AR047116A1 - Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo - Google Patents

Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo

Info

Publication number
AR047116A1
AR047116A1 ARP040104013A ARP040104013A AR047116A1 AR 047116 A1 AR047116 A1 AR 047116A1 AR P040104013 A ARP040104013 A AR P040104013A AR P040104013 A ARP040104013 A AR P040104013A AR 047116 A1 AR047116 A1 AR 047116A1
Authority
AR
Argentina
Prior art keywords
preparation
ligands
nickel
phosphory
procedure
Prior art date
Application number
ARP040104013A
Other languages
English (en)
Inventor
Gerd Haderlein
Robert Baumann
Michael Bartsch
Dieter Jung
Hermann Luyken
Jens Scheidel
Wolfgang Siegel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of AR047116A1 publication Critical patent/AR047116A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Powder Metallurgy (AREA)

Abstract

Reivindicacion 1: Procedimiento para la preparacion de un complejo de níquel (0) con ligandos de fosforo, que contiene al menos un átomo central de níquel y al menos un ligando con contenido de fosforo, caracterizado porque un aducto de níquel (II)- éter es reducido en presencia de al menos un ligando con contenido de fosforo. Reivindicacion 11: Uso de las mezclas que contienen complejos de níquel (0) con ligandos de fosforo de acuerdo con la reivindicacion 10 en la hidrocianacion y la isomerizacion de alquenos y en la hidrocianacion y la isomerizacion de nitrilos no saturados.
ARP040104013A 2003-10-30 2004-11-01 Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo AR047116A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10351003A DE10351003A1 (de) 2003-10-30 2003-10-30 Verfahren zur Herstellung von Nickel-Phosphorligand-Komplexen

Publications (1)

Publication Number Publication Date
AR047116A1 true AR047116A1 (es) 2006-01-11

Family

ID=34485179

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP040104013A AR047116A1 (es) 2003-10-30 2004-11-01 Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo

Country Status (11)

Country Link
US (1) US20070083057A1 (es)
EP (1) EP1682270A2 (es)
JP (1) JP2007509888A (es)
KR (1) KR20060120174A (es)
CN (1) CN1874844A (es)
AR (1) AR047116A1 (es)
BR (1) BRPI0415975A (es)
CA (1) CA2542994A1 (es)
DE (1) DE10351003A1 (es)
TW (1) TW200533674A (es)
WO (1) WO2005042157A2 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2850966B1 (fr) * 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
WO2007046799A1 (en) 2005-10-18 2007-04-26 Invista Technologies S.A R.L. Process of making 3-aminopentanenitrile
EP1825914A1 (de) 2006-02-22 2007-08-29 Basf Aktiengesellschaft Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen
EP1996598B1 (en) * 2006-03-17 2013-10-16 Invista Technologies S.à.r.l. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US8906334B2 (en) 2007-05-14 2014-12-09 Invista North America S.A R.L. High efficiency reactor and process
EP2164587B1 (en) 2007-06-13 2018-04-04 INVISTA Textiles (U.K.) Limited Process for improving adiponitrile quality
EP2229353B1 (en) * 2008-01-15 2018-01-03 INVISTA Textiles (U.K.) Limited Hydrocyanation of pentenenitriles
EP2229354B1 (en) 2008-01-15 2013-03-20 Invista Technologies S.à.r.l. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
WO2009117498A2 (en) * 2008-03-19 2009-09-24 Invista Technologies S.A R.L. Methods of making cyclododecatriene and methods of making laurolactone
JP5619753B2 (ja) 2008-10-14 2014-11-05 インヴィスタテクノロジーズ エスアエルエル ２−第二級−アルキル−４，５−ジ−（直鎖−アルキル）フェノール類を製造する方法
EP2462103A4 (en) * 2009-08-07 2014-01-08 Invista Tech Sarl HYDROGENATION AND ESTERIFICATION TO FORM DIESTERS
EP2574190B1 (en) 2010-07-07 2014-01-22 Invista Technologies S.à.r.l. Process for making nitriles
CN108002970A (zh) * 2017-12-26 2018-05-08 濮阳盛华德化工有限公司 一种1,5-环辛二烯的制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE758083A (fr) * 1969-10-27 1971-04-27 Int Nickel Ltd Stabilisants et leur preparation
US3624116A (en) * 1969-11-03 1971-11-30 Int Nickel Co Nickel derivatives of methylene bis-salicylic acid and process for preparing the same
US3846461A (en) * 1972-10-25 1974-11-05 Du Pont Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US3903120A (en) * 1973-06-19 1975-09-02 Du Pont Preparation of zerovalent nickel complexes from elemental nickel
US5523453A (en) * 1995-03-22 1996-06-04 E. I. Du Pont De Nemours And Company Process for hydrocyanation
US6557358B2 (en) * 2001-06-28 2003-05-06 Kendro Laboratory Products, Inc. Non-hydrocarbon ultra-low temperature system for a refrigeration system
US6893996B2 (en) * 2001-11-26 2005-05-17 Invista North America S.A.R.L. Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation

Also Published As

Publication number Publication date
TW200533674A (en) 2005-10-16
DE10351003A1 (de) 2005-05-25
EP1682270A2 (de) 2006-07-26
KR20060120174A (ko) 2006-11-24
BRPI0415975A (pt) 2007-01-23
WO2005042157A2 (de) 2005-05-12
US20070083057A1 (en) 2007-04-12
WO2005042157A3 (de) 2005-07-21
CA2542994A1 (en) 2005-05-12
JP2007509888A (ja) 2007-04-19
CN1874844A (zh) 2006-12-06

Similar Documents

Publication Publication Date Title
AR047116A1 (es) Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo
MY120453A (en) Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenesnitriles.
AR046826A1 (es) Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo, mezcla obtenida por dicho procedimiento y uso de dicha mezcla en hidrocianacion e isomerizacion de alquenos y de nitrilos no saturados.
BR9812207A (pt) Catalisador, processos para preparar um catalisador, misturas de mononitrilas c5 monoolefìnicas e adiponitrila, e, uso de catalisadores
DE69627207T2 (de) Verfahren zur Herstellung von Phosphorochloriditen
MY116491A (en) Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
ATE181321T1 (de) Katalysatorzusammensetzung aus einzähningen phosphiteliganden und nickel zur hydrocyanierung von monoolefinen
BR9510347A (pt) Processo para a hidrocianação de fase gasosa de compostos diolefínicos
AR046569A1 (es) Uso de halogenuros de niquel (ii) secados por el metodo azeotropico
BR9810978A (pt) Processos para preparar misturas de mononitrilas e para preparar adiponitrila, e, uso de catalisadores
ATE193292T1 (de) Sulfonierte phenylphosphane enthaltende komplexverbindungen
MY136308A (en) Supported bis(phosphorus) ligands
CA2237033A1 (en) Improved process for hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
AR036637A1 (es) Fosfonitas, quelatos de fosfonitas, procedimiento para su obtencion, el uso de las mismas como ligandos en complejos de metal de transicion, la utilizacion de los complejos como catalizadores y los procedimientos en presencia de tales complejos de metal transitorio como catalizadores
ATE457028T1 (de) Nickel komplexe mit phosphitliganden
ES2078228T3 (es) Fosfitos ionicos y su uso en procedimientos catalizados por metales de transicion homogeneos.
AR048153A1 (es) Procedimiento continuo para la preparacion de pentenonitrilos lineales
ES2180335T3 (es) Ligandos y complejos para la hidrogenacion enantioselectiva.
DE69510816D1 (de) Katalysierte gasphasenisomerisierung von nicht konjugierten 2-alkyl-3-monoalkennitrilen
BRPI0511027A (pt) ligantes de cicloolefina fosfina e seu uso em catálise
ES2107904T3 (es) Complejos metalicos de macromoleculas dendrimeras, agentes de diagnostico que los contienen asi como procedimiento para la preparacion de los complejos y agentes.
MY125822A (en) Hydrocyanation of olefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
EP0982314A3 (de) Valeraldehyd und Verfahren zu seiner Herstellung
MY139556A (en) Catalyzed vapor-phase hydrocyanation of diolefinic compounds
ES2132508T3 (es) Procedimiento para la produccion de aldehidos.

Legal Events

Date Code Title Description
FB Suspension of granting procedure