999-09-16 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phosphonitliganden und Verfahren zur Hydroformylierung |
DE19825212A1 (de) | 1998-06-05 | 1999-12-09 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
RU2226228C2 (ru) * | 1999-08-20 | 2004-03-27 | Дю Пон Де Немур Энтернасьональ С.А. | Способ электрохимического получения ni(о) фосфитных и дифосфитных комплексов |
DE10049265A1 (de) * | 2000-09-28 | 2002-04-11 | Basf Ag | Verfahren zur Trennung von Pentennitril-Isomeren |
DE10136488A1 (de) * | 2001-07-27 | 2003-02-06 | Basf Ag | Ni(O) enthaltendes Katalysatorsystem |
DE10150286A1 (de) * | 2001-10-12 | 2003-04-17 | Basf Ag | Phosphinite |
US6660876B2 (en) | 2001-11-26 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
MY138064A (en) * | 2002-01-24 | 2009-04-30 | Basf Ag | Method for the separation of acids from chemical reaction mixtures by means of ionic fluids |
TW504991U (en) * | 2002-01-31 | 2002-10-01 | Kuo-Chan Weng | Inner lock device for sliding rail of drawer |
US6660877B2 (en) | 2002-03-07 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphonite ligands and their use in hydrocyanation |
EP1344770A1 (en) * | 2002-03-12 | 2003-09-17 | E.I. du Pont de Nemours and Company | Process for the hydrocyanation of butadiene |
FR2850966B1 (fr) | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
DE10311122A1 (de) * | 2003-03-12 | 2004-09-23 | Basf Ag | Verfahren zur Hydrocyanierung einer olefinisch ungesättigten Verbindung |
FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
DE10350999A1 (de) | 2003-10-30 | 2005-06-02 | Basf Ag | Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen |
DE102004004718A1 (de) * | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Hydrocyanierung |
DE102004004682A1 (de) | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Herstellung von Adipodinitril durch Hydrocyanierung von 1,3-Butadien |
DE102004004721A1 (de) * | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Trennung von Pentennitril-Isomeren |
JP4509125B2 (ja) * | 2004-01-29 | 2010-07-21 | ビーエーエスエフ ソシエタス・ヨーロピア | 直鎖のペンテンニトリルの製造方法 |
DE102004004697A1 (de) * | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Herstellung von Pentennitrilen aus n-Butan |
EP2322503B1 (en) | 2005-10-18 | 2014-12-31 | Invista Technologies S.à.r.l. | Process of making 3-aminopentanenitrile |
KR20080104315A (ko) * | 2006-03-17 | 2008-12-02 | 인비스타 테크놀러지스 에스.에이.알.엘 | 염기성 첨가제를 사용한 처리에 의한 트리오르가노포스파이트의 정제 방법 |
US7880028B2 (en) * | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
US7709674B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L | Hydrocyanation process with reduced yield losses |
US7919646B2 (en) * | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
US8906334B2 (en) | 2007-05-14 | 2014-12-09 | Invista North America S.A R.L. | High efficiency reactor and process |
US8101790B2 (en) | 2007-06-13 | 2012-01-24 | Invista North America S.A.R.L. | Process for improving adiponitrile quality |
WO2009091790A1 (en) | 2008-01-15 | 2009-07-23 | Invista Technologies S.A.R.L. | Hydrocyanation of pentenenitriles |
EP2229354B1 (en) | 2008-01-15 | 2013-03-20 | Invista Technologies S.à.r.l. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
EP2407444A3 (en) * | 2008-03-19 | 2012-12-05 | Invista Technologies S.à.r.l. | Process for the preparation of dodecanedioic acid |
WO2010045131A1 (en) | 2008-10-14 | 2010-04-22 | Invista Technologies S.A.R.L. | Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols |
FR2946649B1 (fr) * | 2009-06-16 | 2012-04-13 | Rhodia Operations | Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique |
KR20120047251A (ko) | 2009-08-07 | 2012-05-11 | 인비스타 테크놀러지스 에스.에이.알.엘. | 디에스테르를 형성하기 위한 수소화 및 에스테르화 |
US8815186B2 (en) | 2009-12-18 | 2014-08-26 | Invista North America S.A.R.L. | Nickel compositions for preparing nickel metal and nickel complexes |
KR20130041172A (ko) | 2010-07-07 | 2013-04-24 | 인비스타 테크놀러지스 에스.에이.알.엘. | 니트릴의 제조 방법 |
DK2614070T3 (en) | 2010-09-07 | 2017-10-16 | Invista Technologies Sarl | NICKEL COMPOSITIONS FOR THE MANUFACTURE OF NICKEL METAL AND NICKEL COMPLEXS |
CN106957244B (zh) * | 2012-06-01 | 2020-05-29 | 英威达纺织(英国)有限公司 | 稳定氢氰化催化剂的方法 |
US9406974B2 (en) * | 2013-04-25 | 2016-08-02 | Samsung Sdi Co., Ltd. | Additive for electrolyte of lithium battery, organic electrolytic solution comprising the same, and lithium battery using the organic electrolytic solution |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2161750A1 (de) | 1971-12-13 | 1973-06-14 | Henkel & Cie Gmbh | Verfahren zur herstellung von tertiaeren aminen |
US3766237A (en) | 1972-01-25 | 1973-10-16 | Du Pont | Hydrocyanation of olefins |
US5175335A (en) | 1991-11-12 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Enantioselective hydrocyanation of aromatic vinyl compounds |
DE4321194A1 (de) | 1993-06-25 | 1995-01-05 | Basf Ag | Phosphorhaltige Calixarene |
US5597569A (en) * | 1993-10-25 | 1997-01-28 | Bristol-Myers Squibb Company | Bryodin 2 a ribosome-inactivating protein isolated from the plant Bryonia dioica |
WO1995028228A1 (en) | 1994-04-14 | 1995-10-26 | E.I. Du Pont De Nemours And Company | Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins |
US5512695A (en) | 1994-04-14 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins |
US5543536A (en) * | 1994-04-26 | 1996-08-06 | E. I. Du Pont De Nemours And Company | Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation |
US5600032A (en) * | 1994-06-29 | 1997-02-04 | Mitsubishi Chemical Corporation | Method for producing an unsaturated alcohol |
TW315370B (pt) | 1994-10-07 | 1997-09-11 | Du Pont | |
IN187044B (pt) * | 1995-01-27 | 2002-01-05 | Du Pont | |
US5523453A (en) | 1995-03-22 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation |
-
1997
- 1997-09-12 DE DE19740180A patent/DE19740180A1/de not_active Withdrawn
-
1998
- 1998-09-08 AR ARP980104469A patent/AR017076A1/es unknown
- 1998-09-09 ID IDW20000485A patent/ID24451A/id unknown
- 1998-09-09 JP JP2000511587A patent/JP2001516640A/ja not_active Withdrawn
- 1998-09-09 BR BR9812207-0A patent/BR9812207A/pt not_active Application Discontinuation
- 1998-09-09 WO PCT/EP1998/005733 patent/WO1999013983A1/de active IP Right Grant
- 1998-09-09 CA CA002303776A patent/CA2303776A1/en not_active Abandoned
- 1998-09-09 DE DE59812339T patent/DE59812339D1/de not_active Expired - Fee Related
- 1998-09-09 KR KR1020007002600A patent/KR100555259B1/ko not_active IP Right Cessation
- 1998-09-09 CN CNB988090449A patent/CN1222358C/zh not_active Expired - Fee Related
- 1998-09-09 ES ES98948941T patent/ES2234158T3/es not_active Expired - Lifetime
- 1998-09-09 EP EP98948941A patent/EP1019190B1/de not_active Expired - Lifetime
- 1998-09-09 US US09/508,051 patent/US6242633B1/en not_active Expired - Fee Related
- 1998-09-09 TW TW087114963A patent/TW400249B/zh not_active IP Right Cessation
- 1998-09-09 AU AU95385/98A patent/AU9538598A/en not_active Abandoned
- 1998-09-10 MY MYPI98004153A patent/MY118720A/en unknown
-
2001
- 2001-02-14 US US09/782,762 patent/US6355833B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2303776A1 (en) | 1999-03-25 |
EP1019190B1 (de) | 2004-12-01 |
MY118720A (en) | 2005-01-31 |
DE59812339D1 (de) | 2005-01-05 |
DE19740180A1 (de) | 1999-03-18 |
TW400249B (en) | 2000-08-01 |
KR100555259B1 (ko) | 2006-03-03 |
US20010014647A1 (en) | 2001-08-16 |
EP1019190A1 (de) | 2000-07-19 |
US6242633B1 (en) | 2001-06-05 |
AU9538598A (en) | 1999-04-05 |
AR017076A1 (es) | 2001-08-22 |
ES2234158T3 (es) | 2005-06-16 |
WO1999013983A1 (de) | 1999-03-25 |
CN1270543A (zh) | 2000-10-18 |
ID24451A (id) | 2000-07-20 |
US6355833B2 (en) | 2002-03-12 |
JP2001516640A (ja) | 2001-10-02 |
CN1222358C (zh) | 2005-10-12 |
KR20010023912A (ko) | 2001-03-26 |
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