AU641584B2 - Ethylene oxide catalyst and process - Google Patents

Ethylene oxide catalyst and process Download PDF

Info

Publication number
AU641584B2
AU641584B2 AU10341/92A AU1034192A AU641584B2 AU 641584 B2 AU641584 B2 AU 641584B2 AU 10341/92 A AU10341/92 A AU 10341/92A AU 1034192 A AU1034192 A AU 1034192A AU 641584 B2 AU641584 B2 AU 641584B2
Authority
AU
Australia
Prior art keywords
oxide
catalyst
weight
percent
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU10341/92A
Other languages
English (en)
Other versions
AU1034192A (en
Inventor
John Edward Buffum
William Herman Gerdes
Ruth Mary Kowaleski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of AU1034192A publication Critical patent/AU1034192A/en
Application granted granted Critical
Publication of AU641584B2 publication Critical patent/AU641584B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066Zirconium or hafnium; Oxides or hydroxides thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU10341/92A 1991-01-22 1992-01-20 Ethylene oxide catalyst and process Ceased AU641584B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US64360691A 1991-01-22 1991-01-22
US643606 1991-01-22

Publications (2)

Publication Number Publication Date
AU1034192A AU1034192A (en) 1992-07-30
AU641584B2 true AU641584B2 (en) 1993-09-23

Family

ID=24581537

Family Applications (1)

Application Number Title Priority Date Filing Date
AU10341/92A Ceased AU641584B2 (en) 1991-01-22 1992-01-20 Ethylene oxide catalyst and process

Country Status (20)

Country Link
US (1) US5145824A (OSRAM)
EP (1) EP0496470B1 (OSRAM)
JP (1) JP3302387B2 (OSRAM)
KR (1) KR100225874B1 (OSRAM)
CN (1) CN1035161C (OSRAM)
AU (1) AU641584B2 (OSRAM)
BR (1) BR9200166A (OSRAM)
CA (1) CA2059711C (OSRAM)
CZ (1) CZ281977B6 (OSRAM)
DE (1) DE69200450T2 (OSRAM)
DK (1) DK0496470T3 (OSRAM)
ES (1) ES2061309T3 (OSRAM)
IN (1) IN184775B (OSRAM)
MX (1) MX9200243A (OSRAM)
PL (1) PL174992B1 (OSRAM)
RU (1) RU2014114C1 (OSRAM)
SA (1) SA92120369B1 (OSRAM)
SK (1) SK279174B6 (OSRAM)
TR (1) TR25623A (OSRAM)
ZA (1) ZA92376B (OSRAM)

Families Citing this family (100)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
ES2100081T3 (es) * 1993-07-07 1997-06-01 Shell Int Research Catalizador de epoxidacion.
US5573989A (en) * 1993-08-06 1996-11-12 Sumitomo Chemical Company, Limited Process for producing olefin oxides
US5418202A (en) * 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5545603A (en) * 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
US5705661A (en) * 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide
US5763630A (en) * 1996-03-18 1998-06-09 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts
US5733842A (en) * 1996-04-30 1998-03-31 Norton Checmical Process Products Corporation Method of making porous catalyst carrier without the addition of pore forming agents
KR100512672B1 (ko) * 1996-07-01 2005-12-21 다우 글로벌 테크놀로지스 인크. 촉매조성물,이의재생방법및이를사용한산화올레핀의제조방법
US5864047A (en) * 1997-04-10 1999-01-26 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing rhenium and potassium promoters
US5861519A (en) * 1997-05-23 1999-01-19 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters
JPH11191963A (ja) * 1997-12-25 1999-07-13 Fujitsu Ltd 電源装置
US6455713B1 (en) 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
AU754631B2 (en) * 1998-11-17 2002-11-21 Nippon Shokubai Co., Ltd. Carrier for catalyst for use in production of ethylene oxide, catalyst for use in production of ethylene oxide, and method for production of ethylene oxide
RU2141378C1 (ru) * 1999-02-22 1999-11-20 Сотников Валерий Васильевич Носитель серебросодержащего катализатора получения оксида этилена и способ его получения
US6172245B1 (en) 1999-12-16 2001-01-09 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
AU2001257241B2 (en) * 2000-05-01 2006-04-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Ethylene oxide catalyst
RU2190466C2 (ru) * 2000-12-04 2002-10-10 Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" Носитель для катализаторов
ZA200200049B (en) * 2001-01-25 2002-07-16 Nippon Catalytic Chem Ind Fixed-bed shell-and-tube reactor and its usage.
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
US7193094B2 (en) * 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
AU2003217756B2 (en) * 2002-02-25 2008-11-20 Shell Internationale Research Maatschappij B.V. Supported silver catalyst and an epoxidation process using the catalyst
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
KR100980123B1 (ko) 2002-06-28 2010-09-03 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법
WO2004039790A1 (en) * 2002-10-28 2004-05-13 Shell Internationale Research Maatschappij B.V. Olefin oxide catalysts
JP2006522138A (ja) * 2003-04-01 2006-09-28 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンのエポキシ化方法とその方法において使用される触媒
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
RU2342993C2 (ru) 2003-05-07 2009-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализаторы, содержащие серебро, получение таких катализаторов и их применение
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
WO2005023418A1 (en) * 2003-08-22 2005-03-17 Union Carbide Chemicals & Plastics Technology Corporation Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
CN101757914A (zh) * 2003-10-16 2010-06-30 陶氏技术投资有限责任公司 用于烯化氧制备的具有提高稳定性、效率和/或活性的催化剂
US6939979B2 (en) * 2003-11-10 2005-09-06 Scientific Design Co., Inc. Oxidation process and catalyst
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
CA2571179C (en) 2004-06-18 2014-06-10 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
BRPI0512169A (pt) 2004-06-18 2008-02-12 Shell Int Research processo para a produção de óxido de olefina, 1,2- diol, 1,2-diol éter,ou alcanolamina
US7767619B2 (en) * 2004-07-09 2010-08-03 Sud-Chemie Inc. Promoted calcium-aluminate supported catalysts for synthesis gas generation
CN101022888A (zh) * 2004-08-12 2007-08-22 国际壳牌研究有限公司 制备成型催化剂的方法、所述催化剂和所述催化剂的用途
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
MX2007002386A (es) * 2004-09-01 2007-04-23 Shell Int Research Proceso para epoxidacion de olefinas, catalizador para uso en el proceso, soporte para uso en la preparacion del catalizador, y proceso para preparar el soporte.
MX2007003418A (es) * 2004-09-24 2007-05-07 Shell Int Research Proceso para seleccionar particulas moldeadas, proceso para instalar un sistema, proceso para hacer reaccionar una alimentacion gaseosa de este sistema, producto de programa de computo y sistema de computo.
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
DE102005023955A1 (de) * 2005-05-20 2006-11-23 Basf Ag Inertmaterial für den Einsatz in exothermen Reaktionen
KR101369619B1 (ko) 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
BRPI0611817A2 (pt) * 2005-06-07 2011-12-20 Saint Gobain Ceramics veìculo catalisador e um processo para preparação do veìculo catalisador
WO2007021742A1 (en) * 2005-08-11 2007-02-22 Shell Internationale Research Maatschappij B.V. A method of preparing a shaped catalyst, the catalyst, and use of the catalyst
CN100577289C (zh) * 2006-01-28 2010-01-06 中国石油化工股份有限公司 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
TW200738332A (en) * 2006-02-03 2007-10-16 Shell Int Research A process for treating a catalyst, the catalyst, and use of the catalyst
BRPI0707608A2 (pt) * 2006-02-10 2011-05-10 Shell Int Research processo para preparar um catalisador, o catalisador, e um processo para a produÇço de àxido de olefina, 1,2-diol,1,2-diol Éter, ou alcanolamina
TWI466718B (zh) * 2006-04-18 2015-01-01 Dow Global Technologies Llc 環氧烷催化劑及其用途
US20070280877A1 (en) * 2006-05-19 2007-12-06 Sawyer Technical Materials Llc Alpha alumina supports for ethylene oxide catalysts and method of preparing thereof
DE102007017080A1 (de) 2007-04-10 2008-10-16 Basf Se Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres
TWI446964B (zh) 2007-05-09 2014-08-01 Shell Int Research 環氧化催化劑,製備該催化劑之方法及製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法
BRPI0811260B8 (pt) 2007-05-11 2017-03-21 Rokicki Andrzej partida de catalisadores de alta seletividade em plantas de óxido de olefina
JP5507446B2 (ja) * 2007-05-18 2014-05-28 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 反応器システム並びにオレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートおよびアルカノールアミンの調製方法
CA2686852A1 (en) 2007-05-18 2008-11-27 Shell Internationale Research Maatschappij B.V. A reactor system, an absorbent and a process for reacting a feed
DE102007028332A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst
DE102007028333A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors
JP5581058B2 (ja) * 2008-01-11 2014-08-27 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
US20110059843A1 (en) * 2008-04-30 2011-03-10 Howard Kevin E Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CN102015101B (zh) * 2008-04-30 2013-11-06 陶氏技术投资有限公司 多孔体前体,成形多孔体,它们的制备方法和基于它们的终端产品
CA2723176C (en) * 2008-04-30 2014-11-25 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
PL2297125T3 (pl) * 2008-05-07 2013-12-31 Shell Int Research Sposób wytwarzania tlenku olefiny, 1,2-diolu, eteru 1,2-diolu, 1,2-węglanu albo alkanoloaminy
CA2723517C (en) 2008-05-07 2017-03-07 Shell Internationale Research Maatschappij B.V. A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
JP2011520895A (ja) 2008-05-15 2011-07-21 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー アルキレンカーボネートおよび/またはアルキレングリコールの調製のための方法
JP2011524857A (ja) 2008-05-15 2011-09-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー アルキレンカーボネートおよびアルキレングリコールの調製のための方法
US20110017348A1 (en) 2008-06-30 2011-01-27 Michio Tanimoto Method of loading solid particles into a fixed-bed multitubular reactor
WO2010009021A2 (en) * 2008-07-14 2010-01-21 Velocys Inc. Process for making ethylene oxide using microchannel process technology
CN102099346A (zh) * 2008-07-14 2011-06-15 巴斯夫欧洲公司 制备环氧乙烷的方法
US8349765B2 (en) * 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
JP5570500B2 (ja) * 2009-03-31 2014-08-13 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
JP2010234264A (ja) * 2009-03-31 2010-10-21 Nippon Shokubai Co Ltd エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
KR101730667B1 (ko) * 2009-04-21 2017-04-26 다우 테크놀로지 인베스트먼츠 엘엘씨. 고 효율 촉매에 의한 지정된 알킬렌 옥사이드 생산 파라미터의 달성 및 유지의 개선법
CA2759496C (en) * 2009-04-21 2018-05-01 Dow Technology Investments Llc Epoxidation reactions and operating conditions thereof
KR101745737B1 (ko) * 2009-04-21 2017-06-09 다우 테크놀로지 인베스트먼츠 엘엘씨. 고 효율 촉매가 노화될 때 고 효율 촉매를 사용하는 간편화된 알킬렌 옥사이드 생산 방법
US8524927B2 (en) * 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
JP2011121048A (ja) 2009-12-09 2011-06-23 Rohm & Haas Co 固体触媒物質をブレンドし、管状構造物に装填する方法
CN102333767B (zh) * 2009-12-28 2014-12-03 陶氏技术投资有限公司 控制氯化银在环氧烷生产中的银催化剂上的产生的方法
JP2013521119A (ja) 2010-03-01 2013-06-10 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エポキシ化触媒、前記触媒の調製方法及びオレフィンオキシドの製造方法
WO2011143097A2 (en) * 2010-05-10 2011-11-17 Advanced Catalyst Technologies, Llc Nanostructured catalyst pellets, catalyst surface treatment and highly selective catalyst for ethylene epoxidation
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
CN104125858B (zh) 2011-12-19 2017-07-11 陶氏技术投资有限责任公司 根据催化剂参考性质配制环氧烷催化剂的方法
CN103357437B (zh) * 2012-03-28 2016-03-30 中国石油化工股份有限公司 制备用于银催化剂的氧化铝载体的方法及其银催化剂
JP6090567B2 (ja) 2012-12-18 2017-03-08 京進工業株式会社 拡管装置
FR3001969B1 (fr) 2013-02-12 2015-08-21 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermiquement integre
FR3001968B1 (fr) 2013-02-12 2015-02-27 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermo-mecaniquement integre
TWI632138B (zh) * 2013-05-16 2018-08-11 科學設計股份有限公司 具有降低鈉含量之建基於銀之環氧乙烷觸媒
CN104549543B (zh) * 2013-10-29 2017-08-25 中国石油化工股份有限公司 氧化铝载体、由其制成的银催化剂及其应用
US11400437B2 (en) 2016-08-08 2022-08-02 Basf Se Catalyst for the oxidation of ethylene to ethylene oxide
JP7107934B2 (ja) 2016-12-02 2022-07-27 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレンエポキシ化触媒のコンディショニング方法およびエチレンオキシドの生成の関連方法
CN108283943B (zh) * 2017-01-10 2021-07-02 中国石油化工股份有限公司 氧化铝载体及其制备方法、乙烯环氧化反应用银催化剂及乙烯环氧化制备环氧乙烷的方法
TWI808125B (zh) * 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
CN111072803B (zh) * 2018-10-19 2022-07-12 中国石油化工股份有限公司 烯烃聚合催化剂载体及其制备方法和应用
TW202239752A (zh) 2020-12-29 2022-10-16 荷蘭商蜆殼國際研究所 用於生產環氧乙烷之製程
TW202237260A (zh) * 2021-01-19 2022-10-01 美商科學設計有限公司 用於製造管間距減小的立式沸騰反應器的管與管板焊接
CN115382525B (zh) * 2021-05-24 2024-05-10 中国石油化工股份有限公司 一种α-氧化铝载体及其制备方法和银催化剂和应用
CN116943746A (zh) * 2022-04-13 2023-10-27 中国石油化工股份有限公司 乙烯环氧化用银催化剂的载体、银催化剂和乙烯环氧化生产环氧乙烷的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3725307A (en) * 1967-01-30 1973-04-03 Halcon International Inc Process for preparing a silver-supported catalyst
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
EP0247414A2 (en) * 1986-05-09 1987-12-02 Mitsubishi Petrochemical Co., Ltd. Silver-deposited catalyst and its use for production of ethylene oxide

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8501862A (nl) * 1985-06-28 1987-01-16 Shell Int Research Werkwijze ter bereiding van een zilver-houdende katalysator.
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
IN169589B (OSRAM) * 1986-10-31 1991-11-16 Shell Int Research
GB8626687D0 (en) * 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4874879A (en) * 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
EP0357292A1 (en) * 1988-08-30 1990-03-07 Imperial Chemical Industries Plc Production of ethylene oxide and catalysts therefor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3725307A (en) * 1967-01-30 1973-04-03 Halcon International Inc Process for preparing a silver-supported catalyst
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
EP0247414A2 (en) * 1986-05-09 1987-12-02 Mitsubishi Petrochemical Co., Ltd. Silver-deposited catalyst and its use for production of ethylene oxide

Also Published As

Publication number Publication date
JPH0584440A (ja) 1993-04-06
KR920014515A (ko) 1992-08-25
KR100225874B1 (ko) 1999-10-15
ZA92376B (en) 1992-09-30
EP0496470B1 (en) 1994-09-28
EP0496470A1 (en) 1992-07-29
DE69200450D1 (de) 1994-11-03
JP3302387B2 (ja) 2002-07-15
CA2059711C (en) 2002-07-30
CN1063427A (zh) 1992-08-12
US5145824A (en) 1992-09-08
MX9200243A (es) 1992-07-01
BR9200166A (pt) 1992-10-06
PL293237A1 (en) 1992-11-02
SA92120369B1 (ar) 2004-07-12
CZ281977B6 (cs) 1997-04-16
DE69200450T2 (de) 1995-02-23
DK0496470T3 (da) 1994-10-24
CN1035161C (zh) 1997-06-18
AU1034192A (en) 1992-07-30
SK279174B6 (sk) 1998-07-08
PL174992B1 (pl) 1998-10-30
TR25623A (tr) 1993-07-01
IN184775B (OSRAM) 2000-09-30
RU2014114C1 (ru) 1994-06-15
ES2061309T3 (es) 1994-12-01
CA2059711A1 (en) 1992-07-23
CS16692A3 (en) 1992-08-12

Similar Documents

Publication Publication Date Title
AU641584B2 (en) Ethylene oxide catalyst and process
US5100859A (en) Catalyst carrier
CA2171213C (en) Epoxidation catalyst and process
AU711973B2 (en) Epoxidation catalyst and process
EP0808215B1 (en) Alkylene oxide catalyst and process
CN102145285A (zh) 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
MXPA97005608A (en) Alkylene oxide catalyst and proc
CA1284985C (en) Process for the preparation of a silver-containing catalyst
JP2013534465A (ja) 酸化エチレン触媒用のキャリア
EP0807017A1 (en) Process for the manufacture of moulded articles that are partly coloured or have regions of different colours
CN112007625B (zh) 一种α-氧化铝载体及制备方法和银催化剂与应用