ATE261191T1 - Lithiierte elektrochemisch aktive verbindungen und ihre herstellung - Google Patents

Lithiierte elektrochemisch aktive verbindungen und ihre herstellung

Info

Publication number
ATE261191T1
ATE261191T1 AT00993800T AT00993800T ATE261191T1 AT E261191 T1 ATE261191 T1 AT E261191T1 AT 00993800 T AT00993800 T AT 00993800T AT 00993800 T AT00993800 T AT 00993800T AT E261191 T1 ATE261191 T1 AT E261191T1
Authority
AT
Austria
Prior art keywords
lithium
mixed metal
metal materials
production
active compounds
Prior art date
Application number
AT00993800T
Other languages
German (de)
English (en)
Inventor
Jeremy Barker
M Yazid Saidi
Original Assignee
Valence Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valence Technology Inc filed Critical Valence Technology Inc
Application granted granted Critical
Publication of ATE261191T1 publication Critical patent/ATE261191T1/de

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • H01M4/623Binders being polymers fluorinated polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Compounds Of Iron (AREA)
  • Steroid Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Replacement Of Web Rolls (AREA)
AT00993800T 2000-01-18 2000-12-22 Lithiierte elektrochemisch aktive verbindungen und ihre herstellung ATE261191T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/484,799 US7001690B2 (en) 2000-01-18 2000-01-18 Lithium-based active materials and preparation thereof
PCT/US2000/035302 WO2001054212A1 (en) 2000-01-18 2000-12-22 Lithium-based electrochemically active materials and preparation thereof

Publications (1)

Publication Number Publication Date
ATE261191T1 true ATE261191T1 (de) 2004-03-15

Family

ID=23925643

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00993800T ATE261191T1 (de) 2000-01-18 2000-12-22 Lithiierte elektrochemisch aktive verbindungen und ihre herstellung

Country Status (10)

Country Link
US (5) US7001690B2 (ja)
EP (2) EP1309021A3 (ja)
JP (2) JP2003520182A (ja)
KR (1) KR100501861B1 (ja)
CN (1) CN100338799C (ja)
AT (1) ATE261191T1 (ja)
AU (1) AU2001229134A1 (ja)
CA (1) CA2394318C (ja)
DE (1) DE60008801T2 (ja)
WO (1) WO2001054212A1 (ja)

Families Citing this family (181)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910382A (en) * 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US6514640B1 (en) * 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US7001690B2 (en) * 2000-01-18 2006-02-21 Valence Technology, Inc. Lithium-based active materials and preparation thereof
US6528033B1 (en) * 2000-01-18 2003-03-04 Valence Technology, Inc. Method of making lithium-containing materials
US6387568B1 (en) 2000-04-27 2002-05-14 Valence Technology, Inc. Lithium metal fluorophosphate materials and preparation thereof
US6777132B2 (en) 2000-04-27 2004-08-17 Valence Technology, Inc. Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials
US8057769B2 (en) 2000-04-27 2011-11-15 Valence Technology, Inc. Method for making phosphate-based electrode active materials
US6964827B2 (en) 2000-04-27 2005-11-15 Valence Technology, Inc. Alkali/transition metal halo- and hydroxy-phosphates and related electrode active materials
US7524584B2 (en) 2000-04-27 2009-04-28 Valence Technology, Inc. Electrode active material for a secondary electrochemical cell
JP4742413B2 (ja) * 2000-09-29 2011-08-10 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP4734700B2 (ja) * 2000-09-29 2011-07-27 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP4734701B2 (ja) * 2000-09-29 2011-07-27 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP2002117845A (ja) * 2000-10-06 2002-04-19 Toyota Central Res & Dev Lab Inc リチウム二次電池正極活物質用リチウム鉄複合酸化物
JP4491950B2 (ja) * 2000-10-06 2010-06-30 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP4848582B2 (ja) * 2000-10-06 2011-12-28 ソニー株式会社 正極活物質の製造方法
JP3988374B2 (ja) * 2000-10-06 2007-10-10 ソニー株式会社 非水電解液二次電池
US6645452B1 (en) * 2000-11-28 2003-11-11 Valence Technology, Inc. Methods of making lithium metal cathode active materials
JP4686859B2 (ja) * 2000-12-27 2011-05-25 株式会社デンソー 正極活物質および非水電解質二次電池
US6984470B2 (en) * 2001-03-26 2006-01-10 Kabushiki Kaisha Toshiba Positive electrode active material and nonaqueous electrolyte secondary battery
US7026068B2 (en) * 2001-12-19 2006-04-11 Nichia Corporation Positive electrode active material for lithium ion secondary battery
CN100414746C (zh) * 2001-12-21 2008-08-27 麻省理工学院 传导性组合物及其制备和应用
US6724173B2 (en) * 2002-02-08 2004-04-20 Valence Technology, Inc. Circuits, apparatuses, electrochemical device charging methods, and lithium-mixed metal electrode cell charging methods
US6815122B2 (en) * 2002-03-06 2004-11-09 Valence Technology, Inc. Alkali transition metal phosphates and related electrode active materials
US20030190527A1 (en) 2002-04-03 2003-10-09 James Pugh Batteries comprising alkali-transition metal phosphates and preferred electrolytes
US20090220838A9 (en) * 2002-04-04 2009-09-03 Jeremy Barker Secondary electrochemical cell
US6849360B2 (en) 2002-06-05 2005-02-01 Eveready Battery Company, Inc. Nonaqueous electrochemical cell with improved energy density
US6794084B2 (en) 2002-07-26 2004-09-21 Valence Technology, Inc. Alkali metal hydrogen phosphates as precursors for phosphate-containing electrochemical active materials
IL152486A0 (en) 2002-10-25 2003-05-29 Meir Eini Alcohol-free cosmetic and pharmaceutical foam carrier
US9211259B2 (en) 2002-11-29 2015-12-15 Foamix Pharmaceuticals Ltd. Antibiotic kit and composition and uses thereof
US10117812B2 (en) 2002-10-25 2018-11-06 Foamix Pharmaceuticals Ltd. Foamable composition combining a polar solvent and a hydrophobic carrier
US7700076B2 (en) 2002-10-25 2010-04-20 Foamix, Ltd. Penetrating pharmaceutical foam
US9668972B2 (en) 2002-10-25 2017-06-06 Foamix Pharmaceuticals Ltd. Nonsteroidal immunomodulating kit and composition and uses thereof
KR101108439B1 (ko) 2002-10-25 2012-01-31 포믹스 리미티드 화장료 및 약제용 거품제
US9265725B2 (en) 2002-10-25 2016-02-23 Foamix Pharmaceuticals Ltd. Dicarboxylic acid foamable vehicle and pharmaceutical compositions thereof
US7820145B2 (en) 2003-08-04 2010-10-26 Foamix Ltd. Oleaginous pharmaceutical and cosmetic foam
US8900554B2 (en) 2002-10-25 2014-12-02 Foamix Pharmaceuticals Ltd. Foamable composition and uses thereof
US7704518B2 (en) 2003-08-04 2010-04-27 Foamix, Ltd. Foamable vehicle and pharmaceutical compositions thereof
US20080138296A1 (en) 2002-10-25 2008-06-12 Foamix Ltd. Foam prepared from nanoemulsions and uses
CA2776449A1 (en) * 2002-12-19 2004-06-19 Valence Technology, Inc. Batteries with alkali metal phosphate electrodes
CN1754275A (zh) * 2002-12-23 2006-03-29 A123系统公司 高能量和高功率密度电化学电池
CN100372162C (zh) * 2003-01-22 2008-02-27 威伦斯技术公司 锂电池组
US7041239B2 (en) * 2003-04-03 2006-05-09 Valence Technology, Inc. Electrodes comprising mixed active particles
US20070141468A1 (en) * 2003-04-03 2007-06-21 Jeremy Barker Electrodes Comprising Mixed Active Particles
US20040202935A1 (en) * 2003-04-08 2004-10-14 Jeremy Barker Cathode active material with increased alkali/metal content and method of making same
US6914417B2 (en) 2003-04-29 2005-07-05 Valence Technology, Inc. Electrical energy systems, power supply apparatuses, and electrical energy supply methods
US7968235B2 (en) 2003-07-17 2011-06-28 Uchicago Argonne Llc Long life lithium batteries with stabilized electrodes
US8795693B2 (en) 2003-08-04 2014-08-05 Foamix Ltd. Compositions with modulating agents
WO2005031954A2 (en) 2003-09-22 2005-04-07 Valence Technology, Inc. Electrical systems, power supply apparatuses, and power supply operations methods
JP2005158673A (ja) * 2003-10-31 2005-06-16 Toyota Motor Corp 電極活物質およびその製造方法ならびに非水電解質二次電池
KR101501958B1 (ko) 2003-12-23 2015-03-16 유니버시떼 드 몬트리얼 전기활성 삽입 화합물의 제조 방법 및 이로부터 얻은 전극 물질
US20050170256A1 (en) * 2004-01-30 2005-08-04 John Cummings Electrical power source apparatuses, electrical power source operational methods, and electrochemical device charging methods
CN1806355A (zh) * 2004-02-06 2006-07-19 A123系统公司 具有高充放电倍率能力的锂二次电池
US8617745B2 (en) * 2004-02-06 2013-12-31 A123 Systems Llc Lithium secondary cell with high charge and discharge rate capability and low impedance growth
US7719227B2 (en) * 2004-02-13 2010-05-18 Valence Technology, Inc. Electrical energy supply methods and electrical energy power supplies
US7960057B2 (en) * 2004-05-17 2011-06-14 Toyota Motor Engineering & Manufacturing North America, Inc. Battery with molten salt electrolyte and phosphorus-containing cathode
US9012096B2 (en) * 2004-05-28 2015-04-21 Uchicago Argonne, Llc Long life lithium batteries with stabilized electrodes
US7872396B2 (en) * 2004-06-14 2011-01-18 Massachusetts Institute Of Technology Electrochemical actuator
US7629080B1 (en) 2004-07-23 2009-12-08 The United States Of America As Represented By The Secretary Of The Army Electrode materials for electrochemical cells
FR2873496B1 (fr) * 2004-07-26 2016-04-01 Commissariat Energie Atomique Electrode pour accumulateur au lithium, procede de fabrication d'une telle electrode et accumulateur au lithium comportant une telle electrode
JP2006155941A (ja) * 2004-11-25 2006-06-15 Kyushu Univ 電極活物質の製造方法
CN100533849C (zh) * 2004-11-26 2009-08-26 皇家飞利浦电子股份有限公司 能量系统、电子模块、电子器件和制造所述能量系统的方法
US20080070107A1 (en) * 2004-12-07 2008-03-20 Shinji Kasamatsu Separator and Non-Aqueous Electrolyte Secondary Battery Using Same
CN101894975B (zh) * 2004-12-16 2011-09-14 U芝加哥阿谷尼有限公司 具有稳定电极的长寿命的锂电池
US7842420B2 (en) * 2005-02-03 2010-11-30 A123 Systems, Inc. Electrode material with enhanced ionic transport properties
US7205067B2 (en) * 2005-02-08 2007-04-17 Valence Technology, Inc. Method and apparatus for dissipation of heat generated by a secondary electrochemical cell
US7851092B2 (en) * 2005-03-02 2010-12-14 U Chicago Argonne Llc Redox shuttles for overcharge protection of lithium batteries
WO2006101779A2 (en) * 2005-03-15 2006-09-28 The University Of Chicago Non-aqueous electrolytes for lithium ion batteries
US20080138710A1 (en) * 2005-05-10 2008-06-12 Ben-Jie Liaw Electrochemical Composition and Associated Technology
US7887954B2 (en) * 2005-05-10 2011-02-15 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
US7799457B2 (en) * 2005-05-10 2010-09-21 Advanced Lithium Electrochemistry Co., Ltd Ion storage compound of cathode material and method for preparing the same
TWI254031B (en) * 2005-05-10 2006-05-01 Aquire Energy Co Ltd Manufacturing method of LixMyPO4 compound with olivine structure
US7700236B2 (en) * 2005-09-09 2010-04-20 Aquire Energy Co., Ltd. Cathode material for manufacturing a rechargeable battery
US7824581B2 (en) * 2007-06-18 2010-11-02 Advanced Lithium Electrochemistry Co., Ltd. Cocrystalline metallic compounds and electrochemical redox active material employing the same
US8158090B2 (en) 2005-08-08 2012-04-17 A123 Systems, Inc. Amorphous and partially amorphous nanoscale ion storage materials
US8323832B2 (en) * 2005-08-08 2012-12-04 A123 Systems, Inc. Nanoscale ion storage materials
US7939201B2 (en) * 2005-08-08 2011-05-10 A123 Systems, Inc. Nanoscale ion storage materials including co-existing phases or solid solutions
US7524529B2 (en) * 2005-09-09 2009-04-28 Aquire Energy Co., Ltd. Method for making a lithium mixed metal compound having an olivine structure
US8367253B2 (en) 2006-02-02 2013-02-05 U Chicago Argonne Llc Lithium-ion batteries with intrinsic pulse overcharge protection
JP2007207637A (ja) * 2006-02-03 2007-08-16 Gs Yuasa Corporation:Kk 非水電解質電池用リン酸鉄リチウム化合物及びその製造方法
US20070190422A1 (en) * 2006-02-15 2007-08-16 Fmc Corporation Carbon nanotube lithium metal powder battery
JP2007227572A (ja) * 2006-02-22 2007-09-06 Sanyo Electric Co Ltd 電気二重層キャパシタ及び電気二重層キャパシタの製造方法
US7723958B2 (en) 2006-03-31 2010-05-25 Valence Technology, Inc. Battery charge indication methods, battery charge monitoring devices, rechargeable batteries, and articles of manufacture
US8158071B2 (en) * 2006-04-29 2012-04-17 Chun-Chieh Chang Method and devices for producing air sensitive electrode materials for lithium ion battery applications
US20070259265A1 (en) * 2006-05-02 2007-11-08 Saidi M Yazid Secondary electrochemical cell having a novel electrode active material
KR20090012262A (ko) * 2006-05-09 2009-02-02 발렌스 테크놀로지, 인코포레이티드 증가된 집전 효율을 갖는 2차 전기화학 전지
US7718319B2 (en) * 2006-09-25 2010-05-18 Board Of Regents, The University Of Texas System Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries
US7960047B2 (en) 2006-10-17 2011-06-14 Valence Technology, Inc. Method and apparatus for monitoring and controlling an electrochemical cell
CA2566906A1 (en) * 2006-10-30 2008-04-30 Nathalie Ravet Carbon-coated lifepo4 storage and handling
US20080260655A1 (en) 2006-11-14 2008-10-23 Dov Tamarkin Substantially non-aqueous foamable petrolatum based pharmaceutical and cosmetic compositions and their uses
US8197719B2 (en) * 2006-11-17 2012-06-12 American Lithium Energy Corp. Electroactive agglomerated particles
US7824802B2 (en) * 2007-01-17 2010-11-02 The United States Of America As Represented By The Secretary Of The Army Method of preparing a composite cathode active material for rechargeable electrochemical cell
WO2008097990A1 (en) * 2007-02-07 2008-08-14 Valence Technology, Inc. Oxynitride-based electrode active materials for secondary electrochemical cells
AU2008222726A1 (en) * 2007-03-08 2008-09-12 Board of Governors for Higher Education, State of Rhode Island and the Providence Plantations Novel electrolyte for lithium ion batteries
US20080221629A1 (en) * 2007-03-09 2008-09-11 Cardiac Pacemakers, Inc. Lamination of Lithium Battery Elements for Implantable Medical Devices
US8641921B2 (en) * 2007-03-19 2014-02-04 Umicore Room temperature single phase Li insertion/extraction material for use in Li-based battery
TW200838983A (en) * 2007-03-22 2008-10-01 Univ Nat Central Phosphate compound fluorescent material
US20080241693A1 (en) * 2007-03-30 2008-10-02 Minoru Fukuchi Lithium transition metal complex oxide for lithium ion secondary battery cathode active material and method for producing the same, lithium ion secondary battery cathode active material, and lithium ion secondary battery
US8021496B2 (en) 2007-05-16 2011-09-20 Fmc Corporation Stabilized lithium metal powder for Li-ion application, composition and process
JP5231535B2 (ja) * 2007-05-28 2013-07-10 ビーワイディー カンパニー リミテッド リチウムイオン二次電池用の正極活物質としてのリチウムリン酸鉄の調製方法
US20080303004A1 (en) * 2007-06-08 2008-12-11 Conocophillips Company Method for producing lithium transition metal polyanion powders for batteries
US20080305256A1 (en) * 2007-06-08 2008-12-11 Conocophillips Company Method for producing lithium vanadium polyanion powders for batteries
US8168329B2 (en) * 2007-06-18 2012-05-01 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
JP5558349B2 (ja) * 2007-07-12 2014-07-23 エー123 システムズ, インコーポレイテッド リチウムイオンバッテリー用の多機能合金オリビン
US20090035661A1 (en) * 2007-08-01 2009-02-05 Jeffrey Swoyer Synthesis of cathode active materials
US8636982B2 (en) 2007-08-07 2014-01-28 Foamix Ltd. Wax foamable vehicle and pharmaceutical compositions thereof
US8324868B2 (en) * 2007-08-24 2012-12-04 Valence Technology, Inc. Power source with temperature sensing
US20090068080A1 (en) * 2007-09-06 2009-03-12 Valence Technology, Inc. Method of Making Active Materials For Use in Secondary Electrochemical Cells
US8475688B2 (en) * 2007-09-20 2013-07-02 Uchicago Argonne, Llc Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes
US20120070746A1 (en) * 2007-09-21 2012-03-22 Sion Power Corporation Low electrolyte electrochemical cells
US8506847B2 (en) * 2007-10-01 2013-08-13 Basf Se Process for the preparation of crystalline lithium-, vanadium-and phosphate-comprising materials
WO2009043729A2 (en) * 2007-10-01 2009-04-09 Basf Se Process for the preparation of porous lithium-, vanadium and phosphate-comprising materials
JP5164256B2 (ja) * 2007-11-12 2013-03-21 国立大学法人九州大学 全固体二次電池
WO2009069006A2 (en) 2007-11-30 2009-06-04 Foamix Ltd. Foam containing benzoyl peroxide
WO2009072007A2 (en) 2007-12-07 2009-06-11 Foamix Ltd. Carriers, formulations, methods for formulating unstable active agents for external application and uses thereof
US20090155689A1 (en) * 2007-12-14 2009-06-18 Karim Zaghib Lithium iron phosphate cathode materials with enhanced energy density and power performance
CN101939862B (zh) 2008-01-08 2014-03-12 赛昂能源有限公司 多孔电极以及相关联的方法
TWI466370B (zh) 2008-01-17 2014-12-21 A123 Systems Inc 鋰離子電池的混合式金屬橄欖石電極材料
JP2011527090A (ja) * 2008-07-03 2011-10-20 ボード オブ ガバナーズ フォー ハイヤー エデュケーション, ステート オブ ロード アイランド アンド プロヴィデンス プランテーションズ 電解質添加物によるリチウムイオン電池電解質の酸化の抑制
US20100154206A1 (en) * 2008-12-19 2010-06-24 Conocophillips Company Process for making composite lithium powders for batteries
WO2010114104A1 (ja) * 2009-04-03 2010-10-07 旭硝子株式会社 リン酸鉄リチウム粒子の製造方法および二次電池の製造方法
US20100266474A1 (en) * 2009-04-16 2010-10-21 Titus Faulkner Method of Making Active Materials for Use in Secondary Electrochemical Cells
US8372540B2 (en) * 2009-04-16 2013-02-12 Valence Technology, Inc. Electrode active material for secondary electrochemical cell
US8637428B1 (en) 2009-12-18 2014-01-28 Simbol Inc. Lithium extraction composition and method of preparation thereof
US9034294B1 (en) 2009-04-24 2015-05-19 Simbol, Inc. Preparation of lithium carbonate from lithium chloride containing brines
US8741256B1 (en) 2009-04-24 2014-06-03 Simbol Inc. Preparation of lithium carbonate from lithium chloride containing brines
US10190030B2 (en) 2009-04-24 2019-01-29 Alger Alternative Energy, Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium
US9051827B1 (en) 2009-09-02 2015-06-09 Simbol Mining Corporation Selective removal of silica from silica containing brines
CA2760186C (en) 2009-04-28 2019-10-29 Foamix Ltd. Foamable vehicle and pharmaceutical compositions comprising aprotic polar solvents and uses thereof
JP2010272272A (ja) * 2009-05-20 2010-12-02 Hitachi Ltd リチウム二次電池用正極及びリチウム二次電池
US8784189B2 (en) * 2009-06-08 2014-07-22 Cfph, Llc Interprocess communication regarding movement of game devices
US8545328B2 (en) * 2009-06-08 2013-10-01 Cfph, Llc Portable electronic charge device for card devices
US8545327B2 (en) * 2009-06-08 2013-10-01 Cfph, Llc Amusement device including means for processing electronic data in play of a game in which an outcome is dependant upon card values
US8419535B2 (en) * 2009-06-08 2013-04-16 Cfph, Llc Mobile playing card devices
US8771078B2 (en) * 2009-06-08 2014-07-08 Cfph, Llc Amusement device including means for processing electronic data in play of a game of chance
US8613671B2 (en) * 2009-06-08 2013-12-24 Cfph, Llc Data transfer and control among multiple computer devices in a gaming environment
US8287386B2 (en) * 2009-06-08 2012-10-16 Cfph, Llc Electrical transmission among interconnected gaming systems
US10935006B2 (en) 2009-06-24 2021-03-02 Terralithium Llc Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines
CA2769677A1 (en) 2009-07-29 2011-02-03 Foamix Ltd. Non surface active agent non polymeric agent hydro-alcoholic foamable compositions, breakable foams and their uses
WO2011013009A2 (en) 2009-07-29 2011-02-03 Foamix Ltd. Non surfactant hydro-alcoholic foamable compositions, breakable foams and their uses
WO2011019493A1 (en) 2009-08-09 2011-02-17 American Lithium Energy Corporation Electroactive particles, and electrodes and batteries comprising the same
WO2011025823A1 (en) 2009-08-25 2011-03-03 A123 Systems, Inc. Mixed metal olivine electrode materials for lithium ion batteries having improved specific capacity and energy density
US20110206992A1 (en) * 2009-08-28 2011-08-25 Sion Power Corporation Porous structures for energy storage devices
IN2012DN02063A (ja) * 2009-08-28 2015-08-21 Sion Power Corp
US9660267B2 (en) 2009-09-18 2017-05-23 A123 Systems, LLC High power electrode materials
WO2011035235A1 (en) * 2009-09-18 2011-03-24 A123 Systems, Inc. Ferric phosphate and methods of preparation thereof
US9849142B2 (en) 2009-10-02 2017-12-26 Foamix Pharmaceuticals Ltd. Methods for accelerated return of skin integrity and for the treatment of impetigo
EP2482788B1 (en) 2009-10-02 2022-12-14 Journey Medical Corporation Topical tetracycline compositions
US20110135810A1 (en) * 2009-12-03 2011-06-09 Marina Yakovleva Finely deposited lithium metal powder
KR101621383B1 (ko) * 2009-12-22 2016-05-16 삼성에스디아이 주식회사 리튬 전지
DE102010006076A1 (de) * 2010-01-28 2011-08-18 Süd-Chemie AG, 80333 Elektrode für eine Sekundärlithiumionenbatterie
DE102010006083B4 (de) * 2010-01-28 2014-12-11 Süd-Chemie Ip Gmbh & Co. Kg Substituiertes Lithium-Mangan-Metallphosphat
ES2750527T3 (es) 2010-02-17 2020-03-26 All American Lithium LLC Procedimientos de preparación de carbonato de litio altamente puro y de otros compuestos que contienen litio altamente puro
JPWO2011111628A1 (ja) * 2010-03-09 2013-06-27 旭硝子株式会社 リン酸化合物、二次電池用正極、及び二次電池の製造方法
SG187660A1 (en) * 2010-08-20 2013-03-28 Univ Singapore Mesoporous metal phosphate materials for energy storage application
US20120164319A1 (en) * 2010-12-21 2012-06-28 Lang Christopher M Method of Forming a Metal Phosphate Coated Cathode for Improved Cathode Material Safety
WO2012088509A1 (en) 2010-12-23 2012-06-28 Wildcat Discovery Technologies, Inc. Lithium-ion battery materials with improved properties
US9577261B2 (en) * 2011-03-18 2017-02-21 Semiconductor Energy Laboratory Co., Ltd. Lithium ion secondary battery and method for manufacturing the same
JP5553057B2 (ja) * 2011-05-09 2014-07-16 ソニー株式会社 正極活物質及び非水電解質電池
US11476462B2 (en) 2011-06-22 2022-10-18 National Tsing Hua University LiFePO4 precursor for manufacturing electrode material of Li-ion battery and method for manufacturing the same
TWI443899B (zh) * 2011-06-22 2014-07-01 Nat Univ Tsing Hua 鋰離子電池之磷酸鋰鐵粉末及其製作方法
FR2978137A1 (fr) * 2011-07-21 2013-01-25 Saint Gobain Ct Recherches Produit fondu a base de lithium
CN102683684B (zh) * 2011-12-12 2015-09-30 张雅静 硒、钡掺杂磷酸铁锂纳米正极材料及其制备方法
CN103165881B (zh) * 2011-12-12 2017-06-30 张健 掺杂磷酸铁锂纳米正极材料及其制备方法
CN102496711B (zh) * 2011-12-13 2013-04-10 海门容汇通用锂业有限公司 一种高比表面积微米级磷酸亚铁锂的制造方法
US9090476B2 (en) 2012-03-22 2015-07-28 Chun-Chieh Chang Direct deposition of graphene on substrate material
US9059466B2 (en) 2012-03-22 2015-06-16 Chun-Chieh Chang Direct synthesis of lithium ion battery electrode materials using graphene treated raw materials as the reactant
JP5821877B2 (ja) * 2012-03-27 2015-11-24 Tdk株式会社 リチウムイオン二次電池
CN105190966B (zh) 2012-12-19 2018-06-12 锡安能量公司 电极结构及其制造方法
WO2014120238A1 (en) 2013-02-01 2014-08-07 Tronox Llc Improved lithium manganese oxide compositions
US20150209654A1 (en) 2013-11-12 2015-07-30 Deq Systems Corp. Reconfigurable playing cards and game display devices
WO2015153485A1 (en) 2014-04-01 2015-10-08 The Research Foundation For The State University Of New York Electrode materials for group ii cation-based batteries
US9711784B2 (en) 2014-05-01 2017-07-18 Sion Power Corporation Electrode fabrication methods and associated systems and articles
US10673065B2 (en) * 2015-04-07 2020-06-02 Brown University Cation energy storage device and methods
US10398641B2 (en) 2016-09-08 2019-09-03 Foamix Pharmaceuticals Ltd. Compositions and methods for treating rosacea and acne
US11909046B2 (en) 2017-03-07 2024-02-20 The Research Foundation For The State University Of New York Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions
US10604414B2 (en) 2017-06-15 2020-03-31 Energysource Minerals Llc System and process for recovery of lithium from a geothermal brine
US11251430B2 (en) 2018-03-05 2022-02-15 The Research Foundation For The State University Of New York ϵ-VOPO4 cathode for lithium ion batteries
JP7425751B2 (ja) * 2018-05-30 2024-01-31 ハイドロ-ケベック セラミック、その生成のための方法、およびその使用
WO2020047213A1 (en) * 2018-08-30 2020-03-05 HYDRO-QUéBEC Attritor-mixed positive electrode active materials
EP3844831A4 (en) * 2018-08-30 2022-06-29 Hydro-Québec Coated lithium ion rechargeable battery active materials
CN111816881B (zh) * 2019-08-28 2021-11-26 中南大学 一种类红毛丹壳状3d亲锂复合集流体、锂金属负极及其制备和应用

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US584893A (en) * 1897-06-22 Roller-bearing
US3736184A (en) 1972-03-29 1973-05-29 Mallory & Co Inc P R Metal phosphate and metal arsenate organic electrolyte cells
US4009092A (en) 1976-02-27 1977-02-22 E. I. Du Pont De Nemours And Company Substituted lithium phosphates and solid electrolytes therefrom
US4049891A (en) 1976-06-21 1977-09-20 Massachusetts Institute Of Technology Compositions for fast alkali-metal-ion transport
FR2457018A1 (fr) 1979-02-16 1980-12-12 Accumulateurs Fixes Matiere active positive pour generateur electrochimique a electrolyte non aqueux et methode de preparation de celle-ci
US4434216A (en) 1980-10-24 1984-02-28 Rayovac Corporation Solid state electrolyte
US4512905A (en) 1982-05-18 1985-04-23 The Texas A&M University System Method of making sodium zirconium silico-phosphates
US4707422A (en) 1983-06-27 1987-11-17 Voltaix, Inc. Composite coating for electrochemical electrode and method
FR2563382B1 (fr) 1984-04-24 1986-05-30 Elf Aquitaine Nouveau generateur electrochimique a electrode composite
FR2576712B1 (fr) 1985-01-30 1988-07-08 Accumulateurs Fixes Generateur electrochimique a electrolyte non aqueux
JPS61263069A (ja) 1985-05-17 1986-11-21 Matsushita Electric Ind Co Ltd 電池
US4985317A (en) 1988-11-30 1991-01-15 Japan Synthetic Rubber Co., Ltd. Lithium ion-conductive solid electrolyte containing lithium titanium phosphate
FR2655777A1 (fr) 1989-12-11 1991-06-14 Accumulateurs Fixes Generateur electrochimique rechargeable comprenant une cathode a base d'oxyde de vanadium.
US5262548A (en) 1990-05-21 1993-11-16 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
DE4024409A1 (de) 1990-08-01 1992-02-06 Geismar Guenter Phosphathaltige gruen-, tuerkis- und blaupigmente
US5232794A (en) 1991-10-17 1993-08-03 The United States Of America As Represented By The United States Department Of Energy Ionic conductors for solid oxide fuel cells
JP3177304B2 (ja) 1992-02-18 2001-06-18 三洋電機株式会社 固体電解質及びそれを使用してなるリチウム電池
JPH05325961A (ja) 1992-05-18 1993-12-10 Mitsubishi Cable Ind Ltd リチウム電池
CA2096386A1 (en) * 1992-05-18 1993-11-19 Masahiro Kamauchi Lithium secondary battery
EP0571858B1 (en) 1992-05-18 1996-08-14 Mitsubishi Cable Industries, Ltd. Lithium secondary battery
US5296436A (en) 1993-01-08 1994-03-22 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
JPH06251764A (ja) 1993-02-22 1994-09-09 Fuji Elelctrochem Co Ltd リチウム二次電池
JP2966261B2 (ja) 1993-11-02 1999-10-25 三菱電線工業株式会社 リチウム電池用正極材及びその製造方法
US5496663A (en) 1994-08-19 1996-03-05 Tracor Applied Sciences, Inc. Lithium ion battery with lithium vanadium pentoxide positive electrode
US5514490A (en) 1994-08-30 1996-05-07 Industrial Technology Research Institute Secondary lithium battery using a new layered anode material
JPH08171938A (ja) 1994-12-15 1996-07-02 Mitsubishi Cable Ind Ltd Li二次電池及びその正極
US5721070A (en) * 1995-04-13 1998-02-24 Shackle; Dale R. Alkali metal ion battery electrode material
JP3484003B2 (ja) 1995-11-07 2004-01-06 日本電信電話株式会社 非水電解質二次電池
JP3523397B2 (ja) 1995-11-07 2004-04-26 日本電信電話株式会社 非水電解質二次電池
US5584893A (en) * 1995-11-17 1996-12-17 Valence Technology, Inc. Method of preparing electrodes for an electrochemical cell
JP3319258B2 (ja) 1995-12-21 2002-08-26 ソニー株式会社 リチウム二次電池用正極活物質の製造方法及びリチウム二次電池の製造方法
US6514640B1 (en) * 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US5910382A (en) 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US5871866A (en) 1996-09-23 1999-02-16 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and use thereof
CA2200998A1 (en) 1997-03-25 1998-09-25 Hydro-Quebec New lithium insertion electrode materials based on tetraoxyanions derivatives with olivine structure
JPH1125983A (ja) 1997-07-04 1999-01-29 Japan Storage Battery Co Ltd リチウム電池用活物質
JPH1125998A (ja) * 1997-07-07 1999-01-29 Japan Storage Battery Co Ltd 高分子電解質膜−反応部接合体の製造方法
JP3965657B2 (ja) 1997-10-03 2007-08-29 株式会社ジーエス・ユアサコーポレーション リチウム電池用活物質およびそれを用いたリチウム電池用正極
JP2000060680A (ja) 1998-08-21 2000-02-29 Calsonic Corp 車両用座席の冷暖房装置
US6153333A (en) 1999-03-23 2000-11-28 Valence Technology, Inc. Lithium-containing phosphate active materials
CN1323447C (zh) 1999-04-06 2007-06-27 索尼株式会社 正极活性物质及无水电解质二次电池
JP4949543B2 (ja) 1999-04-06 2012-06-13 ソニー株式会社 LiFePO4の合成方法及び非水電解質電池の製造方法
CA2270771A1 (fr) * 1999-04-30 2000-10-30 Hydro-Quebec Nouveaux materiaux d'electrode presentant une conductivite de surface elevee
JP2001052733A (ja) 1999-08-05 2001-02-23 Matsushita Electric Ind Co Ltd 全固体リチウム二次電池
US6187192B1 (en) * 1999-08-25 2001-02-13 Watervisions International, Inc. Microbiological water filter
JP3504195B2 (ja) 1999-09-16 2004-03-08 日本電信電話株式会社 リチウム二次電池正極活物質およびリチウム二次電池
JP2001110414A (ja) 1999-10-04 2001-04-20 Nippon Telegr & Teleph Corp <Ntt> リチウム二次電池正極活物質およびリチウム二次電池
JP2001110455A (ja) 1999-10-12 2001-04-20 Sony Corp 非水電解質電池
US7001690B2 (en) * 2000-01-18 2006-02-21 Valence Technology, Inc. Lithium-based active materials and preparation thereof
US6528033B1 (en) * 2000-01-18 2003-03-04 Valence Technology, Inc. Method of making lithium-containing materials

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