AR047116A1 - Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo - Google Patents
Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforoInfo
- Publication number
- AR047116A1 AR047116A1 ARP040104013A ARP040104013A AR047116A1 AR 047116 A1 AR047116 A1 AR 047116A1 AR P040104013 A ARP040104013 A AR P040104013A AR P040104013 A ARP040104013 A AR P040104013A AR 047116 A1 AR047116 A1 AR 047116A1
- Authority
- AR
- Argentina
- Prior art keywords
- preparation
- ligands
- nickel
- phosphory
- procedure
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract 4
- 239000011574 phosphorus Substances 0.000 abstract 4
- 150000002815 nickel Chemical group 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 238000005669 hydrocyanation reaction Methods 0.000 abstract 2
- 238000006317 isomerization reaction Methods 0.000 abstract 2
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
- C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
Abstract
Reivindicacion 1: Procedimiento para la preparacion de un complejo de níquel (0) con ligandos de fosforo, que contiene al menos un átomo central de níquel y al menos un ligando con contenido de fosforo, caracterizado porque un aducto de níquel (II)- éter es reducido en presencia de al menos un ligando con contenido de fosforo. Reivindicacion 11: Uso de las mezclas que contienen complejos de níquel (0) con ligandos de fosforo de acuerdo con la reivindicacion 10 en la hidrocianacion y la isomerizacion de alquenos y en la hidrocianacion y la isomerizacion de nitrilos no saturados.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10351003A DE10351003A1 (de) | 2003-10-30 | 2003-10-30 | Verfahren zur Herstellung von Nickel-Phosphorligand-Komplexen |
Publications (1)
Publication Number | Publication Date |
---|---|
AR047116A1 true AR047116A1 (es) | 2006-01-11 |
Family
ID=34485179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP040104013A AR047116A1 (es) | 2003-10-30 | 2004-11-01 | Procedimiento para la preparacion de complejos de niquel (0) con ligandos de fosforo |
Country Status (11)
Country | Link |
---|---|
US (1) | US20070083057A1 (es) |
EP (1) | EP1682270A2 (es) |
JP (1) | JP2007509888A (es) |
KR (1) | KR20060120174A (es) |
CN (1) | CN1874844A (es) |
AR (1) | AR047116A1 (es) |
BR (1) | BRPI0415975A (es) |
CA (1) | CA2542994A1 (es) |
DE (1) | DE10351003A1 (es) |
TW (1) | TW200533674A (es) |
WO (1) | WO2005042157A2 (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2850966B1 (fr) * | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
WO2007046799A1 (en) | 2005-10-18 | 2007-04-26 | Invista Technologies S.A R.L. | Process of making 3-aminopentanenitrile |
EP1825914A1 (de) | 2006-02-22 | 2007-08-29 | Basf Aktiengesellschaft | Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen |
EP1996598B1 (en) * | 2006-03-17 | 2013-10-16 | Invista Technologies S.à.r.l. | Method for the purification of triorganophosphites by treatment with a basic additive |
US7880028B2 (en) | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
US7919646B2 (en) | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
US8906334B2 (en) | 2007-05-14 | 2014-12-09 | Invista North America S.A R.L. | High efficiency reactor and process |
EP2164587B1 (en) | 2007-06-13 | 2018-04-04 | INVISTA Textiles (U.K.) Limited | Process for improving adiponitrile quality |
EP2229353B1 (en) * | 2008-01-15 | 2018-01-03 | INVISTA Textiles (U.K.) Limited | Hydrocyanation of pentenenitriles |
EP2229354B1 (en) | 2008-01-15 | 2013-03-20 | Invista Technologies S.à.r.l. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
WO2009117498A2 (en) * | 2008-03-19 | 2009-09-24 | Invista Technologies S.A R.L. | Methods of making cyclododecatriene and methods of making laurolactone |
JP5619753B2 (ja) | 2008-10-14 | 2014-11-05 | インヴィスタテクノロジーズ エスアエルエル | 2−第二級−アルキル−4,5−ジ−(直鎖−アルキル)フェノール類を製造する方法 |
EP2462103A4 (en) * | 2009-08-07 | 2014-01-08 | Invista Tech Sarl | HYDROGENATION AND ESTERIFICATION TO FORM DIESTERS |
EP2574190B1 (en) | 2010-07-07 | 2014-01-22 | Invista Technologies S.à.r.l. | Process for making nitriles |
CN108002970A (zh) * | 2017-12-26 | 2018-05-08 | 濮阳盛华德化工有限公司 | 一种1,5-环辛二烯的制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE758083A (fr) * | 1969-10-27 | 1971-04-27 | Int Nickel Ltd | Stabilisants et leur preparation |
US3624116A (en) * | 1969-11-03 | 1971-11-30 | Int Nickel Co | Nickel derivatives of methylene bis-salicylic acid and process for preparing the same |
US3846461A (en) * | 1972-10-25 | 1974-11-05 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
US3903120A (en) * | 1973-06-19 | 1975-09-02 | Du Pont | Preparation of zerovalent nickel complexes from elemental nickel |
US5523453A (en) * | 1995-03-22 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation |
US6557358B2 (en) * | 2001-06-28 | 2003-05-06 | Kendro Laboratory Products, Inc. | Non-hydrocarbon ultra-low temperature system for a refrigeration system |
US6893996B2 (en) * | 2001-11-26 | 2005-05-17 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation |
-
2003
- 2003-10-30 DE DE10351003A patent/DE10351003A1/de not_active Withdrawn
-
2004
- 2004-10-28 US US10/576,679 patent/US20070083057A1/en not_active Abandoned
- 2004-10-28 JP JP2006537188A patent/JP2007509888A/ja not_active Withdrawn
- 2004-10-28 CA CA002542994A patent/CA2542994A1/en not_active Abandoned
- 2004-10-28 WO PCT/EP2004/012180 patent/WO2005042157A2/de not_active Application Discontinuation
- 2004-10-28 BR BRPI0415975-6A patent/BRPI0415975A/pt not_active IP Right Cessation
- 2004-10-28 EP EP04790953A patent/EP1682270A2/de not_active Withdrawn
- 2004-10-28 KR KR1020067010436A patent/KR20060120174A/ko not_active Application Discontinuation
- 2004-10-28 CN CNA2004800319810A patent/CN1874844A/zh active Pending
- 2004-10-29 TW TW093133022A patent/TW200533674A/zh unknown
- 2004-11-01 AR ARP040104013A patent/AR047116A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
TW200533674A (en) | 2005-10-16 |
DE10351003A1 (de) | 2005-05-25 |
EP1682270A2 (de) | 2006-07-26 |
KR20060120174A (ko) | 2006-11-24 |
BRPI0415975A (pt) | 2007-01-23 |
WO2005042157A2 (de) | 2005-05-12 |
US20070083057A1 (en) | 2007-04-12 |
WO2005042157A3 (de) | 2005-07-21 |
CA2542994A1 (en) | 2005-05-12 |
JP2007509888A (ja) | 2007-04-19 |
CN1874844A (zh) | 2006-12-06 |
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