WO2006054421A1 - 有機エレクトロルミネセンスパネル及びその製造方法、並びに、カラーフィルタ基板及びその製造方法 - Google Patents
有機エレクトロルミネセンスパネル及びその製造方法、並びに、カラーフィルタ基板及びその製造方法 Download PDFInfo
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- WO2006054421A1 WO2006054421A1 PCT/JP2005/019334 JP2005019334W WO2006054421A1 WO 2006054421 A1 WO2006054421 A1 WO 2006054421A1 JP 2005019334 W JP2005019334 W JP 2005019334W WO 2006054421 A1 WO2006054421 A1 WO 2006054421A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/122—Pixel-defining structures or layers, e.g. banks
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/17—Passive-matrix OLED displays
- H10K59/173—Passive-matrix OLED displays comprising banks or shadow masks
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
- H10K71/13—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing
- H10K71/135—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing using ink-jet printing
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/351—Thickness
Definitions
- the present invention relates to an organic electroluminescence panel and a manufacturing method thereof, and a color filter substrate and a manufacturing method thereof. More specifically, the present invention relates to an organic electroluminescence panel suitable for increasing the size and full color of the panel, a manufacturing method thereof, an organic electroluminescence display device, a color filter substrate, a manufacturing method thereof, a liquid crystal display panel, and a liquid crystal display device. It is.
- EL Organic electroluminescence
- LCDs liquid crystal displays
- PDPs plasma display panels
- Such an organic EL display performs image display by driving an organic EL panel having a configuration in which a self-luminous organic EL element is arranged for each pixel.
- An organic EL element has a structure in which an organic layer including a light-emitting layer is sandwiched between a pair of electrodes, at least one of which has translucency. Since the principle of light emission was first discovered in low molecular weight organic (EL) materials, conventionally, organic layers of organic EL elements have been made of low molecular weight organic materials. . The manufacturing process flow of passive matrix (PM) driven organic EL panels using low molecular weight organic materials has been disclosed (for example, see Non-Patent Document 1).
- PM passive matrix
- FIG. 6 is a schematic plan view showing the structure before the formation of the organic layer of the PM drive type organic EL display device currently in practical use
- Fig. 7 shows a line segment of the organic EL display device shown in Fig. 6.
- FIG. 6 is a schematic cross-sectional view taken along d-d '. Note that R'G'B in Fig. 6 represents red, green and blue pixels, respectively.
- FIG. 6 In the organic EL display device shown in FIG. 6, as shown in FIG. 7, two kinds of insulating film forces of an edge cover (insulating layer) 51 and a force sword separator (cathode partition) 52 are formed on the lower electrode (anode) 50.
- a linear insulator is provided to allow fine patterning of the cathode and coating of the organic thin film during vapor deposition.
- a configuration of an organic EL device in which a knife-tone pattern serving as an edge cover and an insulating layer serving as a force sword separator are formed of a single layer. Is also disclosed (for example, see Patent Document 1).
- the active matrix (AM) drive type in which each pixel is driven independently does not cause the above-described problems and is suitable as a pixel driving method in a large panel.
- the upper electrode is formed on the entire surface as a common electrode for all the pixels, and the stacked portion of the upper electrode and the bank is different from the PM drive type in which the upper electrode is formed in a stripe shape. Therefore, there is room for improvement in that the upper electrode is likely to be disconnected at the boundary between the bank and the lower electrode (physical 'electrical separation due to the step).
- Non-patent Document 1 and Patent Document 1 described above V has been studied for (I) and (II)! /, N! /.
- FIG. 8 is a schematic plan view showing a configuration of a conventional active matrix (AM) drive type full color organic EL panel. Note that R'G'B in Fig. 8 represents red, green and blue pixels, respectively.
- AM active matrix
- the bank 62 is formed with a height tl that can prevent the upper electrode (not shown) from being disconnected.
- the height (thickness) of the bank 62 is tl, the ability to store ink in the bank is low.
- the ink applied to the G (green) pixel area is adjacent to R (red) or B (blue).
- Overflowed into the pixel area and there was a high possibility that color mixing defects would occur. This can be avoided, for example, by reducing the amount of ink applied (collected) at one time, but in order to obtain a film thickness necessary for obtaining desired light emission characteristics (light emission efficiency, life).
- liquid crystal displays are required to be enlarged in the same manner as organic EL displays. For this reason, application of a wet process such as an ink jet printing method is also being considered in the formation of a colored layer of a color filter substrate for a liquid crystal display. Therefore, when manufacturing a color filter substrate, it has been required to prevent color mixing between adjacent pixels and disconnection of the upper electrode due to overflow or drawing of the liquid material.
- Non-patent document 1 E'Express (E Express), “OLED display "Manufacturing Process 2003”, Yi 'Express Co., 2003, CD-ROM
- Patent Document 1 Japanese Unexamined Patent Publication No. 2003-100466 (2nd, 12th, 14th pages, Fig. 3)
- the present invention has been made in view of the above-described situation, and is caused by overflow or drawing of a liquid material when an organic film such as a light emitting layer or a colored layer is formed by a coating method such as an ink jet printing method.
- Organic electroluminescence panel in which color mixing between adjacent pixels is suppressed and step breakage of the upper electrode (physical 'electrical separation due to the step) is reduced, its manufacturing method, and organic electroluminescence display device,
- Another object of the present invention is to provide a color filter substrate, a manufacturing method thereof, a liquid crystal display panel, and a liquid crystal display device.
- the present inventor has made various studies on the configuration of an organic electroluminescence panel in which color mixing and stepping of the upper electrode are effectively suppressed.
- two or more bank regions having different film thicknesses, and a planar shape surrounded by the two or more bank regions includes a quadrilateral or a substantially quadrangular organic film region with rounded vertices or sides.
- the present invention is an organic electroluminescence panel in which a lower electrode, a bank, an organic film, and an upper electrode are formed on a substrate, and the organic electroluminescence panel has two or more film thicknesses different from each other.
- An organic electroluminescence panel having a bank region and an organic film region having a substantially quadrilateral shape surrounded by a bank region and two or more bank regions and rounded at a vertex or a side.
- “above” includes the numerical value.
- the planar shape of the organic film region is viewed from the normal direction of the substrate surface. This is the shape when As long as the organic electroluminescence (EL) panel of the present invention has such a component as an essential component, other components are included or not included. It is not particularly limited.
- a bank is a structure (convex portion) that separates a plurality of organic film regions (dot-like organic films), and is composed of two or more bank regions having different film thicknesses.
- a preferable form of the bank is a form in which the film thickness differs between the vertical side and the horizontal side of the organic film region.
- the organic film region is surrounded by two or more bank regions having different film thicknesses. Since the ink droplets after landing tend to be spherical, the film thickness of the bank in the vertical direction with respect to the organic film region Even if the thickness of the bank is small, it is possible to suppress the overflow of the ink and prevent the ink from flowing into the adjacent pixels because the bank in the horizontal direction is thick.
- a bank region having a relatively thin film thickness is used as a first bank region, and another bank region having a film thickness larger than that of the first bank region is used as a second bank region.
- the first bank region is a rectangular region, it is preferable that the first bank region constitutes the short side of the organic film region having a rectangular shape or a substantially rectangular planar shape with rounded apexes or short sides. According to such an embodiment having a relatively thin bank on the short side of the organic film region, the effects of the present invention can be sufficiently achieved.
- the first bank region when the planar shape of the organic film region is a square or a substantially square with a rounded apex, the first bank region may be disposed on one of a pair of sides.
- the first bank area is preferably arranged on a rounded side.
- the organic electroluminescence panel of the present invention is preferably driven by an active matrix (AM) driving method or a static driving method.
- AM active matrix
- the organic EL panel has the force that the upper electrode is configured as an electrode common to all pixels. Even in such a form, the effects of the present invention can be sufficiently achieved.
- a bank region having a relatively thin film thickness is defined as a first bank region, and another bank region having a film thickness larger than the first bank region is defined as a first bank region.
- the first bank area constitutes a side separating the same color in a pixel configuration including a plurality of colors. According to such a form, since the first bank area is located on the side separating the same color, even if the ink flows into the adjacent pixel beyond the first bank area, the color mixture is It will not occur. In such a form, it is preferable that the pixel configuration has a plurality of colors arranged in stripes.
- the thickness of the relatively thin region is tl
- the thickness of the relatively thick region is t2. It is preferable that the relationship of t2> tl X l. 5 is satisfied. Thereby, it is possible to effectively suppress the ink from flowing into the adjacent pixels, and at the same time, it is possible to effectively reduce the disconnection of the upper electrode. In order to make the effects of the present invention more remarkable, it is more preferable to satisfy the relationship of t2> tl X 3.0.
- the values of tl and t2 are appropriately adjusted according to the film thickness of the organic layer, etc.
- the preferable lower limit of the force tl is 0.5 m, and the preferable upper limit is 2.0 / z m. Moreover, the preferable lower limit of t2 is 1.5 m, and the preferable upper limit is 10. O / z m.
- the cross-sectional shape of the relatively thick region is preferably a forward taper shape.
- the bank having a forward taper shape means that the cross-sectional shape of the bank when cut along a plane perpendicular to the substrate is substantially trapezoidal with the lower side being wider (the upper base is shorter than the lower base). means .
- the relatively thick bank (second bank area) and the relatively thin bank (first bank area) both have a forward tapered cross-sectional shape. It is a form to do.
- the bank has a relatively thick region (second bank region) formed discontinuously.
- the film thickness is relatively thick and the area (second bank area)
- the bank with the relatively thin film thickness (first bank area) should be preferentially formed at the intersection between the bank pattern and the bank pattern of the relatively thin film thickness area (first bank area).
- the present invention is also a method for manufacturing an organic electroluminescent panel in which a lower electrode, a bank, an organic film, and an upper electrode are formed on a substrate, wherein the bank forming step includes a photosensitive resin. It is also a method for manufacturing an organic electroluminescence panel in which banks are formed with different film thicknesses by providing a difference in exposure amount for each region when patterning a bank forming material by a photolithography process. According to such a method for producing an organic EL panel of the present invention, banks having different film thicknesses can be formed by a relatively simple method of providing a difference in exposure amount, and coating, exposure, development, Each bank formation process, such as the beta process, can be completed once. Therefore, it is possible to shorten the manufacturing process of the organic EL panel having a configuration in which the bank thickness is different.
- the present invention is also an organic electroluminescence display device comprising the organic electroluminescence panel or the organic electroluminescence panel produced using the method for producing the organic electroluminescence panel.
- the organic EL display device of the present invention it is possible to suppress the occurrence of color mixing at the time of applying a liquid material and the occurrence of step breakage of the upper electrode at the laminated portion of the upper electrode and the bank.
- An electroluminescent display device can be provided.
- the present invention is also a color filter substrate in which a bank, a colored layer, and an upper electrode are formed on the substrate, wherein the color filter substrate includes two or more bank regions having different film thicknesses, and two or more It is also a color filter substrate having a colored layer region surrounded by a bank region and having a quadrilateral shape or a substantially quadrangular shape whose apex or side is rounded.
- the color filter (CF) substrate of the present invention is different from the organic EL panel of the present invention in that it does not have a lower electrode as an essential component, and has a colored layer as a component instead of an organic film.
- the organic EL panel of the present invention in that a colored layer is formed between banks using an inkjet method or the like, and an upper electrode is formed on the colored layer or the upper layer of the bank. Therefore, even with the CF substrate of the present invention, the colored layer region is added to the organic EL panel of the present invention.
- the same structure as that of the organic film region it is possible to prevent the liquid materials from being mixed with each other when the colored layer forming ink is applied, and the upper electrode is disconnected (physical due to the step). Target / electrical separation).
- a bank region having a relatively thin film thickness is used as the first bank region, a film thickness is thicker than the first bank region, and another bank region is used as the second bank region.
- (1) A configuration in which the first bank area constitutes a short side of a colored layer area having a rectangular shape or a substantially rectangular planar shape with rounded vertices or sides, (2) ) A configuration in which the first bank region constitutes the side separating the same color in a pixel configuration including a plurality of colors.
- the pixel configuration is arranged in a plurality of chromaticity stripes.
- the present invention is also a method for manufacturing a color filter substrate in which a bank, a colored layer, and an upper electrode are formed on a substrate, wherein the bank forming step includes photolithography using a bank forming material containing a photosensitive resin. It is also a method for manufacturing a color filter substrate in which banks are formed with different film thicknesses by providing a difference in exposure amount for each region when patterning by a process. According to the CF substrate manufacturing method of the present invention, it is possible to form banks with different film thicknesses by a relatively simple method of providing a difference in exposure amount. It is possible to shorten the manufacturing process of the CF substrate having the structure.
- the present invention is also a liquid crystal display panel including the color filter substrate manufactured using the color filter substrate or the color filter substrate manufacturing method.
- the driving method for the liquid crystal display panel of the present invention an AM driving method or a static driving method is suitable.
- the present invention is also a liquid crystal display device including the liquid crystal display panel. According to the liquid crystal display device of the present invention, the color mixing of the colored layer and the disconnection of the upper electrode are effectively suppressed, so that a good display quality can be realized.
- the invention's effect [0026]
- two or more bank regions having different film thicknesses, and the two or more bank regions are surrounded, and the planar shape is rounded on the quadrilateral or the apex or the side. Since it has a substantially quadrilateral organic film region, when forming an organic film such as a light-emitting layer by a coating method such as ink jet printing, it is possible to prevent the liquid material from overflowing or being pulled in between adjacent pixels.
- the color mixing can be suppressed mainly by using the bank with the thicker film thickness.
- the bank with the thinner film thickness can be used for the upper electrode step break (physical / electrical separation due to the step). By providing, it can reduce.
- two or more bank regions having different film thicknesses and a substantially quadrilateral shape that is surrounded by two or more bank regions and whose planar shape is a quadrangle or whose apexes or sides are rounded.
- the film thickness is mainly about color mixing between adjacent pixels due to overflow or drawing of the liquid material. This can be suppressed by using the bank on the thicker side, and the upper electrode step break (physical 'electrical separation due to the step) can be reduced by providing the bank on the thinner film side. Can do.
- FIG. 1 is a schematic front view showing a configuration of an active matrix (AM) -driven full-color organic electroluminescence (EL) display device according to Embodiment 1 of the present invention.
- AM active matrix
- EL organic electroluminescence
- G′B represents red, “green” and blue pixels, respectively.
- the lower electrode 11 functioning as a pixel electrode is isolated from each other in units of dots (for each pixel) as shown in FIG.
- the upper electrode 13 is configured as an electrode common to all pixels.
- a transparent conductive film such as ITO (indium tin oxide) or IZO (zinc tin oxide) is used as the lower electrode 11.
- aluminum (A1), silver (Ag), platinum (Pt), nickel (Ni), etc. are used to enhance reflectivity.
- an alloy film containing them is used.
- a method for forming these films is not particularly limited, but a sputtering method is common.
- the bank 12 is necessary for patterning ink (coating liquid) containing an organic material in a predetermined shape using an ink jet printing method.
- photosensitive resin such as polyimide resin, acrylic resin, novolac resin is generally used.
- photosensitive resin By using photosensitive resin as the bank material, pattern formation is possible through a series of processes including application of the resin material, pre-beta, exposure, development, and post-beta, and the manufacturing process can be shortened. It is preferable to give the surface of the bank 12 a property of repelling the coating liquid (liquid repellency) and the inside of the bank 12 (the surface of the lower electrode 11) a property of getting wet with the coating liquid (lyophilic).
- the lyophilic property can be imparted by ultraviolet (UV) -ozone treatment or oxygen plasma treatment, and the liquid repellency property can be imparted by plasma treatment using a fluorine-based gas such as carbon tetrafluoride.
- the bank 12 acts as a first bank 12a and a second bank 12b having different film thicknesses.
- FIG. 2 is a schematic cross-sectional view of the bank 12 shown in FIG. 1 taken along line aa ′.
- the electrical connection between the adjacent pixels of the upper electrode is ensured in the region where the first bank 12a is formed.
- the first bank 12a having a relatively small film thickness is provided on the short side portion of the pixel when the pixel shape is a rectangle or a substantially rectangular shape with a rounded apex or short side. This is because ink droplets have the property of becoming spherical, and it is considered that ink droplets do not overflow even if the film thickness is thinner in the short side direction than in the long side direction. Power.
- the first banks 12a are provided in the direction in which the same color is arranged.
- the disconnection of the upper electrode can be reduced, and even if the ink leaks to the adjacent pixel, it only appears as a difference in dry film thickness, and no color mixing occurs.
- the first bank 12a and the second bank 12b are both forward tapered in cross-sectional shape. This makes it easier for the droplets on the bank 12 to slide down during application of the droplets, so that patterning can be performed reliably.
- the method of patterning the first bank 12a (application to post-beta) and then patterning the second bank 12b by the same process is of course applicable.
- the portion of the first bank 12a is exposed with an exposure amount smaller than the exposure amount of the opening (ie, the transmissive portion) of the bank 12, so that tl A method of patterning while leaving the film thickness as much as possible can be suitably used.
- the processes required for bank formation such as the coating process, exposure process, development process, and beta process can be completed once, thereby shortening the manufacturing process.
- This manufacturing process can be applied when a positive photosensitive resin is used as the bank material.
- the organic layer (organic film) 20 has a laminated structure including at least a hole transport layer 17 and a light emitting layer 18, as shown in FIGS. 3 (d) and 4. I prefer U ⁇ .
- a high molecular weight organic EL material is used as the organic layer 20, and an ink for forming the hole transport layer 17 [polyethylenedioxythiophene] is formed using an inkjet printing method.
- PPS polyethylene sulfonic acid
- PDF light emitting layer forming ink
- the film was dried to form a laminated film (the thickness of each layer was about lOOnm).
- the hole transport layer 17 may be made of a material such as poly-phosphorus, and the light-emitting layer 18 may be made of a material such as poly-p-phenylene vinylene, polyspirofolene len-based, or polycarbcarbazole.
- the upper electrode 13 in the case of the bottom emission type, aluminum (A1), silver (Ag) In the case of a reflective film such as a top emission type, a transparent conductive film such as ⁇ or ⁇ is used. In the present invention, as long as at least one of the lower electrode 11 and the upper electrode 13 has a light-transmitting property, it is possible to take out light emission even with a translucent electrode side force.
- a method for forming the upper electrode 13 is not particularly limited, but a vapor deposition method or a sputtering method capable of suppressing film formation damage is generally used.
- a metal having a low work function (an alkali metal such as lithium (Li) or the like) is interposed between the upper transmissive electrode 13 and the light emitting layer 18 in order to improve the electron injection efficiency. It is preferable to insert a film (not shown) of an alkaline earth metal such as calcium (Ca) or a fluoride or oxide thereof.
- Figures 3 (a) to 3 (d) show the production flow of the organic EL display device shown in Figure 1 before the formation of the upper electrode by vapor deposition of the ink for forming the organic layer b— It is a schematic diagram explaining using the state of the structural change of the cut surface in b '.
- Fig. 3 (a) shows the state before applying the ink
- (b) shows the state when the ink 16 for forming the hole transport layer is landed
- (c) shows the hole when the ink 16 is dried.
- the state when the transport layer 17 is formed shows that after forming the light emitting layer 18 on the hole transport layer 17 by the ink jet printing method to complete the organic layer 20, the upper electrode 13 is formed by vapor deposition.
- Each situation is shown.
- the first bank 12a has a thinner film thickness (lower height) than the second bank 12b, and the ink may be stored while partially riding on the bank 12.
- the planar shape of the opening 14 of the link 12 preferably has an aspect ratio close to 1: 1 (that is, close to a circle or a square).
- a thin film transistor (TFT) is placed in the black area 15 in FIG.
- the width of the first bank 12a can be widened, thereby preventing ink from leaking to adjacent pixels. Further, since the taper angle of the cross section can be reduced, it is easy to ensure the conduction of the upper electrode 13.
- FIGS. 4 (a) to 4 (d) show the production flow of the organic EL display device shown in FIG. 1 and the line segment until the completion of formation of the upper electrode by vapor deposition.
- FIG. 7 is a schematic diagram illustrating the state of structural change of the cut surface at c-c ′.
- 4 (a) shows the state before ink application
- (b) shows the state when the ink 16 for forming the hole transport layer is landed
- (c) shows the state after the ink 16 is dried.
- the state when the hole transport layer 17 is formed, (d) is after the organic layer 20 is completed by forming the light emitting layer 18 on the hole transport layer 17 by the ink jet printing method.
- FIG. 9 shows the state when the upper electrode 13 is formed by vapor deposition.
- the second bank 12b is thicker than the first bank 12a, as shown in FIG. 4 (b), the ink runs on the bank 12 or the ink flows to the adjacent dots. Then, the phenomenon can be suppressed.
- the force that may cause the upper electrode 13 to break off The second bank 12b is discontinuous as shown in Fig. 1. Since the current flows in the direction in which R′G′B is arranged, the resistance value of the upper electrode can be effectively reduced.
- FIG. 5 is a schematic front view showing a configuration of a passive matrix (PM) drive full-color organic electroluminescence (EL) display device according to Embodiment 2 of the present invention.
- PM passive matrix
- EL organic electroluminescence
- the lower electrode 11 is a stripe extending in the column direction (vertical direction in FIG. 5) as shown in FIG.
- the upper electrode (not shown) is formed in a striped pattern extending in the row direction (lateral direction in FIG. 5).
- the pixel region 14 is surrounded by two banks 12 (first bank 12a and second bank 12b) having different forms.
- the lower electrode 11 is patterned in a stripe shape extending in the column direction.
- the first bank 12a is formed in a striped pattern so as to be orthogonal to the lower electrode 11.
- the second bank 12b is patterned at a predetermined interval in a region surrounded by the lower electrode 11 and the first bank 12a.
- the second bank 12b is formed such that its upper surface is higher than the upper surface of the first bank 12a formed on the lower electrode 11. If the film thickness of the first bank 12a is tl and the film thickness of the portion of the second bank 12b that is above the lower electrode 11 is t2, then t2> tl X l.5 It is preferable to set so.
- the formation of the first bank 12a and the formation of the second bank 12b are preferably performed in the same step from the viewpoint of shortening the manufacturing process.
- a width sword force sword separator 19 is formed on the first bank 12a in a pattern that is wider than the first bank 12a. Subsequently, a hole is formed in the pixel region 14 using an inkjet printing method. Organic films such as a transport layer and a light emitting layer are formed in order. At this time, since the long side of the pixel region 14 is constituted by the second bank 12b having a sufficient height, leakage defects such as color mixing can be sufficiently suppressed. Finally, an upper electrode (force sword) is formed in a striped pattern in the row direction in a region sandwiched between force sword separators 19.
- the upper electrode may be disconnected at the boundary region between the second bank 12b and the pixel region 14, but the film thickness between the force sword separator 19 and the second bank 12b is thin.
- the bank region it is possible to ensure sufficient conduction in the lateral direction of the upper electrode (the direction in which R′G′B in FIG. 5 is aligned). Therefore, the organic EL display device of the present embodiment can also provide the effects of the present invention.
- Embodiments 1 and 2 described above are also applied to a color filter substrate used in a liquid crystal display panel or the like by not forming the lower electrode 11 and replacing the organic layer 20 with a colored layer.
- the ink (coating liquid) used for forming the colored layer a photosensitive resin monomer-containing solution in which a pigment is dispersed can be used.
- the color filter substrate is bonded to the thin film transistor array substrate, and the liquid crystal layer is injected between the color filter substrate and the thin film transistor array substrate. Then, a liquid crystal orientation is controlled by applying a voltage between the upper electrode provided on the color filter substrate and the pixel electrode provided on the thin film transistor array substrate.
- FIG. 1 is a schematic front view showing the configuration of an active matrix (AM) driven full-color organic electoluminescence (EL) display device according to Embodiment 1 of the present invention.
- AM active matrix
- EL organic electoluminescence
- FIG. 2 is a schematic cross-sectional view when the bank 12 shown in FIG. 1 is cut along a line aa ′.
- FIG. 6 is a schematic diagram illustrating the structural change of the cut surface in b ′.
- (a) is before ink application
- (B) is the state when the ink 16 for forming the hole transport layer is landed
- (c) is the state when the ink 16 is dried to form the hole transport layer 17
- ( d) shows a state where the upper electrode 13 is formed by vapor deposition after forming the light emitting layer 18 on the hole transport layer 17 by the ink jet printing method to complete the organic layer 20.
- FIG. 4 (a) to (d) are line segments of the manufacturing flow of the organic EL display device shown in Fig. 1 until the formation of the upper electrode by vapor deposition before the ink for forming the organic layer 20 is formed.
- FIG. 5 is a schematic diagram illustrating the structural change of the cut surface at cc.
- (a) shows the state before the ink application
- (b) shows the state when the ink 16 for forming the hole transport layer is landed
- (c) shows the state where the ink 16 is dried and the hole transport layer 17 is dried.
- D shows the state when the upper electrode 13 is formed by vapor deposition after forming the light emitting layer 18 on the hole transport layer 17 by the inkjet printing method to complete the organic layer 20. Each state is shown.
- FIG. 5 is a schematic front view showing a configuration of a noble matrix (PM) -driven full-color organic electroluminescence (EL) display device according to Embodiment 2 of the present invention.
- PM noble matrix
- EL organic electroluminescence
- FIG. 6 is a schematic plan view showing the structure of a passive matrix (PM) driven organic EL display device that is currently in practical use.
- PM passive matrix
- FIG. 7 is a schematic cross-sectional view of the organic EL display device shown in FIG. 6 cut along line dd ′.
- FIG. 8 is a schematic plan view showing the configuration of a conventional active matrix (AM) driven full-color organic EL panel.
- AM active matrix
- TFT Thin film transistor
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Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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US11/577,407 US7923919B2 (en) | 2004-10-28 | 2005-10-20 | Organic electroluminescent panel and production method thereof, and color filter substrate and production method thereof |
JP2006544821A JP4812627B2 (ja) | 2004-10-28 | 2005-10-20 | 有機エレクトロルミネセンスパネル及びその製造方法、並びに、カラーフィルタ基板及びその製造方法 |
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JP2010262940A (ja) | 2010-11-18 |
JPWO2006054421A1 (ja) | 2008-05-29 |
US20080036374A1 (en) | 2008-02-14 |
JP5031074B2 (ja) | 2012-09-19 |
US7923919B2 (en) | 2011-04-12 |
JP4812627B2 (ja) | 2011-11-09 |
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