AR028795A1 - Catalizador y procedimiento para la trimerizacion de olefinas - Google Patents

Catalizador y procedimiento para la trimerizacion de olefinas

Info

Publication number
AR028795A1
AR028795A1 ARP010103276A ARP010103276A AR028795A1 AR 028795 A1 AR028795 A1 AR 028795A1 AR P010103276 A ARP010103276 A AR P010103276A AR P010103276 A ARP010103276 A AR P010103276A AR 028795 A1 AR028795 A1 AR 028795A1
Authority
AR
Argentina
Prior art keywords
catalyst
trimerization
procedure
olefins
groups
Prior art date
Application number
ARP010103276A
Other languages
English (en)
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of AR028795A1 publication Critical patent/AR028795A1/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/60—Groups characterized by their function
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/01—Cp or analog bridged to a non-Cp X neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
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    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
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    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un procedimiento para la trimerizacion de olefinas que comprende poner en contacto una olefina monomérica o una mezcla de olefinas, bajo condiciones de trimerizacion, con un catalizador que comprende: (a) una fuente de un metal de transicion de los Grupos 3 a 10; (b) un ligando que contiene al menos un átomo de fosforo, arsénico o antimonio enlazado a por lo menos un grupo hidrocarbilo o heterohidrocarbilo que tiene un sustituyente polar, pero excluyendo el caso en donde todos esos sustituyentes polares son grupos fosfano, arsano o estibano; y opcionalmente (c) un activador.
ARP010103276A 2000-07-11 2001-07-10 Catalizador y procedimiento para la trimerizacion de olefinas AR028795A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0016895.5A GB0016895D0 (en) 2000-07-11 2000-07-11 Olefin oligomerisation

Publications (1)

Publication Number Publication Date
AR028795A1 true AR028795A1 (es) 2003-05-21

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ARP010103276A AR028795A1 (es) 2000-07-11 2001-07-10 Catalizador y procedimiento para la trimerizacion de olefinas

Country Status (23)

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US (2) US6800702B2 (es)
EP (1) EP1299189B1 (es)
JP (1) JP5507781B2 (es)
KR (1) KR100845444B1 (es)
CN (1) CN100402152C (es)
AR (1) AR028795A1 (es)
AU (1) AU2001267743A1 (es)
BG (1) BG107539A (es)
BR (1) BR0112470B1 (es)
CA (1) CA2412990C (es)
EG (1) EG22912A (es)
ES (1) ES2662900T3 (es)
GB (1) GB0016895D0 (es)
HU (1) HUP0400497A2 (es)
MX (1) MXPA03000301A (es)
MY (1) MY128288A (es)
NO (1) NO20030108L (es)
PL (1) PL358746A1 (es)
RU (1) RU2299096C2 (es)
SK (1) SK172003A3 (es)
TW (1) TW562696B (es)
WO (1) WO2002004119A1 (es)
ZA (1) ZA200210392B (es)

Families Citing this family (169)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4266827B2 (ja) * 2001-12-20 2009-05-20 サソル テクノロジー （ピーティーワイ）リミテッド クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化
EP1456152B1 (en) 2001-12-20 2012-06-13 Sasol Technology (Pty) Ltd Trimerisation and oligomerisation of olefins using a chromium based catalyst
US7297832B2 (en) 2002-12-20 2007-11-20 Sasol Technology (Pty) Limited Tetramerization of olefins
MY145849A (en) * 2002-12-20 2012-04-30 Shell Int Research Diesel fuel compositions
CA2509700A1 (en) 2002-12-20 2004-07-08 Sasol Technology (Pty) Limited Tandem tetramerisation-polymerisation of olefins
US7525009B2 (en) 2002-12-20 2009-04-28 Sasol Technology (Pty) Limited Trimerisation of olefins
ATE477053T1 (de) 2002-12-20 2010-08-15 Sasol Tech Pty Ltd Tetramerisierung von olefinen
US7273959B2 (en) 2003-10-10 2007-09-25 Shell Oil Company Catalytic trimerization of olefinic monomers
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US7285607B2 (en) * 2004-05-18 2007-10-23 Sasol, Chemical Industries, Limited Polymerisation of olefinic compounds
EP1765495B1 (en) * 2004-06-18 2011-09-07 Sasol Technology (Pty) Ltd Oligomerisation in the presence of both a tetramerisation catalyst and a further oligomerisation catalyst
EP1756024B1 (en) * 2004-06-18 2018-08-15 Sasol Technology (Pty) Ltd Oligomerisation of olefinic compounds in an aliphatic medium
JP2006218437A (ja) * 2005-02-14 2006-08-24 Sumitomo Chemical Co Ltd オレフィンの三量化触媒およびその触媒を用いたオレフィンの三量化方法
JP4982952B2 (ja) * 2005-02-14 2012-07-25 住友化学株式会社 エチレンの三量化触媒およびその触媒を用いたエチレンの三量化方法
US7414006B2 (en) * 2005-03-09 2008-08-19 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
JP5448142B2 (ja) * 2005-03-09 2014-03-19 エクソンモービル・ケミカル・パテンツ・インク オレフィンのオリゴマー化
US7259123B2 (en) 2005-04-08 2007-08-21 Shell Oil Company Catalytic trimerization and tetramerization of olefinic monomers
JP2007039641A (ja) * 2005-06-28 2007-02-15 Sumitomo Chemical Co Ltd オレフィンオリゴマーの製造方法
US7323611B2 (en) 2005-06-28 2008-01-29 Sumitomo Chemical Company Limited Process for producing olefin oligomer
US8461406B2 (en) 2005-07-12 2013-06-11 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds in the presence of a diluted metal containing activator
US7550639B2 (en) 2005-07-27 2009-06-23 Sumitomo Chemical Company, Limited Process for producing olefin oligomer
JP2007056002A (ja) * 2005-07-27 2007-03-08 Sumitomo Chemical Co Ltd オレフィンオリゴマーの製造方法
RU2008125139A (ru) * 2005-11-21 2009-12-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Каталитическая олигомеризация олефиновых мономеров
BRPI0618826A2 (pt) * 2005-11-21 2016-09-13 Shell Int Research processo para a trimerização e tetramerização simultânea de monômeros olefínicos
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
US7687672B2 (en) * 2006-02-03 2010-03-30 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
WO2007092136A2 (en) * 2006-02-03 2007-08-16 Exxonmobil Chemical Patents, Inc. Process for generating alpha olefin comonomers
US7982085B2 (en) * 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
BRPI0707407A2 (pt) * 2006-02-03 2011-05-03 Ineos Europe Ltd catalisadores de metais de transição
US7858833B2 (en) * 2006-02-03 2010-12-28 Exxonmobil Chemical Patents Inc. Process for generating linear alpha olefin comonomers
KR100784118B1 (ko) * 2006-02-09 2007-12-12 한국화학연구원 올레핀의 삼량체 제조방법 및 그를 이용한고비점알킬레이트 제조 방법
US7378537B2 (en) 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
US8404915B2 (en) * 2006-08-30 2013-03-26 Exxonmobil Chemical Patents Inc. Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations
EP2125845A1 (en) 2006-12-22 2009-12-02 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
JP5421118B2 (ja) * 2006-12-22 2014-02-19 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ オレフィンモノマーのオリゴマー化用配位子及び触媒
EA024462B1 (ru) 2006-12-28 2016-09-30 Мицубиси Кемикал Корпорейшн СПОСОБ ПОЛУЧЕНИЯ НИЗКОМОЛЕКУЛЯРНОГО ПОЛИМЕРА α-ОЛЕФИНА
WO2008085659A1 (en) 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine ether catalysts
EP2104679A1 (en) 2007-01-08 2009-09-30 ExxonMobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts
WO2008085658A1 (en) 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine thioether catalysts
KR101074202B1 (ko) 2007-01-18 2011-10-14 에스케이종합화학 주식회사 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법
KR101095796B1 (ko) * 2007-02-08 2011-12-21 에스케이종합화학 주식회사 담지용 에틸렌 사량체화 촉매계 및 이를 이용한 에틸렌 사량체화 방법
CA2583007C (en) 2007-03-29 2015-03-31 Nova Chemicals Corporation Amino phosphine
MY148530A (en) * 2007-05-28 2013-04-30 Sasol Tech Pty Ltd Two stage activation of oligomerisation catalyst and oligomerisation of olefinic compounds inthe presence of an oligomerisation catalyst so activated
CN101720253B (zh) * 2007-07-11 2013-07-17 林德股份公司 用于乙烯二聚、三聚和/或四聚的催化剂组合物和方法
KR101057576B1 (ko) 2007-08-16 2011-08-17 에스케이종합화학 주식회사 선택적 에틸렌 올리머고화 촉매계
EP2217550B1 (en) * 2007-11-07 2015-07-29 Sasol Technology (Proprietary) Limited Process for polymerising or oligomerising a hydrocarbon
BRPI0819904B1 (pt) * 2007-11-28 2018-02-06 Linde Aktiengesellschaft. Composição catalisadora e processo para oligomerização de etileno
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
EP2080745B1 (en) * 2007-12-27 2010-07-28 Linde AG Method for oligomerisation of ethylene and reactor system therefore
ES2367133T3 (es) * 2008-04-04 2011-10-28 Saudi Basic Industries Corporation Catalizador para la oligomerización de etileno, procedimiento para la preparación del mismo y procedimiento de oligomerización que usa el mismo.
US8217128B2 (en) 2008-09-04 2012-07-10 Amyris, Inc. Farnesene interpolymers
US8592543B2 (en) 2008-09-04 2013-11-26 Derek James McPhee Polyfarnesenes
CA2639882C (en) * 2008-09-29 2016-07-12 Nova Chemicals Corporation Tetramerization
CA2639870A1 (en) * 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
US8436111B2 (en) * 2008-10-01 2013-05-07 Bridgestone Corporation Nickel catalyst system for the preparation of high CIS polybutadiene
US20100094070A1 (en) * 2008-10-15 2010-04-15 Headwaters Technology Innovation, Llc Ethylene trimerization using a supported chromium-tantalum catalyst
US8084659B2 (en) * 2008-10-22 2011-12-27 Lummus Technology, Inc. Hexene upgrading
KR101065596B1 (ko) * 2009-01-29 2011-09-19 에스케이종합화학 주식회사 고활성과 고선택적인 에틸렌 올리머고화 촉매 및 이를 이용한 헥센 또는 옥텐의 제조방법
EP2396112B1 (en) 2009-02-16 2014-05-07 Sasol Technology (Pty) Ltd Oligomerisation of olefinic compounds in the presence of an activated oligomerisation catalyst
EP2239056B1 (en) * 2009-04-09 2011-07-20 Saudi Basic Industries Corporation Catalyst composition and process for oligomerization of ethylene
BR112012009098B1 (pt) * 2009-10-19 2018-05-22 Sasol Technology PTY Oligomerização de compostos olefínicos com formação reduzida de polímero
CN102107146B (zh) * 2009-12-29 2013-10-16 中国石油天然气股份有限公司 一种用于乙烯三聚合成己烯-1的催化剂及其应用
BR122020019821B1 (pt) 2009-12-31 2021-11-09 Chevron Phillips Chemical Company Lp Composto de n2-fosfinil amidina, complexo de sal metálico do referido composto e métodos para preparação dos mesmos
WO2011085951A1 (en) 2010-01-15 2011-07-21 Basell Polyolefine Gmbh Oligomerization of olefins
RU2430116C1 (ru) * 2010-01-29 2011-09-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ полимеризации и сополимеризации олефиновых олигомеров
US20120309997A1 (en) 2010-02-12 2012-12-06 Enantia, S.L. Enantiomerically Enriched Aminodiphosphines as Ligands for the Preparation of Catalysts for Asymmetric Synthesis
BR112012007895B8 (pt) * 2010-03-03 2022-11-08 Sk Global Chemical Co Ltd Composto de complexo de cromo para oligomerização seletiva de etileno, composição de catalisador de complexo de cromo para oligomerização seletiva de etileno e método de preparação de 1-hexeno ou 1-octeno a partir de etileno
SG183230A1 (en) 2010-03-09 2012-09-27 Exxonmobil Chem Patents Inc System and method for selective trimerization
CA2703435C (en) * 2010-05-12 2017-05-02 Nova Chemicals Corporation Oligomerization process using a chromium p-n-p catalyst with added alkyl zinc
CN106000393B (zh) 2010-05-24 2019-11-19 希路瑞亚技术公司 纳米线催化剂
CA2716714C (en) 2010-10-06 2017-05-16 Nova Chemicals Corporation Tetramerization ligands
CA2718455C (en) * 2010-10-22 2017-08-22 Nova Chemicals Corporation Ethylene oligomerization using partially hydrolyzed tma in a non-aromatic solvent
WO2012055943A2 (en) 2010-10-28 2012-05-03 Basell Polyolefine Gmbh Oligomerization of olefins
WO2012062469A1 (en) 2010-11-10 2012-05-18 Stichting Dutch Polymer Institute Ethylene oligomerization catalyst
CA2723515C (en) 2010-12-01 2018-05-15 Nova Chemicals Corporation Heat management in ethylene oligomerization
US20120172645A1 (en) * 2010-12-29 2012-07-05 Chevron Phillips Chemical Company Lp Olefin Oligomerization catalysts and Methods of Making and Using Same
CA2737713C (en) * 2011-04-20 2018-10-30 Nova Chemicals Corporation Activation for oligomerization
EA029867B1 (ru) 2011-05-24 2018-05-31 Силурия Текнолоджиз, Инк. Катализаторы для нефтехимического катализа
KR101471156B1 (ko) * 2011-06-14 2014-12-10 주식회사 엘지화학 선택적 에틸렌 올리고머화 촉매계
CN104039451B (zh) 2011-11-29 2018-11-30 希路瑞亚技术公司 纳米线催化剂及其应用和制备方法
US8957235B2 (en) 2011-12-12 2015-02-17 Chevron Phillips Chemical Company Lp Preparation of transition metal carboxylates
US9956548B2 (en) * 2011-12-12 2018-05-01 Chevron Phillips Chemical Company Lp Preparation of an olefin oligomerization catalyst
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
WO2013106771A2 (en) 2012-01-13 2013-07-18 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
CA2765429C (en) 2012-01-25 2019-12-31 Nova Chemicals Corporation P-n-p ligand
US9446397B2 (en) 2012-02-03 2016-09-20 Siluria Technologies, Inc. Method for isolation of nanomaterials
KR101846031B1 (ko) 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계
US8524972B1 (en) 2012-04-18 2013-09-03 Exxonmobil Chemical Patents Inc. Low temperature steam stripping for byproduct polymer and solvent recovery from an ethylene oligomerization process
CA2866971C (en) 2012-05-09 2020-07-07 Sasol Technology (Proprietary) Limited Oligomerisation of olefinic compounds with reduced polymer formation
US9469577B2 (en) 2012-05-24 2016-10-18 Siluria Technologies, Inc. Oxidative coupling of methane systems and methods
WO2013177461A2 (en) 2012-05-24 2013-11-28 Siluria Technologies, Inc. Catalytic forms and formulations
FR2992962B1 (fr) * 2012-07-04 2015-06-26 Axens Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
NL1039868C2 (en) 2012-11-01 2014-05-06 Stichting Dutch Polymer Inst Process for producing an oligo(alpha-olefin) and the use of a particular form of methylaluminoxane in such process.
KR101483248B1 (ko) 2012-11-15 2015-01-16 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 에틸렌 올리고머화용 촉매계, 이의 제조 방법 및 이를 이용한 에틸렌 올리고머화 방법
AU2013355038B2 (en) 2012-12-07 2017-11-02 Lummus Technology Llc Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
CA2800268C (en) 2012-12-21 2020-02-25 Nova Chemicals Corporation Continuous ethylene tetramerization process
EP2764913A1 (en) 2013-02-11 2014-08-13 Linde AG Method for purifying a crude PNPNH compound
EP2764914A1 (en) * 2013-02-11 2014-08-13 Linde AG Metalated PNPNH ligand, catalyst composition and use thereof in the oligomerization of ethylene
EP2764915B1 (en) 2013-02-11 2017-03-22 Linde AG Purification method for a crude PNPNH compound
US9616421B2 (en) 2013-02-27 2017-04-11 Mitsui Chemicals, Inc. Catalyst for olefin multimerization and method for producing olefin multimer in presence of catalyst for olefin multimerization
CA2902192C (en) 2013-03-15 2021-12-07 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
RU2525118C1 (ru) * 2013-03-28 2014-08-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Каталитическая система процесса тримеризации этилена в альфа-олефины
MX364016B (es) 2013-05-09 2019-04-11 Sasol Tech Pty Ltd Oligomerizacion de etileno para mezclas de 1-hexeno y 1-octeno.
SG10201901004SA (en) 2013-05-09 2019-03-28 Sasol Tech Pty Ltd Tetramerisation of ethylene
CN105228974B (zh) 2013-05-09 2021-01-19 沙索技术有限公司 乙烯低聚成1-己烯和1-辛烯的混合物的低聚方法
EP2832445A1 (en) * 2013-07-29 2015-02-04 Linde AG Catalyst composition and process for oligomerization of ethylene
EP3074119B1 (en) 2013-11-27 2019-01-09 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA2835683C (en) 2013-12-05 2021-07-06 Nova Chemicals Corporation Ethylene oligomerization with mixed ligands
CA2837590C (en) 2013-12-23 2020-12-15 Nova Chemicals Corporation Continuous ethylene oligomerization with in-situ catalyst preparation
CN108264444A (zh) * 2014-01-06 2018-07-10 沙特基础工业公司 用于乙烯反应中的催化剂活化的改良的预形成方法
CN110655437B (zh) 2014-01-08 2022-09-09 鲁玛斯技术有限责任公司 乙烯成液体的系统和方法
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
EP3097068A4 (en) 2014-01-09 2017-08-16 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
WO2015168601A2 (en) 2014-05-02 2015-11-05 Siluria Technologies, Inc. Heterogeneous catalysts
GB201408616D0 (en) * 2014-05-15 2014-06-25 Scg Chemicals Co Ltd Solid-supported catalyst, use of the same and process for producing polymers
WO2015194801A1 (ko) * 2014-06-18 2015-12-23 주식회사 엘지화학 올레핀 올리고머의 제조 방법
WO2015194887A1 (ko) 2014-06-18 2015-12-23 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
KR101607214B1 (ko) 2014-06-18 2016-03-29 주식회사 엘지화학 올레핀 올리고머의 제조 방법
KR20170035889A (ko) 2014-07-24 2017-03-31 사빅 글로벌 테크놀러지스 비.브이. 1-헥센 및/또는 1-옥텐을 제조하기 위한 에틸렌의 올리고머화를 위한 촉매 조성물 및 에틸렌의 올리고머화 방법
EP3194070B1 (en) 2014-09-17 2020-12-23 Lummus Technology LLC Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ethane
CN105481662B (zh) * 2014-09-18 2017-10-24 江苏和成新材料有限公司 制备用于生产含二氟甲氧基液晶化合物的中间体的方法
KR101757369B1 (ko) 2014-12-11 2017-07-12 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
WO2016129845A1 (ko) * 2015-02-12 2016-08-18 주식회사 엘지화학 비활성화제 및 이를 이용한 올레핀 올리고머화의 부산물 저감 방법
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
EP3243847B1 (en) * 2015-05-15 2020-08-26 LG Chem, Ltd. Catalytic composition and method of preparing polyolefin using same
KR101768194B1 (ko) 2015-05-15 2017-08-16 주식회사 엘지화학 촉매 조성물 및 이를 이용한 폴리올레핀의 제조방법
KR101757835B1 (ko) 2015-06-12 2017-07-13 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
WO2016205411A2 (en) 2015-06-16 2016-12-22 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US20170107162A1 (en) 2015-10-16 2017-04-20 Siluria Technologies, Inc. Separation methods and systems for oxidative coupling of methane
KR101982789B1 (ko) 2015-12-04 2019-05-27 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
EP3429747A2 (en) 2016-03-16 2019-01-23 Siluria Technologies, Inc. Catalysts and methods for natural gas processes
US9944573B2 (en) 2016-04-13 2018-04-17 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
US10329212B2 (en) 2016-05-27 2019-06-25 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
KR102545533B1 (ko) 2016-05-27 2023-06-21 에스케이이노베이션 주식회사 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
US10414699B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Process improvements in selective ethylene oligomerizations
US10414698B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
KR102301007B1 (ko) * 2016-06-23 2021-09-10 보레알리스 아게 촉매 비활성화 방법
KR102428770B1 (ko) 2016-07-14 2022-08-04 에스케이이노베이션 주식회사 에틸렌의 올리고머화 방법
WO2018012792A1 (en) 2016-07-14 2018-01-18 Sk Innovation Co., Ltd. Oligomerization of ethylene
KR102218261B1 (ko) * 2016-07-15 2021-02-23 퍼블릭 조인트 스톡 컴퍼니 “시부르 홀딩” 올레핀의 올리고머화 방법
KR102563683B1 (ko) 2016-07-18 2023-08-07 에스케이이노베이션 주식회사 올레핀의 올리고머화 방법
US20180169561A1 (en) 2016-12-19 2018-06-21 Siluria Technologies, Inc. Methods and systems for performing chemical separations
ES2960342T3 (es) 2017-05-23 2024-03-04 Lummus Technology Inc Integración de procedimientos de acoplamiento oxidativo del metano
US10232339B2 (en) 2017-06-06 2019-03-19 Chevron Phillips Chemical Company Lp Fouling protection for an oligomerization reactor inlet
KR102450815B1 (ko) 2017-06-16 2022-10-05 에스케이이노베이션 주식회사 헤테로원자 리간드, 이를 포함하는 올리고머화 촉매 및 올리고머 제조방법
US10836689B2 (en) 2017-07-07 2020-11-17 Lummus Technology Llc Systems and methods for the oxidative coupling of methane
US10294171B2 (en) 2017-09-22 2019-05-21 Chevron Phillips Chemical Company Lp Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene
US10493442B2 (en) 2017-09-22 2019-12-03 Chevron Phillips Chemical Company Lp Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10183960B1 (en) 2017-09-22 2019-01-22 Chevron Phillips Chemical Company Lp Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10464862B2 (en) 2017-09-28 2019-11-05 Chevron Phillips Chemical Company Lp Oligomerization reactions using aluminoxanes
WO2019168249A1 (ko) 2018-02-27 2019-09-06 에스케이이노베이션 주식회사 리간드, 이를 포함하는 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
KR102605188B1 (ko) 2018-02-27 2023-11-24 에스케이이노베이션 주식회사 리간드, 이를 포함하는 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
KR20200004501A (ko) * 2018-07-04 2020-01-14 한국화학연구원 전환율 및 선택도가 향상된 올레핀 제조용 촉매 및 그 제조방법
US11826743B2 (en) 2019-01-15 2023-11-28 China Petroleum & Chemical Corporation Halogen-containing compound and use thereof as catalyst ligand in ethylene oligomerization
CN113747970B (zh) 2019-01-30 2024-05-07 鲁姆斯科技有限责任公司 用于甲烷氧化偶联的催化剂
JP2020158420A (ja) * 2019-03-26 2020-10-01 三井化学株式会社 オレフィン多量化用触媒およびその触媒存在下で行うオレフィン多量体の製造方法
US11492305B1 (en) 2021-11-08 2022-11-08 Chevron Phillips Chemical Company, Lp Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene
US11583843B1 (en) 2021-11-08 2023-02-21 Chevron Phillips Chemical Company, Lp Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene
US11505513B1 (en) 2021-11-08 2022-11-22 Chevron Phillips Chemical Company, Lp Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene
CN114509517A (zh) * 2022-02-21 2022-05-17 祁国庆 利用气相色谱-质谱联用仪分析工业乙烯、丙烯中砷烷、膦烷的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3300458A (en) * 1963-08-19 1967-01-24 Union Carbide Corp Continuous processes for the production of ethylene polymers and catalysts suitable therefor
US4472525A (en) 1983-06-06 1984-09-18 Shell Oil Company Ethylene oligomerization process
US4668838A (en) * 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
US4689437A (en) * 1986-07-21 1987-08-25 Union Carbide Corporation Oligomerization to alpha-olefins
US5198563A (en) * 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
US5811618A (en) * 1991-10-16 1998-09-22 Amoco Corporation Ethylene trimerization
CA2115639C (en) * 1993-03-03 2004-10-19 Feng-Jung Wu Ethylene trimerization
JPH08283405A (ja) * 1995-03-22 1996-10-29 Shell Internatl Res Maatschappij Bv 一酸化炭素とオレフィン性不飽和化合物との共重合化方法
JPH09143228A (ja) * 1995-11-22 1997-06-03 Sumitomo Chem Co Ltd エチレン−α−オレフィン共重合体の製造方法
AU2302797A (en) 1996-04-04 1997-10-29 Bp Chemicals Limited Novel catalyst composition
GB9918635D0 (en) 1999-08-06 1999-10-13 Bp Chem Int Ltd Polymerisation process
KR101057576B1 (ko) * 2007-08-16 2011-08-17 에스케이종합화학 주식회사 선택적 에틸렌 올리머고화 촉매계

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