WO2008117504A1 - カーボン含有改質ポリスチレン系樹脂粒子、発泡性カーボン含有改質ポリスチレン系樹脂粒子、カーボン含有改質ポリスチレン系樹脂発泡粒子、カーボン含有改質ポリスチレン系樹脂発泡成形体およびこれらの製造方法 - Google Patents

カーボン含有改質ポリスチレン系樹脂粒子、発泡性カーボン含有改質ポリスチレン系樹脂粒子、カーボン含有改質ポリスチレン系樹脂発泡粒子、カーボン含有改質ポリスチレン系樹脂発泡成形体およびこれらの製造方法 Download PDF

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Publication number
WO2008117504A1
WO2008117504A1 PCT/JP2007/075171 JP2007075171W WO2008117504A1 WO 2008117504 A1 WO2008117504 A1 WO 2008117504A1 JP 2007075171 W JP2007075171 W JP 2007075171W WO 2008117504 A1 WO2008117504 A1 WO 2008117504A1
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WIPO (PCT)
Prior art keywords
carbon
polystyrene resin
containing modified
modified polystyrene
particle
Prior art date
Application number
PCT/JP2007/075171
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English (en)
French (fr)
Inventor
Shinji Ishida
Masahiko Ozawa
Original Assignee
Sekisui Plastics Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2007082129A external-priority patent/JP5138254B2/ja
Application filed by Sekisui Plastics Co., Ltd. filed Critical Sekisui Plastics Co., Ltd.
Priority to CN200780052367.6A priority Critical patent/CN101636423B/zh
Priority to BRPI0721526-6A priority patent/BRPI0721526A2/pt
Priority to US12/593,135 priority patent/US8841353B2/en
Priority to EP07860393.3A priority patent/EP2133372B1/en
Publication of WO2008117504A1 publication Critical patent/WO2008117504A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C08J9/0071—Nanosized fillers, i.e. having at least one dimension below 100 nanometers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene

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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

　本発明のカーボン含有改質ポリスチレン系樹脂粒子は、カーボン含有ポリプロピレン系樹脂を含有し、前記カーボン含有ポリプロピレン系樹脂１００質量部に対して、ポリスチレン系樹脂を１００質量部以上４００質量部未満含有し、かつ、ＡＴＲ法赤外分光分析により測定された粒子中心部の赤外線吸収スペクトルから得られる６９８ｃｍ－１および１３７６ｃｍ－１における吸光度比（Ｄ６９８／Ｄ１３７６）より算出される粒子中心部のポリスチレン系樹脂比率が、粒子全体のポリスチレン系樹脂比率に対して１．２倍以上である。
PCT/JP2007/075171 2007-03-27 2007-12-27 カーボン含有改質ポリスチレン系樹脂粒子、発泡性カーボン含有改質ポリスチレン系樹脂粒子、カーボン含有改質ポリスチレン系樹脂発泡粒子、カーボン含有改質ポリスチレン系樹脂発泡成形体およびこれらの製造方法 WO2008117504A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN200780052367.6A CN101636423B (zh) 2007-03-27 2007-12-27 含碳改性聚苯乙烯系树脂颗粒、发泡性含碳改性聚苯乙烯系树脂颗粒、含碳改性聚苯乙烯系树脂发泡颗粒、含碳改性聚苯乙烯系树脂发泡成形体以及它们的制造方法
BRPI0721526-6A BRPI0721526A2 (pt) 2007-03-27 2007-12-27 Partícula de resina tipo poliestireno modificada contendo carbono, partícula de resina tipo poliestireno modificada contendo carbono espumável, partícula espumada de resina tipo poliestireno modificada contendo carbono, partícula espumada de resina tipo poliestireno modificada contendo carbono, produto moldado espumado de resina tipo poliestireno modificada contendo carbono, e seus processos de produção
US12/593,135 US8841353B2 (en) 2007-03-27 2007-12-27 Carbon-containing modified polystyrene type resin particle, foamable carbon-containing modified polystyrene type resin particle, carbon-containing modified polystyrene type resin foamed particle, carbon-containing modified polystyrene type resin foamed molded product, and production methods thereof
EP07860393.3A EP2133372B1 (en) 2007-03-27 2007-12-27 Particle of carbon-containing modified polystyrene resin, expandable particle of carbon-containing modified polystyrene resin, expanded particle of carbon-containing modified polystyrene resin, molded foam of carbon-containing modified polystyrene resin, and processes for producing these

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-082128 2007-03-27
JP2007082129A JP5138254B2 (ja) 2007-03-27 2007-03-27 自己消火性カーボン含有改質ポリスチレン系樹脂粒子、発泡性自己消火性カーボン含有改質ポリスチレン系樹脂粒子、自己消火性カーボン含有改質ポリスチレン系樹脂発泡粒子、自己消火性カーボン含有改質ポリスチレン系樹脂発泡成形体およびこれらの製造方法
JP2007-082129 2007-03-27
JP2007082128 2007-03-27

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WO2008117504A1 true WO2008117504A1 (ja) 2008-10-02

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PCT/JP2007/075171 WO2008117504A1 (ja) 2007-03-27 2007-12-27 カーボン含有改質ポリスチレン系樹脂粒子、発泡性カーボン含有改質ポリスチレン系樹脂粒子、カーボン含有改質ポリスチレン系樹脂発泡粒子、カーボン含有改質ポリスチレン系樹脂発泡成形体およびこれらの製造方法

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US (1) US8841353B2 (ja)
EP (1) EP2133372B1 (ja)
KR (1) KR101115807B1 (ja)
BR (1) BRPI0721526A2 (ja)
TW (1) TWI391435B (ja)
WO (1) WO2008117504A1 (ja)

Cited By (7)

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JP2011208066A (ja) * 2010-03-30 2011-10-20 Sekisui Plastics Co Ltd 発泡成形体、車両用内装材、車両用タイヤスペーサおよび車両用ラゲージボックス
JP2012184355A (ja) * 2011-03-07 2012-09-27 Sekisui Plastics Co Ltd 予備発泡粒子および発泡成形体
JP2012214552A (ja) * 2011-03-31 2012-11-08 Sekisui Plastics Co Ltd シード重合用ポリプロピレン系樹脂粒子、その製造方法、複合樹脂粒子、発泡性複合樹脂粒子、予備発泡粒子および発泡成形体
WO2014157647A1 (ja) 2013-03-29 2014-10-02 積水化成品工業株式会社 複合樹脂粒子ならびにその発泡性複合樹脂粒子、予備発泡粒子および発泡成形体
JP2015129315A (ja) * 2011-09-01 2015-07-16 株式会社ジェイエスピー 複合樹脂発泡粒子及びその成形体
JP2017066359A (ja) * 2015-09-29 2017-04-06 積水化成品工業株式会社 スチレン改質ポリオレフィン系樹脂粒子とその製造方法、発泡性粒子、発泡粒子および発泡成形体
WO2017056743A1 (ja) * 2015-09-29 2017-04-06 積水化成品工業株式会社 スチレン改質ポリオレフィン系樹脂粒子とその製造方法、発泡性粒子、発泡粒子および発泡成形体

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CN105637022B (zh) 2013-09-30 2019-03-01 积水化成品工业株式会社 含炭黑复合树脂预发泡颗粒及其制造方法及发泡成形体
EP3437820A4 (en) 2016-03-29 2019-10-16 Kaneka Corporation METHOD FOR MANUFACTURING COMPOSITE MOLDING WITH EXPANSION, MOLDING UNIT WITH EXPANSION IN MOLD, COMPOSITE MOLDING WITH EXPANSION, AND MOLD FOR COMPOSITE MOLDING WITH EXPANSION
EP3437819B1 (en) 2016-03-29 2022-09-21 Kaneka Corporation Foamed composite molding and method for manufacturing foamed composite molding
JP2017179140A (ja) 2016-03-30 2017-10-05 積水化成品工業株式会社 酸化防止剤含有発泡性樹脂粒子とその製造方法、発泡粒子及び発泡成形体
JP7117247B2 (ja) 2016-12-21 2022-08-12 株式会社カネカ 型内発泡成形体ユニット、および型内発泡成形体ユニットの製造方法

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