WO2013157145A1 - 電子写真用感光体、その製造方法および電子写真装置 - Google Patents
電子写真用感光体、その製造方法および電子写真装置 Download PDFInfo
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- WO2013157145A1 WO2013157145A1 PCT/JP2012/060784 JP2012060784W WO2013157145A1 WO 2013157145 A1 WO2013157145 A1 WO 2013157145A1 JP 2012060784 W JP2012060784 W JP 2012060784W WO 2013157145 A1 WO2013157145 A1 WO 2013157145A1
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/05—Organic bonding materials; Methods for coating a substrate with a photoconductive layer; Inert supplements for use in photoconductive layers
- G03G5/0528—Macromolecular bonding materials
- G03G5/0557—Macromolecular bonding materials obtained otherwise than by reactions only involving carbon-to-carbon unsatured bonds
- G03G5/0564—Polycarbonates
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0605—Carbocyclic compounds
- G03G5/0607—Carbocyclic compounds containing at least one non-six-membered ring
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0609—Acyclic or carbocyclic compounds containing oxygen
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
- G03G5/06147—Amines arylamine alkenylarylamine
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0666—Dyes containing a methine or polymethine group
- G03G5/0672—Dyes containing a methine or polymethine group containing two or more methine or polymethine groups
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/043—Photoconductive layers characterised by having two or more layers or characterised by their composite structure
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/043—Photoconductive layers characterised by having two or more layers or characterised by their composite structure
- G03G5/047—Photoconductive layers characterised by having two or more layers or characterised by their composite structure characterised by the charge-generation layers or charge transport layers
Definitions
- the present invention relates to an electrophotographic photosensitive member (hereinafter also simply referred to as “photosensitive member”) used in an electrophotographic printer, a copying machine, a fax machine, etc., a manufacturing method thereof, and an electrophotographic apparatus.
- the present invention relates to an electrophotographic photoreceptor having excellent wear resistance, photoresponsiveness and gas resistance by a combination of a resin binder, a charge transporting material, and an additive, a manufacturing method thereof, and an electrophotographic apparatus.
- the electrophotographic photoreceptor has a basic structure in which a photosensitive layer having a photoconductive function is provided on a conductive substrate.
- organic electrophotographic photoreceptors using organic compounds as functional components responsible for charge generation and transport have been actively researched and developed due to advantages such as material diversity, high productivity, and safety. Application to printers and printers is ongoing.
- a photoconductor needs to have a function of holding a surface charge in a dark place, a function of receiving light to generate a charge, and a function of transporting the generated charge.
- a so-called single layer type photoreceptor having a single photosensitive layer having both of these functions, a charge generation layer mainly responsible for charge generation upon light reception, and a surface charge in a dark place.
- So-called laminated type (functional separation type) photoreceptor comprising a photosensitive layer in which a functionally separated layer is laminated with a charge transporting layer that has a function of retaining the charge and a function of transporting the charge generated in the charge generation layer during light reception There is.
- the photosensitive layer is generally formed by applying a coating solution prepared by dissolving or dispersing a charge generating material, a charge transporting material and a resin binder in an organic solvent onto a conductive substrate.
- a coating solution prepared by dissolving or dispersing a charge generating material, a charge transporting material and a resin binder in an organic solvent onto a conductive substrate.
- polycarbonate is often used as a resin binder, particularly in the outermost layer. This is because polycarbonate has characteristics of being strong against friction generated between paper and a blade for removing toner, having excellent flexibility, and good exposure transparency.
- bisphenol Z-type polycarbonate is widely used as the resin binder.
- a technique using such a polycarbonate as a resin binder is described in, for example, Patent Document 1.
- various studies have been made on the polycarbonate structure in order to improve the wear resistance of the surface of the photoreceptor, but it has not been sufficient.
- electrophotographic printing devices are becoming increasingly durable and sensitive, High-speed responsiveness has been demanded.
- electrophotographic printing devices are also strongly required to be less affected by gases such as ozone and NOx generated in the device and fluctuations in image characteristics due to changes in the usage environment (room temperature and humidity). Has been.
- ozone As for the gas generated in the apparatus, ozone is widely known.
- ozone is generated by a charger or roller charger that performs corona discharge, and remains or stays in the device, the organic substance that composes the photoconductor is oxidized, causing oxidation. It is considered that the structure of the photoconductor is destroyed and the characteristics of the photoconductor are remarkably deteriorated. Further, it is conceivable that ozone in the air oxidizes nitrogen in the air to form NOx, and this NOx denatures an organic substance constituting the photoconductor.
- the outermost surface layer of the photoreceptor itself is affected, but also an adverse effect caused by the gas flowing into the inside of the photosensitive layer is considered.
- the outermost surface layer of the photoreceptor itself may be scraped off due to friction with the various members described above, although the amount of the surface layer itself may be scraped off, but if harmful gas flows into the photosensitive layer, the structure of the organic substance in the photosensitive layer Therefore, it can be said that it is also an important issue to suppress the inflow of this harmful gas into the photosensitive layer.
- the surface of the photoconductor may be contaminated by ozone, nitrogen oxide, or the like generated when the photoconductor is charged.
- the adhered substances reduce the lubricity of the surface of the photoconductor, making it easier for paper dust and toner to adhere, causing the blade to squeal, turn over, scratches on the photoconductor surface, etc. There is a problem that it tends to occur.
- Patent Documents 2 and 3 Various polycarbonate resin structures have been proposed to improve the durability of the photoreceptor surface.
- Patent Documents 2 and 3 a polycarbonate resin including a specific structure is proposed, but studies on compatibility with various charge transport materials and additives and resin solubility are not sufficient.
- Patent Document 4 proposes a polycarbonate resin having a specific structure.
- a resin having a bulky structure has a large space between polymers, and a discharge substance, a contact member, foreign matter, etc. during charging easily penetrate into the photosensitive layer. Therefore, it is difficult to obtain sufficient durability.
- Patent Document 5 a polycarbonate having a special structure has been proposed in order to improve printing durability and coating properties, but the description regarding the charge transport material and additive to be combined is not sufficient, and long-term use is made. There is a problem that it is difficult to maintain stable electrical characteristics at the time.
- Patent Document 6 proposes a stilbene derivative
- Patent Document 7 proposes a tris (4-styrylphenyl) amine derivative.
- these documents do not fully study the resin binder and additives combined with the charge transport material, and change the operating environment, maintain the electrical characteristics during long-term use, improve wear resistance, and stain resistance. It was not possible to maintain everything.
- JP-A-61-62040 JP 2004-354759 A Japanese Patent Laid-Open No. 4-179961 JP 2004-85644 A JP-A-3-273256 JP 59-216853 A JP 2012-27139 A International Publication No. 2011/108064 Pamphlet JP 2007-279446 A
- an object of the present invention is to provide an electrophotographic photoreceptor that has high photoresponsiveness, stable electrical characteristics even after repeated use, and high durability. More specifically, an object of the present invention is to provide an electrophotographic photoreceptor having excellent wear resistance, responsiveness, and gas resistance by combining a resin binder having a specific structure, a charge transport material and an additive, It is to provide a manufacturing method and an electrophotographic apparatus.
- the present inventors have intensively studied the composition of the photosensitive layer, and as a result, a polycarbonate containing a specific structural unit is used as a resin binder, and a specific charge transport material, a specific additive, As a result of the combination use, it was found that durability could be improved, a high photoresponsiveness and an electrophotographic photoreceptor excellent in electrical characteristics could be realized, and the present invention was completed. .
- the electrophotographic photoreceptor of the present invention is an electrophotographic photoreceptor having a photosensitive layer on a conductive substrate.
- the photosensitive layer contains at least a resin binder, a charge transport material and an additive, and the resin binder includes a structural unit represented by the following general formula (1) and a structural unit represented by the following general formula (2).
- a polycarbonate resin comprising a copolymer, wherein the charge transport material contains at least one stilbene compound represented by the following general formula (3), (4) or (5), and the additive is It contains at least one of diester compounds represented by the following general formula (6).
- R 1 and R 2 may be the same or different, and are a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, a halogen atom, a substituted or unsubstituted group having 6 to 12 carbon atoms.
- R 3 and R 4 may be the same or different, and may be a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, a halogenated alkyl group, or a carbon atom.
- R 5 and R 6 may be the same or different and each represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a methoxy group
- Ar 1 , Ar 2 , Ar 3 may be the same or different and is a hydrogen atom or a substituted or unsubstituted aryl group
- the photosensitive layer preferably forms the outermost surface layer of the photoreceptor.
- the photosensitive layer is formed by sequentially laminating a charge generation layer and a charge transport layer, and the charge transport layer contains the polycarbonate resin, the stilbene compound, and the diester compound. Is preferred.
- R 1 and R 2 are each independently a hydrogen atom or a methyl group, and X is a cyclohexylidene group.
- the copolymerization ratio of the structural unit represented by the general formula (1) in the copolymer is from 15 mol% to 90 mol%.
- the content of the diester compound is preferably 0.05% by mass to 20% by mass with respect to the total solid content of the photosensitive layer.
- the method for producing an electrophotographic photoreceptor of the present invention is a method for producing an electrophotographic photoreceptor including a step of forming a photosensitive layer by applying a coating solution on a conductive substrate.
- a coating solution polycarbonate resin containing the copolymer of the structural unit represented by the said General formula (1) and the structural unit represented by the said General formula (2), the said General formula (3), (4) Or using at least one of the stilbene compounds represented by (5) and at least one of the diester compounds represented by the general formula (6). is there.
- the electrophotographic apparatus of the present invention is characterized in that the electrophotographic photoreceptor of the present invention is mounted.
- a polycarbonate resin containing the specific structural unit is used as a resin binder for the photosensitive layer, and a specific charge transport material and a specific additive are used in combination with the polycarbonate resin. While maintaining the electrophotographic characteristics of the photoconductor, it is possible to realize a photoconductor excellent in high light response, gas resistance and solvent crack resistance, and having good environmental characteristics.
- FIG. 1 A) to (c) are schematic cross-sectional views showing an example of the electrophotographic photoreceptor of the present invention. It is a schematic block diagram which shows an example of the electrophotographic apparatus of this invention.
- FIG. 1 is a schematic cross-sectional view showing an electrophotographic photosensitive member according to an embodiment of the present invention, in which (a) is a negatively charged type laminated electrophotographic photosensitive member, and (b) is a positively charged type single photosensitive member.
- a layer type electrophotographic photoreceptor, (c) shows a positively charged type laminated electrophotographic photoreceptor.
- the layers are sequentially stacked.
- an undercoat layer 2 and a single layer type photosensitive layer 5 having both charge generation and charge transport functions are sequentially laminated on a conductive substrate 1.
- an undercoat layer 2, a charge transport layer 4 having a charge transport function, and a charge generation layer 3 having both charge generation and charge transport functions are provided on a conductive substrate 1.
- the photosensitive layers are sequentially laminated.
- the undercoat layer 2 may be provided as necessary.
- the “photosensitive layer” of the present invention includes both a laminated photosensitive layer in which a charge generation layer and a charge transport layer are laminated, and a single-layer photosensitive layer.
- the photosensitive layer contains at least a resin binder, a charge transport material and an additive
- the resin binder is represented by the structural unit represented by the general formula (1) and the general formula (2).
- the additive is characterized in that it contains at least one of the diester compounds represented by the general formula (6).
- the present invention is more effective when the photosensitive layer containing the polycarbonate resin, stilbene compound and diester compound is the outermost surface layer of the photoreceptor.
- the photoreceptor of the present invention is not limited as long as it has at least a photosensitive layer on a conductive substrate.
- the photosensitive layer is a laminated type including at least a charge generation layer and a charge transport layer.
- the photoreceptor of the present invention is preferably a negatively charged laminated photoreceptor in which a charge generation layer and a charge transport layer are laminated in this order on a conductive substrate as shown in FIG.
- the charge transport layer constituting the outermost surface layer of the photoreceptor includes the polycarbonate resin having the specific structure, the stilbene compound, and the diester compound.
- the conductive substrate 1 serves as a support for each layer constituting the photoconductor as well as serving as an electrode of the photoconductor, and may have any shape such as a cylindrical shape, a plate shape, or a film shape.
- a metal such as aluminum, stainless steel, nickel, or a material obtained by conducting a conductive treatment on the surface of glass, resin, or the like can be used.
- the undercoat layer 2 is made of a resin-based layer or a metal oxide film such as alumite.
- the undercoat layer 2 is used to control the charge injection property from the conductive substrate 1 to the photosensitive layer, or to cover defects on the surface of the conductive substrate 1 and to adhere the photosensitive layer to the conductive substrate 1. It is provided as necessary for the purpose of improvement.
- the resin material used for the undercoat layer 2 include insulating polymers such as casein, polyvinyl alcohol, polyamide, melamine, and cellulose, and conductive polymers such as polythiophene, polypyrrole, and polyaniline. Alternatively, they can be used in combination as appropriate. These resins may be used by containing a metal oxide such as titanium dioxide or zinc oxide.
- the charge generation layer 3 is formed by a method such as applying a coating solution in which particles of a charge generation material are dispersed in a resin binder, and receives light to generate charges. Further, at the same time as the charge generation efficiency is high, the injection property of the generated charges into the charge transport layer 4 is important, the electric field dependency is small, and it is desirable that the injection is good even at a low electric field.
- charge generation materials include phthalocyanines such as X-type metal-free phthalocyanine, ⁇ -type metal-free phthalocyanine, ⁇ -type titanyl phthalocyanine, ⁇ -type titanyl phthalocyanine, Y-type titanyl phthalocyanine, ⁇ -type titanyl phthalocyanine, amorphous-type titanyl phthalocyanine, and ⁇ -type copper phthalocyanine.
- phthalocyanines such as X-type metal-free phthalocyanine, ⁇ -type metal-free phthalocyanine, ⁇ -type titanyl phthalocyanine, ⁇ -type titanyl phthalocyanine, Y-type titanyl phthalocyanine, ⁇ -type titanyl phthalocyanine, amorphous-type titanyl phthalocyanine, and ⁇ -type copper phthalocyanine.
- the content of the charge generation material in the charge generation layer 3 is preferably 80 to 20% by mass, more preferably 30 to 70% by mass, based on the solid content in the charge generation layer 3.
- the resin binder of the charge generation layer 3 polycarbonate resin, polyester resin, polyamide resin, polyurethane resin, vinyl chloride resin, vinyl acetate resin, phenoxy resin, polyvinyl acetal resin, polyvinyl butyral resin, polystyrene resin, polysulfone resin, diallyl phthalate resin Further, it is possible to use a combination of a polymer and a copolymer of a methacrylic ester resin as appropriate.
- the content of the resin binder in the charge generation layer 3 is preferably 20 to 80% by mass, more preferably 30 to 70% by mass with respect to the solid content in the charge generation layer 3.
- the charge generation layer 3 since the charge generation layer 3 only needs to have a charge generation function, its film thickness is determined by the light absorption coefficient of the charge generation material, and is generally 1 ⁇ m or less, preferably 0.5 ⁇ m or less.
- the charge generation layer 3 can also be formed by using a charge generation material as a main component and adding a charge transport material or the like thereto.
- the charge transport layer 4 is mainly composed of a resin binder, a charge transport material, and an additive.
- the resin binder of the charge transport layer 4 it is necessary to use a polycarbonate resin made of a copolymer of the structural units represented by the general formulas (1) and (2). Specific examples of the copolymer of the structural units represented by the general formulas (1) and (2) are shown below.
- the copolymer polycarbonate resin according to the present invention is not limited to the one having this exemplified structure.
- the ratio of m to n is such that m is usually 15 to 90 mol%, preferably 25 to 75 mol%, more preferably when the total amount of m and n is 100 mol%. Is selected to be 30 to 60 mol%.
- the viscosity average molecular weight of the polycarbonate resin according to the present invention is preferably 10,000 to 100,000, more preferably 20,000 to 70,000, and further preferably 40,000 to 60,000.
- the above-described copolymer polycarbonate resin may be used alone, or may be used by mixing with other resins.
- other resins include various polycarbonate resins such as bisphenol A type, bisphenol Z type, bisphenol A type-biphenyl copolymer, bisphenol Z type-biphenyl copolymer, polyphenylene resin, polyester, etc.
- the content of the resin binder in the charge transport layer 4 is preferably 10 to 90% by mass, and more preferably 20 to 80% by mass with respect to the solid content in the charge transport layer 4.
- the charge transport material of the charge transport layer 4 at least one of stilbene compounds represented by the above general formula (3), (4) or (5) is used.
- Examples of the structure of the stilbene compound represented by the general formula (3), (4) or (5) according to the present invention are shown below. However, the compounds used in the present invention are not limited to these.
- the content of the charge transport material in the charge transport layer 4 is preferably 10 to 90% by weight, more preferably 20 to 80% by weight, and even more preferably 30 to 30% by weight with respect to the solid content in the charge transport layer 4. 60% by mass.
- a hydrazone compound, a pyrazoline compound, a pyrazolone compound, an oxadiazole compound, an oxazole compound, Arylamine compounds, benzidine compounds, other stilbene compounds, styryl compounds, poly-N-vinylcarbazole, polysilane, and the like can be used in appropriate combinations.
- the content of these charge transport materials is the above general formula (3), (4 ) Or (5) is preferably 0 to 90% by mass, more preferably 0 to 80% by mass, and still more preferably 10 to 80% by mass.
- the content of the additive in the charge transport layer 4 is preferably 0.05 to 20% by mass, more preferably 0.1 to 20% by mass, and still more preferably based on the solid content in the charge transport layer 4. Is 0.5 to 10% by mass, particularly preferably 5 to 10% by mass.
- the thickness of the charge transport layer 4 is preferably in the range of 3 to 50 ⁇ m and more preferably in the range of 15 to 40 ⁇ m in order to maintain a practically effective surface potential.
- the photosensitive layer 5 in the case of a single layer type is mainly composed of a charge generation material, a hole transport material, an electron transport material (acceptor compound) and a resin binder.
- the charge generation material for example, phthalocyanine pigments, azo pigments, anthanthrone pigments, perylene pigments, perinone pigments, polycyclic quinone pigments, squarylium pigments, thiapyrylium pigments, quinacridone pigments and the like can be used. These charge generation materials can be used alone or in combination of two or more.
- the azo pigment is a disazo pigment, a trisazo pigment
- the perylene pigment is N, N′-bis (3,5-dimethylphenyl) -3,4: 9,10.
- metal-free phthalocyanine As the perylene-bis (carboximide) and phthalocyanine pigment, metal-free phthalocyanine, copper phthalocyanine, and titanyl phthalocyanine are preferable. Furthermore, X-type metal-free phthalocyanine, ⁇ -type metal-free phthalocyanine, ⁇ -type copper phthalocyanine, ⁇ -type titanyl phthalocyanine, ⁇ -type titanyl phthalocyanine, Y-type titanyl phthalocyanine, amorphous titanyl phthalocyanine, Japanese Patent Laid-Open No. 8-209003, US Pat.
- the content of the charge generating material is preferably 0.1 to 20% by mass, more preferably 0.5 to 10% by mass, based on the solid content of the single-layer type photosensitive layer 5.
- the hole transport material it is necessary to use at least one of stilbene compounds represented by the above general formula (3), (4) or (5), and together with this, a hydrazone compound, a pyrazoline compound, Pyrazolone compounds, oxadiazole compounds, oxazole compounds, arylamine compounds, benzidine compounds, other stilbene compounds, styryl compounds, poly-N-vinylcarbazole, polysilane, etc. can be used alone or in appropriate combination. .
- a material suitable for combination with a charge generation material is preferable in addition to excellent transport ability of holes generated upon light irradiation.
- the content of the hole transport material is preferably 3 to 80% by mass, more preferably 5 to 60% by mass with respect to the solid content of the single-layer type photosensitive layer 5.
- Electron transport materials include succinic anhydride, maleic anhydride, dibromosuccinic anhydride, phthalic anhydride, 3-nitrophthalic anhydride, 4-nitrophthalic anhydride, pyromellitic anhydride, pyromellitic acid , Trimellitic acid, trimellitic anhydride, phthalimide, 4-nitrophthalimide, tetracyanoethylene, tetracyanoquinodimethane, chloranil, bromanyl, o-nitrobenzoic acid, malononitrile, trinitrofluorenone, trinitrothioxanthone, dinitrobenzene, Dinitroanthracene, dinitroacridine, nitroanthraquinone, dinitroanthraquinone, thiopyran compounds, quinone compounds, benzoquinone compounds, diphenoquinone compounds, naphthoquinone compounds, anthraquinone compounds, stilbes Quinone compounds, mention may be made
- a polycarbonate resin made of a copolymer of structural units represented by the above general formulas (1) and (2) as the resin binder of the single-layer type photosensitive layer 5.
- Examples of the copolymer polycarbonate resin include the same ones as described above.
- the above-mentioned copolymer polycarbonate resin may be used alone or in combination with other resins.
- other resins include various polycarbonate resins such as bisphenol A type, bisphenol Z type, bisphenol A type-biphenyl copolymer, bisphenol Z type-biphenyl copolymer, polyphenylene resin, polyester, etc.
- Resin polyvinyl acetal resin, polyvinyl butyral resin, polyvinyl alcohol resin, vinyl chloride resin, vinyl acetate resin, polyethylene resin, polypropylene resin, acrylic resin, polyurethane resin, epoxy resin, melamine resin, silicone resin, polyamide resin, polystyrene resin, polyacetal Resins, polyarylate resins, polysulfone resins, methacrylic acid ester polymers, copolymers thereof, and the like can be used. Furthermore, the same kind of resins having different molecular weights may be mixed and used.
- the content of the resin binder is preferably 10 to 90% by mass and more preferably 20 to 80% by mass with respect to the solid content of the single-layer type photosensitive layer 5.
- the single-layer type photosensitive layer 5 As an additive for the single-layer type photosensitive layer 5, it is necessary to use at least one of the diester compounds represented by the general formula (6).
- the content of the additive in the single-layer type photosensitive layer 5 is preferably 0.05 to 20% by mass, more preferably 0.1 to 15% by mass with respect to the solid content of the single-layer type photosensitive layer 5. More preferably, it is 0.5 to 10% by mass.
- the film thickness of the single-layer type photosensitive layer 5 is preferably in the range of 3 to 100 ⁇ m and more preferably in the range of 5 to 40 ⁇ m in order to maintain a practically effective surface potential.
- the charge transport layer 4 is mainly composed of a charge transport material and a resin binder.
- the charge transporting material and the resin binder for the charge transporting layer 4 the same materials as those mentioned for the charge transporting layer 4 according to the negatively charged laminated photoreceptor can be used. Further, the content of each material and the film thickness of the charge transport layer 4 can be the same as those in the negatively charged laminated photoreceptor.
- the polycarbonate resin which consists of a copolymer of the structural unit represented by the said General formula (1) and (2) can be used arbitrarily.
- the charge generation layer 3 provided on the charge transport layer 4 is mainly composed of a charge generation material, a hole transport material, an electron transport material (acceptor compound), and a resin binder.
- a charge generation material As the charge generation material, hole transport material, electron transport material, and resin binder of the charge generation layer 3, the same materials as those mentioned for the single layer type photosensitive layer 5 in the single layer type photoreceptor can be used.
- the content of each material and the film thickness of the charge generation layer 3 can be the same as those of the single-layer photosensitive layer 5 in the single-layer photoreceptor.
- At least one of the stilbene compounds represented by the above general formula (3), (4) or (5) is contained as a hole transport material of the charge generation layer 3.
- the resin binder of the charge generation layer 3 it is necessary to contain a polycarbonate resin made of a copolymer of the structural units represented by the general formulas (1) and (2).
- the diester compounds represented by the general formula (6) it is necessary to contain at least one of the diester compounds represented by the general formula (6) as an additive for the charge generation layer 3.
- the compound represented by Structural Formula (6) can be used as the additive in the charge transport layer 4 as necessary.
- an antioxidant or a light stabilizer is added to the photosensitive layer of either a laminated type or a single layer type for the purpose of improving environmental resistance and stability against harmful light.
- Deterioration preventing agents such as can be contained.
- Compounds used for such purposes include chromanol derivatives such as tocopherol and esterified compounds, polyarylalkane compounds, hydroquinone derivatives, etherified compounds, dietherified compounds, benzophenone derivatives, benzotriazole derivatives, thioether compounds, phenylenediamine derivatives. Phosphonic acid ester, phosphorous acid ester, phenol compound, hindered phenol compound, linear amine compound, cyclic amine compound, hindered amine compound and the like.
- the photosensitive layer may contain a leveling agent such as silicone oil or fluorine oil for the purpose of improving the leveling property of the formed film and imparting lubricity.
- a leveling agent such as silicone oil or fluorine oil
- metal oxides such as silicon oxide (silica), titanium oxide, zinc oxide, calcium oxide, aluminum oxide (alumina), zirconium oxide, etc. for the purpose of adjusting film hardness, reducing friction coefficient, and imparting lubricity
- Metal sulfides such as barium sulfate and calcium sulfate, metal nitride fine particles such as silicon nitride and aluminum nitride, fluorine resin particles such as tetrafluoroethylene resin, fluorine comb-type graft polymerization resin, etc. Also good.
- other known additives can be contained as long as the electrophotographic characteristics are not significantly impaired.
- the method for producing a photoreceptor of the present invention includes a step of forming a photosensitive layer by applying a coating solution on a conductive substrate.
- a coating solution the structural unit represented by the above general formula (1) and the above general formula A polycarbonate resin containing a copolymer with the structural unit represented by (2), at least one of the stilbene compounds represented by the above general formula (3), (4) or (5), and the above general It is characterized in that a compound containing at least one of diester compounds represented by formula (6) is used.
- various coating methods such as a dip coating method or a spray coating method can be applied to the coating solution, and the coating solution is not limited to any one of the coating methods.
- the electrophotographic photoreceptor of the present invention can achieve the desired effect when applied to various machine processes. Specifically, a charging process such as a contact charging method using a roller or a brush, a non-contact charging method using a corotron or scorotron, and a developing method such as a non-magnetic one component, a magnetic one component, or a two component. A sufficient effect can be obtained also in the development process such as the contact development and non-contact development methods used.
- FIG. 2 shows a schematic configuration diagram of an electrophotographic apparatus equipped with the electrophotographic photoreceptor of the present invention.
- the electrophotographic apparatus 60 of the present invention includes the electrophotographic photoreceptor 7 of the present invention including the conductive substrate 1, the undercoat layer 2 and the photosensitive layer 300 coated on the outer peripheral surface thereof. Further, the electrophotographic apparatus 60 includes a roller charging member 21, a high-voltage power source 22 that supplies an applied voltage to the roller charging member 21, an image exposure member 23, and a developing device, which are disposed on the outer peripheral edge of the photoreceptor 7.
- a developing device 24 having a roller 241, a paper feeding member 25 having a paper feeding roller 251 and a paper feeding guide 252, a transfer charger (direct charging type) 26, and a cleaning device 27 having a cleaning blade 271; And a static elimination member 28.
- the electrophotographic apparatus 60 of the present invention can be a color printer.
- Example 1 A coating solution A is prepared by dissolving and dispersing 3 parts by mass of alcohol-soluble nylon (trade name “CM8000”, manufactured by Toray Industries, Inc.) and 7 parts by mass of aminosilane-treated titanium oxide fine particles in 90 parts by mass of methanol. did.
- the coating liquid A was dip-coated on the outer periphery of an aluminum cylinder having an outer diameter of 30 mm as the conductive substrate 1 and dried at a temperature of 100 ° C. for 30 minutes to form an undercoat layer 2 having a thickness of 3 ⁇ m.
- Y-type titanyl phthalocyanine 1 part by mass of Y-type titanyl phthalocyanine as a charge generation material and 1.5 parts by mass of a polyvinyl butyral resin (trade name “ESREC KS-1” manufactured by Sekisui Chemical Co., Ltd.) as a resin binder are added to 60 parts by mass of dichloromethane. Dissolve and disperse to prepare coating solution B.
- the coating solution B was dip-coated on the undercoat layer 2 and dried at a temperature of 80 ° C. for 30 minutes to form a charge generation layer 3 having a thickness of 0.25 ⁇ m.
- a coating solution C was prepared. On the charge generation layer 3, the coating solution C was dip coated and dried at a temperature of 90 ° C. for 60 minutes to form a charge transport layer 4 having a film thickness of 25 ⁇ m, thereby preparing a negatively charged laminated photoreceptor.
- Example 2 A photoconductor was prepared in the same manner as in Example 1 except that the additive represented by the chemical formula (6-1) used in Example 1 was changed to the additive represented by the chemical formula (6-2). did.
- Example 3 A photoconductor was produced in the same manner as in Example 1 except that the molecular weight of the resin (1) used in Example 1 was changed to 50000 and the amount of the additive was changed to 0.2 parts by mass.
- Example 4 A photoconductor was produced in the same manner as in Example 3 except that the amount of the additive used in Example 3 was changed to 1 part by mass.
- Example 5 A photoconductor was prepared in the same manner as in Example 3 except that the amount of the additive used in Example 3 was changed to 2 parts by mass.
- Example 6 A photoconductor was prepared in the same manner as in Example 3 except that the amount of the additive used in Example 3 was changed to 10 parts by mass.
- Example 7 A photoconductor was produced in the same manner as in Example 3 except that the amount of the additive used in Example 3 was changed to 20 parts by mass.
- Example 8 A photoconductor was prepared in the same manner as in Example 3 except that the amount of the additive used in Example 3 was changed to 30 parts by mass.
- Example 9 A photoconductor was prepared in the same manner as in Example 3 except that the amount of the additive used in Example 3 was changed to 40 parts by mass.
- Example 10 A photoconductor was prepared in the same manner as in Example 3, except that the additive represented by the chemical formula (6-1) used in Example 3 was changed to the additive represented by the chemical formula (6-2). did.
- Example 11 A photoconductor was prepared in the same manner as in Example 10 except that the amount of the additive used in Example 10 was changed to 1 part by mass.
- Example 12 A photoconductor was produced in the same manner as in Example 10 except that the amount of the additive used in Example 10 was changed to 2 parts by mass.
- Example 13 A photoconductor was prepared in the same manner as in Example 10 except that the amount of the additive used in Example 10 was changed to 10 parts by mass.
- Example 14 A photoconductor was produced in the same manner as in Example 10 except that the amount of the additive used in Example 10 was changed to 20 parts by mass.
- Example 15 A photoconductor was prepared in the same manner as in Example 10 except that the amount of the additive used in Example 10 was changed to 30 parts by mass.
- Example 16 A photoconductor was produced in the same manner as in Example 10 except that the amount of the additive used in Example 10 was changed to 40 parts by mass.
- Example 17 In Example 5, a photoreceptor was prepared in the same manner as in Example 5 except that 2 parts by mass of the additive represented by the chemical formula (6-2) was further added.
- Example 18 In Example 6, a photoreceptor was produced in the same manner as in Example 6 except that 10 parts by mass of the additive represented by the chemical formula (6-2) was added.
- Example 19 In Example 7, a photoreceptor was prepared in the same manner as in Example 7, except that 20 parts by mass of the additive represented by the chemical formula (6-2) was further added.
- Example 20 A photoconductor was produced in the same manner as in Example 6 except that the amount of the resin (1) used in Example 6 was changed to 140 parts by mass and the amount of the charge transport material was changed to 60 parts by mass.
- Example 21 A photoconductor was prepared in the same manner as in Example 13 except that the amount of the resin (1) used in Example 13 was changed to 140 parts by mass and the amount of the charge transport material was changed to 60 parts by mass.
- Example 22 A photoconductor was produced in the same manner as in Example 6 except that the amount of the resin (1) used in Example 6 was changed to 110 parts by mass and the amount of the charge transport material was changed to 90 parts by mass.
- Example 23 A photoconductor was prepared in the same manner as in Example 13 except that the amount of the resin (1) used in Example 13 was changed to 110 parts by mass and the amount of the charge transport material was changed to 90 parts by mass.
- Example 24 A photoconductor was produced in the same manner as in Example 1 except that the molecular weight of the resin (1) used in Example 1 was changed to 60000.
- Example 25 A photoconductor was prepared in the same manner as in Example 2 except that the molecular weight of the resin (1) used in Example 2 was changed to 60000.
- Example 26 A photoconductor was prepared in the same manner as in Example 1 except that the charge transporting material used in Example 1 was changed to the compound represented by the formula (4-1).
- Example 27 A photoconductor was prepared in the same manner as in Example 2, except that the charge transporting material used in Example 2 was changed to the compound represented by the formula (4-1).
- Example 28 A photoconductor was prepared in the same manner as in Example 3 except that the charge transporting material used in Example 3 was changed to the compound represented by the formula (4-1).
- Example 29 A photoconductor was prepared in the same manner as in Example 4 except that the charge transporting material used in Example 4 was changed to the compound represented by the formula (4-1).
- Example 30 A photoconductor was prepared in the same manner as in Example 5 except that the charge transporting material used in Example 5 was changed to the compound represented by the formula (4-1).
- Example 31 A photoconductor was prepared in the same manner as in Example 6 except that the charge transporting material used in Example 6 was changed to the compound represented by the above formula (4-1).
- Example 32 A photoreceptor was produced in the same manner as in Example 7, except that the charge transporting material used in Example 7 was changed to the compound represented by the formula (4-1).
- Example 33 A photoreceptor was produced in the same manner as in Example 8, except that the charge transporting material used in Example 8 was changed to the compound represented by the formula (4-1).
- Example 34 A photoreceptor was produced in the same manner as in Example 9, except that the charge transporting material used in Example 9 was changed to the compound represented by the formula (4-1).
- Example 35 A photoconductor was prepared in the same manner as in Example 10 except that the charge transporting material used in Example 10 was changed to the compound represented by the formula (4-1).
- Example 36 A photoconductor was prepared in the same manner as in Example 11, except that the charge transporting material used in Example 11 was changed to the compound represented by the formula (4-1).
- Example 37 A photoconductor was prepared in the same manner as in Example 12, except that the charge transporting material used in Example 12 was changed to the compound represented by the formula (4-1).
- Example 38 A photoconductor was prepared in the same manner as in Example 13, except that the charge transporting material used in Example 13 was changed to the compound represented by the above formula (4-1).
- Example 39 A photoreceptor was produced in the same manner as in Example 14, except that the charge transporting material used in Example 14 was changed to the compound represented by the formula (4-1).
- Example 40 A photoconductor was prepared in the same manner as in Example 15, except that the charge transporting material used in Example 15 was changed to the compound represented by the formula (4-1).
- Example 41 A photoreceptor was produced in the same manner as in Example 16, except that the charge transporting material used in Example 16 was changed to the compound represented by the formula (4-1).
- Example 42 A photoconductor was prepared in the same manner as in Example 17, except that the charge transporting material used in Example 17 was changed to the compound represented by the above formula (4-1).
- Example 43 A photoreceptor was produced in the same manner as in Example 18, except that the charge transporting material used in Example 18 was changed to the compound represented by the formula (4-1).
- Example 44 A photoreceptor was produced in the same manner as in Example 19, except that the charge transporting material used in Example 19 was changed to the compound represented by the formula (4-1).
- Example 45 A photoreceptor was produced in the same manner as in Example 20, except that the charge transporting material used in Example 20 was changed to the compound represented by the formula (4-1).
- Example 46 A photoconductor was prepared in the same manner as in Example 21, except that the charge transporting material used in Example 21 was changed to the compound represented by the above formula (4-1).
- Example 47 A photoconductor was prepared by the same method as that of Example 22 except that the charge transporting material used in Example 22 was changed to the compound represented by the above formula (4-1).
- Example 48 A photoconductor was prepared in the same manner as in Example 23 except that the charge transporting material used in Example 23 was changed to the compound represented by the above formula (4-1).
- Example 49 A photoconductor was prepared in the same manner as in Example 24 except that the charge transporting material used in Example 24 was changed to the compound represented by the above formula (4-1).
- Example 50 A photoconductor was prepared by the same method as that of Example 25 except that the charge transporting material used in Example 25 was changed to the compound represented by the above formula (4-1).
- Example 51 A photoconductor was produced in the same manner as in Example 1 except that the resin (1) used in Example 1 was changed to resin (2) (viscosity average molecular weight 50000) represented by the following structural formula.
- Example 52 A photoconductor was prepared in the same manner as in Example 51 except that the additive represented by the chemical formula (6-1) used in Example 51 was changed to the additive represented by the chemical formula (6-2). did.
- Example 53 A photoconductor was prepared by the same method as that of Example 51 except that the charge transporting material used in Example 51 was changed to the compound represented by the above formula (4-1).
- Example 54 A photoreceptor was produced in the same manner as in Example 52 except that the charge transport material used in Example 52 was changed to the compound represented by the formula (4-1).
- Example 55 A photoconductor was prepared in the same manner as in Example 1 except that the resin (1) used in Example 1 was changed to resin (3) (viscosity average molecular weight 50000) represented by the following structural formula.
- Example 56 A photoconductor was prepared in the same manner as in Example 55 except that the additive represented by the chemical formula (6-1) used in Example 55 was changed to the additive represented by the chemical formula (6-2). did.
- Example 57 A photoconductor was prepared by the same method as that of Example 55 except that the charge transporting material used in Example 55 was changed to the compound represented by the above formula (4-1).
- Example 58 A photoconductor was prepared by the same method as that of Example 55 except that the charge transporting material used in Example 56 was changed to the compound represented by the above formula (4-1).
- Comparative Example 1 A photoconductor was produced in the same manner as in Example 1 except that the resin used in Example 1 was changed to resin (4) (viscosity average molecular weight 50000) represented by the following structural formula.
- Comparative Example 2 A photoconductor was prepared in the same manner as in Example 2 except that the resin used in Example 2 was changed to resin (4).
- Comparative Example 3 A photoconductor was prepared in the same manner as in Example 26 except that the resin used in Example 26 was changed to Resin (4).
- Comparative Example 4 A photoconductor was prepared in the same manner as in Example 27 except that the resin used in Example 27 was changed to Resin (4).
- Comparative Example 5 A photoconductor was prepared in the same manner as in Comparative Example 1 except that the resin used in Comparative Example 1 was changed to Resin (5) (viscosity average molecular weight 50000) represented by the following structural formula.
- Comparative Example 6 A photoconductor was prepared in the same manner as in Comparative Example 2 except that the resin used in Comparative Example 2 was changed to Resin (5).
- Comparative Example 7 A photoconductor was prepared in the same manner as in Comparative Example 3 except that the resin used in Comparative Example 3 was changed to Resin (5).
- Comparative Example 8 A photoconductor was prepared in the same manner as in Comparative Example 4 except that the resin used in Comparative Example 4 was changed to Resin (5).
- Comparative Example 9 A photoconductor was prepared in the same manner as in Example 6, except that the charge transporting material used in Example 6 was changed to the compound represented by the following structural formula (9).
- Comparative Example 10 A photoconductor was prepared in the same manner as in Example 13 except that the charge transporting material used in Example 13 was changed to the compound represented by the formula (9).
- Example 6 Comparative Example 11 In Example 6, a photoreceptor was produced in the same manner as in Example 6 except that no additive was added.
- Example 35 a photoconductor was prepared by the same method as that in Example 35 except that no additive was added.
- Example 59 A photoconductor was prepared in the same manner as in Example 6 except that the amount of the additive in Example 6 was changed to 50 parts by mass.
- Example 60 A photoconductor was prepared in the same manner as in Example 35 except that the amount of the additive in Example 35 was changed to 50 parts by mass.
- the photosensitive member is irradiated with 1.0 ⁇ W / cm 2 of exposure light dispersed at 780 nm using a filter for 5 seconds from the time when the surface potential becomes ⁇ 600 V.
- E 1/2 ( ⁇ J / cm 2 ) for the amount of light required to attenuate the light until ⁇ 300 V, and Vr 5 ( ⁇ V) as the residual potential on the surface of the photoreceptor 5 seconds after the exposure.
- the surface of the photoconductor was charged to ⁇ 800 V in the dark using Cynthia 93 in an environment of a temperature of 5 ° C. and a humidity of 10%. Thereafter, the photoconductor is rotated (167 rpm), exposure is performed with a light quantity of 0.35 ⁇ J / cm 2 , and a surface potential meter is arranged at positions 30 ms and 90 ms after exposure to measure the surface potential. Went. The difference in surface potential after 90 ms and 30 ms was evaluated as responsiveness.
- the photoconductors produced in Examples 1 to 60 and Comparative Examples 1 to 12 were modified so that the surface potential of the photoconductor could be measured, and a two-component development type digital copying machine (manufactured by Canon Inc., image runner color 2880), printing 10000 sheets of A4 paper, measuring the potential stability by measuring the exposure part potential (VL) before and after printing, and measuring the film thickness of the photoreceptor, Evaluation was performed on the amount of wear ( ⁇ m) after printing. At the same time, image evaluation (memory evaluation) was also conducted.
- the image evaluation was performed by reading the presence or absence of a memory phenomenon in which the checkered flag appears in the halftone portion in the print evaluation of the image sample having the checker flag pattern in the first half portion and the halftone portion in the second half portion.
- the result shows ⁇ if the memory was not observed, ⁇ if the memory was slightly observed, ⁇ if the memory was clearly observed, and the original image and shade appear as well.
- (Positive) was determined for the image
- (Negative) was determined for the image in which the density was reversed from that of the original image, that is, when the image was inverted.
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Abstract
Description
前記感光層が、少なくとも樹脂バインダ、電荷輸送材料および添加剤を含有し、該樹脂バインダが下記一般式(1)で表される構造単位と下記一般式(2)で表される構造単位との共重合物からなるポリカーボネート樹脂を含み、該電荷輸送材料が下記一般式(3)、(4)または(5)で表されるスチルベン化合物のうちの少なくとも1種を含み、かつ、該添加剤が下記一般式(6)で表されるジエステル化合物のうちの少なくとも1種を含むことを特徴とするものである。
(一般式(1)中、R1およびR2は、同一であっても異なっていてもよく、水素原子、炭素数1~12のアルキル基、ハロゲン原子、炭素数6~12の置換若しくは無置換のアリール基、または、炭素数1~12のアルコキシ基であり、cは0~4の整数であり、Xは、単結合、‐O‐、‐S‐、‐SO‐、‐CO‐、‐SO2‐または‐CR3R4‐(R3およびR4は、同一であっても異なっていてもよく、水素原子、炭素数1~12のアルキル基、ハロゲン化アルキル基、または、炭素数6~12の置換若しくは無置換のアリール基である)、炭素数5~12の置換若しくは無置換のシクロアルキリデン基、炭素数2~12の置換若しくは無置換のα,ωアルキレン基、‐9,9‐フルオレニリデン基、炭素数6~12の置換若しくは無置換のアリーレン基、または、炭素数6~12のアリール基若しくはアリーレン基を含有する2価の基であり、m,nは各モノマーのモル比率を表す)
(一般式(3)中、R5およびR6は、同一であっても異なっていてもよく、水素原子、置換若しくは非置換のアルキル基、または、メトキシ基であり、Ar1,Ar2,Ar3は同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアリール基である)
(一般式(4)中、R7、R8、R9およびR10は、同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアルキル基である)
(一般式(5)中、R11、R12、R13、R14およびR15は、同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアルキル基である)
(一般式(6)中、Aは下記式(7)のうちのいずれかで表される有機基であり、Bは下記式(8)のうちのいずれかで表される有機基である)
前記塗布液として、上記一般式(1)で表される構造単位と上記一般式(2)で表される構造単位との共重合物を含むポリカーボネート樹脂、上記一般式(3)、(4)または(5)で表されるスチルベン化合物のうちの少なくとも1種、および、上記一般式(6)で表されるジエステル化合物のうちの少なくとも1種を含有するものを用いることを特徴とするものである。
導電性基体1は、感光体の電極としての役目を有すると同時に、感光体を構成する各層の支持体ともなるものであり、円筒状や板状、フィルム状などのいずれの形状でもよい。導電性基体1の材質としては、アルミニウムやステンレス鋼、ニッケルなどの金属類、あるいは、ガラスや樹脂などの表面に導電処理を施したもの等を使用することができる。
本発明において、単層型の場合の感光層5は、主として電荷発生材料、正孔輸送材料、電子輸送材料(アクセプター性化合物)および樹脂バインダからなる。
正帯電積層型感光体において、電荷輸送層4は、主として電荷輸送材料と樹脂バインダとにより構成される。かかる電荷輸送層4の電荷輸送材料および樹脂バインダとしては、負帯電積層型感光体に係る電荷輸送層4について挙げたものと同じ材料を用いることができる。また、各材料の含有量、および、電荷輸送層4の膜厚についても、負帯電積層型感光体におけるのと同様とすることができる。なお、樹脂バインダとしては、上記一般式(1)および(2)で表される構造単位の共重合物からなるポリカーボネート樹脂を任意に用いることができる。
アルコール可溶性ナイロン(東レ(株)製、商品名「CM8000」)3質量部と、アミノシラン処理された酸化チタン微粒子7質量部とを、メタノール90質量部に溶解、分散させて、塗布液Aを調製した。導電性基体1としての外径30mmのアルミニウム製円筒の外周に、この塗布液Aを浸漬塗工し、温度100℃で30分間乾燥して、膜厚3μmの下引き層2を形成した。
で示される共重合ポリカーボネート樹脂(樹脂(1),粘度平均分子量40000)130質量部と、前記化学式(6-1)で示される添加剤10質量部とを、ジクロロメタン1000質量部に溶解して、塗布液Cを調製した。上記電荷発生層3上に、塗布液Cを浸漬塗工し、温度90℃で60分間乾燥して、膜厚25μmの電荷輸送層4を形成し、負帯電積層型感光体を作製した。
実施例1で使用した前記化学式(6-1)で示される添加剤を、前記化学式(6-2)で示される添加剤に変えた以外は実施例1と同様の方法で、感光体を作製した。
実施例1で使用した樹脂(1)の分子量を50000に変え、添加剤の量を0.2質量部に変えた以外は実施例1と同様の方法で、感光体を作製した。
実施例3で使用した添加剤の量を1質量部に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例3で使用した添加剤の量を2質量部に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例3で使用した添加剤の量を10質量部に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例3で使用した添加剤の量を20質量部に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例3で使用した添加剤の量を30質量部に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例3で使用した添加剤の量を40質量部に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例3で使用した前記化学式(6-1)で示される添加剤を、前記化学式(6-2)で示される添加剤に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例10で使用した添加剤の量を1質量部に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例10で使用した添加剤の量を2質量部に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例10で使用した添加剤の量を10質量部に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例10で使用した添加剤の量を20質量部に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例10で使用した添加剤の量を30質量部に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例10で使用した添加剤の量を40質量部に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例5において、さらに、前記化学式(6-2)で示される添加剤を2質量部加えた以外は実施例5と同様の方法で、感光体を作製した。
実施例6において、さらに、前記化学式(6-2)で示される添加剤を10質量部加えた以外は実施例6と同様の方法で、感光体を作製した。
実施例7において、さらに、前記化学式(6-2)で示される添加剤を20質量部加えた以外は実施例7と同様の方法で、感光体を作製した。
実施例6で使用した樹脂(1)の量を140質量部に変え、電荷輸送材料の量を60質量部に変えた以外は実施例6と同様の方法で、感光体を作製した。
実施例13で使用した樹脂(1)の量を140質量部に変え、電荷輸送材料の量を60質量部に変えた以外は実施例13と同様の方法で、感光体を作製した。
実施例6で使用した樹脂(1)の量を110質量部に変え、電荷輸送材料の量を90質量部に変えた以外は実施例6と同様の方法で、感光体を作製した。
実施例13で使用した樹脂(1)の量を110質量部に変え、電荷輸送材料の量を90質量部に変えた以外は実施例13と同様の方法で、感光体を作製した。
実施例1で使用した樹脂(1)の分子量を60000に変えた以外は実施例1と同様の方法で、感光体を作製した。
実施例2で使用した樹脂(1)の分子量を60000に変えた以外は実施例2と同様の方法で、感光体を作製した。
実施例1で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例1と同様の方法で、感光体を作製した。
実施例2で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例2と同様の方法で、感光体を作製した。
実施例3で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例3と同様の方法で、感光体を作製した。
実施例4で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例4と同様の方法で、感光体を作製した。
実施例5で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例5と同様の方法で、感光体を作製した。
実施例6で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は、実施例6と同様の方法で感光体を作製した。
実施例7で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例7と同様の方法で、感光体を作製した。
実施例8で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例8と同様の方法で、感光体を作製した。
実施例9で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例9と同様の方法で、感光体を作製した。
実施例10で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例10と同様の方法で、感光体を作製した。
実施例11で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例11と同様の方法で、感光体を作製した。
実施例12で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例12と同様の方法で、感光体を作製した。
実施例13で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例13と同様の方法で、感光体を作製した。
実施例14で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例14と同様の方法で、感光体を作製した。
実施例15で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例15と同様の方法で、感光体を作製した。
実施例16で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例16と同様の方法で、感光体を作製した。
実施例17で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例17と同様の方法で、感光体を作製した。
実施例18で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例18と同様の方法で、感光体を作製した。
実施例19で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例19と同様の方法で、感光体を作製した。
実施例20で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例20と同様の方法で、感光体を作製した。
実施例21で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例21と同様の方法で、感光体を作製した。
実施例22で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例22と同様の方法で、感光体を作製した。
実施例23で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例23と同様の方法で、感光体を作製した。
実施例24で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例24と同様の方法で、感光体を作製した。
実施例25で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例25と同様の方法で、感光体を作製した。
実施例51で使用した前記化学式(6-1)で示される添加剤を、前記化学式(6-2)で示される添加剤に変えた以外は実施例51と同様の方法で、感光体を作製した。
実施例51で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例51と同様の方法で、感光体を作製した。
実施例52で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は実施例52と同様の方法で、感光体を作製した。
実施例55で使用した前記化学式(6-1)で示される添加剤を、前記化学式(6-2)で示される添加剤に変えた以外は実施例55と同様の方法で、感光体を作製した。
実施例55で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は、実施例55と同様の方法で感光体を作製した。
実施例56で使用した電荷輸送材料を前記式(4-1)で示される化合物に変えた以外は、実施例55と同様の方法で感光体を作製した。
実施例2で使用した樹脂を樹脂(4)に変えた以外は実施例2と同様の方法で、感光体を作製した。
実施例26で使用した樹脂を樹脂(4)に変えた以外は実施例26と同様の方法で、感光体を作製した。
実施例27で使用した樹脂を樹脂(4)に変えた以外は実施例27と同様の方法で、感光体を作製した。
比較例2で使用した樹脂を樹脂(5)に変えた以外は比較例2と同様の方法で、感光体を作製した。
比較例3で使用した樹脂を樹脂(5)に変えた以外は比較例3と同様の方法で、感光体を作製した。
比較例4で使用した樹脂を樹脂(5)に変えた以外は比較例4と同様の方法で、感光体を作製した。
実施例13で使用した電荷輸送材料を前記式(9)で示される化合物に変えた以外は実施例13と同様の方法で、感光体を作製した。
実施例6において、添加剤を加えない以外は実施例6と同様の方法で、感光体を作製した。
実施例35において、添加剤を加えない以外は実施例35と同様の方法で、感光体を作製した。
実施例6の添加剤の量を50質量部に変えた以外は実施例6と同様の方法で、感光体を作製した。
実施例35の添加剤の量を50質量部に変えた以外は実施例35と同様の方法で、感光体を作製した。
上述した実施例1~60および比較例1~12で作製した感光体の電気特性、実機特性および耐ソルベントクラック特性を、下記の方法で評価した。その結果を、下記の表中に示す。
実施例1~60および比較例1~12で作製した感光体について、温度22℃、湿度50%の環境で、感光体の表面を暗所にてコロナ放電により-650Vに帯電せしめた後、帯電直後の表面電位V0を測定した。続いて、暗所で5秒間放置後、表面電位V5を測定して、下記計算式(1)、
Vk5=V5/V0×100 (1)
に従って、帯電後5秒後における電位保持率Vk5(%)を求めた。次に、ハロゲンランプを光源とし、フィルターを用いて780nmに分光した1.0μW/cm2の露光光を、感光体に、表面電位が-600Vになった時点から5秒間照射して、表面電位が-300Vとなるまで光減衰するのに要する露光量をE1/2(μJ/cm2)、露光後5秒後の感光体表面の残留電位をVr5(-V)として評価した。
実施例1~60および比較例1~12で作製した感光体について、温度5℃、湿度10%の環境で、Cynthia 93を用いて、感光体の表面を暗所にて-800Vに帯電させた後、感光体を回転させ(167rpm)、0.35μJ/cm2の光量での露光を行い、露光から30ms後および90ms後の位置となるように表面電位計を配置して、表面電位の測定を行った。90ms後と30ms後の表面電位の差を応答性として評価した。
実施例1~60および比較例1~12で作製した感光体について、感光体の表面電位も測定できるように改造を施したHP製のプリンターLJ4250に搭載して、低温低湿(LL)から高温高湿(HH)までの使用環境ごとの感光体の露光部電位を評価した。また、画像評価(メモリー評価)も実施した。
上記実機特性の評価と同じ条件にて、実施例1~60および比較例1~12において作製した感光体を用いて10枚印字した後、各感光体をケロシンに60分間浸漬させた。その後、再度同条件下で白紙を印刷して、クラックによって生じる印字不具合(黒スジ)の有無を確認した。画像の黒スジがある場合を○、ない場合を×として示した。
2 下引き層
3 電荷発生層
4 電荷輸送層
5 単層型感光層
7 感光体
21 ローラ帯電部材
22 高圧電源
23 像露光部材
24 現像器
241 現像ローラ
25 給紙部材
251 給紙ローラ
252 給紙ガイド
26 転写帯電器(直接帯電型)
27 クリーニング装置
271 クリーニングブレード
28 除電部材
60 電子写真装置
300 感光層
Claims (13)
- 導電性基体上に感光層を有する電子写真用感光体において、
前記感光層が、少なくとも樹脂バインダ、電荷輸送材料および添加剤を含有し、該樹脂バインダが下記一般式(1)で表される構造単位と下記一般式(2)で表される構造単位との共重合物からなるポリカーボネート樹脂を含み、該電荷輸送材料が下記一般式(3)、(4)または(5)で表されるスチルベン化合物のうちの少なくとも1種を含み、かつ、該添加剤が下記一般式(6)で表されるジエステル化合物のうちの少なくとも1種を含むことを特徴とする電子写真用感光体。
(一般式(1)中、R1およびR2は、同一であっても異なっていてもよく、水素原子、炭素数1~12のアルキル基、ハロゲン原子、炭素数6~12の置換若しくは無置換のアリール基、または、炭素数1~12のアルコキシ基であり、cは0~4の整数であり、Xは、単結合、‐O‐、‐S‐、‐SO‐、‐CO‐、‐SO2‐または‐CR3R4‐(R3およびR4は、同一であっても異なっていてもよく、水素原子、炭素数1~12のアルキル基、ハロゲン化アルキル基、または、炭素数6~12の置換若しくは無置換のアリール基である)、炭素数5~12の置換若しくは無置換のシクロアルキリデン基、炭素数2~12の置換若しくは無置換のα,ωアルキレン基、‐9,9‐フルオレニリデン基、炭素数6~12の置換若しくは無置換のアリーレン基、または、炭素数6~12のアリール基若しくはアリーレン基を含有する2価の基であり、m,nは各モノマーのモル比率を表す)
(一般式(3)中、R5およびR6は、同一であっても異なっていてもよく、水素原子、置換若しくは非置換のアルキル基、または、メトキシ基であり、Ar1,Ar2,Ar3は同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアリール基である)
(一般式(4)中、R7、R8、R9およびR10は、同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアルキル基である)
(一般式(5)中、R11、R12、R13、R14およびR15は、同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアルキル基である)
(一般式(6)中、Aは下記式(7)のうちのいずれかで表される有機基であり、Bは下記式(8)のうちのいずれかで表される有機基である)
- 前記感光層が、感光体の最表面層をなす請求項1記載の電子写真用感光体。
- 前記感光層が、電荷発生層と電荷輸送層とを順次積層してなり、かつ、該電荷輸送層が、前記ポリカーボネート樹脂、前記スチルベン化合物および前記ジエステル化合物を含有する請求項1記載の電子写真用感光体。
- 前記一般式(1)中、R1およびR2がそれぞれ独立に水素原子またはメチル基であり、かつ、Xがシクロヘキシリデン基である請求項1記載の電子写真用感光体。
- 前記共重合物における、前記一般式(1)で表される構造単位の共重合比が、15モル%以上90モル%以下である請求項1記載の電子写真用感光体。
- 前記ジエステル化合物の含有量が、前記感光層の固形分の全量に対し、0.05質量%~20質量%である請求項1記載の電子写真用感光体。
- 導電性基体上に塗布液を塗布して感光層を形成する工程を含む電子写真用感光体の製造方法において、
前記塗布液として、下記一般式(1)で表される構造単位と下記一般式(2)で表される構造単位との共重合物を含むポリカーボネート樹脂、下記一般式(3)、(4)または(5)で表されるスチルベン化合物のうちの少なくとも1種、および、下記一般式(6)で表されるジエステル化合物のうちの少なくとも1種を含有するものを用いることを特徴とする電子写真用感光体の製造方法。
(一般式(1)中、R1およびR2は、同一であっても異なっていてもよく、水素原子、炭素数1~12のアルキル基、ハロゲン原子、炭素数6~12の置換若しくは無置換のアリール基、または、炭素数1~12のアルコキシ基であり、cは0~4の整数であり、Xは、単結合、‐O‐、‐S‐、‐SO‐、‐CO‐、‐SO2‐または‐CR3R4‐(R3およびR4は、同一であっても異なっていてもよく、水素原子、炭素数1~12のアルキル基、ハロゲン化アルキル基、または、炭素数6~12の置換若しくは無置換のアリール基である)、炭素数5~12の置換若しくは無置換のシクロアルキリデン基、炭素数2~12の置換若しくは無置換のα,ωアルキレン基、‐9,9‐フルオレニリデン基、炭素数6~12の置換若しくは無置換のアリーレン基、または、炭素数6~12のアリール基若しくはアリーレン基を含有する2価の基であり、m,nは各モノマーのモル比率を表す)
(一般式(3)中、R5およびR6は、同一であっても異なっていてもよく、水素原子、置換若しくは非置換のアルキル基、または、メトキシ基であり、Ar1,Ar2,Ar3は同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアリール基である)
(一般式(4)中、R7、R8、R9およびR10は、同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアルキル基である)
(一般式(5)中、R11、R12、R13、R14およびR15は、同一であっても異なっていてもよく、水素原子、または、置換若しくは非置換のアルキル基である)
(一般式(6)中、Aは下記式(7)のうちのいずれかで表される有機基であり、Bは下記式(8)のうちのいずれかで表される有機基である)
- 請求項1記載の電子写真用感光体を搭載したことを特徴とする電子写真装置。
- 請求項2記載の電子写真用感光体を搭載したことを特徴とする電子写真装置。
- 請求項3記載の電子写真用感光体を搭載したことを特徴とする電子写真装置。
- 請求項4記載の電子写真用感光体を搭載したことを特徴とする電子写真装置。
- 請求項5記載の電子写真用感光体を搭載したことを特徴とする電子写真装置。
- 請求項6記載の電子写真用感光体を搭載したことを特徴とする電子写真装置。
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Cited By (7)
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JP2018054744A (ja) * | 2016-09-27 | 2018-04-05 | 京セラドキュメントソリューションズ株式会社 | 電子写真感光体、プロセスカートリッジ及び画像形成装置 |
JP2018189941A (ja) * | 2017-04-28 | 2018-11-29 | 京セラドキュメントソリューションズ株式会社 | 電子写真感光体、プロセスカートリッジ及び画像形成装置 |
JP2019020672A (ja) * | 2017-07-21 | 2019-02-07 | 京セラドキュメントソリューションズ株式会社 | 電子写真感光体、プロセスカートリッジ及び画像形成装置 |
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Also Published As
Publication number | Publication date |
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TW201351073A (zh) | 2013-12-16 |
JP5871061B2 (ja) | 2016-03-01 |
US20140369715A1 (en) | 2014-12-18 |
US10254665B2 (en) | 2019-04-09 |
JPWO2013157145A1 (ja) | 2015-12-21 |
TWI599860B (zh) | 2017-09-21 |
CN104169803A (zh) | 2014-11-26 |
KR20150004794A (ko) | 2015-01-13 |
CN104169803B (zh) | 2018-09-04 |
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