AR019984A1 - Compuestos de aluminio tricoordinado; dimeros aductos y mezclas de los mismos, utiles como activadores de catalizadores de polimerizacion de olefinas;composiciones catalizadoras que incluyen dichos compuestos activadores; procesos de polimerizacion de monomeros polimerizables por adicion utilizando - Google Patents
Compuestos de aluminio tricoordinado; dimeros aductos y mezclas de los mismos, utiles como activadores de catalizadores de polimerizacion de olefinas;composiciones catalizadoras que incluyen dichos compuestos activadores; procesos de polimerizacion de monomeros polimerizables por adicion utilizandoInfo
- Publication number
- AR019984A1 AR019984A1 ARP990103826A ARP990103826A AR019984A1 AR 019984 A1 AR019984 A1 AR 019984A1 AR P990103826 A ARP990103826 A AR P990103826A AR P990103826 A ARP990103826 A AR P990103826A AR 019984 A1 AR019984 A1 AR 019984A1
- Authority
- AR
- Argentina
- Prior art keywords
- hydrocarbyl
- compounds
- formula
- mixtures
- addition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000012190 activator Substances 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003213 activating effect Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 6
- 125000004122 cyclic group Chemical group 0.000 abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 3
- 125000004429 atom Chemical group 0.000 abstract 2
- 239000000539 dimer Substances 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- -1 adducts Substances 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Se trata de compuestos que corresponden a la formula AlAr1Q1Q2, o dímeros, aductos, mezclas de los mismos y mezclas adicionales con compuestos de aluminiode formula AlAr13, donde: Ar1 es una fraccion hidrocarbilo fluorada aromática de 6 a 30 átomos de carbono; Q1 es Ar1 o un grupo hidrocarbilo de C1-20,sustituido opcionalmente con uno o más grupos ciclohidrocarbilo, hidrocarbiloxi, hidrocarbilsiloxi, hidrocarbilsililoamino hidrocarbilsililo,sililhidrocarbilodi(hidrocarbilsil)amino, hidrocarbilamino, di(hidrocarbil)amino, di(hidrocarbil) fosfino, o hidrocarbilsulfuro que tienen de 1 a 20 átomos diferentes a H, yopcionalmente, dichos sustituyentes pueden estar ligados covalentemetne entre sí para formar uno o más anillos fusionados o sistemasde anillos; y Q2 es ungrupo ariloxi, arilsulfuro o di(hidrocarbil)amido, opcionalmente sustituido con uno o más grupos hidrocarbilo, ciclohidrocarbilo, hidrocarbiloxi,hidrocarbilosiloxi, hidrocarbilsililamino, hidrocarbilsililo, sililhidrocarbilo, di(hidrocarbilsilil)amino, hidrocarbilamino, di(hidrocarbil)amino,di(hidrocarbil)fosfino, o hidrocarbilsulfuro que tienen 1 a 20 átomos diferentes de hidrogeno, o además opcionalmente dichos sustituyentes pueden estar ligadoscovalentemente entre sí para formar uno o más anillos fusionados o sistemas de anillos fusionados o sistemas de anillos, teniendo Q2 de 3 a 20 átomosdiferentes a hidrogeno. Dichos compuestos de aluminio tricoordinados y los aductos son utiles como activadores para polimerizaciones de olefinas. La invencionincluye los procesos de polimerizacion por adiccion de monomeros, poniendo en contacto dichos monomeros con dichas composiciones catalizadoras, opcionalmenteen presencia de hidrocarburos alifáticos, alicíclicos, aromáticos inertes y, además la preparacion de dichos complejos de formula Al1ArQ1Q2 dímeros, aductos ymezclas de los mismos, haciendo reaccionar bajo condiciones de intercambio de ligandos, compuestos de trifluoroarilaluminio o trifluoroarilboro de formulaAr13Me1 donde Me1 es aluminio o boro y Ar1 tiene el significado indicado con un compuesto organometálico del grupo 13 de la tabla periodica de formula Q32Me2Q2
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9680198P | 1998-08-17 | 1998-08-17 | |
| US10048798P | 1998-09-16 | 1998-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR019984A1 true AR019984A1 (es) | 2002-03-27 |
Family
ID=26792101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP990103826A AR019984A1 (es) | 1998-08-17 | 1999-07-30 | Compuestos de aluminio tricoordinado; dimeros aductos y mezclas de los mismos, utiles como activadores de catalizadores de polimerizacion de olefinas;composiciones catalizadoras que incluyen dichos compuestos activadores; procesos de polimerizacion de monomeros polimerizables por adicion utilizando |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6187940B1 (es) |
| EP (1) | EP1105397B1 (es) |
| JP (1) | JP4435420B2 (es) |
| AR (1) | AR019984A1 (es) |
| AT (1) | ATE233772T1 (es) |
| AU (1) | AU4440399A (es) |
| CA (1) | CA2336793C (es) |
| DE (1) | DE69905728T2 (es) |
| TW (1) | TW469272B (es) |
| WO (1) | WO2000009513A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
| ATE220682T1 (de) * | 1998-08-17 | 2002-08-15 | Dow Chemical Co | Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung |
| ATE233772T1 (de) * | 1998-08-17 | 2003-03-15 | Dow Global Technologies Inc | Drei-koordinierte alluminium- katalysatoraktivatorverbindung |
| IT1304181B1 (it) * | 1998-12-17 | 2001-03-08 | Enichem Spa | Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine. |
| US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6300439B1 (en) | 1999-11-08 | 2001-10-09 | Univation Technologies, Llc | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
| DE60011140T2 (de) * | 1999-11-24 | 2005-05-25 | Dow Global Technologies, Inc., Midland | Vorbereitung von polymerisationskatalysator und polymerisationsverfahren |
| US6673735B1 (en) | 1999-11-24 | 2004-01-06 | Dow Global Technologies Inc. | Preparation of catalyst compositions |
| US6541410B1 (en) * | 2000-06-23 | 2003-04-01 | Exxonmobil Chemical Patents Inc. | Siloxy substituted cocatalyst activators for olefin polymerization |
| CN104892814B (zh) * | 2004-06-16 | 2017-11-10 | 陶氏环球技术有限责任公司 | 选择聚合改性剂的方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993014132A1 (en) | 1992-01-06 | 1993-07-22 | The Dow Chemical Company | Improved catalyst composition |
| CA2164525C (en) | 1993-06-24 | 2005-03-01 | David D. Devore | Titanium (ii) or zirconium (ii) complexes and addition polymerization catalysts therefrom |
| US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| IT1273701B (it) | 1994-07-29 | 1997-07-09 | Enichem Elastomers | Derivati metallorganici del grupo iiia e procedimento per la loro preparazione |
| US5616664A (en) | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
| WO1997027228A1 (en) * | 1996-01-26 | 1997-07-31 | The Dow Chemical Company | Improved olefin addition polymerization catalyst composition |
| EP0914353B1 (en) * | 1996-07-23 | 2002-09-04 | The Dow Chemical Company | Olefin polymerization catalyst composition comprising group 13 compound |
| US5854166A (en) * | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
| US5895771A (en) * | 1997-06-05 | 1999-04-20 | Akzo Nobel Nv | Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations |
| DE69902548T2 (de) * | 1998-08-11 | 2003-04-10 | The Dow Chemical Co., Midland | Katalysatoraktivatorverbindung |
| ATE220682T1 (de) * | 1998-08-17 | 2002-08-15 | Dow Chemical Co | Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung |
| ATE233772T1 (de) * | 1998-08-17 | 2003-03-15 | Dow Global Technologies Inc | Drei-koordinierte alluminium- katalysatoraktivatorverbindung |
| EP1114055B1 (en) * | 1998-09-16 | 2002-11-27 | Dow Global Technologies Inc. | Dinuclear fluoroaryl aluminum alkyl complexes |
-
1999
- 1999-06-11 AT AT99927518T patent/ATE233772T1/de not_active IP Right Cessation
- 1999-06-11 CA CA2336793A patent/CA2336793C/en not_active Expired - Fee Related
- 1999-06-11 DE DE69905728T patent/DE69905728T2/de not_active Expired - Lifetime
- 1999-06-11 JP JP2000564964A patent/JP4435420B2/ja not_active Expired - Lifetime
- 1999-06-11 US US09/330,671 patent/US6187940B1/en not_active Expired - Lifetime
- 1999-06-11 WO PCT/US1999/013343 patent/WO2000009513A1/en not_active Ceased
- 1999-06-11 EP EP99927518A patent/EP1105397B1/en not_active Expired - Lifetime
- 1999-06-11 AU AU44403/99A patent/AU4440399A/en not_active Abandoned
- 1999-07-30 AR ARP990103826A patent/AR019984A1/es unknown
- 1999-07-30 TW TW088113068A patent/TW469272B/zh active
-
2000
- 2000-10-31 US US09/702,442 patent/US6528449B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69905728T2 (de) | 2003-12-24 |
| EP1105397A1 (en) | 2001-06-13 |
| EP1105397B1 (en) | 2003-03-05 |
| DE69905728D1 (de) | 2003-04-10 |
| ATE233772T1 (de) | 2003-03-15 |
| TW469272B (en) | 2001-12-21 |
| WO2000009513A1 (en) | 2000-02-24 |
| CA2336793A1 (en) | 2000-02-24 |
| CA2336793C (en) | 2010-01-26 |
| AU4440399A (en) | 2000-03-06 |
| JP2002522546A (ja) | 2002-07-23 |
| US6528449B1 (en) | 2003-03-04 |
| JP4435420B2 (ja) | 2010-03-17 |
| US6187940B1 (en) | 2001-02-13 |
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