WO2005080337A1 - Ester d'oxime, composition photopolymérisable et filtre coloré les utilisant - Google Patents

Ester d'oxime, composition photopolymérisable et filtre coloré les utilisant Download PDF

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Publication number
WO2005080337A1
WO2005080337A1 PCT/JP2005/002818 JP2005002818W WO2005080337A1 WO 2005080337 A1 WO2005080337 A1 WO 2005080337A1 JP 2005002818 W JP2005002818 W JP 2005002818W WO 2005080337 A1 WO2005080337 A1 WO 2005080337A1
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Prior art keywords
carbon
carbon atoms
prime
group
atom
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PCT/JP2005/002818
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English (en)
Japanese (ja)
Inventor
Junji Mizukami
Yasuhiro Kameyama.
Toshiyuki Urano
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Mitsubishi Chemical Corporation
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Priority to CN2005800056044A priority Critical patent/CN1922142B/zh
Publication of WO2005080337A1 publication Critical patent/WO2005080337A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/80—[b, c]- or [b, d]-condensed
    • C07D209/94—[b, c]- or [b, d]-condensed containing carbocyclic rings other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/80—[b, c]- or [b, d]-condensed
    • C07D209/82—Carbazoles; Hydrogenated carbazoles
    • C07D209/86—Carbazoles; Hydrogenated carbazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B55/00—Azomethine dyes
    • C09B55/002—Monoazomethine dyes
    • C09B55/003—Monoazomethine dyes with the -C=N- group attached to an heteroring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B55/00—Azomethine dyes
    • C09B55/005—Disazomethine dyes
    • C09B55/006—Disazomethine dyes containing at least one heteroring
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/201—Filters in the form of arrays
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/031—Organic compounds not covered by group G03F7/029

Definitions

  • the present invention relates to an oxester compound useful as a photopolymerization initiator and a photopolymerizable compound containing the same. It is effective for the iter polymerizable material used in the production of optical filters used for latitudinals, particles, solid particles, glasses, etc.
  • the present invention relates to an it-polymerizable material suitable for producing a Black Max (hereinafter, referred to as a "below”), which is excellent in resolution, and an iter having a high degree of performance.
  • the oxester compound according to the present invention is a polymerization initiator having high sensitivity, it can also be used for photosensitivity, which is not limited to B, such as ospeca () and color.
  • photosensitivity which is not limited to B, such as ospeca () and color.
  • 003 Fitter is usually formed by forming a black check on a transparent surface such as glass, plastic, etc., and sequentially forming three, three or more different hues with a slice-like shake tan. .
  • Turn size is
  • 5700 is a degree. Also, the number of superimpositions / is manufactured by the technique of the degree.
  • Typical methods of 004 bits include color method, printing, pigment, and electricity.
  • a high degree of photopolymerization containing a material formation of an iterative image by repeating image light, development, and necessity by laying on a transparent material, forming an iterative image, and the like. Widely used due to its excellent thermal durability and few defects such as jaws It is.
  • B is generally arranged in a child-like or slice-zyk-like manner between red, green, and blue color tans, and a resistor (T hn F m T T ansso). For this reason, B must be highly sophisticated. Come, is money such as gum
  • the general method was Since the transparent layer is deposited on the transparent layer, and the evening layer is etched through the process, a high degree of film quality can be obtained.
  • the manufacturing process is a method of long productivity, and there are problems such as the occurrence of environmental problems due to the liquid for the etching process.
  • the method of increasing the amount of the coloring material and the amount of the coloring material has the problem of deteriorating the photosensitivity (black discoloration), development, resolution, and adhesion.
  • the accuracy and reliability required for color filters cannot be obtained. In other words, it hinders the practical use of a photosensitive material that can exhibit sensitivity and resolution under sexual conditions.
  • a particular oxetide compound is a compound itself, and has been found to be free from the initiation of photopolymerization and to complete the light.
  • the compound is present in an oxester compound represented by the formula (1) or (2).
  • [, 22] (, R, even if they are each replaced, a prime of 225, a carbon of 20 carbons, a carbon of 32 carbons, a carbon of 8 20 carbons, a carbon of 20 carbons
  • Akiboboaki represents thioaki, an anoalkyl group having 0 or 20 carbon atoms, or an anoaki group having 20 carbon atoms, and R "may form a ring together with R.
  • Each of these may be an acine with a prime number of 0, (CC), CC or a combination thereof (where 0 is 0).
  • R " may be replaced by a prime of 2 2, a carbon of 325, a carbon of 4, or a carbon of 7 20. And a group having 20 carbon atoms and a group having 20 carbon atoms and 772 carbon atoms.
  • R aroma indicates that it contains. :
  • R may form a ring together with R, and each may have a prime 0 alkyne, (C C) (C C), or a combination thereof (where 0 is 3).
  • R indicates that the fragrance includes.
  • R may be replaced by a prime number of 225, a carbon atom of a carbon atom of 320, an anoaki group of a carbon atom of 8 and a carbon atom of 20 or R, R Form a ring with , Even if each has, a prime 0 akin, (CC) (CC) or a combination thereof (where 0 is 3)
  • Prime numbers may be replaced 2 Oxide compound characterized by being an aki group.
  • R is an optionally substituted aryl group having a prime number of 20,
  • the prime number is 20
  • the carbon number is 20
  • the carbon number is 3
  • the carbon number is 2
  • the carbon number is 8, and the carbon number is 20. It exists in an oxester compound characterized by a nokabo group. Further, the present invention resides in an oxide compound represented by the formula (3) or the formula (4).
  • R 4 R 3 030 Prime 2 even if they are transposed 2 5, carbon atoms of 20 carbon atoms, carbon atoms of 320 carbon atoms, carbon atoms of 8 20 carbon atoms, and carbon atoms of 20 carbon atoms are thioalkyl and carbon atoms.
  • R forms a ring and a
  • each of the RRs or Rs has a prime zero alkyne, CC) (CC) or only (Is 0 3).
  • CC CC
  • Is 0 3 only alkyne
  • R even if it is exchanged, each is a prime of 22, a carbon of 325, a quake of carbon, a carbon of 7 20, a carbon of 20, an carbon of 20 This indicates a cabo group with a prime number of 720.
  • R, R, R, and RR are each independently a hydrogen atom, a gene, an aryl having 2 carbon atoms, an alkyl having 2 carbon atoms, and an arc having 58 carbon atoms.
  • G carbon number 620, carbon number 720, carbon number 720, zoi, carbon number 22, aq, carbon number 20, aq.
  • A a carbon akabo akai with a carbon number of 820, a carbon akaboa aka with a carbon number of 32, a carbon akabo with a carbon abo, , , ,
  • R, R, R, R, and R R are R, SR or R R
  • R is a hydrogen atom, even if it is exchanged, it is a prime with two carbon atoms, a carbon with a carbon number, a carbon with 32 carbon atoms, a carbon with 32 carbon atoms, a carbon with 62 carbon atoms, (C 2) (Is 20
  • an aki group having 35 carbon atoms and R is a hydrogen atom, even if each is substituted by an aki having 2 carbon atoms, an aki having 28 carbon atoms, or a 32 carbon atom.
  • a prime number of 35 with a carbon number of 6 20 are each independently a prime atom, may be replaced with a prime of 2, or a carbon of 24.
  • Aki with 20 carbon atoms, a quake with 5.8 carbon atoms, an alkay with 2 220 carbon atoms, a Zonoy with 7200 carbon atoms, and an ash with 22 carbon atoms are the ado with 20 carbon atoms,, and 2 carbon atoms. 25 carbon atoms, 0 carbon atoms, 3 carbon atoms, 2 carbon atoms, 8 carbon atoms, 20 carbon atoms, 20 carbon atoms, and a carbon atom.
  • 0 represents an ano group or an anoaki group having 20 carbon atoms.
  • R may form a ring together with R, in which case R and R are bonded to each other to form a divalent trivalent bond, each of which has a prime 0 Aki, (CC) (CC) or a combination (is 0).
  • R each of which may be replaced by a prime number a, a carbon number
  • R, R, R, and R R have the same meanings as in the above (3).
  • RR or R may be bonded to each other to form a divalent trivalent bond, and each of these may have the prime zero acine, (CC) (CC) Or a combination of them (of 3),
  • R is an optionally substituted alkyl group of 22
  • R, R, R, and RR each independently represent a hydrogen atom, a gene, an alkyl group having a prime number of 2, a carbon atom number of 62, or a carbon atom number of 20. , Or, one of R,, R, RR is
  • R is an optionally substituted aryl group having a prime number of 20,
  • R, R, R, and RR each independently represent a hydrogen atom, a gene, an optionally substituted axium having 2 carbon atoms, an ai R having 620 carbon atoms, or an ai R having 20 carbon atoms; , R,, R, RR is one of
  • Each of them is independently a prime atom, and may be replaced by a prime of two atoms, a core of 24 carbon atoms, and a prime group of 35 carbon atoms of 3
  • RR are bonded to each other and are present in an oxester compound characterized by forming a ring with R.
  • R is a hydrogen atom, a gene, a two-prime space, a twenty-two carbon atom, a six-carbon carbon atom, The 20's are crazy.
  • R may combine with each other to form a structure.
  • R, R, R and RR have the same meanings as in the above (5). 004 7
  • R are the same as defined in the above (4).
  • R, and RR represent a hydrogen atom, a gene, an even-substituted aki, a 22-a, a 6-a, and a carbon
  • the 20's are crazy.
  • RRRRs may be combined with each other to form a structure; R, RR, R " 16
  • each of Aki and Akai having a prime number of 20 include at least one species selected from the group consisting of an Ai group and an Aki group having a prime number of 35. 004 Also, in (5) above,
  • a prime number 2 5 carbon number 3 A carbon of 0, a carbon number of 8 20 A prime of carbon 20 anoaki groups, Or May form a ring.
  • R or R are combined with each other to form a divalent linkage, which is a prime-free acine, CC) (CC), or a combination thereof, each having 0 3),
  • Prime numbers may be replaced ,,, A hydrogen atom, a gene, and even if they are interchanged, a prime of two atoms, a carbon of 22 and a carbon of 62 , Carbon number The 20's are crazy.
  • R, and R R are present in an oxester compound characterized in that they may be bonded to each other to form a structure.
  • R is an optionally substituted aryl group having a prime number of 20,
  • a prime number An aquai group having 20 carbon atoms, an akabokai compound having 32 carbon atoms, and a cabocaine having 8 20 carbon atoms.
  • R, R, and R R are present in an oxester compound characterized by being capable of bonding to each other to form a structure.
  • the present invention resides in an oxester compound represented by the formula (8) or the formula (9).
  • a prime number 2 5 carbon atoms of 20 carbon atoms, carbon atoms of 320 carbon atoms, carbon atoms of 8 20 carbon atoms, and carbon atoms of 20 carbon atoms are thioalkyl and carbon atoms.
  • 20 represents an ano group or an anoaki group having 20 carbon atoms. Also, Even if they may form a ring, they each have a prime of 0, an aki, (CC), CC or a combination thereof (where 0 is 3).
  • R has the same meaning as in parentheses in the claim.
  • [0049] may have a substituent, and represents a condensation.
  • p represents the number 25.
  • X represents an ano group having 0 or 20 carbon atoms or an anoaki group having 20 carbon atoms.
  • R may form a ring or may have each of the prime numbers 0 alkyne, (C C) (C C or a combination thereof (where 0 is 3)).
  • [0052] may have a substituent, Represents.
  • Each may be replaced by a prime number 2 2 5, carbon number 0 carbon, carbon number 8 20 carbon, or carbon number It represents 20 anoaki groups. Also, Form a ring with
  • R is linked to each other to form a divalent trivalent chain, and even if each has R, a space having a prime of 0, (CC) (CC) Or a combination thereof (is 0 3), and is present in an oxide compound characterized by being R, an optionally substituted alkyl group having 22 atoms.
  • R is an optionally substituted aki group having a prime number of 20,
  • oxester compound characterized in that it is an aquai group having 20 carbon atoms, an aquacarbon group having 32 carbon atoms, and an anokabo group having 20 carbon atoms and a prime number of 20 carbon atoms.
  • Another aspect of the present invention resides in a photopolymerizable composition containing (b) a material and (c) a polymerization initiator, wherein (c) is the above-mentioned oxester compound. .
  • the present invention resides in the polymerizability described in the above (a), which is another act of (b), which is an act having a group.
  • Another aspect of the present invention resides in (b) the polymerizability according to any one of the above, which is an acryl obtained by reacting a hydrate of a novolak (a hydrahydrate).
  • the present invention also provides a photopolymerizable compound, and (d) a polymerizable compound according to any one of the above, which further comprises (d) a polymerizable monomer.
  • the present invention resides in the polymerizability according to the above-mentioned (1), which comprises a molecular dispersant.
  • the present invention also includes a polymerizable substance according to any one of the above, which is characterized by containing photo-polymerizable property and (a).
  • Another aspect of the present invention resides in a color filter characterized by having an image formed by polymerization according to any one of the above.
  • Another aspect of the present invention resides in an apparatus having an image formed by polymerization according to any one of the above.
  • the light-active oxester system can be used by initiating a new high-sensitivity photopolymerization.
  • photopolymerization useful for coloration can be constituted.
  • a colorizer using a light source is superior in accuracy, flatness, and durability, and can improve the position of a child.
  • the manufacturing process and the body of the calafita contain no harmful qualities, the danger to the human body is reduced and the integrity is improved. Furthermore, it is not restricted to B,
  • FIG. 1 is a diagram schematically showing how an antenna is changed by heat.
  • W 2 antennae composed of plane and base of image
  • Fees can be used,
  • Pigments are preferred from the viewpoints of,, and.
  • pigments of various colors such as a blue pigment, a green pigment, a red pigment, a yellow pigment, a violet pigment, a pigment, a brown pigment, and a black pigment can be used.
  • color pigments examples include C. Gumingen R3 457, 8, 926 36 45 48 55 554 55. Of these, C. Gumeng 7, 7 and 36 are preferred.
  • the charges are C. Gummen, 2, 5, 3 679 9 202
  • C. Gumenge 387 is preferred.
  • Color pigments include C
  • C. gummio 923 preferred is C. gummio io 23.
  • color a single color or a combination of red, green, and blue can be used. You can choose from these black colors, inorganic and organic materials, and materials.
  • German colors include carbon black, acetyl black, lamp black, Black, black, black, umbrella, titanium black, and the like. Of these, carbon black and titanium bra are particularly preferred from the viewpoint of images and notes. The following brands can be listed as options for the carbon bra.
  • C..nan other mixed pigments are represented by C..nan.
  • the above-described carbon black may be used in combination with other black-colored machines and organic materials. Other faces have lower sex than carbon black, so mixing is restricted.
  • Method of heating and reducing in an atmosphere (349 5432), Method of reducing ultra-fine titanium obtained by decomposition of tetrachloride water containing hydrogen (57 205322), Method of reducing titanium dioxide or titanium hydroxide at a high temperature in an atmosphere (665069), a method in which a sodium substance is attached to titanium dioxide or titanium hydroxide, and a high temperature is reduced with an antenna (96260). It is not something.
  • titanium black examples include Mitsubishi Tear Titanium Black 0S2S and 3R33C.
  • (B) is used if it is explicitly polymerizable.
  • the mixture is not particularly limited, but an agent having a carboxy group is particularly preferred.
  • the weight-average molecular weight measured by GPC is usually 200 20, preferably 300 00000.
  • the above is the above, there are many cases where problems occur in the film. Conversely, if the resin exceeds the above-mentioned range, the acidification of the saturated nocabonic acid is likely to occur and the production may be difficult.
  • Saturated pumps include titanium, cinnamon, cinnamon, and
  • methacrylic acid and are preferably acetic acid and acetic acid, particularly because acetic acid is rich in reactivity.
  • Saturated nocarbon can be reacted at the temperature of, for example, 550 ° C., for example, by using the following method.
  • the use of iron, thiocyanate, methyanide, dimethyate, and trianthane, etc., and tetraammonium ride, tetrathium ride, and tetraammonium ride, etc. Can be.
  • B-saturated non-bottle is prepared by
  • the box of 0.5.2 is preferable to the key, and the box of 0 .. is more preferable. If the amount of 0-saturated nocabone is too small, the amount of unsaturated groups will be insufficient, and the reaction with the basic acid will also be insufficient. Also, it is not advantageous that a large amount of a xy group remains. On the other hand, a high dose of 9-saturated nobon will remain as a response to the step. In the case of misalignment, the tendency tends to be worse.
  • Saturation power is a key to which the step has been added, and further polybasic acids to be added are anhydrous in, anhydrous, anhydrous anhydrous, anhydrous anhydrous, anhydrous anhydrous, dry anhydrous anhydrous, anhydrous anhydrous dry anhydrous
  • Anhydrous methine, anhydrous meth, anhydrous benzoterabone, anhydrous methoxide, anhydrous methine teradone, anhydrous kund, anhydrous methideradita, and anhydrous terracapone Can be Or anhydrous anhydride, anhydrous anhydride, anhydrous anhydride, anhydrous lid, anhydrous terado lid, anhydrous zahido lid, anhydrous pimeth, anhydrous meth, bifter carbo anhydride, and particularly preferred compounds are anhydrous Terradophthalic acid and bifteravon anhydride.
  • the same method can be used, and the, j saturation power bon can be obtained under the same conditions as the reaction of the step.
  • Basic acid It is preferred that the value of the compound is 0.sup.50, and particularly preferred is that of 240.sup.40. Aka with a value lower than the above is poor, and the ability to exceed the above range is inferior.
  • the bi-system includes, for example, (meta) ac, quin, isoquin, in, anhydrous in, anhydrous tan, lan, the saturation power of lan, bon, styrene, methine, hydroxine, methyl ( Meta),)), pi)),), pliers),)),)), 2)), ⁇ , ⁇ ), ⁇ (meta), ⁇ (meta), ⁇ Petaji (meta) ac, di (meta) ac, methanochi (meta) ac, (meta) acin, (meta) ac, (meta) acd, chi (meta) acd, , Meth (meth) aquat, methanothio (meta) aquat, and polymers of compounds such as bi.
  • styrene (meta) ac (meta) ac More preferred is a copolymer consisting of styrene 330, (meth) ac 070, and (meta) ac 060.
  • a copolymer composed of 525,) Ac2060 and (meth) ac555 is preferred.
  • these carbones have an acid value of 30250 g O, preferably 50 200, and more preferably 70%.
  • the above-mentioned carboxy system has a thiosaturation.
  • the proportion of the compound having two or more unsaturated groups, such as, for example, a saturated carboxy group of (meth) ac or a further unsaturated carbonate in the body of the former compound having a saturated group is preferably 90 to 90%. Reactions obtained by co-polymerization to a large extent are mentioned.
  • the average numerator and cab is usually above 000, preferably above 5,000, usually below 30000, preferably below 20000, more preferably below 0000, particularly preferably below 5000. .
  • it is usually above 000, preferably above 5,000, more preferably above 2,000, usually below 00000, preferably below 50000, more preferably below 200,000, particularly preferably below 0,000. 000 below.
  • the fragrance indicates that implies. 0095] 2 CR
  • R fragrance represents, which means.
  • the oxide compound represented by () or the formula (2), and the preferred compound are the compounds represented by (3) or the formula (4).
  • R 4 R 3 (The symbols are the same as those defined in (3) above.)
  • each may be replaced by a prime number 2 2 5, carbon atoms of 3200 carbon atoms, carbon atoms of 820 carbon atoms, prime numbers It represents 20 anoaki groups.
  • R may form a ring together. In that case, RR,
  • R is bonded to each other to form a divalent trivalent bond, which is a prime zero acyne, (CC) (CC) or a combination thereof, each having Is 0 3),
  • R, R, R, and RR each independently represent a hydrogen atom, a gene, an optionally substituted axi, a carbon atom of 620, or a carbon atom , R , R , R R
  • the first one is , Each independently represents a prime atom, a prime atom of 2, a carbon atom of 24, or a prime number of 6 to 20 carbon atoms, each of which may be exchanged; And may form a ring together.
  • Preferred Prime numbers may be replaced 20 aki groups
  • a prime number 20 a carbon number A cocoa group of 20 carbons, an aquaboa of 32 carbon atoms, a caboacay of 8 20 carbon atoms, and an anokabo group of 20 primes,
  • R, R, R, and RR each independently represent a hydrogen atom, a gene, an alkyl group having a prime number of 2, a carbon atom number of 62, or a carbon atom number of 20.
  • R ,,, R, RR indicates the RR,,
  • R R is independently a prime atom, a radical of 2 primes, a radical of 24 carbons, or a prime of 6 20 radicals of 35 carbons, each of which may be transposed.
  • R R are bonded to each other and b
  • R and R may form a ring.
  • the more preferred oxide compound is the following () () Compound.
  • Each may be replaced by a prime number 2 Of carbon atoms having 0 carbon atoms, carbon atoms having 32 carbon atoms, carbon atoms having 8 20 carbon atoms, carbon atoms having 5 carbon atoms, carbon atoms having 5 carbon atoms, and carbon atoms having 22 carbon atoms It is a diakinoaki group having the number 5 or an oxanoaki group having 35 carbon atoms, Is Are bonded to each other to form an alkyne of the prime number 5, (CC) or a combination thereof, even if each has.
  • CC prime number 5
  • 0 04 More preferably, even if they are transposed, they each have a prime of 2 2, a carbon of 3 2, a carbon of 8 20, a carbon of 0 0, and a carbon of 0.
  • the amino group R 28 or R a R or R 28 may be bonded to each other to form an alkenyl group having a prime number of 0, (CC) or a combination thereof.
  • the number is 0 3, or 2 is preferable.
  • Each may be replaced by a prime number 2 Oysters, oysters with 32 carbon atoms, quayies with 38 carbon atoms, zois with 75 carbon atoms, oysters with 5 carbon atoms, and 20 carbon atoms It represents a cabo group with a carbon number of 720 and an anocarbo group with a carbon number of 32 and a prime number of 75.
  • R, R,, and R R each independently represent a hydrogen atom, a gene, an aryl having 2 prime atoms or 22 carbon atoms even if
  • R denotes R R, R ,, R R,,
  • R R may be bonded to each other to form a structure together with R.
  • R may be, even if transposed, a prime of 2 carbons, a carbon of 22 carbons, a carbon of 22 carbons, a carbon of 58 carbons, a carbon of 62 carbons, a carbon of 3 carbons.
  • a carbon is a carbon atom with 35 carbon atoms. Represents an aki group. Where R , R , R , Joined together a
  • a structure may be formed in R.
  • R is a hydrogen atom, even if it is exchanged, it is a prime with 2 carbon atoms, a carbon with 28 carbon atoms, a carbon with 32 carbon atoms, a carbon with 32 carbon atoms, a carbon with 62 carbon atoms, C) (is a number of 20,
  • R is a hydrogen atom
  • the prime number is 2
  • the carbon number is 28
  • the carbon number is Prime number of Represents the group of R, independently of each other, a prime atom, a prime having two carbon atoms, a carbon atom having a carbon atom, and a carbon atom having a carbon atom of 35
  • Each may be replaced by a prime 6 5, 5 carbons, 5 carbons, 8 carbons, 25 carbons, 75 carbons, and 22 carbons.
  • a prime 72, an ad 5 carbon, an ac 25, a carbon 0, an ac 3 0, an aki 5 carbon, A 3 is an amino of the formula 22, an anoaki of 5 carbons and an anoaki of 3 5 a 3
  • R or R may be bonded to each other to form an alkyne having a prime number of 5 (C C or a combination thereof)
  • each of them may have a prime of 65, an aki of 0 carbons, a quaki of 58 carbons, an ark of 22 carbons, and a zoi of 72 carbons.
  • Aki is an amino group having 28 carbon atoms, or when R and R or R are combined to form an aryl having a prime number of 0, (CC) or a combination thereof. is there.
  • the number is 0 3, or 2 is preferred.
  • a prime number A a 5 carbon, a 3 5 carbon, a 85 carbon, a 35 carbon, a 5 carbon, a carbon 20 anokabo groups.
  • R is a hydrogen atom, a gene, a primed two-axis, a two-carbon a, a six-carbon 20 carbon, The 20's are crazy.
  • R, R, R " R may be bonded to each other to form a structure; R, R, R, R " 16
  • each of the primes 20 and Akai includes at least one species selected from an Ay group and an Aki group with a prime number 35.
  • the chemistry of the oxide compound of the formula 2 may be replaced by R “ , R “ , R, R, or RR ".
  • the substitution may be, for example, a fluorine atom, a chlorine atom, an element atom, or an atom. And the like.
  • Genic acid groups such as anionic groups can be mentioned, and in the meaning, meth, thi, puppy, isoppi, thi, isochi, thi, a,,,,,, and A prime of a branch with a prime number of 8, a prime of a branch, a prime, a cup, a pen, a prime, a prime of 3 8 A prime of a branch of a prime, a pepe, a prime of 28, a prime of a branch of 8 and a prime of 3 Aki, Ki, Ki, Isopoki, Ki, s Ki, Ki, Aoki, Oki,
  • a plurality of bonds may be combined to form a ring, the formed ring may be saturated or unsaturated, and may further have each of the cyclic groups. Further, a ring may be formed.
  • R " represents a hydrogen atom, a substituted or unsubstituted, a substituted or unsubstituted, a substituted or unsubstituted or an substituted or unsubstituted aralkyl group, respectively.
  • R or R are combined with each other to form a divalent linkage, which is a prime-free acine, CC) (CC), or a combination thereof, each having 0 3)
  • R R is a compound that may combine with each other to form a structure.
  • R is an optionally substituted aryl group having a prime number of 20,
  • a prime number An aquai group having 20 carbon atoms, an akabokai compound having 32 carbon atoms, and a cabocaine having 8 20 carbon atoms.
  • R, R, and R R may be bonded to each other to form a structure.
  • Prime numbers may be replaced 20 space, 2 carbon atoms , A carbon atom with a carbon number of 320, a carbon atom with a carbon number of 820 20 anoaki groups, and
  • R may form a ring, and the R or R may be bonded to each other to form a divalent valent bond, and each of the R or R may have a prime zero acyne, (CC ) (CC), or a combination thereof (where 0 is 3),
  • R R R R may combine with each other to form a structure, and R R R and R 16
  • Akiaki having a prime number of 20 is a compound containing at least one species selected from the group consisting of an ai group and an aki group having a prime number of 35 even if each of R is replaced.
  • the preferred oxide compound is a compound represented by the following (8) or the formula (9).
  • Prime 2 even if they are transposed 2 5 represents an aboaki group having 320 carbon atoms, an aboaki group having 820 carbon atoms, or an anoaki group having 20 carbon atoms. Also, May form a ring, in which case R Are linked to each other to form a divalent trivalent chain, each of which has a prime number of 0, an acine, CC) (CC or a combination thereof, and (is 0 3 of ),
  • R is an optionally substituted aryl group of 20.
  • the light compound is a part necessary for the light compound to absorb light, and is preferable if the compound has an absorption at 0, preferably at 200,500, and more preferably at 2,500. . Physically, it is composed of zen, funan, pho, acetyl, ide, or a ring thereof, furan, offon, pi, oxo, isozo, thiazo, isoazo, azo, pyrazo.
  • the above oxtide compound can be used alone after clear polymerization, but it can also be used in combination with other photopolymerization, and high sensitivity can be expected by using it in combination.
  • the following compounds can be mentioned.
  • Methyl benzo 3 Methyl benzonone, 4 Methyl benzo 2 benzo 4 benzonone, 2 Cabo benzonone, etc.
  • Xane conductors such as xanane 2 thiozane 2 sopitithioxa 2 kuza, 24 methylthioza 24 thioxane, 2,4 soppithioxane, etc.
  • Benzoic acid steaconductor such as peroxy acid 9 conductors, such as 9 fuses, 9 (P kifu) acridine, etc.
  • 90 conductors such as methizfuzine, etc.
  • a sensitizer may be further added to the above polymerizable substance. It is preferable to add a sensitizer in order to cause photopolymerization in the reaction.
  • sensitizers include compounds having the compounds described in Japanese Patent No. 3239703, Japanese Patent No. 289335, Japanese Patent Application Laid-Open No. 63220, Japanese Patent No. 422958, Japanese Patent No. 4229756. Xanthene described in the report, Phenol described in the 69924 report, 47 2528 report, Japanese Patent 54 55292, Japanese Patent 56 6654, Japanese Patent 59 56403
  • the sensitization having the di group described therein, and the anthony described in 326624 can be mentioned.
  • a compound having one more unsaturated tin group (hereinafter, a tin compound) is used. Physically, it can be obtained from the aliphatic carbon (B) compound unsaturated carbon, the (B) compound and unsaturated carbon, and the unsaturated carbon polyvalent bon aliphatic compound. .
  • Specific examples of the aliphatic boron compound unsaturated carbon include the following: ting diak, tig diak, neopenty diak, xanthodi dia, tipan aku, thiac, peta.
  • Axes such as sujiaku, petasuaku, petasuteraku, pentasteaku, petasupentaaku, pentaxaaku, guseaku, etc.
  • An example of a replacement for a needle and an example of a replacement for a needle include a replacement insta.
  • Examples of the state of the unsaturated carbon of the material include id quinone diac, id quinone dimethac, nziac, nacta, gaac, and the like.
  • Saturation Bones The steps obtained by the reaction of polyvalent boric acid and polyvalent compounds are not necessarily one-step, but typical examples are those of (meth) acrylic acid, tertiary acid and tig. Compounds, (meth) ac, a compound of tonic acid and ching, (meth) ac, a compound of tephthalic acid and sulfur, and a compound of (meth) ac, adip, and dioxen.
  • thi compounds used for this purpose there are also useful compounds such as aquats such as thiacrylates, and steers such as lids such as lids.
  • tin compounds preferred are (meth) aqui, more preferably those having an aqui group. Examples of such a substance include chip ac, titanium ac, pentadiak, pentasac, petasterac, pentastellac, pentaspentaac, pentasquiac, and the like.
  • polymerization initiation is usually 0.50, preferably 45
  • polymerizable monomer is usually 0200, preferably 3800, with respect to (b) 00. is there.
  • (a) excluding the coloring agent it is usually 3070, preferably 3565.
  • (b) 00 is usually 0, preferably 0 for (00).
  • the initiation of polymerization is inferior in terms of the work rate at the above-mentioned degree, and tends to adversely affect the ability to exceed the above range.
  • the polymerizable monomer compound (D) is reduced as described above, problems may occur in durability and thermal properties due to the decrease, and a problem may occur in which development beyond the above range is reduced. Since the color is less likely to be as described above, it is difficult to form a color having a sufficient optical intensity. Conversely, the sensitivity, resolution, and development exceeding the above-mentioned ranges become severe, so that formation becomes difficult.
  • the polymerizability of light is usually (a) color, (b) (
  • agents which can disperse the components constituting the composition and which have a boiling point of 2,000 are preferably selected. More preferred is also the point at 270 C.
  • solvent examples include, but are not limited to:
  • Gua kites such as te, zip pi, pi pi pi, pi pi pi
  • Guziakites such as chinjimetite, chijijite, chijijimete, chijijite, chijijipite, chijijibuti
  • Polyvalents such as Tano, Puno, Butano, Nono, Kuxano, Ching, Pupping, Ching, Zipping, Glycery
  • Geno-hydrocarbons such as acrylonitrile and acrylonitrile, such as 3-kipion and 3-kipionic acid
  • a black powder is dispersed finely, and it is important to stabilize the state. Desirably.
  • 015 Powders are compatible with (a) colorants and (b),
  • an interface such as an ON, a cation, and an ON, and a polymer dispersant can be mentioned.
  • polymer dispersants are preferred, and particularly, polymer dispersants having (e) basicity such as 2, 3 or 3 amino, pyridine, pyridine and pyrazine are advantageously used.
  • Specific examples of the preferred structure as the polymer dispersant having basicity include, for example, a boisoane compound, a compound having two hydroxyl groups in the molecule, and an active element in the same molecule. Dispersion obtained by reacting with a compound having three ano groups is mentioned.
  • isoane compounds described in the above include flavondiisoane, 24diisoane, 2,6diisoane, 4,4 difumeisoane, tan 5isoane, diisoane and the like.
  • Aliphatic isoanes such as diisoane, ginmethisteoisoane, 2,44 methixatin diisoane, and Thai isoane, and fatty isoforms such as 4,4 methine bis (isoanedimethoxane)
  • Aliphatic isoane such as anequindiisoane, teramethinediisoane, etc.
  • Preferable boisoane is a monomer of organic isoane, and most preferred is a monomer of diisoane, which is a monomer of isoane. These may be used alone or in combination.
  • the above boisoanes are suitably used. For example, partial trimming of isoane groups with trianions, phosphines, adducts, metal compounds, and bon salts is performed, and after the trimerization is stopped by addition, unreacted isoane is removed. And a method for obtaining the desired iso-anupo-isoane by removal by the method described above.
  • Compounds having two hydroxyl groups in one molecule include Botte
  • Examples include poteggio, potestio, and mixtures thereof.
  • Examples of the potions include those obtained by homopolymerization of akiki, for example, potting, bopping, potpigging, booki lathing, pookixing, pooki. Octaching and mixtures of two or more of them.
  • testosterio the technology is obtained by reacting a compound of another group with dicarbon or their hydrates, or by reacting the posterior with akiki.
  • a compound of another group with dicarbon or their hydrates, or by reacting the posterior with akiki.
  • (pooxyteratin) adipate and the like can be mentioned.
  • Stegs include zikabo (square, gutta, adipine, n,, a, lid) or their water and gus (chig, ching, chig, ping, zip pig, pu pig). Ping, 2 geo, 2 geo, 3 geo, 4 geo, 23 geo, 3 mesh 5 tagio, neopetting, 2 met 3 geo, 2 met 23 punggio, 2 2 3 E, 5 pentanedio,, 6 xanthia, 2 meth 24 pentandio, 2, 2, 4 meth 3 pentandio, 23 ixandio, 2, 5 meth And fatty acids such as bismethic oxane, fragrances such as kig, bisquinse, etc., and akijia canoa such as methiditanoa).
  • zikabo square, gutta, adipine, n,, a, lid
  • gus chig, ching, chig, ping, zip pig, pu
  • Thing for example, chin dipe, potin dipe, poti dipe, botinopipe dipe, etc., or lacundio or lacnoio, which is obtained by starting the above-mentioned geo-element number 25,
  • Examples include capsules, pometics, and mixtures of two or more thereof.
  • Most preferred is a capracing or a capracun that has begun to have 25 carbon atoms.
  • a po (6 quin) carbon, a po (3 meth 5 pent) carbon, etc. for a poking, a jing, a hydrogen-added bod, a hydrogen-added bop And the like.
  • the average molecular weight of the compound having two hydroxyl groups in one molecule is 300.000, preferably 500.000, more preferably 4,000.
  • a compound having an active element 3 amino group in the same molecule used in the present invention will be described.
  • the hydrogen atom directly bonded to,, an oxygen atom, a nitrogen atom and a sulfur atom include a hydroxyl group and an anothio group, and among them, an ano group, particularly a hydrogen atom of an ano group is preferable. .
  • the ano group is not particularly limited. Examples of the 3 ano include an ano having an aki group having 4 carbon atoms or a structure, more specifically, an azo azo ring.
  • these compounds having a azo group include (3 anoppi) azo, histidine, 2 anazo, and (2 an) azo.
  • Powder powder blending Isoamine 00 has a number average molecular weight of 300,000 having two hydroxyl groups in the same molecule of 200,000, preferably 200, more preferably 30,000, and more preferably 3080, active in the same molecule.
  • the compound having an element and a 3-amino group is 0.225, preferably 0.324.
  • (E) GPC average molecular weight of basic polymer dispersant 000 The range is 200,000, preferably 2,000,000, and more preferably 3,500,000. Below 20,000, the dispersibility and qualitative properties are reduced, and above 200,000, the dissolution and the dispersibility are reduced, and at the same time, the reaction becomes difficult to control. This is performed according to the method described in the preparation of a molecular dispersant. Dissolution at the time of production is usually performed using acetane, methine, methine, cupentanone, couxanone, iso and the like, thi,, bu and the like, zen, g, quin, and the like.
  • Non-propellant such as methidone, methidoxide, etc. is used.
  • a c reaction is used.
  • tin-based such as dibutytinzilla, chinchilla, dibutytinzio, stannath, etc.
  • iron-acetiana-based and trian-based such as thiane and thianzian can be mentioned.
  • the reaction value of the compound having an active element 3 ano group in one molecule is around g by the reaction value.
  • the an value is a value obtained by neutralizing a basic ano group with an acid and expressing the result as 9 numbers corresponding to the acid value.
  • the isoane group remains in the polymer dispersant by the above-mentioned reaction, because the qualities of isoamine formation by the anodic compound are further improved.
  • the color is preferably 0.30, particularly preferably 0.525.
  • a glass dia. Or adiaz having a diameter of 0.8 is preferred.
  • the temperature is between 0 ° C. and 00 ° C., preferably room temperature or o.
  • the exact time varies depending on the size of the liquid (, agent, dispersant) the dog glider, etc. Controlling the amount of ink so that the dissatisfaction of 200.000 is the lowest dispersion is possible. When the amount of discoloration is low, pigments with sufficient dispersion are often left, which are insufficient in terms of development, adhesion, resolution, and the like. In addition, since a large number of ultrafine particles disperse the gloss until the gloss exceeds the above range, the dispersibility is easily impaired.
  • a transparent cloth is coated with a light polymerizable material, a wire foot dita, a tap, etc., and dried.
  • An image is placed on the material, an image is passed through the material, and if necessary, a B image is formed by curing. This work is repeated for the three colors RG to form a fitter image.
  • the image is formed by exposing and developing without forming an acid layer such as a pore because of very high sensitivity and high sensitivity. Is possible.
  • it is a transparent material for a filter, and its quality is not particularly limited.
  • a step pin such as a pin-tefter, a hole such as a pin such as a pin, etc.
  • Various types of glass can be mentioned as thermoplastics such as methyl methacrylate and phone, curable plastics such as resin, polyester resin, and poly (meth) ac. Particularly, glass and heat plastic are preferred from the viewpoint of heat.
  • thermoplastics such as methyl methacrylate and phone
  • curable plastics such as resin, polyester resin, and poly (meth) ac.
  • glass and heat plastic are preferred from the viewpoint of heat.
  • the method is not particularly limited, it is preferable that 0.2 of the black cloth after drying with a cloth is preferably 0..5, and more preferably 0.0.2. In terms of gender, it is preferable that the luminous intensity is higher than 3.0.
  • the target of the pigment is 200 000.
  • hops, R-Ovens, and Ovens can be used, and the range is preferably 40 C and the drying time is 60 minutes.
  • a xenon lamp, a gen lamp, a tungsten lamp, a high-pressure mercury, an ultra-high-pressure mercury, a metal lap, mercury, a low-pressure mercury lap ionizer, a G-za, a kiza, a nitrogen-za, etc. Is mentioned.
  • An optical filter can be used if only a fixed length of light is used.
  • an agent capable of dissolving the diss film there is no particular limitation as long as it is an agent capable of dissolving the diss film.
  • an agent such as methine chloride, kun, or xananone can be used.
  • organic pollution It is preferable to use this highly durable Aca image solution because it has many fire hazards.
  • Examples of such an aka image solution include, but are not limited to, inorganic carbonates such as sodium carbonate, potassium carbonate, sodium, potassium, sodium hydroxide, potassium hydroxide, and the like.
  • An aqueous solution containing a lye agent of the terracium oxide is exemplified.
  • the image solution may contain a water-soluble agent and a compound having a hydroxyl group and a carboxy group, if necessary.
  • examples of the developer include tanshonaum, o having a phosphonium group, o having a borakioxy group, and thio having a terracium group.
  • I can list them. Although there is no particular limitation on the processing method, it is usually performed at a temperature of 050 ° C., preferably at 545 ° C., by a method of spatter, blur, or ultrasonic waves.
  • Trees such as pork and the like are preferable. Gravure is usually employed to achieve this. This is usually zero. After the surface treatment, the surface is treated by treatment with an ultraviolet rubbing cloth, and the surface is adjusted to a crystal state that can be adjusted.
  • a size corresponding to () with the opposing is used, and usually, a size of 281 is preferable.
  • Fospora (S) can be formed on the calafita by the photo-raffi method, and this can be used instead of the spesa.
  • eyes are used, especially ( Transistor) is preferred.
  • the gap of 018 differs depending on the position, but is usually selected within the range of 28 / u.
  • a material such as resin outside the entrance.
  • the material is cured and / or cured by irradiation and / or heating.
  • the pressure is reduced in the vacuum chamber, and after the above-mentioned entrance, the inside of the chamber is closed to be injected into the cell.
  • the decrease in the cell is usually X0Pa, preferably 0Pa. Also, decompress o
  • it is usually 300 ° C., preferably 50 ° C.
  • the temperature is usually between 0 and 60 and then immersed in water.
  • the injected liquid crystal cell is sealed by sealing the entrance, thereby completing (d).
  • any conventional crystal such as an aliphatic or polycyclic compound, may be used, such as an opic crystal or a sap crystal.
  • Tick crystals, mesic crystals, and stick crystals are known as the spic, but any of these may be used.
  • the dissolution is usually supplied in a dispersed state.
  • the method can be performed by a conventional method, for example, a spy, wire, fuff, die, sp method, or the like.
  • the die method is preferred from a comprehensive point of view, such as a drastic reduction of the dose, a complete effect of the spatter adhered by the spin method, and suppression of foreign matter production.
  • dry usually 0.50, preferably uD, particularly preferably around 5.
  • it is important that the quality of the spezes formed at the end of each region is the same. If the variation is large, unevenness may occur This is it. Also, it may be supplied in a tan form by an ink method or the like. 0185] 3 2
  • drying may be performed in a reduced pressure channel without increasing the temperature, and the reduced pressure may be combined.
  • the choice can be made according to the type of drying, classification, use, and the like.
  • a negative scooter is placed on top of the, and irradiates ultraviolet and visible rays through this scutan.
  • the formula by the light may be used. If necessary, in order to prevent the degree of photopolymerizability due to oxygen from being lowered, exposure may be performed after forming a layer such as a layer on the photopolymerizability.
  • the light used in the above is not particularly limited.
  • lamps such as xenon lamps, gen lamps, tungsten lamps, high-pressure mercury, ultra-high-pressure mercury, metallized lamps, mercury, low-pressure mercury, carbon arc lamps, fluorescent lamps, anion lamps, G ion lamps, , Nitrogen, umukadoumza, blue-violet conductor, conductor and the like.
  • optical light can be used.
  • a tan can be formed on the solution by developing with a solution containing an organic compound and an organic compound.
  • This solution may further contain an organic agent, an agent, and a material.
  • the aka compound include sodium hydroxide, potassium hydroxide, lithium hydroxide, sodium carbonate, sodium carbonate, and hydrogencarbonate.
  • Naum, potassium bicarbonate, sodium, Aka such as silicate, metasilicate, nanium, lanthanum, lanthanum hydrogen, lanthanum hydrogen, lanthanum hydrogen, ammonium hydroxide, etc. Tanoan, No. ⁇ Methane, Rickia, Nothop
  • aca compounds such as thiophene, thiamine, thiosopnoa, cinnamon, cinnamonium, teramethium (), and the like. These aca compounds may be a mixture of two or more.
  • on-systems such as bochia chikis, boki chia chis, bok chi axis, axis, noxedo axis, etc .
  • onions such as sphosalts, aquitoshosalts, aqiates, axhonosalts, and squistees, as well as aquisines and annos.
  • agent examples include isopia, benzia, chisse, se, se, pulp, dia, and the like.
  • the substrate after the image is preferably heat cured.
  • the thermosetting conditions at this time are selected such that the temperature is within a range of 00 280 C, preferably within a range of 50 250 C, and the time is selected within a range of 5600.
  • the projection formed on the transparent pole is inclined in multiple directions by using the above-mentioned step.
  • the following is a detailed explanation of the law. 0192] 4 cloth and
  • a black color filter, a black color filter, a black color filter, a black color filter, a black color filter, a light color, a wire, a footer, a dyer, a taper, a sp, etc. Apply a coating of. It is usually 0.55.
  • place the osque on the dry and image through the osc. Is formed by removing unconverted portions by development.
  • developed images are required to have a fineness of width of 520, and finerness tends to be required from the demand for discs.
  • it is preferable that the developed image has a clear image and a lath of the image portion, and that the development time, the time of the developing solution, and the intensity of the developing power are wide.
  • the photosensitive heating condition is adjusted, and the antennae () consisting of the surface and the base surface of the fine image () before heating is the antennae (W2 ), W 2 should be 2 above, preferably 3 above, more preferably 5 above, usually below 0, preferably 8 below.
  • the degree of heating is high or the length of heating is long, while the degree of heating is low or the length of heating is short.
  • Djibouti Jira 0.029 as 50, h) 329 was diluted and diluted with Popping Methiate (PG) 47.
  • PG Popping Methiate
  • a rack oil having a group was obtained. It was 50 g at the time of neutralization.
  • Carabo Black (Ryo Kagaku Co., Ltd., 220) 50 solidified with the polymer dispersant shown in the synthesis, the carbon black, polymer dispersant solution, and PG were prepared in a manner such that the solidity was 5 and the degree was 50. Was added. Of 509. This was used to make a better pass.
  • Ika was used to disperse the particles for 6 times around 2545C.
  • the same amount of dispersion was added using 0.5 Geavis. After that, the variance was separated by iter.
  • Thizo 3.9 (20 o) was dissolved in quenched 20 and ammonium chloride 2.99 (o) was added. While cooling, the methine zoid chloride 4 (o) was kept at a reaction temperature of 5 oC. The temperature was raised to room temperature over a short period of time, and the temperature was further increased to 3 at room temperature. Further reaction
  • the organics were combined and released with 50 sodium solution. Further, the organics were extracted with water 50, and the organics were dried over anhydrous magnesium sulfate. Generated by Kage Karaku Gly (Kisan),
  • C2 was synthesized in the same manner as in the formation of C, except that in place of (2), 3 Taki 96 (Oy) g azo was used instead of (2).
  • the values were as follows.
  • step 3 C3 was synthesized in the same manner as in the formation of C, except that the metal was changed to kunk.
  • the R value was as follows.
  • C3 was synthesized in the same manner as in the formation of C, except that the metac was changed to the k, and the k used in the final stage was changed to the knok.
  • the R values were as follows.
  • step 3 C5 was synthesized in the same manner as in the synthesis of C, except that the metac was changed to c and the c used in the final stage was changed to c.
  • C8 was synthesized in the same manner as in the synthesis of C, except that the metac was changed to a knock.
  • the values were as follows: 8.5d84 dH8ddH79ddH74, m644, q241, q231, 2226s32, s 3 2 3 s 3 5, 3 2 d 3 H
  • Carbon black (made by the company, 220) 50
  • the sensitivity, resolution, and properties were evaluated according to the following criteria, and the result of 2 was obtained.
  • the amount of light (c) capable of forming 20 screens is shown. In other words, it shows that high sensitivity can be achieved by using a light amount for a lens having a low exposure amount.
  • the Tan method was observed with a microscope at a magnification of 200 times.
  • Tan method 0 is greater than X
  • the O value was measured by a Qubeth meter (Rg 27).
  • the O value is a numerical value indicating the shielding force, and indicates that the numerical value is significant.
  • the glass with the imaged image tang is placed on the untreated glass (Nang, 7059) so that the image is in contact with the untreated glass surface, and the weight shown below is applied at a speed of 3 Cs. 5. Work was performed to combine. The evaluation was made according to the criteria below, depending on whether the child was born or not.
  • Example 9 The same process as in Example 9 was carried out except that black (tea, 3C) was used instead of carbon black (Ryoko Chemical Co., Ltd., 220) used as a black color. Obtained. The results are shown in Table 2.
  • step 3 the same process as in comparison 3 was performed except that black (tea, 3C) was used instead of the black black (Ryofuka Chemical, 220) used as a black color to obtain a black star.
  • black titanium, 3C
  • CG24 Initiation of polymerization (Spare-Takeka, CG24) (59) 0233

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  • Optical Filters (AREA)

Abstract

Un ester d'oxime de structure spécifiée. En particulier, dans une composition photopolymérisable comprenant (a) une matière de couleur noire, (b) un liant organique et (c) un initiateur de photopolymérisation, l'ester d'oxime constitue le composant (c). L'ester d'oxime peut être utilisé en tant qu'initiateur de photopolymérisation hautement sensible. La composition photopolymérisable contenant l'ester d'oxime sous la forme d'une couche mince possède une sensibilité et un pouvoir de résolution excellents tout en présentant une capacité élevée de protection lumineuse, de telle sorte qu'elle est susceptible de former une matrice noire (MN) en résine de faible coût mais de grande qualité. Le filtre coloré utilisant cette résine MN possède d'excellentes précision, planéité et durabilité, de telle sorte qu'il est susceptible d'améliorer la qualité d'affichage d'un dispositif à cristaux liquides. De plus, le procédé de production et le filtre coloré en eux-mêmes ne mettent en jeu aucune substance dangereuse, de telle sorte que les dangers pour le corps humain peuvent être réduits et la sécurité environnementale peut être améliorée. Ses applications peuvent concerner des utilisations dans lesquelles aucune matière colorée n'est employée, comme un photo-espaceur ou une nervure (saillie d'alignement découpée en cristaux liquides).
PCT/JP2005/002818 2004-02-23 2005-02-22 Ester d'oxime, composition photopolymérisable et filtre coloré les utilisant WO2005080337A1 (fr)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5533195A (en) * 1978-08-25 1980-03-08 Agfa Gevaert Nv Improved photopolymerizable recording material
JPS55100543A (en) * 1979-01-24 1980-07-31 Agfa Gevaert Nv Photosensitive composition containing ethylenic unsaturated comound* initiator* and sensitizer
JPS604502A (ja) * 1983-06-22 1985-01-11 Daicel Chem Ind Ltd 光重合開始剤
JPS60166306A (ja) * 1984-02-09 1985-08-29 Daicel Chem Ind Ltd 光重合開始剤
JPH05214012A (ja) * 1992-02-05 1993-08-24 Nippon Oil & Fats Co Ltd エチレン系ポリマーの架橋剤および架橋方法
JP2002323762A (ja) * 2001-04-25 2002-11-08 Nippon Kayaku Co Ltd ネガ型着色感光性組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5533195A (en) * 1978-08-25 1980-03-08 Agfa Gevaert Nv Improved photopolymerizable recording material
JPS55100543A (en) * 1979-01-24 1980-07-31 Agfa Gevaert Nv Photosensitive composition containing ethylenic unsaturated comound* initiator* and sensitizer
JPS604502A (ja) * 1983-06-22 1985-01-11 Daicel Chem Ind Ltd 光重合開始剤
JPS60166306A (ja) * 1984-02-09 1985-08-29 Daicel Chem Ind Ltd 光重合開始剤
JPH05214012A (ja) * 1992-02-05 1993-08-24 Nippon Oil & Fats Co Ltd エチレン系ポリマーの架橋剤および架橋方法
JP2002323762A (ja) * 2001-04-25 2002-11-08 Nippon Kayaku Co Ltd ネガ型着色感光性組成物

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KR100897224B1 (ko) 2009-05-14
CN101805282B (zh) 2012-07-04
CN1922142A (zh) 2007-02-28
CN101805282A (zh) 2010-08-18
TWI378919B (en) 2012-12-11
CN1922142B (zh) 2012-05-02
KR20070100810A (ko) 2007-10-11
TW200604172A (en) 2006-02-01

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