WO2002008371A2 - Composition de lavage - Google Patents

Composition de lavage Download PDF

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Publication number
WO2002008371A2
WO2002008371A2 PCT/US2000/020255 US0020255W WO0208371A2 WO 2002008371 A2 WO2002008371 A2 WO 2002008371A2 US 0020255 W US0020255 W US 0020255W WO 0208371 A2 WO0208371 A2 WO 0208371A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
automatic dishwashing
organic solvent
cookware
tableware
Prior art date
Application number
PCT/US2000/020255
Other languages
English (en)
Other versions
WO2002008371A3 (fr
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP00870124A external-priority patent/EP1126070B1/fr
Priority claimed from PCT/US2000/019619 external-priority patent/WO2002008370A2/fr
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to PCT/US2000/020255 priority Critical patent/WO2002008371A2/fr
Priority to BRPI0017112-3A priority patent/BR0017112B1/pt
Priority to JP2001560338A priority patent/JP2005507432A/ja
Priority to ES00980871T priority patent/ES2290059T3/es
Priority to AT00980871T priority patent/ATE369417T1/de
Priority to MXPA02008065A priority patent/MXPA02008065A/es
Priority to CA002397241A priority patent/CA2397241C/fr
Priority to PCT/US2000/032533 priority patent/WO2001060966A1/fr
Priority to EP00980871A priority patent/EP1255807B1/fr
Priority to AU2001218076A priority patent/AU2001218076A1/en
Priority to DE60035902T priority patent/DE60035902T2/de
Priority to CNB008190615A priority patent/CN1225537C/zh
Priority to MXPA03000493A priority patent/MXPA03000493A/es
Priority to CA002414133A priority patent/CA2414133C/fr
Priority to PCT/US2000/034910 priority patent/WO2002008509A1/fr
Priority to AT00986684T priority patent/ATE342336T1/de
Priority to JP2002514258A priority patent/JP3962327B2/ja
Priority to EP00986683A priority patent/EP1305383B1/fr
Priority to DE60031309T priority patent/DE60031309T2/de
Priority to JP2002513861A priority patent/JP2004509175A/ja
Priority to CA002416327A priority patent/CA2416327C/fr
Priority to EP00988267A priority patent/EP1305390B1/fr
Priority to DE60043751T priority patent/DE60043751D1/de
Priority to ES00986682T priority patent/ES2352670T3/es
Priority to PCT/US2000/034906 priority patent/WO2002008374A1/fr
Priority to AT00988267T priority patent/ATE395405T1/de
Priority to EP00986684A priority patent/EP1305389B1/fr
Priority to CA002414140A priority patent/CA2414140C/fr
Priority to MXPA03000492A priority patent/MXPA03000492A/es
Priority to CA002416326A priority patent/CA2416326A1/fr
Priority to ES00988267T priority patent/ES2306676T3/es
Priority to AU2001222874A priority patent/AU2001222874A1/en
Priority to ES00986684T priority patent/ES2273742T3/es
Priority to AT00986683T priority patent/ATE455836T1/de
Priority to MXPA03000490A priority patent/MXPA03000490A/es
Priority to AU2001222876A priority patent/AU2001222876A1/en
Priority to JP2002514260A priority patent/JP2004509176A/ja
Priority to DE60044979T priority patent/DE60044979D1/de
Priority to AU2001224494A priority patent/AU2001224494A1/en
Priority to MXPA03000491A priority patent/MXPA03000491A/es
Priority to AT00986682T priority patent/ATE481471T1/de
Priority to PCT/US2000/034908 priority patent/WO2002008375A1/fr
Priority to ES00986683T priority patent/ES2339420T3/es
Priority to AU2001222873A priority patent/AU2001222873A1/en
Priority to PCT/US2000/034909 priority patent/WO2002008376A1/fr
Priority to DE60038906T priority patent/DE60038906D1/de
Priority to AU2001222875A priority patent/AU2001222875A1/en
Priority to PCT/US2000/034907 priority patent/WO2002008373A1/fr
Priority to EP00986682A priority patent/EP1305388B1/fr
Priority to JP2002514259A priority patent/JP2004515569A/ja
Priority to CN01805165A priority patent/CN1401030A/zh
Priority to JP2001559930A priority patent/JP5000060B2/ja
Priority to PCT/US2001/004694 priority patent/WO2001061099A1/fr
Priority to AU2001238240A priority patent/AU2001238240A1/en
Priority to MXPA02008067A priority patent/MXPA02008067A/es
Priority to EP01910655A priority patent/EP1255887A2/fr
Priority to BR0108441-0A priority patent/BR0108441A/pt
Priority to US10/204,259 priority patent/US7351683B2/en
Priority to CA002396931A priority patent/CA2396931A1/fr
Priority to ARP010100706A priority patent/AR035167A1/es
Priority to ARP010100705A priority patent/AR028508A1/es
Priority to US09/906,479 priority patent/US6557732B2/en
Priority to US09/906,295 priority patent/US20020142931A1/en
Priority to US09/906,491 priority patent/US6750187B2/en
Priority to US09/906,480 priority patent/US6740628B2/en
Priority to PCT/US2001/022707 priority patent/WO2002006438A1/fr
Priority to JP2002512331A priority patent/JP4185360B2/ja
Priority to CA002415308A priority patent/CA2415308A1/fr
Priority to MXPA03000488A priority patent/MXPA03000488A/es
Priority to EP01959008A priority patent/EP1305391B1/fr
Priority to AT04023010T priority patent/ATE328996T1/de
Priority to AT01959008T priority patent/ATE350453T1/de
Priority to PCT/US2001/022706 priority patent/WO2002006436A1/fr
Priority to JP2002512332A priority patent/JP2004506749A/ja
Priority to CA002415304A priority patent/CA2415304A1/fr
Priority to EP01959009A priority patent/EP1305394A1/fr
Priority to DE60106272T priority patent/DE60106272T2/de
Priority to ES01959010T priority patent/ES2225589T3/es
Priority to AT01959010T priority patent/ATE278764T1/de
Priority to DE60125775T priority patent/DE60125775T2/de
Priority to MXPA03000487A priority patent/MXPA03000487A/es
Priority to CA002415302A priority patent/CA2415302A1/fr
Priority to AU2001280605A priority patent/AU2001280605A1/en
Priority to DE60120517T priority patent/DE60120517T2/de
Priority to EP01959010A priority patent/EP1305392B1/fr
Priority to JP2002512330A priority patent/JP2004519527A/ja
Priority to PCT/US2001/022708 priority patent/WO2002006437A1/fr
Priority to ES04023010T priority patent/ES2265133T3/es
Priority to AU2001280606A priority patent/AU2001280606A1/en
Priority to EP04023010A priority patent/EP1493803B1/fr
Priority to AU2001280607A priority patent/AU2001280607A1/en
Priority to ES01959008T priority patent/ES2280389T3/es
Priority to MXPA03000489A priority patent/MXPA03000489A/es
Priority to US09/910,281 priority patent/US20020037822A1/en
Priority to US09/909,233 priority patent/US20020037817A1/en
Priority to US09/909,403 priority patent/US6683036B2/en
Publication of WO2002008371A2 publication Critical patent/WO2002008371A2/fr
Priority to US10/764,931 priority patent/US20040157763A1/en
Priority to US11/151,027 priority patent/US20050233925A1/en
Priority to US11/192,563 priority patent/US7304023B2/en
Priority to US11/212,221 priority patent/US7229955B2/en
Publication of WO2002008371A3 publication Critical patent/WO2002008371A3/fr
Priority to JP2012238209A priority patent/JP2013067802A/ja

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/02—Devices for adding soap or other washing agents
    • D06F39/024—Devices for adding soap or other washing agents mounted on the agitator or the rotating drum; Free body dispensers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/045—Multi-compartment
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C11D2111/14—
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C11D3/3917—Nitrogen-containing compounds

Definitions

  • JP-A- 10,017,900 discloses an automatic dishwashing auxiliary composition comprising non-ionic low foaming surfactant, organic solvent and water. The composition delivers detergency and drying benefits.
  • JP-A-11 ,117,000 discloses a cleaning assistant composition for automatic dishwashing machines comprising surfactant, organic high-molecular polyelectrolyte, water-soluble solvent and water. The claimed assistant composition helps in the cleaning of stubborn dirt such as that due to oil or lipstick.
  • a method of removing cooked-, baked-, or burnt-on food soil such as grease, meat, dairy, fruit, pasta and any other food especially difficult to remove after the cooking process
  • cookware and tableware including stainless steel, glass, plastic, wood and ceramic objects.
  • the method comprises washing the cookware/tableware in an automatic dishwashing machine in the presence of an organic solvent system (comprising a single solvent compound or a mixture of solvent compounds) having a volatile organic content above 1 mm Hg of less than about 50%, preferably less than about 20% and more preferably less than about 10% by weight of the solvent system.
  • volatile organic content of the solvent system is defined as the content of organic components in the solvent system having a vapor pressure higher than the prescribed limit at 25°C and atmospheric pressure.
  • the optimum concentration of the solvent in the wash liquor is from about 100 ppm to about 10000 ppm, preferably from about 200 to about 8000 and more preferably from about 500 to about 5000 ppm.
  • the organic solvent system is preferably used in combination with a surfactant, especially a low foaming non- ionic surfactant and a detergency builder.
  • the removal of cooked-, baked-, or burnt-on food soil from cookware and tableware can be carried out by the use of one or more organic solvent compositions (wherein "solvent composition” is understood to comprise the organic solvent system and optional additional active ingredients and diluents) and one or more automatic dishwashing detergent compositions.
  • solvent composition is understood to comprise the organic solvent system and optional additional active ingredients and diluents
  • automatic dishwashing detergent compositions can be used.
  • the organic solvent composition can be built, unbuilt or generally unbuilt, but when used as an additive composition in conjunction with a dishwashing detergent composition, the solvent composition will normally be relatively unbuilt by comparison with the detergent composition.
  • solvent composition will deliver a minor proportion (less than 50%, preferably less than 25%, more preferably less than 10% by weight) of the total builder delivered to the wash liquor by the one or more solvent compositions and the one or more detergent compositions.
  • general unbuilt is meant that the composition contains less than about 5% by weight of detergency builder.
  • the solvent compositions and automatic dishwashing detergent compositions can be delivered either at the same or at different points of the dishwashing cycle, for example: i) solvent composition and automatic dishwashing detergent composition are independently delivered in the pre-wash cycle and in the main- wash cycle, respectively; ii) a solvent composition and a first automatic dishwashing detergent composition are delivered in the pre-wash cycle and a second automatic dishwashing detergent composition in the main-wash cycle; iii) a first solvent composition and a first automatic dishwashing detergent composition are delivered in the pre-wash cycle and a second solvent composition and a second automatic dishwashing detergent composition in the main-wash cycle; iv) a solvent composition and an automatic dishwashing detergent composition are delivered simultaneously in the main-wash cycle; and v) a solvent composition and an automatic dishwashing detergent composition are delivered in the pre-wash and in the main-wash cycle.
  • the physical form of the organic solvent composition and/or automatic dishwashing detergent composition is preferably such as to prevent intimate mixing of the compositions prior to contact thereof with the wash liquor.
  • the invention can be also reduced to practice using multi-phase, "all-in-one" products.
  • a method of removing cooked-, baked-, or burnt-on food soil from cookware and tableware comprising delivering separate portions of a multi-phase detergent composition into the same or different cycles of an automatic dishwashing machine, wherein the multi-phase detergent composition comprises at least a first phase containing an organic solvent composition and at least a second phase containing an automatic dishwashing detergent composition.
  • the multiphase detergent composition for example could take the form of a multilayer liquid (e.g.
  • the level of solvent delivered to the wash process should be such as to deliver the benefits on cooked-, baked- or burnt-on food soils.
  • the present invention also envisages the use of multiple organic solvent compositions.
  • a method of removing cooked-, baked-, or burnt-on food soil from cookware and tableware comprising delivering a plurality of organic solvent compositions of different solvent characteristics into the same or different cycles of an automatic dishwashing machine, for example, a first solvent composition in the pre-wash cycle and a second solvent composition in the main-wash cycle.
  • the different organic solvent compositions are designed to be specific to different soil and/or substrates.
  • They can be delivered into different cycles of a dishwashing machine, with or without different automatic dishwashing detergent compositions, such that, for example, a first solvent composition and a first automatic dishwashing detergent composition are delivered into the pre-wash cycle and a second solvent composition and a second automatic dishwashing detergent composition are delivered into the main- wash cycle.
  • the organic solvent composition can be in a unit dose form allowing controlled release (for example delayed, sustained, triggered or slow release) of the composition during one or more repeated washing cycles.
  • the solvent composition is contained in a single or multi-compartment pouch.
  • a method of removing cooked-, baked-, or burnt-on food soil from cookware and tableware comprises washing the cookware/tableware in an automatic dishwashing machine with an automatic dishwashing detergent composition comprising surfactant (preferably comprising low-foaming nonionic surfactant), detergency builder and organic solvent system in levels sufficient to provide a wash liquor concentration of from about 10 ppm to about 1000 ppm surfactant, from about 100 ppm to about 5000 ppm detergency builder, and about 100 ppm to about 10,000, preferably from about 500 ppm to about 5000 ppm of organic solvent.
  • surfactant preferably comprising low-foaming nonionic surfactant
  • the organic solvent composition can be in the form of a liquid, paste, cream or gel and can be optionally encapsulated, packaged in a single- or multi-compartment pouch, or absorbed onto a porous carrier material.
  • the solvent composition can be aqueous but preferably is anhydrous.
  • Preferred pouches for use herein are water-soluble, solvent-resistant partially hydrolysed PVA pouches.
  • the optimum organic solvent systems for use herein are characterised by extremely low liquid surface tensions and contact angles on polymerised grease- coated substrates. Moreover, they generally consist of mixed solvent systems displaying synergistic contact angle and low surface tension.
  • the organic solvent system herein preferably has a liquid surface tension at 25°C of less than about 27 mN/m.
  • compositions containing the solvent system preferably display an advancing contact angle on a polymerised grease-coated substrate at 25°C of less than 20°, preferably less than 10° and more preferably less than 5°.
  • the advancing contact angle for compositions based on mixed solvent systems should be less than that of any of the corresponding compositions containing the individual components of the solvent system.
  • Such solvent systems and compositions are found to be optimum for the removal of burnt-on soils having a high carbon content from cookware and tableware.
  • a method of removing cooked-, baked-, or burnt-on food soil from cookware and tableware comprising treating the cookware/tableware with a hard surface cleaning composition comprising an organic solvent system.
  • the organic solvent system desirably has a liquid surface tension of less than about 27 mN/m, preferably less than about 26 mN/m.
  • the hard surface cleaning composition on the other hand desirably display an advancing contact angle on a polymerised grease-coated substrate at 25°C of less than 20°, preferably less than 10° and more preferably less than 5°.
  • the above method comprises the step of pre-treating the cookware/tableware with the hard surface cleaning composition prior to manual or automatic dishwashing.
  • organic solvents are suitable for use herein but preferably the organic solvent is selected from alcohols, amines, esters, glycol ethers, glycols, terpenes and mixtures thereof.
  • the organic solvent system is preferably formulated to meet the constraints on volatile solvent components described above and in highly preferred embodiments the solvent system will contain less than about 50%, preferably less than 20% and more preferably less than 10% of solvent components having a vapor pressure above about 0.1 mm Hg at 25°C and atmospheric pressure.
  • the solvent is essentially free (contains less than about 5% by weight) of solvent components having a boiling point below about 150°C, flash point below about 100°C or a vapor pressure above about 1 mm Hg at 25°C and atmospheric pressure.
  • the organic solvent comprises organoamine (especially alkanolamine) solvent and glycol ether solvent, preferably in a weight ratio of from about 3:1 to about 1 :3, and wherein the glycol ether solvent is selected from ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monobutyl ether, and mixtures thereof.
  • the glycol ether is a mixture of diethylene glycol monobutyl ether and propylene glycol butyl ether, especially in a weight ratio of from about 1 :2 to about 2:1.
  • the invention also relates to detergent packs and multi-component products suitable for use in an automatic dishwashing machine or dishwashing pretreatment to provide baked and burnt-on soil removal and other cleaning benefits.
  • an automatic dishwashing detergent pack comprising two or more automatic dishwashing detergent and/or auxiliary products, storage means comprising separate but associated portions of the two or more products and means, for example electric pump means, for delivering quantities of the two or more products into the same or different cycles of an automatic dishwashing machine.
  • the pack can also comprise means for controlling the relative dispensing rate of the two or more products from the storage means.
  • the pack preferably comprises an organic solvent composition and an automatic dishwashing detergent composition and is used for removing cooked-, baked-, and burnt-on food soil from cookware and tableware.
  • the two or more automatic dishwashing detergent or auxiliary products are in rheology-matched gel-form.
  • Compositions are considered to be rheology-matched if they have similar yield values (differing by less than about 50%, preferably by less than about 20%) and/or similar viscosities (differing by less than about 50%, preferably by less than about 20%) under the same shear conditions.
  • compositions comprising the herein defined solvent systems for direct application to burnt-on and baked-on food soiled cookware and tableware.
  • compositions comprising an organic solvent system having a liquid surface tension of less than about 27 mN/m.
  • Preferred compositions contain from about 1% to about 99% preferably from about 5% to about 50% of organic solvent as herein defined, highly preferred being a mixed solvent system based on alkanolamine and a mixed glycol ether solvent system as described hereinabove.
  • the method for determining contact angle is as follows.
  • a sample plate (prepared as described below) is dipped into and pulled out of a liquid and contact angles calculated after Wilhelmy Method.
  • the force exerted on the sample according to the immersion depth is measured (using a Kruss K12 tensiometer and System K121 software) and is proportional to the contact angle of the liquid on the solid surface.
  • the sample plate is prepared as follows: Spray 30-50 grams of Canola Oil into a beaker. Dip a glass slide (3x9x0.1 cm) into the Oil and thoroughly coat the surface. This results in an evenly dispersed layer of oil on the surface. Adjust the weight of product on the slide's surface until approximately 0.5 g of oil has been delivered and evenly distributed. At this point, bake the slides at 450F for 20 minutes, and allow to cool to room temperature.
  • the product preferably has a viscosity from about 0.1 to about 200 Pa s, preferably from about 0.3 to about 20 Pa s as measured with a Brookfield cylinder viscometer (model LVDII) using 10 ml sample, a spindle S-31 and a speed of 3 rpm. Rheology is measured under ambient temperature conditions (25° C).
  • Preferred polyhydric alcohols used to produce carboxyvinyl polymers include polyols selected from the class consisting of oligosaccarides, reduced derivatives thereof in which the carbonyl group is converted to an alcohol group, an pentaerythritol; most preferred is sucrose or pentaerythritol. It is preferred that the hydroxyl groups of the modified polyol be etherified with alkyl groups, the polyol having at least two allyl ether groups per polyol molecule. When the polyol is sucrose, it is preferred that the sucrose have at least about five allyl ether groups per sucrose molecule. It is preferred that the polyether of the polyol comprise from about 0.1% to about 4% of the total monomers, more preferably from about 0.2% to about 2.5%.
  • Preferred monomeric olefinically unsaturated carboxylic acids for use in producing carboxyvinyl polymers used herein include monomeric, polymerizable, alpha-beta monoolefinically unsaturated lower aliphatic carboxylic acids; more preferred are monomeric monoolefinic acrylic acids of the structure:
  • Carbopol® Various carboxyvinyl polymers, homopolymers and copolymers are commercially available from B. F. Goodrich Company, New York, N.Y., under the trade name Carbopol®. These polymers are also known as carbomers or polyacrylic acids.
  • Carboxyvinyl polymers useful in formulations of the present invention include Carbopol 910 having a molecular weight of about 750,000, Carbopol 941 having a molecular weight of about 1 ,250,000, and Carbopols 934 and 940 having molecular weights of about 3,000,000 and 4,000,000, respectively. More preferred are the series of Carbopols which use ethyl acetate and cyclohexane in the manufacturing process, Carbopol 981 , 2984, 980, and 1382.
  • the cellulosic type thickeners hydroxyethyl and hydroxymethyl cellulose (ETHOCEL and METHOCEL® available from Dew Chemical) can also be used.
  • the present invention envisages the use of solvent compositions as additives for conventional automatic dishwashing detergent compositions. It also envisages multi-component dishwashing products containing purpose-designated combination of solvent compositions and dishwashing detergent compositions. The invention also envisages so called "all-in-one" detergent and hard surface cleaning products having both an alkaline detergent and a solvent functionality. In the case of additive and multi-component products, the invention does not require the two compositions to be in the same physical form.
  • the organic solvent composition can be in any physical form, e.g. liquid, paste, cream, gel, powder, granules or tablets and similarly the automatic dishwashing detergent composition can be in any of these forms.
  • cationic surfactants such as chlorine esters (US-A-4228042, US-A-4239660 and US-A-4260529) and mono C 6 -C ⁇
  • cationic surfactants such as chlorine est
  • Bleaching agent Bleaching agents suitable herein include chlorine and oxygen bleaches, especially inorganic perhydrate salts such as sodium perborate mono-and tetrahydrates and sodium percarbonate optionally coated to provide controlled rate of release (see, for example, GB-A-1466799 on sulfate/carbonate coatings), preformed organic peroxyacids and mixtures thereof with organic peroxyacid bleach precursors and/or transition metal-containing bleach catalysts (especially manganese or cobalt).
  • Inorganic perhydrate salts are typically incorporated at levels in the range from about 1% to about 40% by weight, preferably from about 2% to about 30% by weight and more preferably from abut 5% to about 25% by weight of composition.
  • the suds suppressers suitable for use herein include nonionic surfactants having a low cloud point.
  • Cloud point is a well known property of nonionic surfactants which is the result of the surfactant becoming less soluble with increasing temperature, the temperature at which the appearance of a second phase is observable is referred to as the “cloud point” (See Kirk Othmer, pp. 360-362).
  • a “low cloud point” nonionic surfactant is defined as a nonionic surfactant system ingredient having a cloud point of less than 30° C, preferably less than about 20° C, and even more preferably less than about 10° C, and most preferably less than about 7.5° C.

Abstract

L'invention concerne un procédé permettant d'éliminer les taches dues à la cuisson, à la cuisson au four ou au grillage de nourriture sur des ustensiles de cuisine et des articles de table. Ce procédé consiste à laver les ustensiles de cuisine ou les articles de table dans une machine automatique en présence d'un système de solvant organique présentant une concentration de liqueur de lavage comprise entre environ 100 et environ 5000 ppm. Ce procédé comprend le stockage et la distribution de compositions de solvant organique et d'une composition détergente de lavage de vaisselle à partir de récipients à plusieurs compartiments. Ce procédé permet d'éliminer efficacement les taches teignantes qui sont très difficiles à éliminer à l'aide d'un procédé classique de lavage de vaisselle. L'invention concerne également des compositions détergentes de lavage de vaisselle automatique ainsi que des compositions détergentes pour surfaces dures comprenant des systèmes de solvants organiques pour l'élimination des taches dues à la cuisson, à la cuisson au four ou au grillage de nourriture sur des ustensiles de cuisine et des articles de table.
PCT/US2000/020255 2000-02-17 2000-07-25 Composition de lavage WO2002008371A2 (fr)

Priority Applications (101)

Application Number Priority Date Filing Date Title
PCT/US2000/020255 WO2002008371A2 (fr) 2000-02-17 2000-07-25 Composition de lavage
BRPI0017112-3A BR0017112B1 (pt) 2000-02-17 2000-11-29 composiÇço em bolsa solével em Água e uso da composiÇço.
JP2001560338A JP2005507432A (ja) 2000-02-17 2000-11-29 洗剤製品
ES00980871T ES2290059T3 (es) 2000-02-17 2000-11-29 Producto detergente.
AT00980871T ATE369417T1 (de) 2000-02-17 2000-11-29 Waschmittelerzeugnis
MXPA02008065A MXPA02008065A (es) 2000-02-17 2000-11-29 Producto detergente.
CA002397241A CA2397241C (fr) 2000-02-17 2000-11-29 Compositions en pochettes comprenant du peracide
PCT/US2000/032533 WO2001060966A1 (fr) 2000-02-17 2000-11-29 Produit detergent
EP00980871A EP1255807B1 (fr) 2000-02-17 2000-11-29 Produit detergent
AU2001218076A AU2001218076A1 (en) 2000-02-17 2000-11-29 Detergent product
DE60035902T DE60035902T2 (de) 2000-02-17 2000-11-29 Waschmittelerzeugnis
CNB008190615A CN1225537C (zh) 2000-02-17 2000-11-29 洗涤剂产品
MXPA03000493A MXPA03000493A (es) 2000-07-19 2000-12-21 Composiciones de limpieza.
CA002414133A CA2414133C (fr) 2000-07-19 2000-12-21 Methode de lavage automatique de vaisselle faisant appel a un systeme de solvants organiques
PCT/US2000/034910 WO2002008509A1 (fr) 2000-07-19 2000-12-21 Emballage de detergent
AT00986684T ATE342336T1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
JP2002514258A JP3962327B2 (ja) 2000-07-19 2000-12-21 洗浄性組成物
EP00986683A EP1305383B1 (fr) 2000-07-19 2000-12-21 Composition de nettoyage
DE60031309T DE60031309T2 (de) 2000-07-19 2000-12-21 Reinigungsmittel
JP2002513861A JP2004509175A (ja) 2000-07-19 2000-12-21 洗浄性組成物
CA002416327A CA2416327C (fr) 2000-07-19 2000-12-21 Nettoyant de surface, alcalin et a faible tension superficielle, contenant un compose d'amine organique
EP00988267A EP1305390B1 (fr) 2000-07-19 2000-12-21 Composition de lavage
DE60043751T DE60043751D1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
ES00986682T ES2352670T3 (es) 2000-07-19 2000-12-21 Composición limpiadora.
PCT/US2000/034906 WO2002008374A1 (fr) 2000-07-19 2000-12-21 Composition de nettoyage
AT00988267T ATE395405T1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
EP00986684A EP1305389B1 (fr) 2000-07-19 2000-12-21 Composition de lavage
CA002414140A CA2414140C (fr) 2000-07-19 2000-12-21 Methode de lavage automatique de la vaisselle utilisant un systeme de solvant organique
MXPA03000492A MXPA03000492A (es) 2000-07-19 2000-12-21 Composiciones de limpieza.
CA002416326A CA2416326A1 (fr) 2000-07-19 2000-12-21 Nettoyant de surface dure, alcalin et a faible tension superficielle, comprenant un agent de gonflement de salissures et un adjuvant d'etalement
ES00988267T ES2306676T3 (es) 2000-07-19 2000-12-21 Composicion limpiadora.
AU2001222874A AU2001222874A1 (en) 2000-07-19 2000-12-21 Cleaning composition
ES00986684T ES2273742T3 (es) 2000-07-19 2000-12-21 Composicion limpiadora.
AT00986683T ATE455836T1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
MXPA03000490A MXPA03000490A (es) 2000-07-19 2000-12-21 Composicion de limpieza.
AU2001222876A AU2001222876A1 (en) 2000-07-19 2000-12-21 Detergent pack
JP2002514260A JP2004509176A (ja) 2000-07-19 2000-12-21 洗浄性組成物
DE60044979T DE60044979D1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
AU2001224494A AU2001224494A1 (en) 2000-07-19 2000-12-21 Cleaning composition
MXPA03000491A MXPA03000491A (es) 2000-07-19 2000-12-21 Composicion limpiadora.
AT00986682T ATE481471T1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
PCT/US2000/034908 WO2002008375A1 (fr) 2000-07-19 2000-12-21 Composition de lavage
ES00986683T ES2339420T3 (es) 2000-07-19 2000-12-21 Composicion limpiadora.
AU2001222873A AU2001222873A1 (en) 2000-07-19 2000-12-21 Cleaning composition
PCT/US2000/034909 WO2002008376A1 (fr) 2000-07-19 2000-12-21 Composition de lavage
DE60038906T DE60038906D1 (de) 2000-07-19 2000-12-21 Reinigungsmittel
AU2001222875A AU2001222875A1 (en) 2000-07-19 2000-12-21 Cleaning composition
PCT/US2000/034907 WO2002008373A1 (fr) 2000-07-19 2000-12-21 Composition de nettoyage
EP00986682A EP1305388B1 (fr) 2000-07-19 2000-12-21 Composition de nettoyage
JP2002514259A JP2004515569A (ja) 2000-07-19 2000-12-21 洗浄性組成物
CN01805165A CN1401030A (zh) 2000-02-17 2001-02-13 洗衣用添加剂小袋
JP2001559930A JP5000060B2 (ja) 2000-02-17 2001-02-13 洗濯添加剤用小袋
PCT/US2001/004694 WO2001061099A1 (fr) 2000-02-17 2001-02-13 Sachet d'additifs de blanchisserie
AU2001238240A AU2001238240A1 (en) 2000-02-17 2001-02-13 Laundry additive sachet
MXPA02008067A MXPA02008067A (es) 2000-02-17 2001-02-13 Saco de aditivo para lavanderia.
EP01910655A EP1255887A2 (fr) 2000-02-17 2001-02-13 Sachet d'additifs de blanchisserie
BR0108441-0A BR0108441A (pt) 2000-02-17 2001-02-13 Saché aditivo de lavanderia
US10/204,259 US7351683B2 (en) 2000-02-17 2001-02-13 Laundry additive sachet
CA002396931A CA2396931A1 (fr) 2000-02-17 2001-02-13 Sachet d'additifs de blanchisserie
ARP010100706A AR035167A1 (es) 2000-02-17 2001-02-16 Producto detergente
ARP010100705A AR028508A1 (es) 2000-02-17 2001-02-16 Sachet aditivo para el lavado de ropa y proceso para tratar las telas utilizando dicho sachet.
US09/906,479 US6557732B2 (en) 2000-07-19 2001-07-16 Detergent pack
US09/906,295 US20020142931A1 (en) 2000-07-19 2001-07-16 Gel form automatic dishwashing compositions, methods of preparation and use thereof
US09/906,491 US6750187B2 (en) 2000-07-19 2001-07-16 Cleaning composition
US09/906,480 US6740628B2 (en) 2000-07-19 2001-07-16 Cleaning composition
PCT/US2001/022707 WO2002006438A1 (fr) 2000-07-19 2001-07-18 Compositions se presentant sous forme de gel pour lave-vaisselle automatique, leurs procedes de preparation et d'utilisation
JP2002512331A JP4185360B2 (ja) 2000-07-19 2001-07-18 洗浄性組成物
CA002415308A CA2415308A1 (fr) 2000-07-19 2001-07-18 Composition nettoyante pour surface dure contenant un parfum pour masquer les odeurs
MXPA03000488A MXPA03000488A (es) 2000-07-19 2001-07-18 Composiciones para el lavado automatico de trastes en forma de gel, metodos de preparacion y uso de las mismas.
EP01959008A EP1305391B1 (fr) 2000-07-19 2001-07-18 Compositions nettoyantes
AT04023010T ATE328996T1 (de) 2000-07-19 2001-07-18 Reinigungsmittelzusammensetzungen
AT01959008T ATE350453T1 (de) 2000-07-19 2001-07-18 Reinigungsmittel
PCT/US2001/022706 WO2002006436A1 (fr) 2000-07-19 2001-07-18 Compositions nettoyantes
JP2002512332A JP2004506749A (ja) 2000-07-19 2001-07-18 ゲル状自動食器洗浄用組成物、それらの調製方法、及びそれらの使用
CA002415304A CA2415304A1 (fr) 2000-07-19 2001-07-18 Compositions se presentant sous forme de gel pour lave-vaisselle automatique, leurs procedes de preparation et d'utilisation
EP01959009A EP1305394A1 (fr) 2000-07-19 2001-07-18 Compositions se presentant sous forme de gel pour lave-vaisselle automatique, leurs procedes de preparation et d'utilisation
DE60106272T DE60106272T2 (de) 2000-07-19 2001-07-18 Reinigungsmittelzusammensetzungen
ES01959010T ES2225589T3 (es) 2000-07-19 2001-07-18 Composiciones limpiadoras.
AT01959010T ATE278764T1 (de) 2000-07-19 2001-07-18 Reinigungsmittelzusammensetzungen
DE60125775T DE60125775T2 (de) 2000-07-19 2001-07-18 Reinigungsmittel
MXPA03000487A MXPA03000487A (es) 2000-07-19 2001-07-18 Composiciones de limpieza..
CA002415302A CA2415302A1 (fr) 2000-07-19 2001-07-18 Composition de nettoyage de surfaces dures comprenant un agent de gonflement de souillure et un agent epaississant
AU2001280605A AU2001280605A1 (en) 2000-07-19 2001-07-18 Cleaning compositions
DE60120517T DE60120517T2 (de) 2000-07-19 2001-07-18 Reinigungsmittelzusammensetzungen
EP01959010A EP1305392B1 (fr) 2000-07-19 2001-07-18 Compositions nettoyantes
JP2002512330A JP2004519527A (ja) 2000-07-19 2001-07-18 洗浄性組成物
PCT/US2001/022708 WO2002006437A1 (fr) 2000-07-19 2001-07-18 Compositions nettoyantes
ES04023010T ES2265133T3 (es) 2000-07-19 2001-07-18 Composiciones limpiadoras.
AU2001280606A AU2001280606A1 (en) 2000-07-19 2001-07-18 Gel form automatic dishwashing compositions, methods of preparation and use thereof
EP04023010A EP1493803B1 (fr) 2000-07-19 2001-07-18 Compositions de nettoyage
AU2001280607A AU2001280607A1 (en) 2000-07-19 2001-07-18 Cleaning compositions
ES01959008T ES2280389T3 (es) 2000-07-19 2001-07-18 Composiciones limpiadoras.
MXPA03000489A MXPA03000489A (es) 2000-07-19 2001-07-18 Composiciones limpiadoras.
US09/910,281 US20020037822A1 (en) 2000-07-19 2001-07-19 Cleaning composition
US09/909,233 US20020037817A1 (en) 2000-07-19 2001-07-19 Cleaning composition
US09/909,403 US6683036B2 (en) 2000-07-19 2001-07-19 Cleaning composition
US10/764,931 US20040157763A1 (en) 2000-07-19 2004-01-26 Cleaning composition
US11/151,027 US20050233925A1 (en) 2000-07-19 2005-06-13 Cleaning composition
US11/192,563 US7304023B2 (en) 2000-02-17 2005-07-29 Detergent product
US11/212,221 US7229955B2 (en) 2000-02-17 2005-08-26 Detergent product
JP2012238209A JP2013067802A (ja) 2000-02-17 2012-10-29 洗剤製品

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP00870023 2000-02-17
EP00870124A EP1126070B1 (fr) 2000-02-17 2000-06-09 Sachet avec additives pour le linge
PCT/US2000/019619 WO2002008370A2 (fr) 2000-07-19 2000-07-19 Composition de nettoyage
PCT/US2000/020255 WO2002008371A2 (fr) 2000-02-17 2000-07-25 Composition de lavage

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WO2002008371A2 true WO2002008371A2 (fr) 2002-01-31
WO2002008371A3 WO2002008371A3 (fr) 2008-05-15

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PCT/US2000/032533 WO2001060966A1 (fr) 2000-02-17 2000-11-29 Produit detergent
PCT/US2001/004694 WO2001061099A1 (fr) 2000-02-17 2001-02-13 Sachet d'additifs de blanchisserie

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JP (3) JP2005507432A (fr)
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AR (2) AR028508A1 (fr)
AT (1) ATE369417T1 (fr)
AU (2) AU2001218076A1 (fr)
BR (2) BR0017112B1 (fr)
CA (2) CA2397241C (fr)
DE (1) DE60035902T2 (fr)
ES (1) ES2290059T3 (fr)
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6557732B2 (en) 2000-07-19 2003-05-06 The Procter & Gamble Company Detergent pack
EP1443098A2 (fr) * 2000-11-27 2004-08-04 The Procter & Gamble Company Produit pour faire la vaisselle
GB2436835A (en) * 2005-12-02 2007-10-10 Korea Res Inst Of Bioscience Method for cloning and expressing a target gene by homologous recombination
US7648951B2 (en) 2000-11-27 2010-01-19 The Procter & Gamble Company Dishwashing method
US8156713B2 (en) 2000-11-27 2012-04-17 The Procter & Gamble Company Detergent products, methods and manufacture
EP2443222A2 (fr) * 2009-06-15 2012-04-25 Ecolab USA Inc. Produits de nettoyage hautement alcalins à base de solvant, système de nettoyage et leurs procédés d'utilisation pour le nettoyage de salissures à base de matière grasse à teneur nulle en matière grasse trans
WO2012057643A1 (fr) 2010-10-28 2012-05-03 Instytut Immunologii i Terapii Doświadczalnej PAN Procédé de production de préparations de bactériophages comprenant une purification effectuée par chromatographie d'affinité
US8283300B2 (en) 2000-11-27 2012-10-09 The Procter & Gamble Company Detergent products, methods and manufacture
EP1666579B2 (fr) † 2004-11-22 2012-11-28 The Procter & Gamble Company Poche contenant du liquide soluble dans l'eau
US8367599B2 (en) * 2001-03-16 2013-02-05 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Dishwashing composition with particles
US8431517B2 (en) * 2004-09-28 2013-04-30 The Procter & Gamble Company Surface corrosion protection detergent compositions containing polyvalent metal compounds and high levels of low foaming, nonionic surfactants
EP2940116A1 (fr) * 2014-04-30 2015-11-04 The Procter and Gamble Company Composition détergente
US20150315529A1 (en) * 2013-01-14 2015-11-05 Henkel Ag & Co. Kgaa Low-water to water-free liquid cleaning agent
EP2850167A4 (fr) * 2012-05-14 2015-11-18 Ecolab Usa Inc Solution de retrait d'étiquette pour des bouteilles de boisson consignées
US9487735B2 (en) 2012-05-14 2016-11-08 Ecolab Usa Inc. Label removal solution for low temperature and low alkaline conditions
US9630206B2 (en) 2005-05-12 2017-04-25 Innovatech, Llc Electrosurgical electrode and method of manufacturing same
US10982373B2 (en) 2016-06-09 2021-04-20 Conopco, Inc. Laundry liquid mixing apparatus
US11131055B2 (en) 2018-02-26 2021-09-28 Conopco, Inc. Methods and system for monitoring and replenishing one or more laundry components
US11807974B2 (en) 2017-10-05 2023-11-07 Conopco, Inc. Methods and devices for individualized laundry
US11910982B2 (en) 2019-11-01 2024-02-27 Conopco Inc. Recyclable auto-dosing container

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2443113C (fr) 2001-05-14 2009-12-01 The Procter & Gamble Company Produit de nettoyage comprenant trois zones distinctes
US6521581B1 (en) 2001-12-14 2003-02-18 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Water-soluble package with multiple distinctly colored layers of liquid laundry detergent
GB2387598A (en) * 2002-04-20 2003-10-22 Reckitt Benckiser Nv Water-soluble container and a process for its preparation
DE602004007774T2 (de) * 2003-03-11 2008-04-30 Reckitt Benckiser N.V. Verpackung enthaltend wasch- oder reinigungsmittel
DE102004019138A1 (de) * 2004-04-16 2005-11-10 Henkel Kgaa Bleichmittelhaltiges Wasch- oder Reinigungsmittel in wasserlöslicher oder wasserdispergierbarer Portionsverpackung
GB2417250A (en) * 2004-08-20 2006-02-22 Reckitt Benckiser Nv Multi-chamber bottle containg a liquid detergent composition
ES2340798T3 (es) 2005-02-17 2010-06-09 The Procter And Gamble Company Composicion para el cuidado de tejidos.
US20090233830A1 (en) * 2008-03-14 2009-09-17 Penny Sue Dirr Automatic detergent dishwashing composition
GB0811399D0 (en) * 2008-06-20 2008-07-30 Edwards David B Cushion Pack
EP2210520A1 (fr) * 2009-01-22 2010-07-28 The Procter & Gamble Company Paquet comprenant un matériau adhésif de fourniture de parfum
US8188027B2 (en) 2009-07-20 2012-05-29 The Procter & Gamble Company Liquid fabric enhancer composition comprising a di-hydrocarbyl complex
US20110240510A1 (en) * 2010-04-06 2011-10-06 Johan Maurice Theo De Poortere Optimized release of bleaching systems in laundry detergents
JP5883294B2 (ja) * 2011-11-22 2016-03-09 菱江化学株式会社 漂白剤、洗浄漂白剤及び殺菌剤
EP2746381A1 (fr) * 2012-12-21 2014-06-25 The Procter & Gamble Company Kit de nettoyage
DE102013004428A1 (de) 2013-03-15 2014-09-18 Clariant International Ltd. Verfahren zum Waschen und Reinigen von Textilien
CN103408119A (zh) * 2013-08-05 2013-11-27 东华大学 一种用于印染废水的快速无机絮凝脱色剂及其制备方法和应用
CN103408118A (zh) * 2013-08-05 2013-11-27 东华大学 一种絮凝氧化处理印染废水的方法
EP2857487A1 (fr) 2013-10-07 2015-04-08 WeylChem Switzerland AG Poche à compartiments multiples comprenant des compositions de nettoyage, processus de lavage et utilisation de produits de lavage et de nettoyage de textiles et plats
EP2857485A1 (fr) 2013-10-07 2015-04-08 WeylChem Switzerland AG Poche à compartiments multiples comprenant des compositions de nettoyage sans alkanolamine, processus de lavage et utilisation de produits de lavage et de nettoyage de textiles et plats
EP2857486A1 (fr) 2013-10-07 2015-04-08 WeylChem Switzerland AG Poche à compartiments multiples comprenant des compositions de nettoyage, processus de lavage et utilisation de produits de lavage et de nettoyage de textiles et plats
BR112017007583A2 (pt) * 2014-10-17 2018-01-30 Basf Se recipiente, e, processo para fabricação de um recipiente ou um compartimento de um recipiente.
PL3237672T3 (pl) * 2014-12-23 2020-04-30 Electrolux Appliances Aktiebolag Sposób obsługiwania pralki do materiałów pranych z wykorzystaniem pakietu dawkowego oraz pralka do materiałów pranych
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EP3342846B1 (fr) * 2016-12-31 2020-04-08 Grupa Inco S.A. Capsule auto-dissoluble pour la préparation de solutions de lavage
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DE102019126124A1 (de) * 2019-09-27 2021-04-01 Henkel Ag & Co. Kgaa Verfahren zur Herstellung Tensid enthaltender Zusammensetzungen in einem sequenziellen Verfahren
EP4263779A1 (fr) * 2020-12-21 2023-10-25 Unilever IP Holdings B.V. Composition de traitement de linge
EP4279571A1 (fr) * 2022-05-19 2023-11-22 The Procter & Gamble Company Composition de lavage comprenant des spores

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1945038A1 (de) * 1969-09-05 1971-03-11 Miele & Cie Verfahren zum Reinigen von wasserunloeslichen Verschmutzungen in Geschirrspuelmaschinen
EP0460810A1 (fr) * 1990-05-07 1991-12-11 Colgate-Palmolive Company (a Delaware corporation) Composition détergente à base liquide non-aqueuse pour lave vaisselle automatique
US5102573A (en) * 1987-04-10 1992-04-07 Colgate Palmolive Co. Detergent composition
WO1994028108A1 (fr) * 1993-06-01 1994-12-08 Ecolab Inc. Nettoyant epaissi pour surfaces dures
WO1995006102A1 (fr) * 1993-08-27 1995-03-02 Colgate-Palmolive Company Microemulsion liquide non aqueuse
US5750487A (en) * 1993-04-12 1998-05-12 Colgate-Palmolive Co. Tricritical point compositions
WO1999024539A1 (fr) * 1997-11-10 1999-05-20 The Procter & Gamble Company Procede pour ramollir des salissures sur des surfaces dures
WO1999053003A1 (fr) * 1998-04-16 1999-10-21 Minnesota Mining And Manufacturing Company Composition de produit chimique de nettoyage

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL266614A (fr) * 1960-07-07
US4410441A (en) * 1982-04-26 1983-10-18 Lever Brothers Company Product for treating fabrics in a washing machine
DE3326249A1 (de) * 1983-07-21 1985-01-31 Henkel Kgaa Wasch-, spuel- oder reinigungsmittelverpackung
US4743394A (en) * 1984-03-23 1988-05-10 Kaufmann Edward J Concentrated non-phosphate detergent paste compositions
GB8605734D0 (en) * 1986-03-07 1986-04-16 Unilever Plc Dispensing treatment agents
US4765916A (en) * 1987-03-24 1988-08-23 The Clorox Company Polymer film composition for rinse release of wash additives
US4973416A (en) * 1988-10-14 1990-11-27 The Procter & Gamble Company Liquid laundry detergent in water-soluble package
TR24867A (tr) * 1989-08-23 1992-07-01 Unilever Nv CAMASIR MUAMELE MAMULü
DE4009532A1 (de) * 1990-03-24 1991-09-26 Henkel Kgaa Waschmittel-formkoerper
EP0752466A1 (fr) * 1995-07-05 1997-01-08 The Procter & Gamble Company Compositions détergentes non-aqueuses contenant un système effervescent
JPH11514027A (ja) * 1996-06-28 1999-11-30 ザ、プロクター、エンド、ギャンブル、カンパニー コートされた粒子を含有している非水性液体クリーニング組成物
JP4015727B2 (ja) * 1997-10-21 2007-11-28 ディバーシー・アイピー・インターナショナル・ビー・ヴイ 洗浄助剤組成物

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1945038A1 (de) * 1969-09-05 1971-03-11 Miele & Cie Verfahren zum Reinigen von wasserunloeslichen Verschmutzungen in Geschirrspuelmaschinen
US5102573A (en) * 1987-04-10 1992-04-07 Colgate Palmolive Co. Detergent composition
EP0460810A1 (fr) * 1990-05-07 1991-12-11 Colgate-Palmolive Company (a Delaware corporation) Composition détergente à base liquide non-aqueuse pour lave vaisselle automatique
US5750487A (en) * 1993-04-12 1998-05-12 Colgate-Palmolive Co. Tricritical point compositions
WO1994028108A1 (fr) * 1993-06-01 1994-12-08 Ecolab Inc. Nettoyant epaissi pour surfaces dures
WO1995006102A1 (fr) * 1993-08-27 1995-03-02 Colgate-Palmolive Company Microemulsion liquide non aqueuse
WO1999024539A1 (fr) * 1997-11-10 1999-05-20 The Procter & Gamble Company Procede pour ramollir des salissures sur des surfaces dures
WO1999053003A1 (fr) * 1998-04-16 1999-10-21 Minnesota Mining And Manufacturing Company Composition de produit chimique de nettoyage

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6557732B2 (en) 2000-07-19 2003-05-06 The Procter & Gamble Company Detergent pack
EP1479756A2 (fr) * 2000-11-27 2004-11-24 The Procter & Gamble Company Procédé pour laver la vaisselle
US8156713B2 (en) 2000-11-27 2012-04-17 The Procter & Gamble Company Detergent products, methods and manufacture
US8357647B2 (en) 2000-11-27 2013-01-22 The Procter & Gamble Company Dishwashing method
EP1479756A3 (fr) * 2000-11-27 2004-12-01 The Procter & Gamble Company procédé pour laver la vaisselle
US8658585B2 (en) 2000-11-27 2014-02-25 Tanguy Marie Louise Alexandre Catlin Detergent products, methods and manufacture
US8518866B2 (en) 2000-11-27 2013-08-27 The Procter & Gamble Company Detergent products, methods and manufacture
US7648951B2 (en) 2000-11-27 2010-01-19 The Procter & Gamble Company Dishwashing method
EP1443098A3 (fr) * 2000-11-27 2004-09-08 The Procter & Gamble Company Produit pour faire la vaisselle
EP1443098A2 (fr) * 2000-11-27 2004-08-04 The Procter & Gamble Company Produit pour faire la vaisselle
US8283300B2 (en) 2000-11-27 2012-10-09 The Procter & Gamble Company Detergent products, methods and manufacture
US8250837B2 (en) 2000-11-27 2012-08-28 The Procter & Gamble Company Detergent products, methods and manufacture
US8367599B2 (en) * 2001-03-16 2013-02-05 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Dishwashing composition with particles
US8431517B2 (en) * 2004-09-28 2013-04-30 The Procter & Gamble Company Surface corrosion protection detergent compositions containing polyvalent metal compounds and high levels of low foaming, nonionic surfactants
EP1666579B2 (fr) † 2004-11-22 2012-11-28 The Procter & Gamble Company Poche contenant du liquide soluble dans l'eau
US11246645B2 (en) 2005-05-12 2022-02-15 Innovatech, Llc Electrosurgical electrode and method of manufacturing same
US9630206B2 (en) 2005-05-12 2017-04-25 Innovatech, Llc Electrosurgical electrode and method of manufacturing same
US10463420B2 (en) 2005-05-12 2019-11-05 Innovatech Llc Electrosurgical electrode and method of manufacturing same
GB2436835B (en) * 2005-12-02 2008-04-30 Korea Res Inst Of Bioscience Method for cloning and expressing target gene by homologous recombination
GB2436835A (en) * 2005-12-02 2007-10-10 Korea Res Inst Of Bioscience Method for cloning and expressing a target gene by homologous recombination
EP2443222A2 (fr) * 2009-06-15 2012-04-25 Ecolab USA Inc. Produits de nettoyage hautement alcalins à base de solvant, système de nettoyage et leurs procédés d'utilisation pour le nettoyage de salissures à base de matière grasse à teneur nulle en matière grasse trans
EP2443222A4 (fr) * 2009-06-15 2013-07-03 Ecolab Usa Inc Produits de nettoyage hautement alcalins à base de solvant, système de nettoyage et leurs procédés d'utilisation pour le nettoyage de salissures à base de matière grasse à teneur nulle en matière grasse trans
WO2012057643A1 (fr) 2010-10-28 2012-05-03 Instytut Immunologii i Terapii Doświadczalnej PAN Procédé de production de préparations de bactériophages comprenant une purification effectuée par chromatographie d'affinité
US9951302B2 (en) 2012-05-14 2018-04-24 Ecolab Usa Inc. Label removal solution for low temperature and low alkaline conditions
US9487735B2 (en) 2012-05-14 2016-11-08 Ecolab Usa Inc. Label removal solution for low temperature and low alkaline conditions
US9856434B2 (en) 2012-05-14 2018-01-02 Ecolab Usa Inc. Label removal solution for returnable beverage bottles
EP2850167A4 (fr) * 2012-05-14 2015-11-18 Ecolab Usa Inc Solution de retrait d'étiquette pour des bouteilles de boisson consignées
US10597615B2 (en) 2012-05-14 2020-03-24 Ecolab Usa Inc. Label removal solution for low temperature and low alkaline conditions
US20150315529A1 (en) * 2013-01-14 2015-11-05 Henkel Ag & Co. Kgaa Low-water to water-free liquid cleaning agent
EP2940116A1 (fr) * 2014-04-30 2015-11-04 The Procter and Gamble Company Composition détergente
WO2015167837A1 (fr) * 2014-04-30 2015-11-05 The Procter & Gamble Company Composition de détergent
US10190078B2 (en) 2014-04-30 2019-01-29 The Procter & Gamble Company Detergent
US10982373B2 (en) 2016-06-09 2021-04-20 Conopco, Inc. Laundry liquid mixing apparatus
US11807974B2 (en) 2017-10-05 2023-11-07 Conopco, Inc. Methods and devices for individualized laundry
US11131055B2 (en) 2018-02-26 2021-09-28 Conopco, Inc. Methods and system for monitoring and replenishing one or more laundry components
US11910982B2 (en) 2019-11-01 2024-02-27 Conopco Inc. Recyclable auto-dosing container

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JP2005507432A (ja) 2005-03-17
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JP2013067802A (ja) 2013-04-18
DE60035902T2 (de) 2008-04-17
DE60035902D1 (de) 2007-09-20
WO2001061099A1 (fr) 2001-08-23
EP1255807A1 (fr) 2002-11-13
ES2290059T3 (es) 2008-02-16
AU2001218076A1 (en) 2001-08-27
CA2397241A1 (fr) 2001-08-23
CN1401030A (zh) 2003-03-05
MXPA02008067A (es) 2003-02-27
BR0108441A (pt) 2002-12-17
AR035167A1 (es) 2004-05-05
CN1434857A (zh) 2003-08-06
ATE369417T1 (de) 2007-08-15
EP1255807B1 (fr) 2007-08-08
WO2001060966A1 (fr) 2001-08-23
CN1225537C (zh) 2005-11-02
WO2001061099A8 (fr) 2002-05-16
JP2004500460A (ja) 2004-01-08
AR028508A1 (es) 2003-05-14
BR0017112A (pt) 2003-01-14
EP1255887A2 (fr) 2002-11-13
WO2001060966A8 (fr) 2003-01-03
AU2001238240A1 (en) 2001-08-27
WO2002008371A3 (fr) 2008-05-15
MXPA02008065A (es) 2003-02-27
BR0017112B1 (pt) 2011-06-14
JP5000060B2 (ja) 2012-08-15

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