ES2188171T3 - Procedimiento para la produccion de catalizadores soportados. - Google Patents

Procedimiento para la produccion de catalizadores soportados.

Info

Publication number
ES2188171T3
ES2188171T3 ES99924953T ES99924953T ES2188171T3 ES 2188171 T3 ES2188171 T3 ES 2188171T3 ES 99924953 T ES99924953 T ES 99924953T ES 99924953 T ES99924953 T ES 99924953T ES 2188171 T3 ES2188171 T3 ES 2188171T3
Authority
ES
Spain
Prior art keywords
formula
substituted
hydrogen
iii
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99924953T
Other languages
English (en)
Inventor
Martin Stork
Klaus Mullen
Markus Klapper
Matthias Koch
Heike Gregorius
Ursula Rief
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Max Planck Gesellschaft zur Foerderung der Wissenschaften eV
Basell Polyolefine GmbH
Original Assignee
Max Planck Gesellschaft zur Foerderung der Wissenschaften eV
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Max Planck Gesellschaft zur Foerderung der Wissenschaften eV, Basell Polyolefine GmbH filed Critical Max Planck Gesellschaft zur Foerderung der Wissenschaften eV
Application granted granted Critical
Publication of ES2188171T3 publication Critical patent/ES2188171T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Procedimiento para la producción de un catalizador soportado, caracterizado porque comprende las siguientes etapas del procedimiento: (1) producción de un copolimerizado, que contiene al menos las siguientes unidades de monómeros I y II **(Fórmula)** donde las variables tienen el significado siguiente: A un enlace químico directo o un grupo **(Fórmula)** X un grupo saliente sustituible, R1 los restos siguientes, iguales o diferentes: hidrógeno, arilo sustituido o no sustituido, alquilo o alquenilo ramificado o no ramificado y n un número entero de 0 a 8; (2) reacción análoga a polímero del copolimerizado obtenido según (1) con un compuesto ciclopentadienilo III o un compuesto fulveno III a **(Fórmula)** para obtener un copolimerizado correspondiente, en el que al menos una parte de los grupos salientes X están sustituidos por restos III¿ o III¿a **(Fórmula)** donde las variables, independientes entre sí, tienen el siguiente significado: R2, R3, R4, R5 significan hidrógeno, alquilo con 1 hasta 10 átomos de carbono, fenilo sustituido o no sustituido o uno de estos restos es un grupo -QR6 R7 X2, en el que: Q significa carbono, CR6 R7 C, germanio o silicio, R6, R7 significan, independientes entre sí, hidrógeno, metilo, etilo o fenilo, y X2 significa halógeno, metilo, metoxi o etoxi; y R8 son restos iguales o diferentes de los restos alquilo con 1 hasta 4 átomos de carbono o fenilo, sustituido o no sustituido, y (3) reacción del copolimerizado modificado obtenido según (2) con un compuesto IV o IVa **(Fórmula)** en el que las variables tienen el siguiente significado: Cp un resto ciclopentadienilo sustituido o no sustituido, M Ti, Zr o Hf y X3 halógeno, hidrógeno, alquilo con 1 hasta 10 átomos de carbono, alcoxi con 1 hasta 10 átomos de carbono, o amido, donde diferentes sustituyentes X3 pueden tener significado diferente.
ES99924953T 1998-05-15 1999-05-12 Procedimiento para la produccion de catalizadores soportados. Expired - Lifetime ES2188171T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19821949A DE19821949A1 (de) 1998-05-15 1998-05-15 Verfahren zur Herstellung geträgerter Katalysatoren

Publications (1)

Publication Number Publication Date
ES2188171T3 true ES2188171T3 (es) 2003-06-16

Family

ID=7867958

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99924953T Expired - Lifetime ES2188171T3 (es) 1998-05-15 1999-05-12 Procedimiento para la produccion de catalizadores soportados.

Country Status (7)

Country Link
US (1) US6444766B1 (es)
EP (1) EP1086154B1 (es)
JP (1) JP2002515524A (es)
AU (1) AU4142599A (es)
DE (2) DE19821949A1 (es)
ES (1) ES2188171T3 (es)
WO (1) WO1999060035A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19927766A1 (de) * 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
WO2001083520A2 (en) * 2000-05-02 2001-11-08 Theravance,Inc Polyacid glycopeptide derivatives
DE10033147A1 (de) * 2000-07-07 2002-01-17 Max Planck Gesellschaft Fragmentierbarer Katalysatorträger

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK126687B (da) 1959-01-10 1973-08-13 Ciba Geigy Ag Analogifremgangsmåde til fremstilling af glucofuranosider eller 2-0-acylderivater deraf.
US4921825A (en) 1986-12-30 1990-05-01 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and processes for its production
JPH06287215A (ja) * 1993-02-26 1994-10-11 Univ Northwestern 立体規則性オレフィン重合用均質触媒
EP0705281B1 (en) 1993-05-25 1998-03-11 Exxon Chemical Patents Inc. Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
JPH07206914A (ja) * 1994-01-18 1995-08-08 Asahi Chem Ind Co Ltd オレフィン重合用触媒
JPH09302014A (ja) * 1996-05-09 1997-11-25 Denki Kagaku Kogyo Kk エチレン−芳香族ビニル化合物共重合体の製造方法
WO1998001481A1 (de) 1996-07-04 1998-01-15 Basf Aktiengesellschaft Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
KR100205738B1 (ko) * 1996-07-26 1999-07-01 이정국 담지체 계류 담지 촉매 및 그 제조 방법
US6187880B1 (en) * 1999-02-16 2001-02-13 Phillips Petroleum Company Process for producing an olefin polymer using a metallocene

Also Published As

Publication number Publication date
WO1999060035A1 (de) 1999-11-25
DE19821949A1 (de) 1999-11-18
DE59903473D1 (de) 2003-01-02
EP1086154B1 (de) 2002-11-20
EP1086154A1 (de) 2001-03-28
JP2002515524A (ja) 2002-05-28
AU4142599A (en) 1999-12-06
US6444766B1 (en) 2002-09-03

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