AU2003209430B2 - Dental pastes, dental articles, and methods - Google Patents
Dental pastes, dental articles, and methods Download PDFInfo
- Publication number
- AU2003209430B2 AU2003209430B2 AU2003209430A AU2003209430A AU2003209430B2 AU 2003209430 B2 AU2003209430 B2 AU 2003209430B2 AU 2003209430 A AU2003209430 A AU 2003209430A AU 2003209430 A AU2003209430 A AU 2003209430A AU 2003209430 B2 AU2003209430 B2 AU 2003209430B2
- Authority
- AU
- Australia
- Prior art keywords
- dental
- silica
- paste
- filler
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 320
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- 239000003479 dental cement Substances 0.000 claims description 5
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- UEKHZPDUBLCUHN-UHFFFAOYSA-N 2-[[3,5,5-trimethyl-6-[2-(2-methylprop-2-enoyloxy)ethoxycarbonylamino]hexyl]carbamoyloxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC(=O)NCCC(C)CC(C)(C)CNC(=O)OCCOC(=O)C(C)=C UEKHZPDUBLCUHN-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
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- 239000012955 diaryliodonium Substances 0.000 description 1
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 description 1
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- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
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- 238000010902 jet-milling Methods 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
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- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
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- 238000011326 mechanical measurement Methods 0.000 description 1
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- 125000002524 organometallic group Chemical group 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 150000002921 oxetanes Chemical class 0.000 description 1
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000007406 plaque accumulation Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005903 polyol mixture Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
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- 239000012966 redox initiator Substances 0.000 description 1
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- 239000000565 sealant Substances 0.000 description 1
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- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
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- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
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- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/70—Preparations for dentistry comprising inorganic additives
- A61K6/71—Fillers
- A61K6/76—Fillers comprising silicon-containing compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35359302P | 2002-01-31 | 2002-01-31 | |
| US60/353,593 | 2002-01-31 | ||
| PCT/US2003/002649 WO2003063804A1 (en) | 2002-01-31 | 2003-01-29 | Dental pastes, dental articles, and methods |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2003209430A1 AU2003209430A1 (en) | 2003-09-18 |
| AU2003209430B2 true AU2003209430B2 (en) | 2008-09-11 |
Family
ID=27663227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2003209430A Ceased AU2003209430B2 (en) | 2002-01-31 | 2003-01-29 | Dental pastes, dental articles, and methods |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7393882B2 (enExample) |
| EP (1) | EP1471875A1 (enExample) |
| JP (2) | JP4748938B2 (enExample) |
| CN (1) | CN1319507C (enExample) |
| AU (1) | AU2003209430B2 (enExample) |
| CA (1) | CA2473861C (enExample) |
| WO (1) | WO2003063804A1 (enExample) |
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| US7709029B2 (en) * | 2001-01-24 | 2010-05-04 | Ada Foundation | Calcium-containing restoration materials |
| US20040206932A1 (en) * | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
| AU2004266623B8 (en) | 2003-08-12 | 2011-10-27 | 3M Deutschland Gmbh | Self-etching dental compositions and methods |
| US20060004121A1 (en) * | 2004-03-10 | 2006-01-05 | Xingzhe Ding | Polymer-brush modified fillers for composites |
| JP2005320491A (ja) * | 2004-05-11 | 2005-11-17 | Hitachi Chem Co Ltd | 接着剤組成物、それを用いたフィルム状接着剤及び回路接続材料、並びに回路部材の接続構造及びその製造方法 |
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| US20090306277A1 (en) * | 2006-08-29 | 2009-12-10 | Goenner Emily S | Resin systems including reactive surface-modified nanoparticles |
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| US8057231B2 (en) * | 2006-12-02 | 2011-11-15 | Viscomi Brian D | Direct press on veneer |
| DE112006004170T5 (de) * | 2006-12-06 | 2009-10-15 | Kabushiki Kaisha Shofu | Zahnzement-Zusammensetzung auf Harzbasis |
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| US9078815B2 (en) | 2011-07-13 | 2015-07-14 | Dentsply International Inc. | Self-cure activator |
| WO2013028397A2 (en) | 2011-08-23 | 2013-02-28 | 3M Innovative Properties Company | Dental compositions comprising addition-fragmentation agents |
| CN104053627B (zh) | 2011-11-02 | 2018-06-01 | 3M创新有限公司 | 制造喷嘴的方法 |
| WO2014033280A2 (de) | 2012-08-31 | 2014-03-06 | Kettenbach Gmbh & Co. Kg | Radikalisch polymerisierbares dentalmaterial, gehärtetes produkt und verwendung |
| JP6351608B2 (ja) | 2012-11-12 | 2018-07-04 | スリーエム イノベイティブ プロパティズ カンパニー | 付加開裂剤を含む歯科用組成物 |
| WO2014099317A1 (en) | 2012-12-17 | 2014-06-26 | 3M Innovative Properties Company | Addition-fragmentation oligomers |
| JP6099443B2 (ja) * | 2013-03-18 | 2017-03-22 | 株式会社トクヤマデンタル | 歯科用組成物、およびその製造方法 |
| JP6300899B2 (ja) | 2013-03-20 | 2018-03-28 | スリーエム イノベイティブ プロパティズ カンパニー | 高屈折率の付加−開裂剤 |
| EP2986269A1 (en) | 2013-04-15 | 2016-02-24 | 3M Innovative Properties Company | Dental composition containing high refractive index monomers |
| DE102013007894A1 (de) * | 2013-05-08 | 2014-11-13 | Heraeus Kulzer Gmbh | Langlebiges Dentalmaterial mit verbesserten transparenten Eigenschaften |
| CN103319832B (zh) * | 2013-06-13 | 2015-08-19 | 北京化工大学 | 齿科修复用光固化复合树脂及其制备方法 |
| CN105555855B (zh) | 2013-09-20 | 2018-08-14 | 3M创新有限公司 | 包含三硫代碳酸酯的加成-断裂剂 |
| EP3052050B1 (en) | 2013-10-04 | 2021-07-28 | 3M Innovative Properties Company | Dental mill blank |
| JP6138366B2 (ja) | 2013-10-16 | 2017-05-31 | スリーエム イノベイティブ プロパティズ カンパニー | アリルジスルフィド含有付加開裂オリゴマー |
| MX367806B (es) * | 2013-12-20 | 2019-09-06 | Colgate Palmolive Co | Partículas de sílice de núcleo-cubierta y uso para reducción del mal olor. |
| US11400032B2 (en) | 2013-12-20 | 2022-08-02 | Colgate-Palmolive Company | Tooth whitening oral care product with core shell silica particles |
| WO2015126657A1 (en) | 2014-02-18 | 2015-08-27 | 3M Innovative Properties Company | Addition-fragmentation oligomers having high refractive index groups |
| JP5716118B1 (ja) | 2014-07-29 | 2015-05-13 | 株式会社松風 | ペースト性状の劣化を軽減した複合材料 |
| JP5716119B1 (ja) | 2014-07-29 | 2015-05-13 | 株式会社松風 | 安定したペースト性状をした歯科用複合材料 |
| US10350297B2 (en) | 2014-10-31 | 2019-07-16 | 3M Innovative Properties Company | Dental materials and methods |
| WO2016069290A1 (en) | 2014-10-31 | 2016-05-06 | 3M Innovative Properties Company | Dental materials and methods |
| WO2016133668A1 (en) | 2015-02-20 | 2016-08-25 | 3M Innovative Properties Company | Addition-fragmentation oligomers |
| WO2016140950A1 (en) | 2015-03-05 | 2016-09-09 | 3M Innovative Properties Company | Composite material having ceramic fibers |
| JP2017048121A (ja) * | 2015-08-31 | 2017-03-09 | 三井化学株式会社 | 歯科用組成物、歯科用ミルブランク、歯科部材及びその製造方法、義歯床及びその製造方法、並びに、有床義歯及びその製造方法 |
| US10758456B2 (en) | 2015-11-06 | 2020-09-01 | 3M Innovative Properties Company | Redox polymerizable composition with photolabile transition metal complexes |
| WO2017079189A1 (en) | 2015-11-06 | 2017-05-11 | 3M Innovative Properties Company | Redox polymerizable dental composition with photolabile transition metal complexes |
| US10792228B2 (en) | 2015-11-11 | 2020-10-06 | 3M Innovative Properties Company | Kit of parts for producing a glass ionomer cement, process of production and use thereof |
| CN108368202B (zh) | 2015-12-03 | 2020-10-16 | 3M创新有限公司 | 具有光不稳定还原剂的氧化还原可聚合组合物 |
| EP3411006A1 (en) | 2016-02-05 | 2018-12-12 | 3M Innovative Properties Company | Dental compositions comprising nanoparticles providing a refractive index differential between polymerizable resin and filler |
| JP2017218403A (ja) * | 2016-06-06 | 2017-12-14 | 三井化学株式会社 | 歯科用組成物、歯科用ミルブランク、歯科部材及びその製造方法、義歯床及びその製造方法、並びに、有床義歯及びその製造方法 |
| US10968197B2 (en) | 2016-10-20 | 2021-04-06 | 3M Innovative Properties Company | Photoinitiators with protected carbonyl group |
| WO2018074600A1 (ja) * | 2016-10-21 | 2018-04-26 | クラレノリタケデンタル株式会社 | 分包型の歯科用セメント |
| WO2018102484A1 (en) | 2016-12-01 | 2018-06-07 | 3M Innovative Properties Company | Basic core material encapsulated in an inorganic shell suitable for use in biological carrier materials |
| EP3579810A1 (en) | 2017-02-13 | 2019-12-18 | 3M Innovative Properties Company | Self-adhesive dental resin composition and use thereof |
| WO2018154911A1 (ja) * | 2017-02-27 | 2018-08-30 | 株式会社ジーシー | 歯科用硬化性組成物 |
| TWI630244B (zh) * | 2017-03-07 | 2018-07-21 | 國立陽明大學 | 三維列印用牙科材料及其製備方法與應用 |
| US11160733B2 (en) | 2017-05-15 | 2021-11-02 | 3M Innovative Properties Company | Dental adhesive composition, preparation and use thereof |
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| EP3787588A2 (en) | 2018-05-02 | 2021-03-10 | 3M Innovative Properties Company | One-part dental adhesive composition for fixing dental composite materials |
| JP2021525610A (ja) | 2018-06-06 | 2021-09-27 | スリーエム イノベイティブ プロパティズ カンパニー | ２剤型歯科用シーラント、シリンジ装置で塗布する方法、及びキット |
| US12161523B2 (en) | 2018-06-06 | 2024-12-10 | Solventum Intellectual Properties Company | Hardenable dental compositions comprising basic core material encapsulated in an inorganic shell and dispensing devices therewith |
| US11446214B2 (en) | 2018-08-08 | 2022-09-20 | Gc Corporation | Curable dental composite |
| US12193903B2 (en) | 2018-09-14 | 2025-01-14 | Solventum Intellectual Properties Company | Composite materials including ceramic fibers and nanoclusters, dental products, kits, and methods of making and using same |
| US11642199B2 (en) | 2018-09-24 | 2023-05-09 | 3M Innovative Properties Company | Dental appliance with cosmetic therapeutic aqueous solution |
| CN112789263A (zh) | 2018-10-09 | 2021-05-11 | 3M创新有限公司 | 具有悬挂式胺基团的加成-断裂剂 |
| WO2020100041A1 (en) | 2018-11-14 | 2020-05-22 | 3M Innovative Properties Company | Storage stable two-component dual cure dental composition |
| CN109771301B (zh) * | 2019-01-17 | 2021-08-31 | 东华大学 | 一种雪花状介孔SiO2纳米颗粒增强牙科复合树脂及其制备方法 |
| JP2023512105A (ja) | 2020-02-03 | 2023-03-23 | スリーエム イノベイティブ プロパティズ カンパニー | 積層造形によって表面改質３次元物品を製造するためのプロセス、改質された表面を有する３次元物品及びその使用 |
| US12209172B2 (en) | 2020-04-08 | 2025-01-28 | 3M Innovative Properties Company | Curable compositions and methods of using the same |
| WO2021205326A1 (en) | 2020-04-08 | 2021-10-14 | 3M Innovative Properties Company | Curable compositions and methods of using the same |
| US12404419B2 (en) | 2020-11-05 | 2025-09-02 | 3M Innovative Properties Company | Imide addition-fragmentation agents |
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| WO2023105315A1 (en) | 2021-12-06 | 2023-06-15 | 3M Innovative Properties Company | Dental compositions |
| EP4444809A1 (en) | 2021-12-06 | 2024-10-16 | 3M Innovative Properties Company | Adhesives comprising cyclic imide addition-fragmentation and adhesion agents |
| JP2023151496A (ja) | 2022-03-31 | 2023-10-16 | 株式会社ジーシー | 処理シリカ分散単量体組成物の製造方法 |
| EP4629958A1 (en) | 2022-12-06 | 2025-10-15 | Solventum Intellectual Properties Company | Surface-treated filler, dental composition containing such a filler, process of production and use thereof |
| CN116327609B (zh) * | 2023-04-04 | 2025-05-16 | 桂林凯文彼德科技有限公司 | 一种膏状树脂、其制备方法及其应用 |
Family Cites Families (182)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2731326A (en) * | 1951-08-31 | 1956-01-17 | Du Pont | Process of preparing dense amorphous silica aggregates and product |
| US2984628A (en) | 1956-11-29 | 1961-05-16 | Du Pont | Concentrated zirconia and hafnia aquasols and their preparation |
| US3018262A (en) | 1957-05-01 | 1962-01-23 | Shell Oil Co | Curing polyepoxides with certain metal salts of inorganic acids |
| US3066112A (en) | 1959-01-30 | 1962-11-27 | Rafael L Bowen | Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate |
| US3179623A (en) | 1959-01-30 | 1965-04-20 | Rafael L Bowen | Method of preparing a monomer having phenoxy and methacrylate groups linked by hydroxy glyceryl groups |
| NL298323A (enExample) | 1959-12-24 | |||
| US3442817A (en) | 1966-04-15 | 1969-05-06 | Du Pont | Preparation of zirconia and hafnia sols |
| US3514252A (en) | 1967-07-07 | 1970-05-26 | Grace W R & Co | Process for the preparation of stabilized zirconia powders |
| US3860556A (en) | 1968-03-15 | 1975-01-14 | Minnesota Mining & Mfg | Low water absorption dental restorative |
| US3539533A (en) | 1968-06-14 | 1970-11-10 | Johnson & Johnson | Dental filling material |
| CA878004A (en) | 1968-06-14 | 1971-08-10 | Ii Henry L. Lee | Dental filling package |
| US3708296A (en) | 1968-08-20 | 1973-01-02 | American Can Co | Photopolymerization of epoxy monomers |
| US3709706A (en) | 1969-05-16 | 1973-01-09 | Minnesota Mining & Mfg | Refractory fibers and other articles of zirconia and silica mixtures |
| US3629187A (en) | 1969-06-25 | 1971-12-21 | Dentsply Int Inc | Dental compositions containing adduct of 2 2' - propane bis 3-(4-phenoxy)-1 2-hydroxy propane - 1 - methacrylate and isocyanate |
| US3709866A (en) | 1970-06-01 | 1973-01-09 | Dentsply Int Inc | Photopolymerizable dental products |
| FR2122353B1 (enExample) * | 1971-01-22 | 1974-02-15 | Aerospatiale | |
| US3766132A (en) | 1971-02-12 | 1973-10-16 | Lee Pharmaceuticals | Diacrylate esters of low viscosity and the use thereof as binders in dental restorative compositions |
| US3751399A (en) | 1971-05-24 | 1973-08-07 | Lee Pharmaceuticals | Polyacrylate resin compositions |
| GB1408265A (en) | 1971-10-18 | 1975-10-01 | Ici Ltd | Photopolymerisable composition |
| US3808006A (en) | 1971-12-06 | 1974-04-30 | Minnesota Mining & Mfg | Photosensitive material containing a diaryliodium compound, a sensitizer and a color former |
| US3729313A (en) | 1971-12-06 | 1973-04-24 | Minnesota Mining & Mfg | Novel photosensitive systems comprising diaryliodonium compounds and their use |
| US3729813A (en) * | 1972-01-24 | 1973-05-01 | Rockwell International Corp | Method of forming an impregnated textile bobbin |
| US3860566A (en) * | 1972-09-20 | 1975-01-14 | Phillips Petroleum Co | Capping and curing of mercaptoelechelic polymers |
| US3741769A (en) | 1972-10-24 | 1973-06-26 | Minnesota Mining & Mfg | Novel photosensitive polymerizable systems and their use |
| US4115346A (en) | 1974-02-12 | 1978-09-19 | Kulzer & Co. Gmbh | Hydroxy group containing diesters of acrylic acids and their use in dental material |
| DE2406557C3 (de) | 1974-02-12 | 1981-02-19 | Kulzer & Co Gmbh, 6380 Bad Homburg | Hydroxyl-Gruppen enthaltende Diester von Acrylsäuren und diese enthaltendes Zahnfüllungsmaterial |
| AU497960B2 (en) | 1974-04-11 | 1979-01-25 | Minnesota Mining And Manufacturing Company | Photopolymerizable compositions |
| GB1512981A (en) | 1974-05-02 | 1978-06-01 | Gen Electric | Curable epoxide compositions |
| US4250311A (en) | 1974-05-02 | 1981-02-10 | General Electric Company | P, As, and Sb hexafluoride onium salts as photoinitiators |
| GB1569021A (en) | 1976-03-17 | 1980-06-11 | Kuraray Co | Adhesive cementing agents containing partial phosphonic orphosphonic acid esters |
| US4150012A (en) | 1977-01-21 | 1979-04-17 | Minnesota Mining And Manufacturing Company | Discernible dental sealant |
| US4292029A (en) | 1978-05-15 | 1981-09-29 | University Of Michigan | Hydrophobic composite restorative materials and their use in tooth treatment |
| US4387240A (en) | 1978-06-02 | 1983-06-07 | Minnesota Mining And Manufacturing Company | Oligomeric methacryl substituted alkylsiloxanes |
| US4216288A (en) | 1978-09-08 | 1980-08-05 | General Electric Company | Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents |
| DE2850917A1 (de) | 1978-11-24 | 1980-06-04 | Bayer Ag | Dentalwerkstoffe auf basis von organischen kunststoffen in pastoeser form |
| EP0013491B1 (en) | 1979-01-05 | 1982-10-20 | Imperial Chemical Industries Plc | Dispersions of siliceous solids in liquid organic media |
| US4327014A (en) | 1979-04-11 | 1982-04-27 | Kanebo Ltd. | Resin-forming material, implant material and compositions for restorative material suitable for medical or dental use |
| US4250053A (en) | 1979-05-21 | 1981-02-10 | Minnesota Mining And Manufacturing Company | Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems |
| US4389497A (en) * | 1979-11-22 | 1983-06-21 | Espe Fabrik Parmazeutischer Praparate Gmbh | Use of agglomerates of silicic acid as fillers in dental materials |
| US4379695A (en) | 1980-06-02 | 1983-04-12 | Scientific Pharmaceuticals, Inc. | Dental material comprising dimethyacrylate adducts of glycidyl methacrylate with diesters of bis(hydroxymethyl) tricyclo[5.2.1.02,6 ]decane and dicarboxylic acids |
| JPS5828878B2 (ja) | 1980-08-20 | 1983-06-18 | 三金工業株式会社 | 環状ピロ燐酸エステル誘導体 |
| JPS5774369A (en) | 1980-10-28 | 1982-05-10 | Mitsui Petrochem Ind Ltd | Coating composition |
| DE3170993D1 (en) | 1981-03-24 | 1985-07-25 | Blendax Werke Schneider Co | Dental filling material |
| US4491508A (en) | 1981-06-01 | 1985-01-01 | General Electric Company | Method of preparing curable coating composition from alcohol, colloidal silica, silylacrylate and multiacrylate monomer |
| JPS5879818A (ja) | 1981-11-05 | 1983-05-13 | Etsuro Kato | 結晶質ジルコニアのコロイドゾル及びその製造方法 |
| JPS58135131A (ja) | 1982-02-02 | 1983-08-11 | Etsuro Kato | ジルコニア系微粉末の製造方法 |
| US4512743A (en) | 1982-02-05 | 1985-04-23 | Johnson & Johnson Dental Products Company | Method for masking discoloration on teeth |
| DE3366408D1 (en) | 1982-05-19 | 1986-10-30 | Ciba Geigy Ag | Photopolymerisation with organometal salts |
| EP0094915B1 (de) | 1982-05-19 | 1987-01-21 | Ciba-Geigy Ag | Härtbare, Metallocenkomplexe enthaltende Zusammensetzungen, daraus erhältliche aktivierte Vorstufen und deren Verwendung |
| US5089536A (en) | 1982-11-22 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Energy polmerizable compositions containing organometallic initiators |
| JPS59107969A (ja) | 1982-12-08 | 1984-06-22 | 加藤 悦朗 | ジルコニア系固溶体単結晶超微粒子の分散したゾルおよび製造方法 |
| DE3316851A1 (de) | 1983-05-07 | 1984-11-08 | Bayer Ag, 5090 Leverkusen | Polymerisierbare dentalmassen und hieraus hergestellte dentalformkoerper |
| US5073476A (en) | 1983-05-18 | 1991-12-17 | Ciba-Geigy Corporation | Curable composition and the use thereof |
| US4545924A (en) | 1983-06-13 | 1985-10-08 | Owens-Corning Fiberglas Corporation | Production of a magnesium chloride gel system useful in ceramics and fiber production |
| US4442240A (en) | 1983-07-14 | 1984-04-10 | Bisco, Inc. | Dental filling materials |
| US4612138A (en) | 1983-08-04 | 1986-09-16 | Nalco Chemical Company | Stable acidic and alkaline metal oxide sols |
| JPS60103033A (ja) | 1983-11-01 | 1985-06-07 | Chichibu Cement Co Ltd | ジルコニア系超微粉末の製造方法 |
| DE3341888A1 (de) | 1983-11-19 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | Anorganisch-organische fuellstoffe, verfahren zu deren herstellung sowie deren verwendung in polymerisierbaren massen |
| DE3342601C1 (de) | 1983-11-25 | 1985-03-14 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien |
| JPS60137827A (ja) | 1983-12-23 | 1985-07-22 | Shin Etsu Chem Co Ltd | ジルコニア微粉末の製造方法 |
| US4544359A (en) | 1984-01-13 | 1985-10-01 | Pentron Corporation | Dental restorative material |
| DE3403040A1 (de) | 1984-01-30 | 1985-08-08 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Dentales fuellungsmaterial |
| JPS60176920A (ja) | 1984-02-21 | 1985-09-11 | Etsuro Kato | ジルコニア系単結晶超微粒子の分散したゾルおよび製造方法 |
| US4503169A (en) | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
| JPS60255622A (ja) | 1984-05-30 | 1985-12-17 | Toyo Soda Mfg Co Ltd | 焼結性に優れたジルコニア系微粉末の製造方法 |
| US5137448A (en) | 1984-07-31 | 1992-08-11 | Dentsply Research & Development Corp. | Dental impression method with photocuring of impression material in light transmissive tray |
| US5177120A (en) | 1984-07-31 | 1993-01-05 | Dentsply Research & Development Corp. | Chain extended urethane diacrylate and dental impression formation |
| US4547531A (en) | 1984-08-02 | 1985-10-15 | Pentron Corporation | Two component (paste-paste) self-curing dental restorative material |
| DE3430801A1 (de) | 1984-08-22 | 1986-03-06 | Bayer Ag, 5090 Leverkusen | Verwendung von poroesen fuellstoffen in polymerisierbaren massen, solche massen und deren verwendung zur herstellung von formkoerpern |
| GR852068B (enExample) | 1984-08-30 | 1985-12-24 | Johnson & Johnson Dental Prod | |
| US4746685A (en) | 1984-08-31 | 1988-05-24 | Nippon Oil And Fats Co., Ltd. | Light curable dental composition |
| DE3443221A1 (de) | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| EP0184467A3 (en) | 1984-12-06 | 1988-06-08 | Berger, Jenson and Nicholson Limited | Water reducible coating compositions |
| US4661540A (en) | 1984-12-06 | 1987-04-28 | Berger, Jenson & Nicholson Limited | Water reducible coating compositions |
| DE3502594A1 (de) | 1985-01-26 | 1986-07-31 | Etablissement Dentaire Ivoclar, Schaan | Roentgenopaker dentalwerkstoff |
| US4642126A (en) | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
| US4619817A (en) | 1985-03-27 | 1986-10-28 | Battelle Memorial Institute | Hydrothermal method for producing stabilized zirconia |
| US5276068A (en) | 1985-03-29 | 1994-01-04 | Jeneric/Pentron, Inc. | Dental resin materials |
| JPS61227917A (ja) | 1985-04-03 | 1986-10-11 | Nippon Shokubai Kagaku Kogyo Co Ltd | ジルコニア系球形微粒子粉末の製造方法 |
| JPS61270217A (ja) | 1985-05-23 | 1986-11-29 | Denki Kagaku Kogyo Kk | 結晶質酸化ジルコニウム微粉末の製法 |
| US4652274A (en) | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
| JPS6265932A (ja) | 1985-09-13 | 1987-03-25 | Nippon Mining Co Ltd | 高強度ジルコニア微粉末の製造方法 |
| JPS6291421A (ja) | 1985-10-18 | 1987-04-25 | Tokyo Inst Of Technol | 酸化ジルコニウム微粒子の製造方法 |
| US4772530A (en) | 1986-05-06 | 1988-09-20 | The Mead Corporation | Photosensitive materials containing ionic dye compounds as initiators |
| US4772511A (en) | 1985-11-22 | 1988-09-20 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous zirconia microspheres |
| JPH0764563B2 (ja) | 1985-11-27 | 1995-07-12 | 悦朗 加藤 | 結晶質ジルコニアの微粉末及びその製造方法 |
| JPH0651568B2 (ja) | 1985-11-29 | 1994-07-06 | 電気化学工業株式会社 | 酸化ジルコニウム系微粉末の製法 |
| JPH0729771B2 (ja) | 1986-01-14 | 1995-04-05 | 悦朗 加藤 | 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法 |
| JPS62212224A (ja) | 1986-03-14 | 1987-09-18 | Taiyo Yuden Co Ltd | ジルコニア系固溶体結晶質微粉末の製造方法 |
| JPS62226815A (ja) | 1986-03-27 | 1987-10-05 | Nippon Shokubai Kagaku Kogyo Co Ltd | ジルコニア系コロイドゾルの製造方法 |
| JPS62260718A (ja) | 1986-05-06 | 1987-11-13 | Shigeyuki Somiya | 水熱法による高純度ジルコニア−アルミナ系超微粉末の製造方法 |
| JPS632809A (ja) | 1986-06-19 | 1988-01-07 | Nippon Shokubai Kagaku Kogyo Co Ltd | 高純度ジルコニアゾルの製造方法 |
| US4719091A (en) | 1986-07-01 | 1988-01-12 | Corning Glass Works | Preparation of mono-sized zirconia powders by forced hydrolysis |
| US4778671A (en) | 1986-07-14 | 1988-10-18 | Corning Glass Works | Preparation of unagglomerated metal oxide particles with uniform particle size |
| DE3777940D1 (de) | 1986-09-27 | 1992-05-07 | Nissan Chemical Ind Ltd | Verfahren zur herstellung von feinem zirkonoxydpulver. |
| DE3642290C1 (de) | 1986-12-11 | 1987-07-02 | Dentaire Ivoclar Ets | Verfahren zur Verbesserung der Haftung von Kunststoffen auf Metallen |
| US4874450A (en) | 1987-01-29 | 1989-10-17 | The Mead Corporation | Laminating transparent or translucent materials using ionic dye-counter ion complexes |
| DE3863940D1 (de) | 1987-02-25 | 1991-09-05 | Nippon Catalytic Chem Ind | Verfahren zur erzeugung sehr kleiner, anorganischer, kugelfoermiger teilchen. |
| CA1323949C (en) | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
| US4792577A (en) | 1987-07-16 | 1988-12-20 | Johnson & Johnson Consumer Products, Inc. | Stain-resistant no-mix orthodontic adhesive |
| US4886624A (en) | 1987-08-19 | 1989-12-12 | Rhone-Poulenc, Inc. | Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid |
| US4859716A (en) | 1987-11-06 | 1989-08-22 | Den-Mat Corporation | Microfilled dental composite and method for making it |
| FR2629071B1 (fr) | 1988-03-22 | 1991-03-15 | Produits Refractaires | Oxyde de zirconium reactif et sa preparation |
| US4885332A (en) | 1988-04-11 | 1989-12-05 | Minnesota Mining And Manufacturing Company | Photocurable abrasion resistant coatings comprising silicon dioxide dispersions |
| US4985340A (en) | 1988-06-01 | 1991-01-15 | Minnesota Mining And Manufacturing Company | Energy curable compositions: two component curing agents |
| US5234870A (en) | 1988-07-21 | 1993-08-10 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol and method for production thereof |
| US4954414A (en) | 1988-11-08 | 1990-09-04 | The Mead Corporation | Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same |
| JPH0667816B2 (ja) | 1988-11-11 | 1994-08-31 | 株式会社クラレ | 歯科用修復材 |
| US5275759A (en) | 1989-02-10 | 1994-01-04 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol, method for production thereof, porous ceramic-producing slurry, and porous ceramic product obtained by use thereof |
| IT1228692B (it) * | 1989-03-20 | 1991-07-03 | Piero Rusconi Clerici | Prodotto stratiforme in foglio per imballaggio. |
| US5248706A (en) | 1989-04-22 | 1993-09-28 | Degussa Aktiengesellschaft | Process for preparing a pasty dental material which is an organopolysiloxane filler combined with a polymerizable bonding agent |
| US5219899A (en) | 1989-04-22 | 1993-06-15 | Degussa Aktiengesellschaft | Pasty dental material which is an organopolysilane filler combined with a polymerizable bonding agent |
| DE3913250A1 (de) | 1989-04-22 | 1990-10-25 | Degussa | Dentalmaterial (ii) |
| US5057393A (en) | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
| JPH0717820Y2 (ja) | 1989-08-18 | 1995-04-26 | 国産電機株式会社 | 内燃機関安全装置 |
| US5126394A (en) | 1989-10-18 | 1992-06-30 | Dow Corning Corporation | Radiation curable abrasion resistant coatings from colloidal silica and acrylate monomer |
| US5190583A (en) | 1989-12-04 | 1993-03-02 | Transfer-Electric Gesellschaft Fur | Aqueous coating composition and the use thereof for coating to be protected from light, especially ultraviolet radiation |
| DE69006472T2 (de) | 1989-12-21 | 1994-09-01 | Minnesota Mining & Mfg | Zahnärztliche Zusammensetzungen, Verfahren zur Herstellung von geformten, zahnärztlichen Artikeln via "photoiniferte Polymerisation" von zahnärztlichen Zusammensetzungen und dadurch erzeugte geformte, zahnärztliche Artikel. |
| US5084586A (en) | 1990-02-12 | 1992-01-28 | Minnesota Mining And Manufacturing Company | Novel initiators for cationic polymerization |
| US5124417A (en) | 1990-02-12 | 1992-06-23 | Minnesota Mining And Manufacturing Company | Initiators for cationic polymerization |
| US5037579A (en) | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
| US5055372A (en) | 1990-04-23 | 1991-10-08 | The Mead Corporation | Photohardenable composition containing borate salts and ketone initiators |
| US5332779A (en) | 1990-06-04 | 1994-07-26 | Kawasaki Steel Corporation | Polymerizable silica sol, adamantane derivative for use in the sol and cured resin prepared using the same |
| DE9103321U1 (de) | 1991-03-19 | 1992-08-27 | Thera Patent GmbH & Co KG Gesellschaft für industrielle Schutzrechte, 8031 Seefeld | Transparentversiegelter Dentalkunststoffkörper |
| US5332429A (en) | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
| DE4123946A1 (de) | 1991-07-19 | 1993-01-28 | Degussa | Dentalmaterial mit alumoorganopolysiloxan-fuellstoff |
| JP2732968B2 (ja) | 1991-09-06 | 1998-03-30 | 鐘紡株式会社 | 歯科用充填組成物 |
| FR2681534B1 (fr) | 1991-09-20 | 1995-01-27 | Rhone Poulenc Chimie | Solutions collouidales concentrees de particules monocristallines non agregees d'oxydes de metaux, leur procede de preparation et leur application a l'obtention de films. |
| DE4133621A1 (de) | 1991-10-10 | 1993-04-22 | Inst Neue Mat Gemein Gmbh | Nanoskalige teilchen enthaltende kompositmaterialien, verfahren zu deren herstellung und deren verwendung fuer optische elemente |
| FR2689876B1 (fr) | 1992-04-08 | 1994-09-02 | Hoechst France | Dispersions silico-acryliques, leur procédé d'obtention, leur application en stéréophotolithographie et procédé de préparation d'objets en résine. |
| DE4212633A1 (de) | 1992-04-15 | 1993-10-21 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung oberflächenmodifizierter nanoskaliger keramischer Pulver |
| WO1993023333A1 (en) | 1992-05-20 | 1993-11-25 | E.I. Du Pont De Nemours And Company | Process for making inorganic gels |
| JPH06191827A (ja) | 1992-09-04 | 1994-07-12 | Ohara Inc | シリカ球状単分散粒子の製造方法 |
| JP3449378B2 (ja) * | 1993-04-13 | 2003-09-22 | 株式会社トクヤマ | 歯科用充填修復材料及び義歯床用樹脂組成物 |
| US5502087A (en) | 1993-06-23 | 1996-03-26 | Dentsply Research & Development Corp. | Dental composition, prosthesis, and method for making dental prosthesis |
| US5460701A (en) | 1993-07-27 | 1995-10-24 | Nanophase Technologies Corporation | Method of making nanostructured materials |
| JP3859737B2 (ja) | 1994-04-25 | 2006-12-20 | 三菱レイヨン株式会社 | 歯科用複合材料 |
| JP3437881B2 (ja) | 1994-05-12 | 2003-08-18 | 三菱レイヨン株式会社 | 硬化性組成物、複合充填材、及び歯科用修復材料 |
| TW343961B (en) | 1994-06-17 | 1998-11-01 | Nissan Chemical Ind Ltd | Aqueous zirconia sol and method of preparing same |
| DE4422118A1 (de) | 1994-06-24 | 1996-01-04 | Merck Patent Gmbh | Präparationen von monodispersen kugelförmigen Oxidpartikeln |
| JP3214982B2 (ja) * | 1994-07-04 | 2001-10-02 | 株式会社トクヤマ | 無機組成物 |
| US5856373A (en) | 1994-10-31 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Dental visible light curable epoxy system with enhanced depth of cure |
| JP3542425B2 (ja) | 1994-11-17 | 2004-07-14 | キヤノン株式会社 | インクジェット記録用水系分散インク、これを用いるインクジェット記録方法、インクカートリッジ、記録ユニットおよび記録装置 |
| DE19508586C2 (de) | 1995-03-13 | 1997-07-10 | Degussa | Polymerisierbarer Dentalwerkstoff |
| EP0767141B1 (en) | 1995-03-15 | 2003-08-13 | Hoya Corporation | Process for preparing precipitate of metal oxide |
| US5698483A (en) | 1995-03-17 | 1997-12-16 | Institute Of Gas Technology | Process for preparing nanosized powder |
| DE19515820A1 (de) | 1995-04-29 | 1996-10-31 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung schwach agglomerierter nanoskaliger Teilchen |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| US5694701A (en) | 1996-09-04 | 1997-12-09 | Minnesota Mining And Manufacturing Company | Coated substrate drying system |
| BR9610657A (pt) | 1995-09-18 | 1999-02-17 | Minnesota Mining & Mfg | Processo e aparelho para separar componentes de uma mistura e mecanismo de codensação para uso em um sistema de separação de componentes |
| WO1997015526A1 (en) | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
| DE19540623A1 (de) | 1995-10-31 | 1997-05-07 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung von Kompositmaterialien mit hohem Grenzflächenanteil und dadurch erhältliche Kompositmaterialien |
| US5886069A (en) | 1995-11-13 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Titanium dioxide particles having substantially discrete inorganic particles dispersed on their surfaces |
| JP3495171B2 (ja) | 1996-01-25 | 2004-02-09 | サンメディカル株式会社 | 歯科用充填組成物 |
| CH691970A5 (de) | 1996-03-04 | 2001-12-14 | Ciba Sc Holding Ag | Alkylphenylbisacylphosphinoxide und Photoinitiatormischungen. |
| DE19617931C5 (de) * | 1996-04-26 | 2010-07-22 | Ivoclar Vivadent Ag | Verwendung eines gefüllten und polymerisierbaren Materials als Dentalmaterial |
| US5942559A (en) | 1996-08-26 | 1999-08-24 | Ivoclar Ag | Dental light-curing opaquer |
| CA2229923A1 (en) | 1996-09-27 | 1998-03-27 | Southwest Research Institute | Metal oxide compositions and methods |
| US6030914A (en) | 1996-11-12 | 2000-02-29 | Tosoh Corporation | Zirconia fine powder and method for its production |
| JP4086338B2 (ja) | 1996-12-06 | 2008-05-14 | 株式会社松風 | 歯科用弾性修復材料並びにそれを用いた歯科補綴材料の作製方法 |
| US6063830A (en) | 1996-12-06 | 2000-05-16 | Kabushiki Kaisha Shofu | Dental curable composition and artificial tooth |
| US5760126A (en) | 1996-12-20 | 1998-06-02 | Minnesota Mining And Manufacturing Company | Aqueous fluorochemical compositions and abrasion-resistant coatings therefrom |
| US6025406A (en) | 1997-04-11 | 2000-02-15 | 3M Innovative Properties Company | Ternary photoinitiator system for curing of epoxy resins |
| US5998495A (en) | 1997-04-11 | 1999-12-07 | 3M Innovative Properties Company | Ternary photoinitiator system for curing of epoxy/polyol resin compositions |
| US5879715A (en) | 1997-09-02 | 1999-03-09 | Ceramem Corporation | Process and system for production of inorganic nanoparticles |
| US5985168A (en) | 1997-09-29 | 1999-11-16 | University Of Pittsburgh Of The Commonwealth System Of Higher Education | Magnetorheological fluid |
| JP4451501B2 (ja) | 1997-10-03 | 2010-04-14 | デンツプライ インターナショナル インコーポレーテッド | ナノスケールの充填剤を含む歯科材料 |
| DE19806572B4 (de) | 1998-02-17 | 2007-01-25 | 3M Espe Ag | Adhäsive Befestigung von dentalen Füllungsmaterialien |
| US6121344A (en) | 1998-06-19 | 2000-09-19 | Kerr Corporation | Optimum particle sized hybrid composite |
| US6030606A (en) | 1998-06-22 | 2000-02-29 | 3M Innovative Properties Company | Dental restoratives comprising Bis-EMA6 |
| EP1017354B1 (en) | 1998-07-20 | 2005-07-06 | Dentsply International, Inc. | Translucent wear resistant dental enamel material and method |
| US6306926B1 (en) | 1998-10-07 | 2001-10-23 | 3M Innovative Properties Company | Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same |
| JP2002528474A (ja) | 1998-11-03 | 2002-09-03 | ニュー エイジ バイオマテリアルズ，インコーポレーテッド | 歯科複合材料用の改良型フィラー |
| US6680013B1 (en) * | 1999-04-15 | 2004-01-20 | Regents Of The University Of Minnesota | Synthesis of macroporous structures |
| US6417246B1 (en) | 1999-09-21 | 2002-07-09 | Jenerica/Pentron Incorporated | Dental composite materials |
| AU3505400A (en) | 1999-10-28 | 2001-05-08 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
| US6387981B1 (en) | 1999-10-28 | 2002-05-14 | 3M Innovative Properties Company | Radiopaque dental materials with nano-sized particles |
| US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
| US6572693B1 (en) | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
| US6730156B1 (en) | 1999-10-28 | 2004-05-04 | 3M Innovative Properties Company | Clustered particle dental fillers |
| JP2001302429A (ja) | 2000-04-28 | 2001-10-31 | Shiyoufuu:Kk | 凝集物を含有する歯科用複合組成物 |
| US7156911B2 (en) * | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
-
2003
- 2003-01-29 JP JP2003563500A patent/JP4748938B2/ja not_active Expired - Fee Related
- 2003-01-29 CN CNB038030055A patent/CN1319507C/zh not_active Expired - Fee Related
- 2003-01-29 WO PCT/US2003/002649 patent/WO2003063804A1/en not_active Ceased
- 2003-01-29 US US10/353,505 patent/US7393882B2/en not_active Expired - Lifetime
- 2003-01-29 AU AU2003209430A patent/AU2003209430B2/en not_active Ceased
- 2003-01-29 CA CA2473861A patent/CA2473861C/en not_active Expired - Fee Related
- 2003-01-29 EP EP03707591A patent/EP1471875A1/en not_active Withdrawn
-
2008
- 2008-06-11 US US12/137,206 patent/US20080242759A1/en not_active Abandoned
-
2010
- 2010-08-06 JP JP2010176891A patent/JP2011006429A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005517688A (ja) | 2005-06-16 |
| JP4748938B2 (ja) | 2011-08-17 |
| US20030181541A1 (en) | 2003-09-25 |
| EP1471875A1 (en) | 2004-11-03 |
| CN1625383A (zh) | 2005-06-08 |
| WO2003063804A1 (en) | 2003-08-07 |
| CA2473861A1 (en) | 2003-08-07 |
| CA2473861C (en) | 2012-03-13 |
| US7393882B2 (en) | 2008-07-01 |
| JP2011006429A (ja) | 2011-01-13 |
| CN1319507C (zh) | 2007-06-06 |
| US20080242759A1 (en) | 2008-10-02 |
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