AR041620A1 - Complejos de rutenio como (pre)catalizadores para reacciones de metatesis; procedimiento para fabricarlos y procedimiento para fabricar un intermediario de sintesis - Google Patents

Complejos de rutenio como (pre)catalizadores para reacciones de metatesis; procedimiento para fabricarlos y procedimiento para fabricar un intermediario de sintesis

Info

Publication number
AR041620A1
AR041620A1 ARP030103746A ARP030103746A AR041620A1 AR 041620 A1 AR041620 A1 AR 041620A1 AR P030103746 A ARP030103746 A AR P030103746A AR P030103746 A ARP030103746 A AR P030103746A AR 041620 A1 AR041620 A1 AR 041620A1
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AR
Argentina
Prior art keywords
manufacturing
procedure
aryl
alkyl
compounds
Prior art date
Application number
ARP030103746A
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English (en)
Inventor
Grela Karol Dr
Original Assignee
Boehringer Ingelheim Int
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehringer Ingelheim Int filed Critical Boehringer Ingelheim Int
Publication of AR041620A1 publication Critical patent/AR041620A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Indole Compounds (AREA)

Abstract

Compuestos (pre) catalizadores de complejos de rutenio de fórmula (1), compuestos intermedios de síntesis, procedimiento para fabricar los compuestos y procedimiento para fabricar los intermedios. Estos compuestos se pueden usar para catalizar reacciones de olefinas que incluyen polimerización por metátesis con cierre de anillo (RMC), despolimerización de polímeros insaturados, síntesis de polímeros telequélicos, metátesis enoino y síntesis de olefinas. Reivindicación 1: Un compuesto de fórmula (1), en la que L1 es un ligando neutro; X / X´ son ligandos aniónicos; R1 es -alquilo C1-5 o -cicloalquilo C5-6; R2 es H, -alquilo C1-20, -alquenilo C2-20, -alquinilo C2-20 o arilo; R3 es -alquilo C1-6, -alcoxi C1-6 o arilo, en el que el arilo está opcionalmente sustituido con -alquilo C1-6 o -alcoxi C1-6; n es 0, 1, 2 o 3. Reivindicación 15: Un procedimiento para fabricar complejos según una cualquiera de las reivindicaciones 1-9, en el que un compuesto de la fórmula (2) o (2S), según las reivindicaciones 10-14, se hace reaccionar con un complejo de rutenio de fórmula general (5), en la que L1 y L2 son ligandos neutros; R5 es H, -alquilo C1-20, -alquenilo C2-20, -alquinilo C2-20 o arilo; R6 es arilo, vinilo o alenilo; X / X´ son ligandos aniónicos.
ARP030103746A 2002-10-15 2003-10-15 Complejos de rutenio como (pre)catalizadores para reacciones de metatesis; procedimiento para fabricarlos y procedimiento para fabricar un intermediario de sintesis AR041620A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL356652A PL199412B1 (pl) 2002-10-15 2002-10-15 Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania

Publications (1)

Publication Number Publication Date
AR041620A1 true AR041620A1 (es) 2005-05-26

Family

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ARP030103746A AR041620A1 (es) 2002-10-15 2003-10-15 Complejos de rutenio como (pre)catalizadores para reacciones de metatesis; procedimiento para fabricarlos y procedimiento para fabricar un intermediario de sintesis

Country Status (32)

Country Link
US (1) US6867303B2 (es)
EP (1) EP1554294B1 (es)
JP (1) JP4264418B2 (es)
KR (1) KR101057963B1 (es)
CN (1) CN1291996C (es)
AR (1) AR041620A1 (es)
AT (1) ATE332906T1 (es)
AU (1) AU2003271713B2 (es)
BR (1) BR0314856B1 (es)
CA (1) CA2502342C (es)
CO (1) CO5560614A2 (es)
DE (2) DE60306795T2 (es)
DK (1) DK1554294T3 (es)
EA (1) EA008352B1 (es)
EC (1) ECSP055653A (es)
ES (1) ES2268412T3 (es)
HK (1) HK1070076A1 (es)
HR (1) HRP20050339B1 (es)
IL (1) IL168002A (es)
ME (1) ME00345B (es)
MX (1) MXPA05003647A (es)
MY (1) MY127285A (es)
NO (1) NO335760B1 (es)
NZ (1) NZ539944A (es)
PE (1) PE20040510A1 (es)
PL (2) PL199412B1 (es)
RS (1) RS50334B (es)
TW (1) TWI310768B (es)
UA (1) UA79018C2 (es)
UY (1) UY28020A1 (es)
WO (1) WO2004035596A1 (es)
ZA (1) ZA200501533B (es)

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AU2003271713B2 (en) 2010-04-29
PE20040510A1 (es) 2004-09-14
NZ539944A (en) 2007-05-31
NO335760B1 (no) 2015-02-09
MY127285A (en) 2006-11-30
PL199412B1 (pl) 2008-09-30
EP1554294A1 (en) 2005-07-20
AU2003271713A1 (en) 2004-05-04
KR101057963B1 (ko) 2011-08-22
HRP20050339A2 (en) 2006-05-31
KR20050061539A (ko) 2005-06-22
MEP51508A (en) 2011-02-10
PL207783B1 (pl) 2011-02-28
CN1291996C (zh) 2006-12-27
PL356652A1 (en) 2004-04-19
ECSP055653A (es) 2005-07-06
NO20051052L (no) 2005-05-11
CN1571791A (zh) 2005-01-26
TWI310768B (en) 2009-06-11
WO2004035596A1 (en) 2004-04-29
US6867303B2 (en) 2005-03-15
JP2006503085A (ja) 2006-01-26
UY28020A1 (es) 2004-05-31
DE60306795D1 (de) 2006-08-24
IL168002A (en) 2009-11-18
RS50334B (sr) 2009-11-10
DK1554294T3 (da) 2006-11-06
CO5560614A2 (es) 2005-09-30
CA2502342A1 (en) 2004-04-29
US20040127350A1 (en) 2004-07-01
EP1554294B1 (en) 2006-07-12
ES2268412T3 (es) 2007-03-16
EA200500607A1 (ru) 2005-10-27
PL374739A1 (en) 2005-10-31
BR0314856B1 (pt) 2014-05-27
HK1070076A1 (en) 2005-06-10
ME00345B (me) 2011-05-10
BR0314856A (pt) 2005-08-02
ATE332906T1 (de) 2006-08-15
TW200420569A (en) 2004-10-16
DE20320324U1 (de) 2004-05-27
DE60306795T2 (de) 2006-11-16
HRP20050339B1 (hr) 2013-07-31
EA008352B1 (ru) 2007-04-27
MXPA05003647A (es) 2005-06-08
UA79018C2 (en) 2007-05-10
CA2502342C (en) 2012-06-19
ZA200501533B (en) 2006-11-29
JP4264418B2 (ja) 2009-05-20
RS20050287A (en) 2007-06-04

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