WO2017150330A1 - ウエハ加工用テープ - Google Patents
ウエハ加工用テープ Download PDFInfo
- Publication number
- WO2017150330A1 WO2017150330A1 PCT/JP2017/006810 JP2017006810W WO2017150330A1 WO 2017150330 A1 WO2017150330 A1 WO 2017150330A1 JP 2017006810 W JP2017006810 W JP 2017006810W WO 2017150330 A1 WO2017150330 A1 WO 2017150330A1
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- WIPO (PCT)
- Prior art keywords
- wafer processing
- film
- release film
- support member
- processing tape
- Prior art date
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L21/6836—Wafer tapes, e.g. grinding or dicing support tapes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67132—Apparatus for placing on an insulating substrate, e.g. tape
Definitions
- the present invention relates to a wafer processing tape, and more particularly to a wafer processing tape used when a semiconductor wafer or the like is cut and separated (diced) into individual chips.
- a workpiece such as a semiconductor wafer is divided into chips
- the workpiece is fixed using a wafer processing tape and divided by a rotary blade or laser light.
- a weak point called a modified layer is provided inside a semiconductor wafer by a laser beam
- the semiconductor wafer provided with the modified layer is fixed with a wafer processing tape
- the wafer processing tape is pulled and expanded.
- a method of dividing the semiconductor wafer into individual pieces starting from the modified layer is also used.
- the performance required for a wafer processing tape as described above has good fixability during processing, and there is no contamination of the workpiece when the wafer processing tape is peeled off after processing. It was. However, in recent years, in order to confirm the quality after processing, the state of the chip and the like are visually confirmed from the surface on which the wafer processing tape is bonded. Further, as described above, when the modified layer is formed inside the semiconductor wafer by the laser beam, the laser beam irradiation from the surface of the semiconductor wafer on which the wafer processing tape is not bonded, that is, from the circuit surface, When it is difficult due to the pattern, laser light is irradiated from the surface on which the wafer processing tape is bonded through the wafer processing tape. In such a case, the wafer processing tape is required to have a capability of sufficiently transmitting visible light or near infrared light.
- the wafer processing tape As a method of sufficiently transmitting visible light or near-infrared light, adjusting the surface roughness Ra of the back surface of the wafer processing tape to 0.3 ⁇ m or less is disclosed (for example, Patent Document 1).
- the wafer processing tape generally has a long film shape and is stored in the state of a wound body wound up in a roll shape.
- the surface roughness Ra on the back surface of the wafer processing tape is too small, the wound wafer processing tapes easily stick to each other.
- a catch called blocking is easily generated when the tape is drawn out from the wound body. Therefore, Patent Document 1 discloses that the surface roughness Ra of the back surface of the wafer processing tape is preferably 0.1 ⁇ m or more in order to suppress this blocking.
- FIGS. 2, 3A, and 3B are a perspective view, a plan view, and a cross-sectional view of the dicing tape 50, respectively.
- the wafer processing tape 50 includes a release film 51 and an adhesive film 52.
- the adhesive film 52 has a label portion 52a having a circular shape corresponding to the shape of the ring frame for dicing, and a peripheral portion 52b surrounding the outside of the label portion 52a. Around the label portion 52a, there is a portion where the adhesive film 52 does not exist and only the release film 51 exists.
- the label portion 52a of the adhesive film 52 is peeled off from the release film 51, and the back surface of the semiconductor wafer W is pasted as shown in FIG. Adhere and fix the ring frame R.
- the semiconductor wafer W is diced, and then the adhesive film 52 is subjected to a curing process such as ultraviolet irradiation to pick up a semiconductor chip.
- a curing process such as ultraviolet irradiation to pick up a semiconductor chip.
- the wafer processing tape 50 is pre-cut as described above, there are a part of the release film 51 only and a part provided with the label part 52a.
- a winding pressure is applied to the label portion 52a, and even if the surface roughness Ra is in the range shown in Patent Document 1, blocking is likely to occur, and when the wafer processing tape is used, the label portion 52a tends to be unwound from the wound body. In some cases, the label portion 52a adhered to the back surface of the wafer processing tape 50 on the wound body side is carried away.
- an object of the present invention is to prevent the label unit 52a from blocking the back surface of the wafer processing tape when the precut processed wafer processing tape is stored in a roll-shaped state, and the roll
- An object of the present invention is to provide a wafer processing tape capable of satisfactorily feeding out the label portion 52a when unwinding from a state wound in a shape.
- a wafer processing tape has a predetermined shape corresponding to a long release film and a dicing ring frame provided on a first surface of the release film.
- An adhesive film having a label part, a peripheral part surrounding the outside of the label part, and both ends of the release film in the short direction, and the first surface provided with the adhesive film A support member provided on the opposite second surface, and the adhesive film has an arithmetic surface roughness Ra of 0.3 ⁇ m or less on the side not in contact with the release film, and the support member Has a thickness of 30 to 150 ⁇ m.
- the wafer processing tape is provided such that the support member has a region overlapping the label portion with the release film interposed therebetween, and a short portion of the release film in the region overlapping the label portion.
- the maximum width in the hand direction is preferably 25 mm or less.
- the support member preferably has a laminated structure of two or more layers.
- the support member may be an adhesive tape obtained by applying an adhesive to a resin film substrate selected from the group consisting of polyethylene terephthalate, polypropylene, and high-density polyethylene. preferable.
- the label portion when the pre-cut wafer processing tape is stored in the state of being wound in a roll shape, the label portion is prevented from blocking with the back surface of the wafer processing tape and wound in a roll shape.
- the label portion can be fed out satisfactorily.
- (A) is a top view of the tape for wafer processing which concerns on embodiment of this invention, (b) is the same sectional drawing. It is a perspective view of the conventional wafer processing tape.
- (A) is a top view of the conventional tape for wafer processing, (b) is the same sectional drawing. It is sectional drawing which shows the state by which the tape for wafer processing and the ring frame for dicing were bonded together.
- FIG. 1A is a plan view of a wafer processing tape according to an embodiment of the present invention
- FIG. 1B is a cross-sectional view of FIG.
- the wafer processing tape 10 includes a long release film 11, an adhesive film 12, and a support member 13. .
- the adhesive film 12 has a label portion 12a provided on the first surface 11a of the release film 11 and a peripheral portion 12b surrounding the outside of the label portion 12a.
- the peripheral part 12b includes a form that completely surrounds the outside of the label part 12a and a form that is not completely enclosed as illustrated.
- the label portion 12a has a shape corresponding to a ring frame for dicing.
- the support member 13 is a second surface 11b of the release film 11 opposite to the first surface 11a on which the adhesive film 12 is provided, and is provided at both ends of the release film 11 in the short direction. And is provided in a region corresponding to the region of the first surface 11 a over the region of the label portion 12 a that contacts the release film 11. That is, the support member 13 is provided so as to have a region overlapping the label portion 12 a with the release film 11 interposed therebetween.
- the support member 13 can be provided intermittently or continuously along the longitudinal direction of the release film 11, but from the viewpoint of more effectively suppressing the generation of transfer marks, the longitudinal direction of the release film 11. It is preferable to provide continuously along.
- release film 11 used for the wafer processing tape 10 of the present invention a polyethylene terephthalate (PET) series, a polyethylene series, or other known films such as a release-processed film can be used.
- PET polyethylene terephthalate
- the thickness of the release film is not particularly limited and may be set appropriately, but is preferably 25 to 50 ⁇ m.
- the adhesive film 12 of the present invention has the label portion 12a corresponding to the shape of the ring frame for dicing, and the peripheral portion 12b surrounding the outside thereof.
- Such an adhesive film can be formed by removing the peripheral region of the label portion 12a from the film-like adhesive by precut processing.
- the shape corresponding to the shape of the ring frame for dicing is a similar shape that is substantially the same shape as the inside of the ring frame and larger than the size of the inside of the ring frame.
- similar to circle is preferable and it is more preferable that it is circular.
- the adhesive film 12 is not particularly limited, and has a sufficient adhesive strength so that the wafer does not peel when dicing the wafer, and has a low adhesive strength so that it can be easily peeled when picking up the chip after dicing. Anything is acceptable. For example, what provided the adhesive layer in the base film can be used conveniently.
- the base film of the adhesive film 12 may have an arithmetic surface roughness Ra of 0.3 ⁇ m or less on the surface opposite to the adhesive layer (that is, the surface on the side where the adhesive film 12 is not in contact with the release film 11).
- Ra arithmetic surface roughness
- any conventionally known one can be used without any particular limitation.
- a radiation curable material as an adhesive layer mentioned later, it is preferable to use what has radiation transparency.
- the materials include polyethylene, polypropylene, ethylene-propylene copolymer, polybutene-1, poly-4-methylpentene-1, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-acrylic.
- Homopolymers or copolymers of ⁇ -olefins such as methyl acid copolymers, ethylene-acrylic acid copolymers, ionomers or mixtures thereof, polyurethane, styrene-ethylene-butene or pentene copolymers, polyamide-polyols Listed are thermoplastic elastomers such as copolymers, and mixtures thereof.
- the base film may be a mixture of two or more materials selected from these groups, or may be a single layer or a multilayer. The thickness of the base film is not particularly limited and may be set as appropriate, but is preferably 50 to 200 ⁇ m.
- the arithmetic surface roughness Ra of the base film for realizing sufficient permeability is 0.3 ⁇ m or less, more preferably 0.25 ⁇ m or less. If the arithmetic surface roughness Ra is larger than 0.3 ⁇ m, incident light is scattered and sufficient transparency cannot be obtained.
- the parallel line transmittance at 400 to 1100 nm is preferably 80% or more.
- the resin used for the pressure-sensitive adhesive layer of the pressure-sensitive adhesive film 12 is not particularly limited, and a known chlorinated polypropylene resin, acrylic resin, polyester resin, polyurethane resin, epoxy resin, or the like used for the pressure-sensitive adhesive is used. can do. It is preferable to prepare an adhesive by appropriately blending an acrylic adhesive, a radiation polymerizable compound, a photopolymerization initiator, a curing agent and the like into the resin of the adhesive layer 13.
- the thickness of the pressure-sensitive adhesive layer 13 is not particularly limited and may be appropriately set, but is preferably 5 to 30 ⁇ m.
- a radiation-polymerizable compound can be blended in the pressure-sensitive adhesive layer to facilitate peeling from the adhesive layer by radiation curing.
- the radiation polymerizable compound for example, a low molecular weight compound having at least two photopolymerizable carbon-carbon double bonds in a molecule that can be three-dimensionally reticulated by light irradiation is used.
- trimethylolpropane triacrylate pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol monohydroxypentaacrylate, dipentaerythritol hexaacrylate, 1,4-butylene glycol diacrylate, 1,6 hexanediol diacrylate Acrylate, polyethylene glycol diacrylate, oligoester acrylate, and the like are applicable.
- Urethane acrylate oligomers include polyester compounds or polyether compounds such as polyol compounds and polyisocyanate compounds (for example, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 1,3-xylylene diene).
- the pressure-sensitive adhesive layer may be a mixture of two or more selected from the above resins.
- photopolymerization initiator for example, isopropyl benzoin ether, isobutyl benzoin ether, benzophenone, Michler's ketone, chlorothioxanthone, dodecylthioxanthone, dimethylthioxanthone, diethylthioxanthone, benzyldimethyl ketal, ⁇ -hydroxycyclohexyl phenyl ketone, 2-hydroxymethylphenyl Propane or the like can be used.
- the blending amount of these photopolymerization initiators is preferably 0.01 to 5 parts by mass with respect to 100 parts by mass of the acrylic copolymer.
- the support members 13 are both ends in the short direction of the release film 11, and are disposed on the second surface 11 b opposite to the first surface 11 a provided with the adhesive film 12 via the release film 11. It is provided so as to have an area overlapping with the label portion 12a.
- the thickness of the support member 13 is 30 to 150 ⁇ m, more preferably 40 to 140 ⁇ m.
- the wafer processing tape By providing the support member 13, in the state where the wafer processing tape 10 is wound up in a roll shape, the wafer processing tape positioned inside the label portion 12a of the adhesive film 12 and the winding body of the label portion 12a. Since a space can be provided between the back surface and the back surface of the wafer 10 so that they do not adhere to each other, the label portion 52a is prevented from blocking the back surface of the wafer processing tape 10 (the back surface of the release film 11) and wound in a roll shape. When feeding out from the taken state, the label portion 52a can be fed out without being brought to the wound body side.
- the supporting member 13 When the supporting member 13 is thinner than 20 ⁇ m, the label portion 12a and the label portion 12a are wound by the vibration due to the conveyance of the wafer processing tape 10 by the wound body and the attachment to the apparatus when bonding to the wafer ring. There is a possibility that the wafer processing tape 10 located on the inner side of the rotating body may be in close contact with the back surface, and a sufficient effect may not be obtained. On the other hand, if the support member 13 is thicker than 150 ⁇ m, the diameter of the wound body becomes large, the weight increases, and handling becomes difficult.
- the support member 13 preferably has a maximum width x (see FIG. 1A) in the short direction of the release film of an area overlapping the label portion 12a of 25 mm or less.
- the maximum width x of the region where the support member 13 and the label portion 12a overlap is greater than 25 mm, in the state of the wound body, the label portion 12a and the support member 13 positioned inside the wound body of the label portion 12a Since the contact area becomes too large, blocking occurs between the label portion 12a and the support member 13, and the label portion 52a that is about to be unwound from the wound body is stuck to the support member 14 on the wound body side. There is a risk that. Further, the surface of the support member 13 on the side in contact with the wound body side may be rough. If the surface of the support member 13 is rough, the contact area with the wound body side can be reduced.
- the support member 13 may not have a region overlapping the label portion 12a, and may be installed between the outer edge of the label portion 12a and the short-side end portion of the release film.
- an adhesive tape obtained by applying an adhesive to a resin film substrate can be suitably used as the support member 13, for example. By sticking such an adhesive tape to predetermined positions of both end portions of the second surface 11b of the release film 11, the wafer processing tape 10 of this embodiment can be formed. Only one layer of the adhesive tape may be attached, or thin tapes may be laminated.
- the resin film substrate of the adhesive tape is not particularly limited as long as it can withstand the winding pressure, but from the viewpoint of heat resistance, smoothness, and availability, polyethylene terephthalate (PET), polypropylene And high density polyethylene.
- PET polyethylene terephthalate
- polypropylene polypropylene
- high density polyethylene There are no particular limitations on the composition and physical properties of the adhesive of the adhesive tape, and any material that does not peel from the release film 11 in the winding process and storage process of the wafer processing tape 10 may be used.
- a colored support member may be used as the support member 13.
- the type of tape can be clearly identified when the wafer processing tape 10 is rolled up.
- the color of the colored support member depending on the type and thickness of the wafer processing tape 10
- the wafer processing tapes according to Examples and Comparative Examples were produced by the following methods, and the performance was evaluated.
- Base film 1A A polyethylene resin “NUC-8122” manufactured by NUC Co., Ltd. was heated and melted and extruded to prepare a base film 1A having a thickness of 100 ⁇ m. At the time of molding, the surface to which the pressure-sensitive adhesive was not applied was subjected to a rough surface treatment, and the surface roughness was adjusted so that the surface roughness shown in Table 1 was obtained.
- Base film 1B A base film 1B was produced in the same manner as the base film 1A except that EMMA resin “ACRIFT WD201” manufactured by Sumitomo Chemical Co., Ltd. was used.
- Base film 1C A base film 1C was produced in the same manner as the base film 1A, except that an ethylene vinyl acetate copolymer resin “Evertate” manufactured by Sumitomo Chemical Co., Ltd. was used.
- Adhesive composition 2A 2 weights of polyisocyanate “Coronate L” manufactured by Tosoh Corporation as a curing agent for 100 parts by weight of acrylic copolymer (weight average molecular weight 200,000) composed of 2-ethylhexyl acrylate, methyl acrylate and 2-hydroxyethyl acrylate Part A was added to obtain a pressure-sensitive adhesive composition 2A.
- Adhesive composition 2B 2 weights of polyisocyanate “Coronate L” manufactured by Tosoh Corporation as a curing agent for 100 parts by weight of acrylic copolymer (weight average molecular weight 200,000) composed of 2-ethylhexyl acrylate, methyl acrylate and 2-hydroxyethyl acrylate
- acrylic copolymer weight average molecular weight 200,000
- AD-PMT manufactured by Shin-Nakamura Chemical Co., Ltd. as an acrylate oligomer
- Irgacure 184 manufactured by Ciba Geigy Co., Ltd. as a photopolymerization initiator
- Support member 3A To 100 parts by weight of an acrylic resin (mass average molecular weight 600,000, glass transition temperature -20 ° C.), 10 parts by weight of polyisocyanate “Coronate L” manufactured by Tosoh Corporation was mixed as a curing agent to obtain an adhesive composition. .
- the pressure-sensitive adhesive composition was applied to a polyethylene terephthalate film as a resin film base so that the dry film thickness was 10 ⁇ m, dried at 110 ° C. for 3 minutes, and the support member 3A having an overall thickness of 35 ⁇ m, It produced so that it might become 30 mm in width.
- a support member 3B was produced in the same manner as the support member 3A, except that a polyethylene terephthalate film having a thickness different from that of the support member 3A was used so that the total thickness was 48 ⁇ m.
- a support member 3C was produced in the same manner as the support member 3A, except that a polypropylene film was used as the resin film base and the total thickness was 65 ⁇ m.
- a support member 3D was produced in the same manner as the support member 3C except that the pressure-sensitive adhesive composition was applied so that the dry film thickness was 5 ⁇ m and the total thickness was 25 ⁇ m.
- a support member 3E was produced in the same manner as the support member 3A, except that a high-density polyethylene film was used as the resin film substrate and the total thickness was 150 ⁇ m.
- Example 1 The pressure-sensitive adhesive composition 2A was applied to a release film composed of a polyethylene-terephthalate film subjected to a release treatment so that the dry film thickness was 25 ⁇ m, dried at 110 ° C. for 3 minutes, and then bonded to the base film 1A. An adhesive film was prepared. The pressure-sensitive adhesive film was circularly pre-cut with a diameter of 290 mm by adjusting the depth of cut into the release film to be 10 ⁇ m or less.
- the label portion of the adhesive film was bonded so that the maximum width of the overlapping region in the short direction of the release film was 25 mm, and a wafer processing tape according to Example 1 having the structure shown in FIG. 1 was produced.
- Example 1 was used except that the base film, the pressure-sensitive adhesive composition, and the support member shown in Table 1 were used, and the support member was provided so that the maximum width of the region overlapping the label portion became the value shown in Table 1. Thus, wafer processing tapes according to Examples 2 to 6 and Comparative Examples 1 to 3 were produced.
- the wafer processing pressure-sensitive adhesive tapes according to Examples and Comparative Examples were wound into a roll shape so that the number of circular pressure-sensitive adhesive films (label portions) was 50, and a wound body was produced.
- the wafer processing adhesive tape was unwound from the wound body by a laminating device for bonding to the ring frame, and the number of sheets that had been brought to the wound body side without being successfully unwound from the label portion was measured. The results are shown in Table 1.
- the wafer processing tapes of Examples 1 to 6 have an arithmetic surface roughness Ra of 0.3 ⁇ m or less on the side of the adhesive film that is not in contact with the release film, and the thickness of the support member. Is 30 to 150 ⁇ m, it has high permeability and can be fed out from the wound body satisfactorily.
- Examples 1 to 5 in which the maximum width in the short direction of the release film in the region where the support member overlaps the label portion are 25 mm or less were particularly excellent results in evaluating the drawability from the wound body.
- the wafer processing tape of Comparative Example 1 has an arithmetic surface roughness Ra on the side not in contact with the release film of the adhesive film of greater than 0.3 ⁇ m. Sex is not enough.
- the wafer processing tape of Comparative Example 2 since the support member is thinner than 30 ⁇ m, blocking occurs between the label portion and the back surface of the release film, and the label portion is released from the wound body side. There were 8 labels that were stuck to the back of the film and could not be unwound from the roll.
- the comparative example 3 which did not provide a supporting member, there were ten label parts which cannot be drawn out from a wound body.
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Abstract
Description
本発明のウエハ加工用テープ10に用いられる離型フィルム11としては、ポリエチレンテレフタレート(PET)系、ポリエチレン系、その他、離型処理がされたフィルム等周知のものを使用することができる。
離型フィルムの厚さは、特に限定されるものではなく、適宜に設定してよいが、25~50μmが好ましい。
本発明の粘着フィルム12は、上述のように、ダイシング用のリングフレームの形状に対応するラベル部12aと、その外側を囲むような周辺部12bとを有する。このような粘着フィルムは、プレカット加工により、フィルム状粘着剤からラベル部12aの周辺領域を除去することで形成することができる。ダイシング用のリングフレームの形状に対応する形状は、リングフレームの内側と略同じ形状でリングフレーム内側の大きさより大きい相似形である。また、必ずしも円形でなくてもよいが、円形に近い形状が好ましく、円形であることがさらに好ましい。
基材フィルムの厚さは、特に限定されるものではなく、適宜に設定してよいが、50~200μmが好ましい。
支持部材13は、離型フィルム11の短手方向両端部であって、粘着フィルム12が設けられた第1の面11aとは反対の第2の面11b上に、離型フィルム11を介してラベル部12aと重なる領域を有するように設けられている。支持部材13の厚さは30~150μmであり、より好ましくは40~140μmである。
粘接着テープの粘接着剤の組成及び物性については、特に限定はなく、ウエハ加工用テープ10の巻き取り工程及び保管工程において、離型フィルム11から剥離しないものであればよい。
以下、本発明を実施例に基づきさらに詳細に説明するが、本発明はこれら実施例に限定されるものではない。
[基材フィルム1A]
株式会社NUC製ポリエチレン樹脂「NUC-8122」を加熱溶融して、押し出し成形し、厚さ100μmの基材フィルム1Aを作製した。成型時に、粘着剤が塗工されない面に粗面処理を施し、表1に示す表面粗さとなるように、それぞれ表面粗さの調整を行って複数種類の基材フィルムを作製した。
住友化学株式会社製EMMA樹脂「アクリフトWD201」を用いた以外は、基材フィルム1Aと同様にして、基材フィルム1Bを作製した。
住友化学株式会社製エチレン酢酸ビニル共重合樹脂「エバテート」を用いた以外は、基材フィルム1Aと同様にして、基材フィルム1Cを作製した。
[粘着剤組成物2A]
2-エチルヘキシルアクリレート、メチルアクリレート、2-ヒドロキシエチルアクリレートからなるアクリル系共重合体(重量平均分子量20万)100重量部に対して、硬化剤として東ソー株式会社製ポリイソシアネート「コロネートL」を2重量部加え、粘着剤組成物2Aを得た。
2-エチルヘキシルアクリレート、メチルアクリレート、2-ヒドロキシエチルアクリレートからなるアクリル系共重合体(重量平均分子量20万)100重量部に対して、硬化剤として東ソー株式会社製ポリイソシアネート「コロネートL」を2重量部、アクリレート系オリゴマーとして新中村化学工業社製「AD-PMT」を150重量部、光重合開始剤として日本チバガイギー株式会社製「イルガキュア184」を2重量部加え、紫外線硬化型の粘着剤組成物2Aを得た。
[支持部材3A]
アクリル樹脂(質量平均分子量60万、ガラス転移温度-20℃)100重量部に対して、硬化剤として東ソー株式会社製ポリイソシアネート「コロネートL」10質量部を混合して粘着剤組成物を得た。
上記粘着剤組成物を樹脂フィルム基材としてのポリエチレンテレフタレートフィルムに、乾燥膜厚が10μmになるように塗工し、110℃で3分間乾燥し、全体の厚さが35μmの支持部材3Aを、幅30mmとなるよう作製した。
支持部材3Aと異なる厚さのポリエチレンテレフタレートフィルムを使用して全体の厚さが48μmとなるようにした他は、支持部材3Aと同様にして、支持部材3Bを作製した。
樹脂フィルム基材としてポリプロピレンフィルムを用い、全体の厚さが65μmとなるようにした他は、支持部材3Aと同様にして、支持部材3Cを作製した。
上記粘着剤組成物を乾燥膜厚が5μmになるように塗工し、全体の厚さが25μmとなるようにした他は、支持部材3Cと同様にして、支持部材3Dを作製した。
樹脂フィルム基材として高密度ポリエチレンフィルムを用い、全体の厚さが150μmとなるようにした他は、支持部材3Aと同様にして、支持部材3Eを作製した。
樹脂フィルム基材として一方の面をブラスト処理したポリプロピレンフィルムを用い、ブラスト処理した面とは反対側の面に上記粘着剤組成物を塗工し、全体の厚さが65μmとなるようにした他は、支持部材3Cと同様にして、支持部材3Fを作製した。
[実施例1]
離型処理したポリエチレン-テレフタレートフィルムよりなる離型フィルムに粘着剤組成物2Aを乾燥膜厚が25μmになるように塗工し、110℃で3分間乾燥した後、基材フィルム1Aと貼り合わせて粘着フィルムを作製した。粘着フィルムに対して、離型フィルムへの切り込み深さが10μm以下となるように調節して円状に直径290mmの円形プレカット加工を行った。次に、離型フィルム2Aの粘着フィルムが設けられた第1の面とは反対の第2の面であって、且つ、離型フィルム2Aの短手方向両端部に、粘着フィルムのラベル部と重なる領域の、離型フィルムの短手方向における最大幅が25mmとなるように、支持部材3Aを貼合して、図1に示す構造を有する実施例1に係るウエハ加工用テープを作製した。
表1に示す基材フィルム、粘着剤組成物、支持部材を用い、ラベル部と重なる領域の最大幅が表1に示す値となるように支持部材を設けた以外は、実施例1と同様にして実施例2~6、比較例1~3に係るウエハ加工用テープを作製した。
実施例、比較例に係るウエハ加工用粘着テープに用いた粘着フィルムについて、粘着フィルムの離型フィルムに接触していない側の面、すなわち基材フィルムの粘着剤層が設けられていない側の面の算術平均粗さRaを、株式会社ミツトヨ製表面粗さ測定器(サーフテストSJ-301)を使用して、N=10で測定し、平均値を求めた。その結果を表1に示す。
実施例、比較例に係るウエハ加工用粘着テープを、円形形状の粘着フィルム(ラベル部)の数が50枚になるようにロール状に巻き取り、巻回体を作製した。リングフレームに貼合する貼合装置により、巻回体からウエハ加工用粘着テープを繰り出し、ラベル部が上手く繰り出せずに、巻回体側へ持っていかれてしまった枚数を計測した。その結果を表1に示す。
実施例、比較例に係るウエハ加工用粘着テープに用いた粘着フィルムについて、平行光線透過率を測定した。測定は、株式会社島津製作所製UV-3101分光光度計を使用して、400~1100nmの範囲で行い、最も低くなった透過率を求めた。その結果を表1に示す。
11:離型フィルム
12:粘着フィルム
12a:ラベル部
12b:周辺部
13:支持部材
Claims (5)
- 長尺の離型フィルムと、
前記離型フィルムの第1の面上に設けられたダイシング用のリングフレームに対応する所定形状を有するラベル部と、前記ラベル部の外側を囲むような周辺部とを有する粘着フィルムと、
前記離型フィルムの短手方向両端部であって、前記粘着フィルムが設けられた第1の面とは反対の第2の面上に設けられた支持部材とを有し、
前記粘着フィルムは、前記離型フィルムに接触していない側の算術表面粗さRaが0.3μm以下であり、
前記支持部材は、厚さが30~150μmであることを特徴とするウエハ加工用テープ。 - 前記支持部材は、前記離型フィルムを介して前記ラベル部と重なる領域を有するように設けられており、前記ラベル部と重なる領域の、前記離型フィルムの短手方向における最大幅が25mm以下であることを特徴とする請求項1に記載のウエハ加工用テープ。
- 前記支持部材は、前記離型フィルムの長手方向に沿って連続的に設けられていることを特徴とする請求項1または請求項2に記載のウエハ加工用テープ。
- 前記支持部材は、2層以上の積層構造を有することを特徴とする請求項1から請求項3のいずれか1項に記載のウエハ加工用テープ。
- 前記支持部材は、ポリエチレンテレフタレート、ポリプロピレン、及び高密度ポリエチレンからなる群から選択される樹脂フィルム基材に粘接着剤を塗布した粘接着テープであることを特徴とする請求項1から請求項4のいずれか1項に記載のウエハ加工用テープ。
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JP2021061325A (ja) * | 2019-10-07 | 2021-04-15 | 倉敷紡績株式会社 | ダイシングシートおよびダイシングシート用基材フィルム |
KR20220119626A (ko) | 2019-12-23 | 2022-08-30 | 쇼와덴코머티리얼즈가부시끼가이샤 | 다이싱·다이본딩 일체형 필름 및 그 품질 관리 방법, 및 반도체 장치의 제조 방법 |
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