WO2012055821A1 - Lubrifiant épaissi par des fibres oléophiles - Google Patents

Lubrifiant épaissi par des fibres oléophiles Download PDF

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Publication number
WO2012055821A1
WO2012055821A1 PCT/EP2011/068567 EP2011068567W WO2012055821A1 WO 2012055821 A1 WO2012055821 A1 WO 2012055821A1 EP 2011068567 W EP2011068567 W EP 2011068567W WO 2012055821 A1 WO2012055821 A1 WO 2012055821A1
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WO
WIPO (PCT)
Prior art keywords
fibers
oil
oleophilic
lubricant
lubricant according
Prior art date
Application number
PCT/EP2011/068567
Other languages
English (en)
Inventor
Jeroen Bongaerts
Alexander De Vries
Piet Lugt
Dick Meijer
Dries Muller
Rihard Pasaribu
Alejandro Sanz
Richard Schaake
Original Assignee
Aktiebolaget Skf
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aktiebolaget Skf filed Critical Aktiebolaget Skf
Priority to US13/881,451 priority Critical patent/US20130296206A1/en
Priority to EP11774055.5A priority patent/EP2633015A1/fr
Priority to CN201180051577XA priority patent/CN103180420A/zh
Publication of WO2012055821A1 publication Critical patent/WO2012055821A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/04—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
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    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28023—Fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3206—Organic carriers, supports or substrates
    • B01J20/3208—Polymeric carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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    • F16C33/30—Parts of ball or roller bearings
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    • F16C33/66—Special parts or details in view of lubrication
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    • F16C33/6655—Retaining the liquid in or near the bearing in a reservoir in the sealing means
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    • F16N—LUBRICATING
    • F16N7/00—Arrangements for supplying oil or unspecified lubricant from a stationary reservoir or the equivalent in or on the machine or member to be lubricated
    • F16N7/12—Arrangements for supplying oil or unspecified lubricant from a stationary reservoir or the equivalent in or on the machine or member to be lubricated with feed by capillary action, e.g. by wicks
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    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/44—Materials comprising a mixture of organic materials
    • B01J2220/445—Materials comprising a mixture of organic materials comprising a mixture of polymers
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    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
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    • C10M2229/02—Unspecified siloxanes; Silicones
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    • C10N2020/02—Viscosity; Viscosity index
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/02—Bearings
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    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
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    • C10N2050/08—Solids
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    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/298—Physical dimension

Definitions

  • the present invention relates to a lubricant, e.g., grease, comprising oil or lubricating fluid that has been thickened with one or more oleophilic fiber(s).
  • a lubricant e.g., grease
  • oil or lubricating fluid that has been thickened with one or more oleophilic fiber(s).
  • US 2005/0197260 discloses an environmentally-friendly grease composition
  • a vegetable oil and a cellulose fiber as well as also glycerin, a rust inhibitor and/or fatty acid ester, lecithin and/or phophatidyl choline.
  • US 6,482,780 discloses a grease composition for a roller bearing comprising a metal soap- based thickening agent containing a long fiber-like material having a major axis length of at least 3 microns incorporated in a base oil comprising a lubricant having a polar group in its molecular structure and a non-polar lubricant blended in combination.
  • US 5,874,391 discloses a polymer-thickened grease that is prepared by mixing a polymer, such as polypropylene, with a base oil and heating the mixture to fully dissolve the polymer in the base oil. The heated mixture is then rapidly cooled or quenched.
  • US 5,415,791 discloses a lubricating composition for solid lubricant-embedded sliding members comprising 5 to 78% by weight of a solid lubricant powder material, 5 to 30% by weight of a lubricating oil which is in a liquid or paste form at ordinary temperatures, 1 to 15%) by weight of a carrier for absorbing and retaining said lubricating oil, and 15 to 50% by weight of a thermosetting synthetic resin binder.
  • the carrier may be an oleophilic fiber, such as cellulose fiber and polypropylene fiber.
  • a dispersion of oleophilic micro fibers or nano fibers having a very high surface/volume ratio in an oil or other conventional lubricating liquid can be used to produce a lubricant that, at least in certain embodiments, may be capable of carrying up to 100 times its weight of the oil or other lubricating liquid.
  • This aspect is significant in that the structure functionality and formation are made substantially independent of the material.
  • a thickened lubricant such as a grease or a solid oil
  • a thickened lubricant may be prepared by dispersing such fibers, e.g., in a loose state, in the oil or other base lubricating fluid so that the resulting lubricant will have a structured three-dimensional network, which is able to retain and also release the base lubricating fluid, e.g., an oil.
  • This structure can be created by using nano- and/or micro-polymeric fibers that are produced prior to the formation of the lubricant or grease.
  • the polymeric fibers generally maintain their shape when contacted with the oil or other base lubricating fluid, i.e. at least a portion of the polymeric fibers do not dissolve or melt into the oil or other base lubricating fluid during operation or usage.
  • the fibers according to the present teachings may be disposed on a surface in need of lubrication.
  • An oil or other base lubricating fluid is then brought into contact with the surface having the fibers thereon, whereby a lubricant (e.g., a semi-solid lubricant, such as a grease) spontaneously forms by interacting with the fibers.
  • a lubricant e.g., a semi-solid lubricant, such as a grease
  • the fibers may be provided in the form of a fabric material, such as a non-woven pad, mat or cloth.
  • the fabric material may be affixed to a surface in need of lubrication and then the oil or other base lubricating fluid can be brought into contact with the surface/fabric material, thereby spontaneously forming the lubricant, as in the previous embodiment.
  • the fabric material may be dispersed (e.g., after being broken up into small pieces) in the oil or other base lubricating fluid in a manner similar to the loose fibers described above.
  • the present teachings advantageously enable a wide flexibility or choice in the selection of the structuring (fiber or fibrous) material.
  • the material can be selected to satisfy very specific operating conditions and/or to impart the lubricant or grease with advantageous properties, such as temperature stability, particular oil bleeding characteristics, etc.
  • refinements are possible in the physics and chemical tuning of the performance (lubrication, bleeding, fiber reinforcing, etc) as well as the particular processes for making and delivering this lubricant into the systems in need of lubrication.
  • the term "oleophilic" means that the surface of a flat piece of the material (i.e.
  • the material that will be used to form the oleophilic fibers or fibrous material will be readily covered (wetted) by oil or another base lubricating fluid, because that will reduce the total surface energy of the system.
  • a porous structure of an oleophilic material will absorb oil, like a sponge, through capillary action.
  • a higher degree of oleophilicity of the fibrous materials according to the present teachings may be more advantageous in certain embodiments.
  • Fig. 1 shows oil reservoirs defined in an elastomeric seal lip according to one aspect of the present teachings.
  • Fig. 2 shows a seal according to the present teachings having a porous liner layer disposed on the seal lip portion.
  • Fig. 3 is a graph showing the changes in grease consistency relative to fiber density according to experimental examples of the present teachings.
  • present teachings may be utilized with a wide variety of fluids, e.g., oils or other base lubricating fluids, that exhibit lubricating properties at the operating temperatures appropriate for various applications.
  • fluids e.g., oils or other base lubricating fluids
  • Particularly suitable lubricants include, but are not limited to, mineral oils obtained from crude oil, group I, II and III lubricants, group IV lubricants (polyalphaolefins "PAO") and group V lubricants (all others).
  • a more particular, but non-limiting, list of lubricating oils includes mineral oils, synthetic esters, and plant-based oils and their derivatives, such as oils derived from rapeseed, canola, sunflower, canola, and palm.
  • Animal -based oils, their derivatives and synthetic lubricants also may be suitably used in certain aspects of the present teaching including, but not limited to, polyglycols (PG), polyalkylene glycol (PAG), white oils, silicone oils, very-high viscosity index oils (VHVI), water, glycerol and waxes.
  • Particularly preferred oils according to the present teachings are mineral oils, synthetic esters, PAOs and synthetic hydrocarbons.
  • the viscosity of the lubricating fluid (oil) can range from very low (below 1 cSt at 40°C) to very high (several 1000 cSt at 40°C).
  • the most suitable viscosity depends on the application temperature, operating (e.g., rotating) speed, etc., and the present teachings provide for a wide variety of possible lubricating properties.
  • particularly preferred are any of the above oil types that have a viscosity between 10 and 300 cSt at 40°C.
  • the oleophilic fibers that may be utilized to thicken the lubrication fluids or oils according to the present teachings can be made, e.g., from any type of polymeric materials that can be spun into fibers, as well as in conjunction with optional additives.
  • Suitable polymers include, but are not limited to, polyamide (PA), nylon 6,6, polyamide-6,6 (PA-6,6), polyamide-4,6 (PA-4,6), polyurethanes (PU), polybenzimidazole (PBI), polycarbonate (PC), polyacrylinitrile (PAN), acrylonitrile rubber (NBR), polyvinylalcohol (PVA), polylactic acid (PLA), polyethylene-co-vinyl-acetate (PEVA), polymethacryate (PMMA), tetrahydroperfluorooctylacrylate (TAN), polyethylene oxide (PEO), collagen-PEO, polyaniline (PANI), polystyrene (PS), silk-like polymer with fibronectin functionality, polyvinylcarbazole, polyethylene terephtalate (PET), polyacrylic acid (PAA), polypyrene methanol (PM), polyvinylphenol (PVP), polyvinylchloride (PVC), cellulose acetate (
  • PP and PA are particularly preferred.
  • polymers derived from natural or biodegradable sources are also suitable for making fibers that can be utilized with the present teachings, in particular for the production of biodegradable greases.
  • Representative examples of such polymers include, but are not limited to, polysaccharides, such as cellulose, starch, chitin, chitosan, proteins, (poly)peptides and gelatin.
  • a small fraction e.g., 0.1-5%) can be added to grease that primarily contains a second type of fiber so as to impart special properties to the grease.
  • the fibers can be designed to melt at elevated temperatures to form a lubricant.
  • the fibers can contain additives.
  • the fibers can provide a structural function in the lubricant or grease.
  • Fibers A and B in a ratio A:B between 10:90 and 50:50 can be utilized to impart unique properties to the lubricant or grease.
  • the fibers can be between 0.1 and 100 wt% of the final material.
  • a material having 50-100 wt% of fiber can also function as a 'dry' lubricant, preferably if part or all of the fiber melts under application (usage) conditions (e.g., pressure, temperature, shear stress) and forms a lubricant.
  • a micro/nano fiber network can be prepared that will naturally embed, incorporate or absorb oil or another suitable base lubricating fluid, such that the overall process for making the lubricant is simplified to a great extent.
  • Fibers can be made from a variety of different materials mentioned above and the length/diameter ratio of the fibers, as well as the chemical composition (bulk or surface) thereof, can be tuned or suitably selected, as was mentioned above, using a variety of different existing processes that are inherently low cost in nature.
  • a soap-like or sponge-like structure by forming a cloth, pad, fabric, mat or sponge-like network from the fibers described herein, or by appropriately dispersing the fibers in an appropriate lubricant, leads to the generation of new lubricants with one or more specific properties that are believed to be new in the grease/lubricant field.
  • a cloth, pad, fabric or mat material can be produced from a variety of different polymer materials, such as the fiber materials mentioned above.
  • the cloth material may also be made with suitable lubrication additives included within or in the surface of the fibrous network, e.g., a non-woven fibrous network. This provides flexibility in producing unique, low weight structures that will only require the addition of an oil or another base lubricating fluid in order to form the lubricant, such as a grease.
  • the properties of the fibers can be tuned or suitably selected or treated in order to adjust the physical properties (e.g., length, diameter, mixture, etc.) and/or the chemical properties (surface treatment, bulk material, wetting behavior, etc.), which selection and/or treatment will enable the fibers to be suitably adapted to any type of lubricating fluid.
  • the physical properties e.g., length, diameter, mixture, etc.
  • the chemical properties surface treatment, bulk material, wetting behavior, etc.
  • the fibers can be cut to a specific length and thus the fibers can be utilized in a loose or dispersable state.
  • a cloth or fabric made of the fibers may be frozen and then the polymeric fibers are crushed while they are in a brittle state.
  • non-woven fiber fabrics mats can be made, e.g., by melt blowing micron or sub-micron diameter fibers, or by electro-spinning.
  • fiber material mats/cloths that may be advantageously utilized with the present teachings can also be obtained from commercial sources, such as Hills Inc. of W. Melbourne, Florida, U.S.A.
  • a soap-like structure made of micro/nano fibers will not require a heating and cooling process to form the grease, or will require only a minimal heating/cooling process.
  • the fiber network may be organic and/or inorganic.
  • the fiber fabrication method may be made compatible with a very large volume production.
  • the diameter of the fibers is preferably in the micron or nanometer range, while the length of the fibers is preferably in the range of several to tens of microns, most preferably less than 30 microns ( ⁇ ).
  • nanoparticle materials i.e. nanometer-sized particles having a low aspect ratio, e.g., about 1 that could present health hazards, which would limit their application, may be avoided.
  • the fiber diameters are between 50 nm and 10 microns, more preferably between 100 nm and 1 micron.
  • the fibers have a length that is at least 5-10 times the diameter thereof. That is, the fibers preferably have an aspect ratio of at least 5 to 10.
  • the length of the fibers can be suitably modified to effect desirable changes to the structural properties of the grease, its mechanical stability, and its bulk rheological properties. Thus, the fiber length can be optimized for particular application (usage) conditions.
  • the base material for the fibers can be produced and tuned/adapted for a specific application.
  • the base material can also be sent to a final user as a cloth/fabric material or a network of pre-cut fibers. In this case, the final user would only need to add oil (and perform a simple mixing procedure) to produce the lubricant or grease.
  • This aspect of the present teachings provides a great degree of flexibility, because the base material can be shipped worldwide relatively inexpensively, due to its low weight (i.e. unlike oil or greases, which are relatively heavy).
  • the fibers, any fabric or network-like materials made from the fibers, the lubricant fluid/oil and/or the thickened lubricant (e.g., grease) according to the present teachings may include one or more known additives that are commonly used in the lubricant field.
  • the additives may be included to give the lubricant special functionality with respect to the aging of the lubricant (e.g., anti-oxidants), friction reducers, anti-wear, extreme pressure properties, etc.
  • Additives can also be added to give the lubricant or grease a stronger structure by linking or connecting (e.g., bonding) the fibers using suitable polymers, waxes or the like. Fibers having different properties can be used as additives as well.
  • Ceramic particulates silicon, aluminia, zirconia, etc
  • metallic particles metallic particles
  • the additives can be added to the polymer bulk base before the fibers are produced, but could also be added to the dry fibers.
  • Small quantities of a carrier fluid (very suitable is a lubricant with or without additive) can also be added to the dry polymer base material.
  • the oil or lubricating fluid then can be subsequently added to make the final formulation of the thickened lubricant, e.g., the grease.
  • the additive(s) can also be added to the oil, which is then mixed and homogenized with the fibers or fibrous material (e.g., the cloth/fabric made from the fibers).
  • the fibers themselves may serve as an additive.
  • the fibers disclosed herein may be added to known lubricants (e.g., oil, greases and emulsions) to improve the lubrication and tribological performance thereof.
  • multi-property or multi -phase fibers may be referred to as a "JANUS fiber" after the Greek god who had two faces.
  • Such multi-property or multi-phase fibers are highly advantageous to the development of mechanical stability (when needed) and to the ability of the lubricant/grease to self heal. That is, after some type of disruptive mechanical action (e.g. shearing), the fiber structure may preferably heal itself (e.g., self re-assembly) once again into the desired structure (network).
  • the Janus fibers can be produced according to a variety of methods.
  • the fibers can be subjected to a spray treatment, a plasma treatment and/or deposition process that exposes the fiber on one side.
  • a deposition material can be a metal, polymer, small ceramic, metallic or organic nano-particulates that is/are embedded into or attached to the fiber on one side, e.g., the exposed side. This can be done either during the production of the fibers or after the production thereof.
  • the deposition will create fibers with different properties on the exposed and the unexposed sides. Another way is to prepare two different types of polymers in parallel and then form them into one single fiber using existing micro-scale extrusion techniques.
  • Island-In-Sea fibers in which a plurality of nano or micron-scale (bi-component) fibers are extruded in a matrix of a third polymer.
  • Another aspect of the present teachings relates to improve lubrication systems, e.g., for bearings, linear actuators, gears and any other mechanical raceway, track or sliding surface.
  • fibers of the present teachings can be rubbed onto (or otherwise applied to or deposited on) a sliding surface of a device, such as the raceway of a bearing, a gear or a linear device (motor), in order to form a local deposit of the fibers that will provide an oil swollen local reservoir.
  • the fibers can be applied as a preservative measure in order to provide both a better "running-in" of the device and a better long term storage resistance of the mechanical components.
  • This feature of the present teachings provides grease-like local lubrication in an oil-lubricated system (e.g., such as an industrial gearbox). Because the effect is achieved in-situ, it leads to longer surface life and local elimination of the oil starvation phenomena.
  • the present teachings may be applied to provide a layer on the surface, which layer is made by mixing a fiber (predominantly) and lubricant.
  • the resulting dynamic coating will self-regenerate during subsequent cycles and will protect the surface.
  • the fibers may be pre-treated with any suitable additives (e.g., low friction, anti-wear, and/or anti -oxidation agents), they can act as long-lasting, slow-release agents in order to enhance the lubrication function and to ensure longer service life of the mechanical surfaces.
  • solid oil products have been made by saturating a polymer matrix with oil.
  • Such solid oils have an oil content of up to 70%, but are much harder than is usual for lubricating greases. Due to the relatively stiff mechanical structure, they can provide more support than greases, while the relatively high oil content provides better lubrication than can be achieved by pure polymer materials.
  • a fiber-thickened grease according to the present teachings can be prepared such that it has a comparable stiffness to known solid oils and similar materials and therefore has the same functionality.
  • performance can also be improved as compared to known solid oils, because the fibers themselves can also act as a lubricant, i.e. the fibers supplement the lubricating properties of the base oil.
  • fibrous material may shear off during operation, thereby increasing the gap between the functional surface and the "grease" that reduces friction. If lubricating fibers enter the contact, they can provide additional lubrication.
  • the oil bleeding rate of the resulting grease can be tuned, e.g., for various bearing applications.
  • the oil bleeding rate of the resulting grease can be tuned, e.g., for various bearing applications.
  • Such solid oils preferably have a hardness values between 1% and 100% of the hardness of the base material of the polymer fibers.
  • lubricants are provided in the form thickened oils and greases. More specifically, lubricating fluids or oils are thickened with fibers according to the present teachings. While the most appropriate consistency is often determined by the application or usage of the thickened lubricant, the NLGI grade or consistency (the standard set or determined by the National Lubricating Grease Institute) is preferably equal to or greater than 00. More preferably, lubricants according to the present teachings have a consistency or NLGI grade between 1 and 3, e.g., 2. Such thickened greases are particularly suitable for usage in bearings.
  • the optimal fiber density of the thickened lubricant will depend on the required viscosity and consistency of the lubricant for the particular application, as well as the length and diameters of the fibers utilized to thicken the lubricating fluid or oil.
  • preferred fiber weight densities (based on the total lubricant weight) for a fiber-thickened lubricant are generally between about 0.1 and 20%.
  • Preferred fiber densities for a fiber-thickened 'grease' are generally about 2-15%, more preferably between about 5-12%. But, in case the fibers are used in conjunction with other thickeners, the fiber content may be reduced accordingly.
  • the bleeding properties of the oleophilic fiber- thickened lubricants and greases according to the present teachings can be controlled in several different ways by designing the fibrous structure such that it responds to an external stimulus, such as temperature, electric signals, etc.
  • pH can be used to control the release of oil.
  • TAN Total Acid Number
  • structural integrity, oleophilicity and/or shrinking of the product occur with changes in pH or specific chemicals that are released over time.
  • the structural change and hence oil release can be triggered by the consumption of an additive.
  • Fibers prepared from such polymers will act as a self regulating bleeding pump by pumping (sponge contraction) or bleeding (releasing) more oil out of the grease when the temperature increases.
  • a polymer fiber can be used that shrinks or contracts at elevated temperatures, which will have the effect of causing a squeezing or contraction of the fiber network that will, in turn, release (discharge) oil from the grease when the temperature increases. While such materials exist, the contraction/shrinking is usually an irreversible process. However, this shrinkage property may be advantageous in applications that require an emergency release of oil, which will be further described below.
  • the release mechanisms can be activated electrically by either induced heating or by having electro-active polymers forming a part of the soap or network structure of the grease.
  • Another gradual release mechanism involves the use of a grease comprising at least two different types of fibers, in which (at least) one of the fibers has a different melting point than the other(s), as was discussed above.
  • Initial melting of the low melting point fiber will impart a double benefit: a faster release of oil and the transferring of the melted fiber to the surface that will be coated and protected.
  • Fast release mechanisms may involve chemical and electrical triggers to selectively dissolve or melt the fibers for a fast and irreversible release of the oil buffer contained in the grease, as was discussed above.
  • Oil separation typically takes place when grease is stored for long periods of time, e.g., in a drum. In this case, the oil becomes visible as an oil layer on top of the grease. In general, the oil is lighter or less dense than the soap or other thickening material, so that the oil will float on the remaining grease. This separation phenomenon governs the "shelf life" of the grease, i.e. the amount of time that the grease may be safely stored before using. Release of oil On the shelf is therefore undesirable, and this presents a challenge, because the grease must be capable of bleeding sufficient oil in order to function as a good lubricant during operation. Therefore, shelf life and sufficient bleeding characteristics during usage need to be suitably balanced.
  • Oleophilic fiber-thickened greases according to the present teachings can be prepared that exhibit a longer shelf life.
  • two parameters may be controlled to influence the shelf life.
  • the buoyancy of the thickening material in the oil also affects the shelf life.
  • the thickener can be designed such that the specific mass (density) is almost equal to the specific mass (density) of the oil or lubricating fluid comprised in the grease. In this case, the oil or lubricating fluid is less able to float on top of the remaining grease, because they have equal or substantially equal specific masses.
  • the fibers can be coated or treated or thus selected in a manner that will maintain the base oil inside the fiber network (oleophilic properties) for a longer period of time.
  • the oleophilicity of the fibers can be determined according to a variety of techniques that are known in the surface science field. For example, as was described above, the contact angle of a drop of oil or lubricating fluid on a smooth flat surface of the same material as the fiber may provide one indication of the oleophilicity of the fiber. In this case, the lower or shallower the internal contact angle, the more oleophilic the material is. The oil is said to 'wet' the material when the internal contact angle is very shallow. Another method for indicating oleophilicity is to determine the volume of oil that a cloth or other structure (e.g., fabric) made of the fibers can absorb.
  • a cloth or other structure e.g., fabric
  • the structure functionality and formation of the lubricant or grease can be made independent of the material.
  • the polymer fiber network according to the present teachings can be designed so that it retains solid additive particulates within the fiber network and independently of any treatment performed on the fibers themselves.
  • the size of these particulates can be nano-, micro- or meso-scale. Particulates having a size on the order of tens of microns are known as mesoparticles.
  • the retention of a particulate "additives reservoir" in the fiber network can be provided.
  • Nano-, micro- and meso-scale particles having anti-wear properties for example, by admixing non-dissolved zinc dialkyldithiophosphate, ZDDP), anti-friction or friction- reducing properties (for example, by admixing one or more of MoS 2 , WS 2 , and/or PTFE), anti-oxidant properties, and/or anti-corrosion properties can be added as ingredients in the "structure forming" (i.e. fiber network making) process.
  • Anti-corrosion additives and preservatives can also be incorporated into the fiber network.
  • a fiber structure will result that incorporates the required additive/chemistry. That is, the required or desired property or properties is/are present in the lubrication system as long the fibers are contained in the lubrication system, e.g., as a network or as a suspension/dispersion (e.g. a paste).
  • corrosion protection surfaces may be provided by the fiber structure in case an oil type will/can not function and a 'paint' type is not desired.
  • one aspect of the present teachings distinguishes from known polymer- thickened grease technologies in that the structure is rendered substantially independent from the material and hence a grease-like structure can be obtained for a wide range of polymer fiber materials. This avoids or eliminates the operating temperature limit that exists for the above-mentioned known polymer-thickened grease technology.
  • a low to medium melt-temperature polymer with lubricating properties in the fluid state can be mixed with a fiber that is stable at relatively high temperatures.
  • a fiber that is stable at relatively high temperatures At the high temperature, the lower melt- temperature lubricating polymer will start to melt, thereby improving the lubricating properties of the grease.
  • a fiber thickener may be utilized that has good lubricating properties in its own right, such as PTFE, which exhibits high- temperature stability as well.
  • PTFE polysulfonates and other low melting PTFEs.
  • a PTFE or PES-type polymer into the fiber structure, which will provide high temperature stability. Due to the inertness of PTFE, there will be little adhesion of these polymers to the surfaces that need to be lubricated. Such adhesion issues can be overcome by mixing the high-temperature-stable fibers with other polymeric fibers that have higher adhesion properties, such as for example PP. Thus, a mixture, e.g., of PP with PTFE and/or PES (and/or another polymer) can improve the wetting/adhesion properties at high temperatures.
  • a polymer may be used that will melt at a predetermined temperature, at which it begins to act as a lubricant. If a mixture of polymer fibers having a range of melting temperatures is mixed into the structure of the grease, they will sequentially melt as the temperature increases. This would provide the advantageous property that the fibrous polymers, which are incorporated (trapped) into the matrix of the grease, will not easily leak out until they start melting. Fibers made from waxes as well as a mix of low molecular weight polymers combined with high molecular weight oils also provide advantages for high temperature applications. In practice, the molecular weight that can be used remains limited to the limits of the melt blow (or alternative) production process utilized to form the fibers.
  • a low molecular weight component of the polymer may act as a cross-link between strands of high molecular weight material.
  • a 'waxy' polymer i.e., low molecular weight variant to the fiber chemistry
  • the thickener preferably lubricates when it itself enters a tribological contact, for example between a roller body and a raceway, such as exists in a bearing or another mechanical device. It is likely that the thickener will enter the contacts when the grease bleeds and it will be beneficial that the thickener itself has lubricating properties.
  • a low melting polymer can be processed together with a high melting point polymer, whereby the first can contribute to the lubrication properties and the second can maintain the necessary stability of the lubricant, even at high temperatures.
  • the present teachings may be advantageously utilized in a variety of different applications with suitable modifications, including but not limited to use in high speed and/or high temperature applications.
  • the bleeding property of the lubricant or grease can be tuned by adjusting the fiber mix as was described above.
  • the thermal and electric conductivity can be tuned and enhanced based on the nature, density and mix of the fiber network. Thermal conductivity is very advantageous as it helps to reduce the temperature of high speed and high temperatures applications and lowers the risk of reaching temperature limits that are defined by the materials used in the application, such as the lubricating oil(s), the polymer material(s), and the to-be-lubricated surface(s), such as a bearing cage.
  • fibers made from waxes, as well as combinations of low molecular weight polymers combined with high molecular weight oils may be advantageously utilized.
  • Waxes are good natural lubricants when pushed into the contacts.
  • the materials according to this aspect of the present teachings can be designed such that they will start to bleed oil at high speeds due to centrifugal forces.
  • This feature of the present teachings is particularly advantageous in bearing applications, in which one or more cage bars are present, such as in cylindrical roller bearings (CRB), on which a lubricating grease resides. At low speeds, these greases preferably do not bleed oil, and only release oil at high speeds.
  • a preferred grease preferably has a high yield stress and well-balanced or uniform (even) bleeding characteristics.
  • the high yield stress can easily be obtained with the fiber-thickened greases according to the present teachings, because all the fibers themselves exhibit strong solid-like rheological properties. This relates in part to the possibility to fabricate a solid oillike grease as described above.
  • the bleeding rate could be too low if the oil-retaining properties are too strong. In this case, no bleeding would occur, which would result in no effective lubrication. This risk can be mitigated by increasing the bleeding rate by adjusting the oil affinity and mechanical stability of the fiber network.
  • At least some of the above-noted polymers are based on using identical polymers with differing molecular weights. Two different polymers can potentially also be used. Some examples include: o Charged and/or polar fibers, e.g. PAA-PM or PTFE, may be combined with a (possibly low MW) oil dissolved polymer having the opposite charge or polarity. o Amorphous fibers may be combined with a compatible semi-crystalline connecting polymer (e.g., PEI fiber and PEEK).
  • a compatible semi-crystalline connecting polymer e.g., PEI fiber and PEEK
  • crystalline polymers e.g., different polyesters, or other polymers with compatible surface energy, e.g., polyamides having different polarity, e.g., different carbon chain length per repeat unit, ranging up to PE which, when amide terminated, can conceptually be considered as PA infinite.
  • block-copolymers that are compatible with the fibers, e.g., co-polyamides or co-polyesters with polyamide or polyester fibers, respectively.
  • the rheological properties of hot-melt polyamides determine the glass-transition state in the polyamide.
  • the polymers can be chosen such that the glass transition state is any temperature between 60 - 280°C.
  • the flexibility of the material e.g., the tensile strength, modulus, elongation etc., can all be tuned.
  • the H-bonding capacity of polyamide bonds makes them particularly advantageous.
  • amides having functional side groups for cross-linking can be incorporated.
  • the mechanical stability of a complex fluid can be improved if the structure is able to self-assemble after mechanical shearing action into a structure that is similar to its structure before the disruptive action.
  • the basic building blocks of the structure in this case nano- and micro-porous fibers
  • the basic building blocks of the structure should self assemble into the original structure.
  • either the entire fiber or a portion thereof may have a preferential affinity towards each other.
  • This self-attracting affinity may be greater than the affinity of the fiber to the lubricating oil.
  • the fibers will self-assemble and form a percolating network that provides the sponge-like/grease structure.
  • mechanical stability can be increased by introducing areas into the fibers that have a designed affinity towards each other and the lubricating fluid.
  • Heterogeneous fibers can be constructed, in principle, in many different ways. A few representative, non-limiting examples are provided:
  • the fibers can be randomly coated with a more polar material/composition using a chemical or physical deposition method. For example, if a group of fibers is randomly sprayed with polar coating/particles before being cut into smaller fiber lengths, a random collection of fibers can be obtained, many of which are at least partly polar. In this manner, so-called Janus-type fibers (as described above) can be produced, in which one (or a part of one) side or end of the fiber has a different surface chemistry than the other part or end.
  • Heterogeneous fibers can be produced by mixing two polymers in the polymer melt before the fibers are produced (for example, by melt blowing or another technique). Phase separation in the melt or cooling fluid leads to heterogeneous fibers. Examples known in the art of two non-mixing polymers are legion and are not particularly limited in the present teachings. However, a few specific examples will be mentioned, such as, but not limited to a polar polymer like polyethylene oxide (PEO) and a non-polar polymer such as polystyrene (PS) or polypropylene (PP).
  • PEO polyethylene oxide
  • PS polystyrene
  • PP polypropylene
  • the phase-separation and adherence of one phase to the other can be increased by including so-called block co-polymers that are formed by connecting one part of polymer A to another part of polymer B.
  • the properties of the polymer material can be selected to be optimal for the application conditions. Since the fibers will experience shear and compressive forces of varying strength, the fibers should not be too brittle, as breaking of the fibers will cause irreversible destruction of the fiber structure.
  • the fiber material preferably has a relatively low glass transition temperature (Tg), because polymers are more brittle at below their glass transition temperature (Tg) than above it.
  • An additional advantage is that polymers are more elastic and more 'sticky' above their glass temperature. Elasticity is advantageous in certain application of the present teachings, because the fibers and the overall fiber structure will be able to withstand shear forces better than highly rigid fibers that form a more brittle structure.
  • Relatively sticky polymers will provide a stronger bond at the locations where two fibers meet. Another benefit is that the friction forces of two fibers sliding over each other will be higher above the Tg and this also increases the strength of the network of entangled fibers.
  • atactic PP has a Tg of -20°C.
  • PP fibers are preferably used at temperatures above -20°C, most preferably above -10°C. Similar considerations apply to other polymers and their glass transition temperature Tg. In general, for low temperature applications, polymers having lower glass transition temperatures should be selected, whereas polymers having higher glass transition temperatures may be used for relatively high temperature applications.
  • fibers according to the present teachings may be incorporated into a seal, seal-lip or seal-lip dual layer, e.g., of a bearing or shaft seal, in order to reduce friction at the point(s) of contact or along a line of contact.
  • these fibers may be made of a low friction type of material (for example, PTFE, wax or similar materials), which does not migrate or bleed out of the resulting lubricant (after contacting the seal with the base lubricating fluid).
  • the oil-adsorbing property of the fibers according to the present teachings will ensure sufficient retention of oil within the sliding contact point or area, thereby reducing friction and wear.
  • wax -based or wax -like fibers are presently preferred for incorporation into seals in the dual material seal concept mentioned above.
  • a nano- or micro-fibrous network can be integrated into a rubber/elastomeric seal in order to supply oil for lubricating the seal contact.
  • This aspect of the present teachings may be utilized to address the following problem. If a seal is not properly lubricated during its operation, an increase in friction will typically result with a corresponding increase in wear and operating temperature, which in turn decreases the service life of the seal.
  • the fibers or a fibrous network may be simply provided on a smooth surface of the seal (e.g., on the seal lip), e.g., by rubbing the fibers onto the seal surface or by adhering the fibers or a fibrous network onto the seal surface.
  • one or more oil reservoirs such as is shown in Fig. 1, is/are present or provided in the seal surface close to the point(s) or line of contact of the moving parts.
  • Such oil reservoirs are preferably capable of retaining and then releasing oil to the contact point(s) or line, thereby reducing the likelihood of a poorly lubricated seal.
  • friction will be reduced, thereby increasing the seal life and sealing ability while also reducing the risk of leakages.
  • Fibers according the present teachings are preferably disposed (e.g., adhered) in such oil reservoirs in order to improve the oil retention/release properties of the oil reservoirs.
  • oil reservoir(s) is/are located at the 'inside' of the contact.
  • the surface of the metal (steel) that contacts the seal lip may also have recesses adapted to retain oil.
  • the oil reservoir(s) preferably have a largest internal dimension (e.g., an internal diameter) of about 10-200 ⁇ .
  • an oil-swollen seal lip or counter-face may be utilized.
  • reduced friction can be achieved by incorporating or absorbing oil into the seal lip materials.
  • the oil will reside or be located more readily at the contact point(s) (line) of the seal (e.g., elastomer) and metal (e.g., steel shaft), thereby improving the supply of lubricant to the contact point(s) or line in need of lubrication.
  • Reduced friction has many advantages, such as lower energy consumption, lower operating temperatures, and longer seal and lubricant life.
  • Oil swelling can be achieved by appropriately selecting or matching the affinity of the oil (base lubricating fluid) with the elastomeric material forming the seal, e.g., by appropriately adjusting the amount of acrylo-nitrile content in BR rubbers.
  • the oil reservoirs are provided in the seal lip by creating a porous surface area that is capable of absorbing and/or retaining oil without resulting in significant swelling.
  • the advantage of this aspect of the present teachings is that the properties of the porous elastomer material can be tuned (pore size, material stiffness, etc.) to achieve an optimum reservoir function but ideally also good wear resistance. Swollen elastomer materials are well-known to be more susceptible to degradation and wear.
  • one or more lubricant reservoirs are provided or defined on and/or within a surface of the seal (e.g., the seal lip) that contacts a metal surface during operation, e.g., rotation of the seal lip relative to the metal surface (e.g., a shaft).
  • the lubricant reservoir(s) preferably reduce friction, e.g., in a rotating sealing system, in order to achieve the reduced friction advantages mentioned above.
  • Fibers according to the present teachings may be incorporated, adhered, disposed, etc. in the oil reservoir(s) to improve the oil retention properties.
  • the seals may be made from porous rubbers and polymers, e.g., nitrile rubber (NBR) and polyurethane (PU) materials, and can be produced according to any suitable technique known in the art. Other materials can, in principle, be used as well.
  • NBR nitrile rubber
  • PU polyurethane
  • One example is to add salts, such as NaCl or CaC0 3 , to the elastomer mixture prior to molding. After molding the seal, the salts are washed out of the seal lip using an aqueous solution, thereby creating pores in the surface that are capable of absorbing, retaining and/or storing oil during operation of the seal.
  • the oil-swollen porous network may then be produced by adhering an oleophilic nano or micro-porous fiber network according to the present teachings to the seal material, e.g., to the above-mentioned pores.
  • the adhesion is preferably strong enough to provide sufficient wear resistance. This can be achieved by using appropriate adhesion chemistry as is well known in the art.
  • This porous network can also be adhered to a seal counterface (opposing) surface.
  • a thicker 'pad'-like structure comprising fibers according to the present teachings (e.g., a cloth, fabric, pad, mat, etc., as was discussed above) may be adhered to the seal or onto a counterface surface.
  • a heterogeneous mixture of oil-swollen fibrous networks and commonly-used seal materials can be utilized to incorporate pockets of oil-swollen structures into the seal (or counterface) structure.
  • the surface layer (liner) may be porous and may be combined with a standard seal material (such as BR). If the two materials are the same (e.g., both NBR or PU), they can be more readily bonded together during the cross-linking step. This prevents adhesion problems in the bonding layer that might arise when friction forces apply stress to this layer.
  • a standard seal material such as BR
  • FIG. 2 shows a schematic example of a representative dual material seal lip comprising a porous liner layer 1 that is capable of absorbing/releasing oil and a bulk seal material 2 that supports the porous liner layer 1.
  • the bulk seal material 2 is attached to a steel support 3 for further support.
  • the porous liner layer 1 is preferably formed according to the above- mentioned embodiments, i.e. fibers are preferably disposed in oil reservoirs defined in the layer.
  • the fibers may be embedded or incorporated into the material of the porous liner layer 1, e.g., by mixing the fibers with a suitable elastomeric material prior to molding.
  • the fibers may also be adhered to the porous liner layer 1 after the porous liner layer 1 has been formed or the fibers may even by simply deposited onto the surface of the porous liner layer 1, e.g. by rubbing or spraying or otherwise coating.
  • fibers according to the present teachings may be incorporated into a cage of a rolling element bearing.
  • the cage is a source of friction for the rolling elements disposed in the bearing and thus a reduction in friction would be advantageous in such bearing applications.
  • the cage bars or struts (the portions that separate or space the rolling elements) contain a grease reservoir (if the bearing is grease lubricated) that supplies the bearing with oil. Therefore, in this aspect of the present teachings, a grease-like porous fiber network or a structurally more rigid network (with longer interconnected fibers) is preferably located in or on the cage, e.g., in one or more grease reservoirs. Preferably, this porous network is located on a surface of the cage bar(s) adjacent to the rolling element(s) (e.g., roller bodies, such as ball bearings or cylindrical/tapered rollers) so as to be close enough to the rolling elements that need to be lubricated.
  • the rolling element(s) e.g., roller bodies, such as ball bearings or cylindrical/tapered rollers
  • the fibrous network can be physically or chemically attached/adhered to the surface of the cage (e.g., the bars or struts) using adhesion chemistry technology known in the art.
  • fibers according to the present teachings can be rubbed or otherwise deposited onto the surface of the cage or struts prior to assembling the bearing.
  • the cage can be made from metals (sheet metal, steel, brass, for example) or from hard polymers. In case the cage is made of a polymer material, it is also possible to incorporate or embed the fibers into the surface of the cage when manufacturing (e.g., injection molding) the cage.
  • Friction can be reduced by disposing the fibrous network on the side of the cage bar(s) that is (are) in contact with the rolling elements (i.e. against which the cage bar(s) slide(s)).
  • the temperature stability of the fibrous network can be tuned/adapted/adjusted by appropriately selecting the polymeric materials forming the fibers, as was described above.
  • the fabric material (fibrous network) will gently wipe the adjacent rolling element(s) during the operation, thereby redistributing the lubricant layers and causing locally thin layers to be "repaired” and/or replenished. This property will enhance the grease life and bearing life.
  • one or more lubricant (oil) reservoirs may be provided or defined in the bearing cage.
  • a PA fiber mat may be disposed in the lubricant reservoir(s) or cavities and then overmolded.
  • the PA fiber preferably acts like a sponge for retaining and releasing the lubricating fluid or oil.
  • the melting point of the polymer is preferably higher than its crystallisation temperature. In this case, it may be possible to overmold the fiber mat without melting all of the fiber mat. The highest melting points occur in fibers.
  • the molding process parameters may be optimized, e.g., to provide good compatibility with seal materials and/or cages. This property could be used to increase the bearing speed rating by providing a "sticky" thickener on the "splash surface”. Improved lubrication of land- riding cage surfaces also may be provided.
  • An oleophilic CoPA (PA co-polymer) optionally may be added to improve the PA cage surface affinity with oleophilic thickeners, as will be further described below.
  • a fiber structure may be disposed on plane-bearing liners or on washers to improve tribological functionality.
  • a high compression strength matrix can be combined with a low friction surface.
  • Melt-spinnable fibers can have very different chemical properties. For example, their behavior can also be tuned to be very hydrophilic and in this case, the fibers will exhibit a very high affinity to water. Such hygroscopic fibers are capable of advantageously eliminating (absorbing) any free water in the lubrication system as well as any dissolved water. If placed in or on a seal, they can act as an active water removal device for industrial lubricants.
  • One particularly advantageous example of such a system is a sealed bearing wherein the seal is able to adsorb water, which would otherwise be very harmful to the bearing system. Water can result in corrosion and/or hydrolysis of the lubricant, for example, leading to early failures.
  • hydrophilic and/or hygroscopic fibers may be disposed on the surface of a seal in addition or in the alternative to the above-described oleophilic fibers.
  • a melt-spinning process can be used to directly apply fibers according to the present teachings onto the surface of a metallic conductor (e.g., a gear, bearing raceway, axial screws, etc), thereby leading to in situ deposition and a very cost-effective way of using the fibers as an in-service lubricant.
  • the fibers may be sprayed directly onto the bearing/seal or cage surfaces in the production line and then allowed to cool. This manufacturing step could be performed in various ways, e.g., by controlling both the speed of spraying and rotating the target surfaces. This process will result in a fiber coating on the bearing surface that will adsorb oil.
  • the fibers are produced using melt-blowing techniques that directly apply the fibers onto the target object.
  • electro- spinning processes can be utilized for very accurate fiber production and deposition control onto the metallic objects.
  • the fibers may function as a preservative (corrosion-preventing substance) for the bearing.
  • the fibers e.g., applied according the above-described spray-on method
  • the fibers may be used to form, together with an oil, a preservative, i.e. a grease-like layer to prevent corrosion of the metallic bearing or a similar object.
  • This sprayed-on fiber layer can also facilitate beneficial running-in, when appropriate additives are present.
  • conductive seals and cages according to the preceding embodiments.
  • seal or cage polymers are not conductive, another option is to use the super cooling effect so that overmolding is possible.
  • fiber sponge network
  • transport systems conveyor belt, for example
  • oleophilic properties of the fiber material could also be utilized in transport systems (conveyor belt, for example) to improve production processes that suffer in many cases from poor lubrication and thus result in wear contamination of the objects that are being transported. It is also possible to make use of the oleophilic properties of the fiber material to lubricate and hold the oil, which would stop or prevent unwanted excessive oil leakage or contamination onto the products being transported.
  • an oleophilic CoPA (PA co-polymer) may be incorporated in order to improve the PA cage surface affinity with oleophilic thickeners.
  • block copolymers may be used as the thickener fiber material, which will improve structural integrity.
  • Polyamide hydrocarbon technology is particularly advantageous, because it allows one to make more hydrophobic polyamide-based resins that have different compatibility with oil and water than polyamide itself. This technology may be particular advantageous if ester oils or other polar oils are used.
  • amide tackifiers may be used to connect amorphous fibers as additives in PA cages.
  • polymer molecules may be synthesized based on two types of chemical groups, e.g., wherein one is more oleophilic (or non-polar) and the other is more hydrophilic (polar).
  • This can be implemented in a number of ways, such as, e.g., changing the chain length of the hydrocarbon in order to alter the hydrophobic properties of the polymer.
  • fibers are made from these polymers, the oleophilic nature may be tuned in accordance with the length of the hydrocarbon (HC) chains.
  • HC hydrocarbon
  • the rheological properties of hot-melt polyamides may also be used in this aspect of the present teachings.
  • the grease proposed in this aspect of the present teachings is preferably able to: create a large degree of freedom in the hydrophilicitiy/hydrophobicitiy balance in the thickener,
  • the polymers forming the thickener of the grease can be used as "tackifiers".
  • Traditional tackifiers are polymers of high molecular weight, typically in the range from 400,000 to 4,000,000.
  • using polymers molecules as the thickener material and coating the polymers to provide adhesion makes it possible to tune both cohesion and adhesion while controlling bleeding (oil loss).
  • Another aspect of the present teachings concerns embodiments, which enable oil to be pumped or moved within the lubrication system, but wherein the moving parts are lubricated with greases, such as in a gearbox.
  • polymer fiber thickeners and oils may be sprayed inside bearings separately in order to form a self-generating grease inside the bearing.
  • polymer fibers may be processed, e.g., into granules or particles. Oils may then be subsequently sprayed into the bearing separately, e.g., as a fine oil mist. The oil and polymer fiber particles will then (re)combine in situ to form a grease.
  • the fibers may be produced, e.g., by melt-blowing or electro- spinning, and then deposited onto the surface of gears, gearboxes, bearings, etc.
  • the oil is added separately or just before application to the mechanical system.
  • One advantage of this embodiment is that pumping of oil is easier (less energy intensive) than pumping of thick grease, because oil is less viscous. Thus, energy consumption may be reduced without sacrificing lubricating performance.
  • Another advantages of this embodiment is that the distribution of grease inside the bearing, e.g., on the cage, or in the rolling contact, can be fully controlled.
  • Another advantage is the complete freedom and variability of grease formulation depending on re-lubrication needs and operating conditions.
  • bearing may be lubricated with oil to ensure replenishment of the rolling contact, wherein excess oil is adsorbed in the shape and form of grease.
  • polymer fibers for grease thickening may be combined with base oil in a new type of pumping system.
  • base oil is pumped through a pumping line towards the intended point for re-lubrication, where it is combined with a separate addition of fibers according to the present teachings, e.g., polymer fibers.
  • fibers may be sprayed, pumped, or be already present on the contact surface.
  • Polymer fibers may consist of, e.g., solid powder particles.
  • the base oil and polymer thickener fibers may be pumped towards the re- lubrication point without any limitation on pumping, pumping speed or line blockage. Additionally, through direct mixing, there is no effect on grease stability, aging or lubrication performance.
  • the grease can be formulated so that a re-lubrication formulation is possible inline. That is, when grease for re-lubrication is formulated "in-line", its composition and properties may be varied to match varying application (usage) conditions. As a non-limiting example, re-lubrication of main shaft bearings in wind turbines is typically performed under varying conditions, including the ambient conditions (cold weather, summer weather), the running-in phase, storm conditions/vibrating conditions, etc. For cold weather, grease having a lower consistency or viscosity typically is more advantageous than greases having a high consistency or viscosity. During a hot summer, the opposite is true. By varying the grease formulation depending on summer or winter conditions, lubrication may be optimized. Variation of grease formulations may be integrated into the re-lubrication control system. It is possible to mix complex fluids such as greases from a base.
  • a corresponding coating can be provided by the fiber thickened grease in which oleophilic fibers according to the present teachings are utilized.
  • the fibers may be sheared off on the lands between the dimples where the "severity" of the contact is very strong. In the dimples themselves, the contacts stresses are lower and no metal-to-metal contact will occur. This means that such material will not be easily removed from this spot and therefore, such material is an optimal lubricant for these bearing applications.
  • the same idea can also be used for bearing surfaces with a clear lay, such as hard-turned or cross-honed surfaces.
  • the contact intensity will be high on the top of the roughness grooves and, in the case of mixed lubrication, metal -to-metal contact will occur here.
  • the oleophilic grease material will stay in the lower part of the surface topography but will promote replenishment of the top of the grooves by driving a lubricant flow.
  • a nano-fibrous fabric-like material made with fibers according to the present teachings may be used as an anti-fretting solution.
  • the porous and thin layer will retain oil and the added local lubrication will reduce fretting.
  • Electrostatic fiber spinning may be utilized to deposit the fibers on the bearings, e.g., on the outer ring of the bearing, to prevent fretting.
  • the present teachings may be advantageously combined with the above-noted teachings from '319 patent concerning dimples, and thus the contents of the '319 patent, in particular the description of the dimples, are fully incorporated herein by reference.
  • the creation of a dampening surface between metallic components will reduce vibration and noise levels. Wear will be reduced by smoothing the surface (by replenishment) and this will reduce the amount of metallic debris in the contact zone and therefore further reduce wear and noise. Shafts, bearing rings and other components are suitable for this protection mechanism.
  • a type of wick may be disposed so as to make sliding contact between the inner and outer ring, e.g., like a seal made of a fibrous network or fabric.
  • the wick can transport oil from the inner ring to the outer ring or the oil from regions of high oil content to regions of low oil content. This cloth can also be adhered to the seal itself.
  • the thickness of the fibers may be between one monolayer of fibers (or fabric material) to tens of layers up to hundreds of layers. Particularly preferred ranges are between 1-50 layers, more preferably 2-20 layers.
  • the fibers were initially provided in the form of a cloth on a roll, which was subsequently broken by both a homogenizer and the strain applied by a 3 -roll mill.
  • the 3-roll mill is a device that is sometimes used in the art to add additives to grease compositions or to perform other mechanical 'working' and homogenization on the grease.
  • Polypropylene (PP) fibers having an average fiber diameter of about 400 nm were mixed with polyalphaolefin (PAO) having a base oil viscosity of 48 cSt at 40°C.
  • PAO polyalphaolefin
  • the fiber density was 5.6%.
  • the cone penetration was 37.3 mm and the NLGI grade or consistency was 0.
  • Polypropylene (PP) fibers having an average fiber diameter of about 400 nm were mixed with polyalphaolefin (PAO) having a base oil viscosity of 48 cSt at 40°C.
  • PAO polyalphaolefin
  • the fiber density was 5.9%.
  • the cone penetration was 365 mm and the NLGI grade or consistency was 0.
  • Polypropylene (PP) fibers having an average fiber diameter of about 400 nm were mixed with polyalphaolefin (PAO) having a base oil viscosity of 48 cSt at 40°C.
  • PAO polyalphaolefin
  • the fiber density was 6.6%).
  • the cone penetration was 347 mm and the NLGI grade or consistency was 0/1.
  • Polypropylene (PP) fibers having an average fiber diameter of about 400 nm were mixed with polyalphaolefin (PAO) having a base oil viscosity of 48 cSt at 40°C.
  • PAO polyalphaolefin
  • the fiber density was 7.3%).
  • the cone penetration was 324 mm and the NLGI grade or consistency was 1.
  • Polypropylene (PP) fibers having an average fiber diameter of about 400 nm were mixed with polyalphaolefin (PAO) having a base oil viscosity of 48 cSt at 40°C.
  • PAO polyalphaolefin
  • the fiber density was 7.9%).
  • the cone penetration was 313 mm and the NLGI grade or consistency was 1.
  • Example 6 Polypropylene (PP) fibers having an average fiber diameter of about 400 nm were mixed with polyalphaolefin (PAO) having a base oil viscosity of 48 cSt at 40°C. The fiber density was 10%. The cone penetration was 230 mm and the LGI grade or consistency was 3. Fig. 3 graphically shows the change in grease consistency with increasing fiber density.
  • PAO polyalphaolefin
  • a grease comprising an oil and/or lubricating fluid and thickening fibers having a length in the micron range and a diameter or width in the micron or nanometer range, the fibers being oleophilic.
  • a grease according to any preceding embodiment further comprising non-oleophilic fibers having oleophobic and/or hydrophilic and/or hygroscopic properties.
  • the thickening fibers are comprised of a mixture of at least one polar polymer, e.g., polyethylene oxide (PEO), and at least one non-polar polymer, such as polystyrene (PS) or polypropylene (PP).
  • polar polymer e.g., polyethylene oxide (PEO)
  • PS polystyrene
  • PP polypropylene
  • a grease according to any preceding embodiment wherein the fibers form a sponge-like network that absorbs or retains the lubricating fluid or oil. 19. A grease according to embodiment 18, wherein the sponge-like network has the property that it shrinks or contracts as the temperature increases, thereby squeezing out lubricating fluid or oil. 20. A grease according to any preceding embodiment, wherein the grease comprises at least two types of thickening fibers, each having a different melting temperature.
  • a grease according to any preceding embodiment wherein the thickening fibers are formed from a wax and/or further comprising wax.
  • a grease according to any preceding embodiment further comprising a low molecular weight polymer, e.g., a wax, that cross-links thickening fibers having a higher molecular weight.
  • a grease according to embodiment 24, wherein the wax is bees wax or paraffin wax.
  • a fiber according to any preceding embodiment i.e. without the oil or lubricating fluid, preferably constituting between about 0.1 and 100 wt% of a final material, more preferably about 50-100 wt%.
  • an elastomeric material e.g., BR or polyurethane and/or wax fibers disposed in the seal.
  • 33. A bearing surface or seal or bearing cage according to embodiments 29-31, respectively, having a porous surface structure and/or a surface structure that has been chemically treated to cause lubricating fluid or oil to be released from the grease under prescribed operating conditions.
  • 34. A grease, fiber, seal or bearing cage according to any preceding embodiment, wherein the oleophilic thickening fibers have a diameter between about 50 nm and 10 microns, and more preferably between about 100 nm and 1 micron.
  • the oil and/or lubricating fluid comprises one or more of mineral oil, synthetic ester, and plant- based oil and their derivatives, such as oils derived from rapeseed, canola, sunflower, canola and palm.
  • oil and/or lubricating fluid comprises one or more of animal-based oils, their derivatives and synthetic lubricants such as polyglycols (PG), polyalkylene glycol (PAG), white oils, silicone oils, very-high viscosity index oils (VHVI), water, glycerol and waxes.
  • PG polyglycols
  • PAG polyalkylene glycol
  • VHVI very-high viscosity index oils
  • water glycerol and waxes.
  • a grease, fiber, seal or bearing cage according to any preceding embodiment, wherein the fibers comprise one or more of polyamide (PA), nylon 6,6, polyamide-6,6 (PA-6,6), polyamide-4,6 (PA-4,6), polyurethanes (PU), polybenzimidazole (PBI), polycarbonate (PC), polyacrylinitrile (PAN), acrylonitrile rubber (NBR), polyvinylalcohol (PVA), polylactic acid (PLA), polyethylene-co-vinyl-acetate (PEVA), PEVA, polymethacryate (PMMA), tetrahydroperfluorooctylacrylate (TAN), polyethylene oxide (PEO), collagen-PEO, polyaniline (PANI), polystyrene (PS), silk-like polymer with fibronectin functionality, polyninylcarbazole, polyethylene rerephtalate (PET), polyacrylic acid (PAA), polypyrene methanol (PM), polyvinylphenol (P
  • a grease, fiber, seal or bearing cage according to any preceding embodiment, wherein the fiber comprises one or more polymers derived from a natural or biodegradable source, such as, e.g., polysaccharides, such as cellulose, starch, chitin, chitosan, proteins, (poly)peptides and gelatin.
  • a natural or biodegradable source such as, e.g., polysaccharides, such as cellulose, starch, chitin, chitosan, proteins, (poly)peptides and gelatin.

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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L'invention porte sur un lubrifiant comprenant des fibres épaississantes oléophiles dispersées dans une huile et/ou un fluide lubrifiant. Les fibres épaississantes oléophiles ont un diamètre compris entre 50 nm et 10 micromètres et une longueur qui est d'au moins 5 fois le diamètre.
PCT/EP2011/068567 2010-10-25 2011-10-24 Lubrifiant épaissi par des fibres oléophiles WO2012055821A1 (fr)

Priority Applications (3)

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US13/881,451 US20130296206A1 (en) 2010-10-25 2011-10-24 Lubricant thickened with oleophilic fibers
EP11774055.5A EP2633015A1 (fr) 2010-10-25 2011-10-24 Lubrifiant épaissi par des fibres oléophiles
CN201180051577XA CN103180420A (zh) 2010-10-25 2011-10-24 亲油性纤维增稠的润滑剂

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US40641610P 2010-10-25 2010-10-25
US61/406,416 2010-10-25
US41808110P 2010-11-30 2010-11-30
US61/418,081 2010-11-30
US42198510P 2010-12-10 2010-12-10
US61/421,985 2010-12-10
US201061426083P 2010-12-22 2010-12-22
US61/426,083 2010-12-22

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PCT/EP2011/068571 WO2012055823A1 (fr) 2010-10-25 2011-10-24 Appareil destiné à être utilisé dans un système contenant de l'huile et/ou un fluide lubrifiant et son procédé de formation
PCT/EP2011/068577 WO2012055827A1 (fr) 2010-10-25 2011-10-24 Lubrifiant sec contenant des fibres et son procédé d'utilisation
PCT/EP2011/068574 WO2012055825A1 (fr) 2010-10-25 2011-10-24 Système de lubrifiant et son procédé de formation
PCT/EP2011/068567 WO2012055821A1 (fr) 2010-10-25 2011-10-24 Lubrifiant épaissi par des fibres oléophiles
PCT/EP2011/068679 WO2012055882A1 (fr) 2010-10-25 2011-10-25 Composition hydrophile destinée à être utilisée avec un système lubrifiant ainsi qu'un appareil et son procédé d'utilisation

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PCT/EP2011/068577 WO2012055827A1 (fr) 2010-10-25 2011-10-24 Lubrifiant sec contenant des fibres et son procédé d'utilisation
PCT/EP2011/068574 WO2012055825A1 (fr) 2010-10-25 2011-10-24 Système de lubrifiant et son procédé de formation

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US9371498B2 (en) 2016-06-21
US20130296206A1 (en) 2013-11-07
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US20130274159A1 (en) 2013-10-17
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