WO2005089883A1 - マルチピースゴルフボール及びその製造方法 - Google Patents
マルチピースゴルフボール及びその製造方法 Download PDFInfo
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- WO2005089883A1 WO2005089883A1 PCT/JP2005/004500 JP2005004500W WO2005089883A1 WO 2005089883 A1 WO2005089883 A1 WO 2005089883A1 JP 2005004500 W JP2005004500 W JP 2005004500W WO 2005089883 A1 WO2005089883 A1 WO 2005089883A1
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- WIPO (PCT)
- Prior art keywords
- rib
- core
- hardness
- intermediate layer
- main body
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0077—Physical properties
- A63B37/0097—Layers interlocking by means of protrusions or inserts, lattices or the like
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0077—Physical properties
- A63B37/0092—Hardness distribution amongst different ball layers
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B45/00—Apparatus or methods for manufacturing balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0038—Intermediate layers, e.g. inner cover, outer core, mantle
- A63B37/004—Physical properties
- A63B37/0043—Hardness
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/005—Cores
- A63B37/006—Physical properties
- A63B37/0064—Diameter
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0075—Three piece balls, i.e. cover, intermediate layer and core
Definitions
- the present invention relates to a multi-piece gonolev ball having a multilayer structure and a method for producing the same.
- a multi-piece golf ball having a multilayer structure in which the ball is composed of a plurality of layers is one type of golf ball.
- a relatively rigid intermediate layer is coated on a highly rigid core, and the outside of the intermediate layer is covered with a hard cover to improve the rigidity of the core.
- a hard cover is covered with a hard cover to improve the rigidity of the core.
- Patent Document 1 Japanese Patent Publication No. 3-52310
- a multi-piece golf ball according to the present invention is a multi-piece golf ball having a core, an intermediate layer, and a cover, which has been made in order to solve the above problem. And a plurality of ribs formed in the main body.
- the intermediate layer is filled in a recess surrounded by the rib, and the hardness of the intermediate layer is higher than the hardness of the rib. It is characterized by being expensive.
- the hardness of the hardness curve of the intermediate layer is higher, good resilience performance can be obtained, and the flight distance can be increased even when the club head speed is low. Further, the following effects can be obtained.
- the ball when a gonoref ball comes into contact with a golf club, the ball is twisted in the circumferential direction due to friction with the club face surface. Then, the twisted ball applies a force opposite to the back spin to the ball while restoring to the original state by elastic resistance. At this time, as the deformation of the twisted ball increases, the backspin is suppressed and the flight distance can be increased.
- the rib promotes the elastic resistance of the ball to return to the original state, the backspin can be effectively suppressed. More specifically, in the golf ball, since the hardness of the rib is lower than the hardness of the intermediate layer, the rib is deformed more by hitting than the intermediate layer. Since the ribs are configured not as mere protrusions but as walls surrounding the periphery of the intermediate layer, when the ribs are restored, the force on the entire surface of the wall acts greatly from the periphery of the intermediate layer. Thus, a force opposite to the backspin is promoted. As a result, the flight distance can be greatly increased. This effect is particularly apparent when hitting with a club aimed at a flight distance such as a driver.
- the direction of the hit is mainly the tangential direction of the ball, and a circumferential force acts on the ball. Therefore, the circumferential deformation of the intermediate layer is received by the low hardness rib. Therefore, when an iron is used, a soft feeling when hitting can be obtained.
- the golf ball of the present invention can easily produce the core by integrally molding the main body and the rib.
- the hardness of the main body can be the same as the hardness of the rib.
- the hardness of the intermediate layer is higher than the hardness of the ribs as well as the hardness of the main body, the spin amount can be suppressed, and the flight distance can be improved.
- the force acting on the ball more effectively acts on the ribs and the main body than the intermediate layer, so that the soft feeling at the time of hitting can be improved.
- the hardness of the main body portion can be lower than the hardness of the rib.
- the hardness of the main body can be higher than the hardness of the intermediate layer. According to this configuration, the resilience is increased by increasing the hardness of the main body, and the flight distance can be increased.
- the hardness of the main body can be higher than the hardness of the rib and lower than the hardness of the intermediate layer. According to this configuration, the flying distance can be improved by optimizing the spin amount and the rebound performance according to the head speed and the like.
- the height of the rib from the surface of the main body is preferably 2.0-11 mm, more preferably 5.010.5 mm, . This is because if it is larger than 2. Omm, the thickness of the intermediate layer with high hardness will not be too thin and the resilience performance can be kept at an appropriate level. If it is smaller than Omm, the layer thickness of the intermediate layer will be thicker. This is because it is possible to prevent the shot feeling from becoming too hard.
- the shape of the rib can be varied.
- the height of the rib from the surface of the main body is changed to 6.4. 11. Omm is preferred. 8.0-10.5mm is even more preferred.
- the width of the rib is extended so as to increase from the cover side to the core side, and that the recess is formed in a conical shape by the side surface of the rib.
- the width of the base end of the rib is larger than that of the tip end, it is possible to prevent the rib from falling down due to the pressure during molding.
- the ratio of the intermediate layer gradually decreases toward the center of the ball, and accordingly, the ratio of the low hardness and the ratio of the ribs gradually increase. Therefore, the deformation of the ribs is ensured because the ratio of the ribs having low force and hardness, which is less likely to be affected by the impact toward the center of the ball, increases. Therefore, as the rib becomes higher, the force for suppressing the back spin increases, and the flight distance can be further increased.
- the term “cone-shaped” refers to a concave portion force, which is surrounded by the side surface of the S-rib to form a conical-shaped region, and this region is a surface cut by a spherical surface concentric with the core.
- Area force means a shape that becomes smaller from the cover to the core.
- the shape is not particularly limited, and may be polygonal or circular.
- the concave portion may be surrounded by only the rib and formed in a cone shape, or the concave portion may be formed in a cone shape by exposing the main body portion from the back end portion and the side surface of the rib and the main body portion. There is also. However, even when the main body portion is exposed, the exposed portion is formed in a conical shape as a whole with a small amount.
- the diameter of the main body portion is reduced, so that there is an advantage that the core can be easily molded.
- the core diameter is large, for example, when the core is formed of a rubber composition, it is difficult to sufficiently vulcanize to the center, and the hardness of the core varies in the radial direction. Was.
- the diameter of the main body of the core is relatively small as described above, the core can be sufficiently vulcanized to its center.
- a core having a uniform hardness can be molded.
- the ribs can be configured as follows. That is, the force S can be such that each rib has at least one notch communicating with the adjacent recess.
- the formation of the notch in the rib has the following advantages during manufacturing. For example, when a core is formed and then inserted into a molding die together with a material for the intermediate layer and press-molded, in the gonolef ball according to the present invention, the adjacent concave portions communicate with each other at the notch portion. When the press molding is performed, the material for the intermediate layer spreads to each recess through the notch. Therefore, it is possible to simplify the manufacturing equipment and shorten the manufacturing time, since it is not necessary to directly fill each recess with the material for the intermediate layer. Also, when the intermediate layer is formed by injection molding, the intermediate layer can be formed with one or a small number of gates, and the equipment cost can be reduced.
- each of the ribs extends along three great circles drawn on the main body and orthogonal to each other, and the notch is formed in each of the arc sections of the rib separated by the intersection of each great circle.
- a notch having a surface extending along a circular arc section from a point on a normal line of the core passing through an intersection of the great circles, the surface being 90 ° or more with respect to the normal line. It is preferable that they form an angle.
- the four concave portions arranged at the intersections of the great circles communicate with each other, and the material for the intermediate layer is easily distributed.
- this angle forms a draft angle, for example. For example, when molding a core with two molds, an upper mold and a lower mold, the core is easily extracted from the mold.
- the cutout portion may be formed at an intermediate portion in the arc direction of the arc section.
- the notch portion has two surfaces extending from one point on the normal line of the main body portion passing through the center point of the arc direction in each arc section to the intersection side, respectively. It is preferable that the angular force with the line is 48 degrees. In this case, the angle between each of the surfaces and the normal line becomes a draft, and the core is easily extracted from the mold.
- the core can be easily extracted from the molding die even if the two-sided molding die is used. In other words, simply forming the protruding portion makes the protruding portion caught and cannot be removed from the molding die, making production impossible.
- the protruding portion is formed on the main body. Despite the formation of the core, it is easy to extract the core. As a result, it is possible to improve productivity.
- a method for manufacturing a multi-piece golf ball according to the present invention for solving the above problem is a method for manufacturing a multi-piece golf ball including a core, an intermediate layer, and a cover.
- Filling a cavity material with a core material molding a core having a plurality of ribs on the surface of a spherical main body, and a second molding die having a spherical cavity corresponding to the outermost diameter of the core.
- the cavity corresponds to the outermost diameter of the core, so that the material of the intermediate layer is filled with the ribs in contact with the wall surface of the cavity. Therefore, the core can be easily centered, and the center of each layer is Can be matched exactly.
- the above manufacturing method shows an example of a case where the main body and the rib are formed into a body, whereby the hardness of the main body can be set to be substantially the same as the hardness of the rib. .
- a gonolev ball having a different hardness between the main body and the rib can be manufactured as follows. That is, another method for manufacturing the multi-piece golf ball according to the present invention for solving the above-described problem is a method for manufacturing a multi-piece golf ball including a core, an intermediate layer, and a cover, wherein a spherical main body is provided.
- a spherical receiving portion corresponding to the surface of the main body portion, and a cavity having a plurality of grooves formed along the wall surface of the receiving portion and having substantially the same depth from the wall surface.
- Preparing a first molding die and after disposing the main body in the receiving portion of the first molding die, filling the cavity with a material having a hardness different from that of the main body, Forming a core having a plurality of ribs on the surface of the first mold, preparing a second mold having a spherical cavity corresponding to the outermost diameter of the first intermediate layer, and forming the first mold.
- the core removed from the second Forming a middle layer having a hardness higher than that of the rib by filling the cavity surrounded by the rib with a material having a hardness different from that of the rib; And forming a cover.
- a core having a spherical main body and a rib formed on the surface thereof is molded.
- the depth of the groove from the base is adjusted to 6.4- 11.
- Omm is set, the thickness of the intermediate layer having high hardness becomes large, so that a gonolev ball having high resilience performance can be manufactured.
- the core is formed of a rubber composition, the diameter of the main body is relatively small, so that the core can be sufficiently vulcanized and the hardness around the center does not decrease, but the hardness varies as a whole.
- a core without any material can be molded.
- the cavity of the first mold is configured so that a plurality of grooves are connected to form at least one closed region, and at least a part of the groove has a shallower part than other parts. Then, the above-mentioned notch portion can be formed in the rib, and the material can be easily spread to each recess portion in the step of forming the intermediate layer.
- FIG. 1 is a cross-sectional view showing a first embodiment of a golf ball according to the present invention.
- FIG. 2 is a perspective view showing a core of the golf ball of FIG. 1.
- FIG. 3 is a partially enlarged cross-sectional view of the golf ball of FIG. 1.
- FIG. 4 is a cross-sectional view showing a state of the golf ball according to FIG. 1 when hit.
- FIG. 5 is a sectional view showing another example of the core of FIG. 1.
- FIG. 6 is a cross-sectional view showing another example of the core of FIG. 1.
- FIG. 7 is a sectional view showing another example of the core of FIG. 1.
- FIG. 8 is a sectional view showing another example of the core of FIG. 1.
- FIG. 9 is a sectional view showing another example of the core of FIG. 1.
- FIG. 10 is a view illustrating an example of a method of manufacturing the golf ball shown in FIG. 1.
- FIG. 11 shows an example of a method for manufacturing the golf ball shown in FIG. 1.
- FIG. 12 is a view showing another example of the method of manufacturing the golf ball shown in FIG. 1.
- Garden 13 is a cross-sectional view showing a second embodiment of the golf ball of the present invention.
- FIG. 14 is a perspective view of a core (a) of the golf ball shown in FIG. 13 and a semi-finished product (b) including a core and an intermediate layer.
- FIG. 15 is a perspective view showing another example of the core of the golf ball shown in FIG. 13.
- FIG. 16 is a sectional view showing another example of the core of the golf ball shown in FIG. 13.
- FIG. 17 is a sectional view showing another example of the core of the golf ball shown in FIG. 13.
- FIG. 18 is a sectional view showing another example of the core of the golf ball shown in FIG. 13.
- Garden 19 is a sectional view of a golf ball according to a third embodiment of the present invention.
- FIG. 20 is a perspective view showing a main body, ribs, and an intermediate layer of the golf ball shown in FIG. 19.
- FIG. 21 is an illustration for explaining the method of manufacturing the golf ball according to the third embodiment of the present invention.
- FIG. 22 is an illustration for explaining the method of manufacturing the golf ball according to the third embodiment of the present invention.
- FIG. 24 is a graph showing test results of examples of the present invention and comparative examples.
- FIG. 25 is a graph showing test results of Examples and Comparative Examples of the present invention.
- FIG. 1 is a cross-sectional view of the golf ball according to the present embodiment.
- the golf ball 1 according to the present embodiment is a so-called three-piece golf ball in which a core 3 is covered with an intermediate layer 5 and a cover 7 .
- the diameter of the golf ball must be at least 42.67mm, as required by regulations (see R & A and USGA). However, considering the aerodynamic characteristics, it is preferable to make the ball diameter as small as possible, and the arrangement can be set to '42 .7 7.47 mm.
- the core 3 is made of a rubber composition and, as shown in FIG. 2, is made up of a spherical main body 9 and three ribs (projections) 11 integrally formed on the surface thereof. .
- Each rib 11 extends along a great circle which is drawn on the surface of the main body 9 and is orthogonal to each other.
- the ribs 11 form eight recesses 13 on the surface of the main body 9.
- the diameter of the main body 9 is preferably set to 15.4 to 37.3 mm, and the height of the rib 11 is preferably set to 2.0 to 11. Omm.
- the hardness of the core 3 is more preferably from 38 to 58 in Shore D hardness, more preferably from 42 to 48, in order to obtain a soft feeling when hit.
- each rib 11 is formed in a trapezoidal cross section so that its width increases toward the main body 9 side.
- the width a of the radially outward upper end of the rib 11 is 1.5-3.
- the width b of the lower end of the rib 11 in the radial direction is preferably 3.0 to 12.0 mm. Force that can be out of this range
- the portion where the rib 11 is in contact with the inner surface of the cover 7 is not too wide, and the rebound performance at the time of impact is moderate. Can be kept.
- the widths a and b of the respective end portions be increased as the height of the rib 11 increases.For example, when the height of the rib 11 is set to 4.6 mm, the lower end portion Width b can be set to 6. Omm.
- the intermediate layer 5 is made of a rubber composition or an elastomer, covers the surface of the core 3, and has a substantially spherical outer shape. As shown in FIG. 1, the intermediate layer 5 has a thickness approximately equal to the height of the rib 11 and is filled in eight recesses 13 surrounded by the rib 11. The tip of 1 is exposed.
- the hardness of the mid layer 5 needs to be higher than the hardness of the core 3 in order to improve the resilience performance.
- the hardness of the mid layer 5 is preferably 48-66 in Shore D hardness, and more preferably 50-56. preferable. At this time, the hardness of the intermediate layer 5 is preferably 2 to 10 higher in Shore D hardness than the hardness of the core 3, and more preferably 4 to 6 higher.
- the cover 7 is made of an elastomer, covers the tip of the rib 11 and the intermediate layer 5, and has a predetermined dimple (not shown) formed on the surface thereof.
- the layer thickness of the cover 7 is preferably 0.8 to 2.6 mm, more preferably 1.6 to 2. Omm. Although it is possible to out of this range, the reason is that if the layer thickness of the cover 7 is smaller than 0.8 mm, the durability of the cover 7 is significantly reduced and molding becomes difficult, while the thickness exceeds 2.6 mm. This is because the hit feeling becomes too hard.
- the hardness is preferably Shore D hardness 5568.
- the layer thickness of the cover 7 is the radial thickness in which no dimple is formed. It is the value measured along the normal from the outermost point to any point in contact with the intermediate layer.
- the 3 can be manufactured from a known rubber composition containing a base rubber, a cross-linking material, a metal salt of an unsaturated carboxylic acid, a filler and the like.
- a base rubber natural rubber, polyisoprene rubber, styrene butadiene rubber, EPDM, etc. can be used. It is particularly preferable to use high cis polybutadiene having at least 40%, preferably 80% or more of cis 1,4 bonds. It is good.
- the cross-linking agent for example, an organic peroxide such as dicumyl peroxide or t-butyl peroxide can be used, but dicumyl peroxide is particularly preferable.
- the compounding amount is 0.3 to 5 parts by weight, preferably 0.52 parts by weight, based on 100 parts by weight of the base rubber.
- the metal salt of the unsaturated carboxylic acid it is preferable to use a metal salt of a monovalent or divalent unsaturated carboxylic acid having 318 carbon atoms such as acrylic acid or methacrylic acid.
- a metal salt of a monovalent or divalent unsaturated carboxylic acid having 318 carbon atoms such as acrylic acid or methacrylic acid.
- the mixing amount is preferably 10 to 40 parts by weight based on 100 parts by weight of the base rubber. If the amount is less than 10 parts by weight, the resilience performance is reduced and the flight distance is shortened. On the other hand, if the amount is more than 40 parts by weight, the material becomes too hard and the soft feeling may be reduced.
- filler those usually blended in the core can be used.
- zinc oxide, barium sulfate, calcium carbonate and the like can be used.
- the amount is preferably 2 to 50 parts by weight based on 100 parts by weight of the base rubber. If necessary, an antioxidant, a peptizer or the like may be added.
- the intermediate layer 5 is made of a rubber composition or a force rubber composition made of an elastomer as described above, it can be made of the same components as the core 3 described above. However, in order to increase the hardness as compared with the core 3, it is preferable to increase the amount of the unsaturated carboxylic acid.
- the intermediate layer 5 is made of an elastomer, for example, styrene-butadiene-styrene block copolymer (SBS), styrene-isoprene-styrene block copolymer (SIS), styrene-ethylene-butylene-styrene block copolymer ( SEBS), Styrene Styrene-based thermoplastic elastomers such as propylene-styrene block copolymer (SEPS); polyethylene-based or polypropylene-based hard segments, and polypropylene-based thermoplastic segments with butadiene rubber, acrylonitrile-butadiene rubber, and ethylene-propylene rubber as soft segments
- SBS styrene-butadiene-styrene block copolymer
- SIS styrene-isoprene-styrene block copolymer
- SEBS styrene-ethylene-but
- Thermoplastic elastomer Polyurethane as hard segment and polyether or polyester as soft segment. Urethane-based thermoplastic elastomers; polyester-based thermoplastics with a polyester segment as the hard segment and a polyether or polyester as the soft segment Sex elastomer one; polyamide as a hard segment and a polyamide-based thermoplastic elastomer one of the polyether or polyether ester as a soft segment; etc. ionomer resins may be used.
- the cover 7 is made of a known elastomer, and the same material as the above-mentioned intermediate layer can be used.
- the intermediate layer 5 is filled in the recess 13 surrounded by the rib 11, the contact surface with the inner wall surface of the cover 7 is smaller than the rib 11.
- the proportion of the middle class 5 is increasing. Therefore, when the ball is hit, most of the hitting force acts on the mid layer 5 having a higher hardness than the rib 11.
- the club head speed is low, high resilience performance can be obtained and the flight distance can be extended.
- the rib 11 promotes the elastic resistance of the ball to return to the original state, the back spin can be effectively suppressed. More specifically, as shown in FIG. 4 (a), in this golf ball, the hardness of the rib 11 is lower than the hardness of the mid layer 5, so that the golf club C hits the rib 11 1 more than the mid layer 5 does. Greatly deforms. The stress that causes backspin B on the ball itself due to this impact works. When the ball separates from the club C, as shown in FIG. 4 (b), since the hardness is low and the deformation of the rib 11 is restored, the force F is applied in a direction to offset the backspin B by the restoration. Acts.
- the spin is reduced and the jump angle is increased, so that the flight distance can be further increased.
- the rib 11 is configured as a wall surrounding the periphery of the intermediate layer 5 instead of a mere protruding portion, the force at the time when the rib 11 is restored is determined by the entire surface of the wall. It acts greatly from around 5, which promotes backspin B and force F in the opposite direction. Therefore, the backspin amount is reduced, and the flight distance can be greatly increased. Such an effect becomes remarkable especially when a club aiming at a flight distance of a driver or the like is used.
- the current state is represented by a solid line, and the state immediately before that is represented by a broken line.
- the above-mentioned rib can be formed into various shapes. From the viewpoint of efficiently forming the intermediate layer at the time of manufacturing, it is preferable to form the following notch in the rib.
- the notch 24 is formed to have a bottom surface 24a extending along a tangent plane H passing through the intersection P of the great circle. That is, the notch 24 is formed by cutting out the rib 11 by the tangent plane H.
- the cutouts 24 By forming the cutouts 24 in this manner, the four recesses 13 arranged around the intersection point P of the great circle communicate with each other, and as described later, the material for the intermediate layer is passed through the cutouts 24.
- Each recess 13 can be easily spread. In this case, as shown in FIG.
- the bottom surface 24a of the cutout portion 24 may be formed along a plane forming an angle. By doing so, the inclination becomes a draft, and for example, when the mold is composed of two dies, an upper mold and a lower mold, the core 3 can be easily taken out of the mold.
- the notch 24 is formed as described above, as shown in FIG. 5, in each of the arc sections S separated by the respective intersections P in the rib 11, the notch 24 is not formed. It is preferable that the length L in the circular arc direction be 10 mm or more.
- the notch 24 may be formed so as to have a bottom surface 24a along a plane H passing through the middle in the height direction of the rib 11 and perpendicular to the normal line n. .
- the notch 24 is formed by setting the distance D from the upper end of the rib 11 to the bottom surface 24a to 1.2 mm or more.
- the length L is preferably set to 10 mm or more as described above.
- the bottom surface 24a of the notch 24 can be formed along a plane forming an angle of 91-93 ° with the normal line n, thereby forming a draft. .
- a notch may be provided in the middle of each arc section S of the rib 11. That is, as shown in FIG. 8 (a), there are two bottom surfaces 25a extending from one point on the normal m of the main body 9 passing through the center point Q in the arc direction of the arc section S to the intersection point P of both ends. Notch 25 can also be formed. In this case, it is preferable that the bottom surface 25a and the normal m form 45-48 degrees in front view. In this way, as described above, the core 3 can be easily extracted from the mold. However, when the angle is larger than 48 degrees, the length L of the rib in the arc direction becomes short, which is not preferable.
- the depth D of the notch 25 is preferably set to 1.2 mm or more. A force outside this range is also possible. By setting the force in the above range, the material for the intermediate layer can be smoothly circulated between the recessed portions 13. Note that the depth D of the notch 25 refers to the distance from the upper end of the virtual rib 11 when there is no notch 25 to the deepest part of the notch 25.
- the notch 25 extends from one point on the normal m of the main body 9 passing through the center point Q of the arc section S in the arc direction to the intersection P side of both ends.
- a side surface 25b along two planes and an arc-shaped bottom surface 25c connecting the two side surfaces 25b along the main body 9 may be formed.
- the angle between the side surface 25b and the normal m is 45-48 ° in plan view in consideration of the draft angle, as in Fig. 8 (a).
- the bottom surface 25c may be formed so as to pass through an intermediate portion of the rib 11 in the height direction.
- the depth D of the notch is 1.2 mm or more.
- two or more cutouts 25 can be provided in the middle of the arc section S as long as the shape allows easy die cutting.
- the arc section S may have both the notch 24 shown in FIG. 5, FIG. 6, or FIG. 7, and the notch 25 shown in FIG. Les ,.
- the force for making the thickness of the intermediate layer 5 and the height of the rib 11 the same is essential.
- the thickness of the intermediate layer 5 may be thicker than the height of the rib 11.
- it is desirable that the height is slightly higher than the height of the rib 11, for example, within 1.5 mm.
- FIG. 10 and 11 are views showing a method for manufacturing a three-piece golf ball having the core shown in FIG.
- a predetermined amount of unvulcanized rubber composition 37 is placed between upper mold 33 and lower mold 35 having hemispherical concave portions 31.
- This rubber composition is obtained by blending the above-described base rubber, a crosslinking agent, a metal salt of an unsaturated carboxylic acid, a filler, and the like, and kneading the mixture with a kneading machine such as a Panbury mixer. Then, the rubber composition is press-molded at 130 to 180 ° C. to form a core 3 shown in FIG.
- the concave portion 31 of the upper die 33 and the lower die 35 has a groove 39 having a trapezoidal cross section for forming the three ribs 11, and the surface thereof is roughly finished by rough polishing. By roughening the surface in this way, fine irregularities can be formed on the surface of the molded core 3, and the adhesion S to the intermediate layer 5 can be improved.
- the intermediate layer 5 is formed by press molding.
- the mold for forming the intermediate layer is composed of an upper mold 43 and a lower mold 45 having a hemispherical concave portion 41.
- the concave portion 41 of the upper die 43 and the lower die 45 has a rough surface similar to the core molding die, and a plurality of concave burrs 49 are formed around each concave portion 41. .
- an unvulcanized rubber composition 61 is introduced into the concave portion 41 of the lower die 45, and the rubber composition 61 is formed on the core 3 formed as described above.
- the core 3 is arranged between the upper mold 43 and the lower mold 45.
- the upper mold 43 and the lower mold 45 are brought into contact with each other, and the rubber composition 61 is completely vulcanized at 140-165 ° C. for 5-25 minutes to perform press molding.
- the intermediate layer 5 is formed.
- the rubber composition 61 arranged in the upper part of the core 3 and the concave part 41 of the lower mold 45 is filled in the concave part 13 while being pressed on the surface of the core 3.
- the intermediate layer 5 can be formed by injection molding using, for example, a mold as shown in FIG. In this case, if there is no notch, the rubber composition cannot be uniformly filled unless a gate is provided for all the recesses 13.
- the core 3 covered with the intermediate layer 5 is removed from the mold. Subsequently, when the cover 7 is coated on the surface of the intermediate layer 5 by press molding or injection molding so as to be provided with a predetermined dimple hole, a three-piece gonolev ball can be obtained.
- the notch 24 is formed in the rib 11, and the recess 13 that is in contact with the P is in communication via the notch 24, so that the rubber composition 61 is pressed from any position on the surface of the core 3. Even all the recesses 13 are filled. Therefore, the intermediate layer 5 can be coated on the core 3 by one-step press molding, and as a result, the production time can be significantly reduced.
- a method of manufacturing a golf ball having an intermediate layer with a notch is described.
- a golf ball without a notch can be manufactured by a substantially similar method.
- the material is arranged and press-molded so that each recess is filled with the material of the intermediate layer.
- a plurality of grooves corresponding to each recess are formed. It is necessary to provide a seat.
- the hardness of the intermediate layer affects the resilience performance which is higher than that of the core
- the performance of the ball may be changed by changing the layer thickness. it can.
- the thickness of the intermediate layer is increased, it can be more suitable for a club aiming at a flight distance such as a driver.
- the thicker the intermediate layer the more the impact force can be prevented from being transmitted to the core having low hardness. This reduces the amount of deformation of the ball and increases the rebound. As a result, the flight distance can be increased.
- medium The hardness of the intermediate layer is higher than that of the core. Therefore, when the height of the rib is increased, the thickness of the intermediate layer having a high hardness is increased, and the hit feeling becomes harder.
- FIG. 13 is a cross-sectional view of the golf ball according to the present embodiment.
- the golf ball according to the second embodiment has a core 3, an intermediate layer 5, and a cover 7 similarly to the gonolev ball of the first embodiment, and has a concave portion surrounded by a rib 132 formed in a cone shape. is there.
- the diameter of the Gonoref ball is the same as in the first embodiment.
- FIG. 14 is a perspective view showing a core (a) and a semi-finished product (b) in which the core is covered with an intermediate layer.
- the core 3 is formed of a rubber composition and has a spherical main body 131 and three ribs 132 formed on the surface thereof.
- the diameter of the main body 131 is preferably set to 15.4 to 31.3 mm.
- Each of the ribs 132 extends along a great circle that is drawn on the surface of the main body 131 and is orthogonal to each other.
- the ribs 132 form eight recesses 133 on the surface of the main body 131.
- the height of the ribs 51 is preferably 5.0 to 11. Omm, more preferably 7.0 to 9. Omm.
- the height of the rib 132 can be outside the above range, but if the height of the rib is set within 11. Omm, the rib can be prevented from falling down during manufacturing.
- each rib 132 is formed in a trapezoidal cross-section so that its width increases toward the main body 131 side.
- the width a of the radially outer upper end of the rib 132 is preferably 1.5-3. Omm, and the radially inner lower end b of the rib 132 is preferably 7 12 mm. .
- Other possible forces The lower limit of each end of the rib 132 is set in this way, as will be described later, when filling the material for the intermediate layer at the time of manufacture, it comes from the pressure at which the mold is tightened. The deformation of the rib 132 due to the filling pressure of the material can be prevented. As a result, the body 131 is accurately held at the center of the mold The ability to do S.
- each concave portion 133 is formed in a triangular pyramid shape surrounded by three ribs 132 and a slightly exposed surface of the main body 131.
- the intermediate layer 5 has a layer thickness substantially equal to the height of the rib 132, and is filled in eight recesses 133 surrounded by the rib 132 to form a substantially spherical outer shape. At this time, the intermediate layer 5 is formed in a triangular pyramid shape by filling each recess 133. As shown in FIG. 14B, the upper end surface of the rib 132 is exposed from the intermediate layer 5. The hardness of the core 3 and the hardness of the intermediate layer 5 are set in the same manner as in the first embodiment.
- the cover 7 covers the upper end surface of the rib 132 and the intermediate layer 5, and has a predetermined dimple (not shown) formed on the surface thereof.
- the layer thickness of the cover 7 is preferably 0.8-2.6 mm, more preferably 1.6-2. Omm. Further, the hardness is preferably in the range of Shore D hardness 56-68, as in the first embodiment.
- the materials constituting the core 3, the intermediate layer 5, and the cover 7 can be the same as those described in the first embodiment.
- the width of the base end of the rib 132 is larger than the width of the distal end. Can be prevented from falling down.
- the hardness of the rib of the golf ball is low, it is advantageous to configure the rib as described above.
- the thickness of the intermediate layer 5 having a high hardness corresponding to the height of the rib 132 is increased, high resilience performance can be obtained, and the flight distance can be increased even when the club head speed is slow. be able to.
- the proportion occupied by the intermediate layer 5 gradually decreases toward the center of the ball, and accordingly, the hardness of the ball decreases.
- the proportion of ribs 132 is gradually increasing. Therefore, the impact of hitting with the force S that reaches the center of the ball is less and less, but the deformation of the rib is ensured because the ratio of the rib increases. Therefore, even if the ribs are higher, a force in the opposite direction to the back spin described above can be reliably applied, and the flight distance can be further increased.
- the length of the rib 132 is longer, the diameter of the main body portion 131 of the core 3 is reduced. As a result, the core 3 can be sufficiently vulcanized to the center of the core 3 and has no variation in hardness.
- the molding force can be S. Further, the manufacturing time can be shortened.
- a notch can be formed in the rib.
- a notch may be formed in a part of the rib 132.
- each rib 132 has a notch 321 near the intersection on the great circle.
- the notch 321 is formed to have a bottom surface 321a extending along a plane H perpendicular to the normal n of the main body 131 passing through the intersection P of the great circle. . That is, the notch 321 is formed by cutting the rib 132 at the plane H.
- the depth D of the notch 321, that is, the length from the upper end of the virtual rib 132 having no notch 321 to the deepest portion of the notch 321 is preferably set to 1.2-2.4 mm.
- the four recesses 133 arranged around the intersection P of the great circle communicate with each other, and the material for the intermediate layer is passed through the cutouts 321 through the respective recesses 321.
- 133 can be easily distributed.
- the plane H is inclined from the plane H to the center of the rib 11 by 13 degrees, that is, a plane that forms an angle of 91-93 ° with the normal n of the main body 131 in front view
- the bottom surface 321a of the cutout portion 321 may be formed along.
- the inclination becomes a draft, and, for example, when the mold is composed of two dies, an upper mold and a lower mold, the core 3 can be easily removed from the mold.
- a notch may be provided in the middle of each arc section S divided by each intersection P in the rib 132. That is, as shown in FIG. 18, the notch is formed so as to have two bottom surfaces 322a extending from one point Q on the normal m of the main body 131 passing through the center point of the arc section S in the arc direction to the intersection P at both ends.
- the part 322 can also be formed. In this case, it is preferable that the bottom 322a and the normal m form 45-48 degrees in front view. By doing so, as described above, the core 3 can be easily extracted from the mold.
- the configuration of the golf ball according to the present embodiment other than the height and the shape of the ribs is substantially the same as that of the golf ball according to the first embodiment. According to 12), it can be manufactured. (Third Embodiment)
- FIG. 19 is a cross-sectional view of a gonolev ball according to the third embodiment of the present invention.
- the golf ball of the present embodiment includes a core 3, a mid layer 5, and a cover 7, similarly to the gonolev balls of the first and second embodiments.
- the golf balls of the first and second embodiments show an example of a configuration in which the main body and the ribs constituting the core 3 have the same hardness, whereas the golf ball of the present embodiment has The hardness of the main body is different from that of the rib.
- the diameter of the Gonoref ball is the same as in the first embodiment.
- FIG. 20 is a perspective view showing (a) a main body 231, (b) a core 3 in which a rib 232 is provided on the main body 231, and (c) a semi-finished product in which the core 3 is further covered with an intermediate layer 5. is there.
- the main body 231 is formed in a spherical shape and is made of a rubber composition.
- the diameter of the main body 231 is preferably set to 15.128.3 mm, and more preferably set to 17.92 to 25.9 mm.
- the main body 231 can be manufactured from a known rubber composition containing a base rubber, a cross-linking material, a metal salt of an unsaturated carboxylic acid, a filler, and the like.
- a base rubber a high-cis polybutadiene having at least 40% or more, preferably 80% or more of the force S, cis 1,4 bond that can use natural rubber, polyisobrene rubber, styrene butadiene rubber, EPDM, etc. It is particularly preferred that
- a crosslinking agent for example, an organic peroxide such as dicumyl peroxide or t-butyl peroxide can be used, but dicumyl peroxide is particularly preferable.
- the compounding amount is 0.3 to 5 parts by weight, preferably 0.52 parts by weight, based on 100 parts by weight of the base rubber.
- the metal salt of the unsaturated carboxylic acid it is preferable to use a metal salt of a monovalent or divalent unsaturated carboxylic acid having 318 carbon atoms such as acrylic acid or methacrylic acid.
- a metal salt of a monovalent or divalent unsaturated carboxylic acid having 318 carbon atoms such as acrylic acid or methacrylic acid.
- the mixing amount is preferably 10 40 parts by weight with respect to 100 parts by weight of the base rubber.
- filler those usually blended in the core can be used, and for example, zinc oxide, barium sulfate, calcium carbonate and the like can be used.
- the compounding amount is 100 wt. It is preferred to use 2-50 parts by weight per part. If necessary, an antioxidant, a peptizer or the like may be added.
- a known elastomer can be used as a material forming the main body 231.
- each rib 232 extends along a great circle drawn on the surface of the main body 231 and orthogonal to each other.
- the ribs 232 form eight recesses 233 on the surface of the main body 231.
- the rib 232 has the same shape and height as the rib 132 in the second embodiment, and is arranged such that the main body 231 is exposed at the deep end of the recess 233.
- the concave portion 233 is formed in a triangular pyramid shape surrounded by the three ribs 232 and the slightly exposed surface of the main body portion 231.
- the rib 232 is made of a rubber composition, and can be made of the same material as that of the main body 231 described above.
- the hardness of the main body 231 and the hardness of the rib 232 are set to be different, for example, by making the compounding amount of the unsaturated carboxylic acid or the organic peroxide different from that of the main body 231. You.
- the hardness of the rib 232 can be made higher than the hardness of the main body 231 by increasing the amount of the unsaturated carboxylic acid and organic peroxide in the rib 232.
- the intermediate layer 5 has substantially the same layer thickness as the height of the rib 232, and is filled in the eight recesses 233 to form a substantially spherical outer shape. I have. At this time, the intermediate layer 5 is formed in a triangular pyramid shape by filling each recess 233. The upper end face of the rib 232 is exposed from the intermediate layer 5. The hardness of the mid layer 5 is set to be higher than the hardness of the rib 232.
- the intermediate layer 5 can be made of a rubber composition or an elastomer having substantially the same components as the rib 232.
- the rubber composition it is preferable to increase the amount of the unsaturated carboxylic acid and the amount of the organic peroxide in order to make the hardness higher than that of the rib 232.
- the intermediate layer 5 is made of an elastomer, the same material as the intermediate layer 5 of the first embodiment can be exemplified.
- the cover 7 covers the upper end surface of the rib 232 and the intermediate layer 5 and A predetermined dimple is omitted on the surface.
- the cover 7 can be the same as the cover 7 of the first embodiment.
- a notch can be formed in the rib 232, as in the second embodiment (see FIG. 15).
- the hardness of the mid layer 5 is higher than the hardness of the ribs 232, so that the golf ball maintains the soft feeling when using the iron as in the first and second embodiments.
- the flight distance can be increased.
- the hardness of the main body 231 By changing the hardness of the main body 231 according to needs, desired characteristics can be obtained. That is, by setting the hardness of the main body portion 231 to be lower than the hardness of the ribs 232, it is easy to suppress excess spin during use of the driver, and the flying angle can be increased to further increase the flight distance. On the other hand, by making the hardness of the main body portion 231 higher than the hardness of the mid layer 5, the repulsion force increases and the flight distance can be extended.
- the spin amount and The resilience performance can be optimized, and the flight distance can be improved.
- the golf ball of the present embodiment can be manufactured, for example, as follows.
- the rubber composition is pressed in a mold at, for example, 130 to 160 ° C for 5 to 25 minutes to form the main body 231.
- the main body 231 may be made of an elastomer as described above.
- the main body 231 can be formed by injection molding instead of press molding.
- the main body 231 thus formed is placed in the first molding die 102 shown in FIG. 21 (a).
- the first mold 102 is composed of an upper mold 102a and a lower mold 102b, each of which has a hemispherical receiving part 121 corresponding to the surface of the main body part 231.
- a cavity 122 for forming the rib 232 is formed on a wall surface of the receiving portion 121.
- the cavity 122 has a plurality of grooves formed along the great circle of the receiving portion 121 and having substantially the same depth. Force Force The groove at each intersection of the three great circles is shallower than the other parts. ing. As a result, the notch is formed in the rib 232. In addition, the surface of the cavity 122 is roughly finished by rough polishing, whereby fine irregularities can be formed on the surface of the formed rib 232, and the adhesion to the intermediate layer 5 can be improved. Can do.
- the main body 231 is arranged in the receiving portion 121 of the first molding die 2, and the unvulcanized rubber composition, which is a material for the intermediate layer, is provided in the cavity 122.
- the object N1 is placed, for example, is fully vulcanized at 140 to 165 ° C. for 5 to 25 minutes and press-formed to form a plurality of ribs 232 on the surface of the main body 231.
- the second mold 104 includes an upper mold 104a and a lower mold 104b, each of which has a spherical cavity 141 corresponding to the outermost diameter of the rib 232. That is, the upper end face of the rib 232 is in contact with the wall surface of the cavity 141. Also, the cavities 141 of the upper mold 104a and the lower mold 104b have a rough surface similar to the first mold 102, and a plurality of concave burrs 142 are formed around each cavity 141. I have.
- the unvulcanized rubber composition N is inserted into the cavity 141 of the lower mold 104b, and the rubber composition N is placed on the core 3 formed as described above. And the core 3 is arranged between the upper mold 104a and the lower mold 104b. Subsequently, as shown in FIG. 22 (b), the upper mold 104a and the lower mold 104b are brought into contact with each other, and the rubber composition N is completely vulcanized at 140-165 ° C. for 5-25 minutes to perform press molding. The intermediate layer 5 is formed.
- the rubber composition N disposed on the upper part 141 of the core 3 and the cavity 141 of the lower mold 104a is filled in the recessed part 233 while being pressed against the surface of the semi-finished product.
- the rubber composition N spreads over all the concave portions 233 and is uniformly filled.
- the intermediate layer 5 can also be formed by injection molding as described above (see FIG. 12).
- the rubber composition N cannot be uniformly filled unless gates are provided for all the recesses 233.However, the notch is provided in the rib 232 as described above.
- the rubber composition is uniformly filled in each recess 233 through the cutout.
- the notch is formed in the rib 232, and the recess 233 in contact with the P is connected through the notch, so that the rubber composition N is pressed by any positional force on the surface of the core 3. Also, All recesses 233 are filled and filled. Therefore, the intermediate layer 5 can be easily coated on the core 3, and the manufacturing time can be greatly reduced.
- a force elastomer in which the intermediate layer 5 is formed using a rubber composition can also be used. In this case, the intermediate layer 5 can be formed by injection molding.
- a semi-finished product composed of the main body 231, the rib 232 and the intermediate layer 5 is taken out of the second mold 104. Subsequently, the surface of the semi-finished product is covered with a cover 17 by press molding or injection molding so as to be provided with predetermined dimples, whereby the golf ball of the present embodiment is completed.
- a golf ball having the intermediate layer 5 in which the notch portion is formed has been described.
- a golf ball having a notch portion can be manufactured in substantially the same manner.
- the material is arranged and press-molded so that each recess is filled with the material of the intermediate layer.
- a plurality of gates corresponding to each recess are formed. Must be provided.
- the material of the main body 231, the material of the rib 232, and the material of the intermediate layer 5 are appropriately changed.
- the hardness can be individually adjusted, so that a golf ball having desired characteristics as described above can be easily manufactured.
- Table 1 shows the compounding amounts of the materials constituting the golf ball of Example 19 and the golf ball of Comparative Example 13 in parts by weight, and Table 2 shows the amount of each golf ball.
- the thickness of the intermediate layer (height of the rib), the presence or absence of the rib, and the hardness of each member (Shore D hardness) are shown.
- Examples 1 and 5 are golf balls having the same shape as the core 3 shown in FIG. 5 in the first embodiment, and the golf ball of Example 5 is more medium than the golf ball of Example 1.
- the thickness of the interlayer is set small.
- Examples 3, 4, and 6 are golf balls having the same shape as the core 3 shown in FIG. 15 in the second embodiment, and the thickness of the intermediate layer was increased in the order of Examples 3, 4, and 6. It is set large.
- Examples 2, 7, 8, and 9 are golf balls of the second embodiment, and have the same shape as the core 3 shown in FIG.
- the core 3 has a lower rib height than the core 3 shown in FIG.
- Comparative Examples 1 to 3 are conventional three-piece Gonoref balls in which no rib is formed in the core.
- the core, the intermediate layer and the cover are formed concentrically in cross section.
- Comparative Examples 13 and 13 correspond to Examples 1, 2, and 4, respectively, in the thickness of the intermediate layer and the hardness of each member.
- a No. 1 wood (1W: Mizuno 300S_II380 manufactured by Mizuno Corporation, Loft Angle 9 °, Length 44.75 inches (113.66 cm), Shaft hardness S) and No. 5 middle iron (51: Mizuno T_ZOID 'MX_15, Loft angle 27 °, Length 37.5 inches (95 25cm) and a ball hardness test S) were used to measure the flight distance (carry).
- the head speed of the No. 1 wood was 45 m / s
- the head speed of the No. 5 iron was 35 mZs.
- Example 5 A comparison between Example 5 and Examples 1 to 4 showed that when the ribs were lowered to some extent, the intermediate hardness was higher. It can be seen that since the thickness of the layer becomes smaller, the resilience performance tends to decrease and the carry (carry) tends to be hard to extend. On the other hand, a comparison between Example 6 and Examples 14 to 14 reveals that when the ribs are increased to some extent, the feel at impact tends to be hardened due to an increase in the thickness of the intermediate layer.
- Example 7 the force in which the hardness difference between the core and the intermediate layer is 11 As described above, when the hardness of the intermediate layer is somewhat higher than the hardness of the core, the hardness of the intermediate layer becomes more remarkable. It can be seen that the hit feeling tends to be hard. In particular, when hitting with an iron with a slow head speed, the strength, the hardness, and the strength are evaluated.
- Example 8 the force in which the hardness difference between the core and the intermediate layer is 1 If the hardness difference is small to such an extent, the force in the opposite direction to the above-described back spin, where the rib deformation is small, It can be seen that the flight distance is difficult to increase because it works.
- Example 9 the hardness of the core and the hardness of the intermediate layer were both large values, and the hit feeling was hardened, while the maximum flight distance was obtained in each example.
- Example 10 12 and Comparative Example 4 show the hardness (Shore D hardness) of each member constituting the golf balls of Examples 10-12 and Comparative Example 4.
- the thickness of the main body constituting the core was 23.3 mm, and the thickness of the intermediate layer was 8 mm.
- Table 5 shows the amount of the material corresponding to the hardness shown in Table 4 in parts by weight.
- the cover 7 used was the same as in Example 1 above (Shore D hardness 62).
- Example 10 is a Gonoref ball in which the hardness of the main body 231 is lower than the hardness of the rib 232 in the third embodiment shown in FIG.
- the eleventh embodiment is a gonolev ball in which the hardness of the main body 231 is higher than the hardness of the mid layer 5.
- Example 12 is a golf ball in which the hardness of the main body 231 is higher than the hardness of the rib 232 and lower than the hardness of the mid layer 5.
- Comparative Example 4 is a conventional three-piece golf ball having no rib formed on the core, in which the core, the intermediate layer and the cover are formed concentrically in cross section.
- the first wood (1W: Mizuno MP manufactured by Mizuno Corporation) using a hitting robot (SHOT ROBO V manufactured by Miyamae Co., Ltd.) 001, Loft angle 9.5, Shaft: Tour spirit MP Carbon shaft (length 45 inches (114.3cm), shaft hardness S)) was used to measure the flight distance (carry).
- the head speed of the No. 1 wood was 43.5 m / s, and the average value was obtained five times for each.
- an actual hit feeling (hit feeling) test at 1 W with 10 amateurs was performed. The results are shown in Table 6 below.
- the flying distance can be greatly increased.
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Abstract
Description
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JP2009017951A (ja) * | 2007-07-10 | 2009-01-29 | Mizuno Corp | ゴルフボール |
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- 2005-03-15 WO PCT/JP2005/004500 patent/WO2005089883A1/ja active Application Filing
- 2005-03-15 JP JP2006511187A patent/JP4374500B2/ja not_active Expired - Fee Related
- 2005-03-17 US US11/081,733 patent/US7326129B2/en not_active Expired - Fee Related
- 2005-03-18 TW TW094108381A patent/TW200605935A/zh not_active IP Right Cessation
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JP2007275268A (ja) * | 2006-04-05 | 2007-10-25 | Mizuno Corp | ゴルフボール |
JP2008113838A (ja) * | 2006-11-02 | 2008-05-22 | Mizuno Corp | ゴルフボール及びその製造方法 |
JP2009017951A (ja) * | 2007-07-10 | 2009-01-29 | Mizuno Corp | ゴルフボール |
WO2011024859A1 (ja) | 2009-08-27 | 2011-03-03 | 美津濃株式会社 | ゴルフボール |
JP5538402B2 (ja) * | 2009-08-27 | 2014-07-02 | 美津濃株式会社 | ゴルフボール |
JP2013063261A (ja) * | 2011-09-02 | 2013-04-11 | Mizuno Corp | ゴルフボール |
Also Published As
Publication number | Publication date |
---|---|
JP4374500B2 (ja) | 2009-12-02 |
US20050255944A1 (en) | 2005-11-17 |
TWI344855B (ja) | 2011-07-11 |
US7326129B2 (en) | 2008-02-05 |
JPWO2005089883A1 (ja) | 2008-01-31 |
TW200605935A (en) | 2006-02-16 |
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