WO2000033389A1 - Light emitting device with phosphor having high luminous efficacy - Google Patents

Light emitting device with phosphor having high luminous efficacy Download PDF

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Publication number
WO2000033389A1
WO2000033389A1 PCT/US1999/028279 US9928279W WO0033389A1 WO 2000033389 A1 WO2000033389 A1 WO 2000033389A1 US 9928279 W US9928279 W US 9928279W WO 0033389 A1 WO0033389 A1 WO 0033389A1
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WO
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Prior art keywords
lamp
light
light emitting
spectrum
blue light
Prior art date
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Ceased
Application number
PCT/US1999/028279
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English (en)
French (fr)
Inventor
Lionel Monty Levinson
Alok Mani Srivastava
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General Electric Co
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General Electric Co
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Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Priority to EP99964012.1A priority Critical patent/EP1051758B1/en
Priority to JP2000585941A priority patent/JP5085815B2/ja
Priority to AU20338/00A priority patent/AU2033800A/en
Publication of WO2000033389A1 publication Critical patent/WO2000033389A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80—Constructional details
    • H10H20/85—Packages
    • H10H20/851—Wavelength conversion means
    • H10H20/8511—Wavelength conversion means characterised by their material, e.g. binder
    • H10H20/8512—Wavelength conversion materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/7734—Aluminates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/77342—Silicates
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional radiating surfaces
    • H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805—Shape
    • H01L2224/4809—Loop shape
    • H01L2224/48091—Arched
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481—Disposition
    • H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481—Disposition
    • H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48257—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a die pad of the item
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732—Location after the connecting process
    • H01L2224/73251—Location after the connecting process on different surfaces
    • H01L2224/73265—Layer and wire connectors
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80—Constructional details
    • H10H20/84—Coatings, e.g. passivation layers or antireflective coatings
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80—Constructional details
    • H10H20/882—Scattering means

Definitions

  • This invention relates generally to light emitting devices, and more particularly to a lamp which produces white light from a light emitting diode and a phosphor composition.
  • Nichia Chemical Industries Ltd. in Japan has produced light emitting diodes and laser diodes which emit light in the blue and ultraviolet (UV) wavelengths.
  • Nichia has also produced a light source which includes a blue light emitting diode (LED) and a phosphor.
  • the phosphor yttrium-aluminum-garnet doped with trivalent cerium, converts a portion of the blue light into a broad yellow emission.
  • the blue and yellow light together produce white light having a color temperature of about 6ooo- 8ooo° K and a color rendering index (CRI) of about 77.
  • CRI color rendering index
  • the Nichia light source however, has a device luminous efficacy of only about 5 lumens per watt of input electric power.
  • the luminous flux output by the Nichia lamp is relatively small, particularly if the input electric power is limited, e.g. by battery power. It would be desirable, therefore, to have a light source with a higher device luminous efficacy and luminous flux output for improved performance.
  • a lamp comprises a light emitting element such as a light emitting diode or a laser diode which emits blue light, and a phosphor composition which absorbs the blue light having a first spectrum from the light emitting element and emits light having a second spectrum.
  • the phosphor composition comprises at least one of Ba 2 MgSi 2 O 7 :Eu 2+ ; Ba 2 SiO 4 :Eu 2+ ; and (Sr,Ca,Ba)(Al,Ga) 2 S 4 :Eu 2+ .
  • the invention also relates to a light emitting element which emits blue light, and a phosphor composition which absorbs the blue light from the light emitting element having a first spectrum and emits light having a second spectrum, wherein the spectral luminous efficacy of light emitted by the lamp is at least 550 lumens per watt of radiant power.
  • the high spectral luminous efficacy of the output spectrum efficiently converts the power input to the lamp into lumens to provide a high brightness.
  • the device luminous efficacy of the lamp can be 35-45 lumens per watt of input electric power or more.
  • the lamp is particularly useful as a flashlight where brightness may be an important characteristic of the lamp, input power may be limited, and color rendering is less important.
  • Figure 1 is a graph of spectral luminous efficiency which shows the sensitivity of the human eye to different wavelengths of light
  • Figure 2 is a diagram which illustrates the relationship between input power, radiant power, and luminous flux for a light source;
  • Figure 3 is a drawing of a typical light emitting diode;
  • Figure 4 illustrates a lamp which includes a phosphor composition and a light source such as a light emitting diode;
  • Figure 5 is a graph of the emission spectrum of the phosphor Ba 2 MgSi 2 O 7 :Eu 2+ ;
  • Figure 6 is a graph of the emission spectrum of the phosphor Ba 2 SiO 4 :Eu 2+ ;
  • Figure 7 is a graph of the emission spectrum of the phosphor (Sr,Ca,Ba)(Al,Ga) 2 S 4 :Eu 2+ .
  • the human eye is more sensitive to certain wavelengths of light than others. This phenomenon was studied carefully by the Commission International de l'Eclairage (CIE), which created a standard in 1931 known as "the standard observer” based on a large number of observations of the responses of the human eye to light.
  • CIE Commission International de l'Eclairage
  • the standard observer represents the average values of eye sensitivity of a number of individuals as a function of wavelength, and has a maximum value at 555 nanometers (nm), and falls to zero at about 380 nm (ultraviolet) and 780 nm (infrared).
  • the variable sensitivity of the human eye, as represented in the standard observer is plotted in Figure 1, which shows the spectral luminous efficiency V( ⁇ ) as a function of wavelength ⁇ .
  • Luminous flux refers to the time rate of flow of radiant energy (i.e. radiant power) evaluated according to its capacity to produce visual sensation.
  • Radiant power refers to the energy per unit time radiated by the light source.
  • Luminous flux is different from the radiant power because of the variable sensitivity of the eye to different wavelengths of light. For example, a green light source which emits the same radiant power as red light source will have a higher luminous flux because the eye is more sensitive to green light than to red light. This principle is illustrated in Figure 2, which shows the luminous flux as a function of wavelength produced by a radiant power spectrum which is equal for all visible wavelengths.
  • the luminous flux L can be calculated by integrating the product of the radiant power P( ⁇ ) and the luminous efficiency V( ⁇ ) over the desired wavelength range as follows:
  • the coefficient k is the maximum luminous efficacy factor, equal to 683 lumens per watt (lpw) at 555 nm.
  • the maximum luminous efficiency factor k converts watts into lumens.
  • the spectral luminous efficacy quantifies the effectiveness of an output spectrum at generating lumens from radiant power.
  • the spectral luminous efficacy is conventionally defined as the luminous flux divided by the radiant power output by a light source.
  • An output spectrum containing only the wavelength 555 nm has the greatest luminous efficacy, i.e. 683 lumens per watt.
  • the spectral luminous efficacy of the visible light emitted by an incandescent bulb is typically about 300 lumens per watt.
  • the output spectrum of a lamp is designed to provide a h gh spectral luminous efficacy by concentrating the output spectrum around the most sensitive region of the luminous efficiency curve of Figure l.
  • equation (l) which represents the luminous flux output by the light source, is increased without increasing the power input to the light source.
  • the light source comprises a light emitting device, such as an LED or a laser diode, which emits blue light and a phosphor which absorbs the blue light and emits green light.
  • the phosphor is selected to emit green light having an output spectrum concentrated on the most sensitive region of the luminous efficiency curve of Figure l.
  • the blue light emitted by the LED typically has an emission peak at a wavelength greater than 400, typically between 400 and 520 nm, more typically between about 450 and about 470 nm.
  • the full width half maximum value of the blue light emitted by the LED is typically less than about 70 nm, more typically less than about 50 nm, optionally less than about 20 nm.
  • a blue LED may be manufactured by depositing various layers of semiconductor materials on a substrate.
  • a know group of semiconductor materials which is useful in forming light-emitting devices is the gallium nitride (GaN) system.
  • the gallium nitride system refers to semiconductor materials comprising one or more of the group III nitrides, gallium nitride (GaN), aluminum nitride (AlN), and indium nitride (InN).
  • the GaN system allows various wavelengths of light, particularly the shorter wavelengths, to be produced based on the relative amounts of GaN, AlN, and InN in the composition.
  • the GaN system also typically provides the advantages of a relatively high radiant power output, and a smaller temperature sensitivity, as compared with conventional green emitting LEDs.
  • FIG. 3 illustrates an example of an LED 10.
  • the exemplary LED includes a substrate 20, an n-type GaN layer 30, a layer 40 of indium gallium nitride (InGaN) which may form a single or multiple quantum well, a p-type aluminum gallium nitride (AlGaN) layer 50, a p-type GaN layer 60, a positive contact 70, and a negative contact 80.
  • the various semiconductor layers 30, 40, 50, and 60 are typically deposited on one another by chemical vapor deposition (CVD).
  • each layer may comprise In x GayAl " ( ⁇ - ⁇ - y )N, where o ⁇ x ⁇ i and o ⁇ y ⁇ i.
  • the invention encompasses other light emitting devices such as laser diodes.
  • semiconductor materials other than the GaN system can be used, such as gallium arsenide (GaAs) and its alloys, silicon, and silicon carbide (SiC).
  • LEDs and laser diodes which emit in the blue wavelengths are known in the art. See, for example, U. S. Patent Nos. 5,813,753; 5,813,752; 5,338,944; 5,416,342; 5,604,763; and 5,644,584. LEDs and laser diodes which emit blue and UN radiation are also described in Shuji ⁇ akamura and Gerhard Fasol, "The Blue Laser Diode” (1997).
  • FIG. 4 illustrates a lighting apparatus according to an exemplary embodiment of the invention.
  • the lighting apparatus 200 includes a light source 210 which may be an LED or a laser diode, for example, powered by leads 212, 214.
  • the light source 210 and a portion of the leads 212, 214 are encapsulated within a transmissive body 220 which may comprise a silicone, glass, or plastic material, for example.
  • the phosphor composition 230 may be formed on an outer surface of the transmissive body 230, as shown in Figure 4, or directly on the light source 210 within the transmissive body 230.
  • the phosphor composition may be added to a liquid suspension medium, such as the nitrocellulose/butyl acetate binder and solvent solution used in commercial lacquers. Many other liquids including water with a suitable dispersant and thickener or binder, such as polyethylene oxide, can be used.
  • the phosphor-containing suspension is painted or coated or otherwise applied on the LED and dried.
  • the lighting apparatus 200 may also include a plurality of scattering particles, such as titanium dioxide (TiO 2 ) or aluminum oxide (Al 2 O 3 ) particles, embedded in the transmissive body 230, for example if a laser diode is used as the light source 210.
  • a plurality of scattering particles such as titanium dioxide (TiO 2 ) or aluminum oxide (Al 2 O 3 ) particles, embedded in the transmissive body 230, for example if a laser diode is used as the light source 210.
  • the LED Upon application of a current to the leads 212, 214, the LED produces a blue light which is converted by the phosphor composition 230 to green light.
  • the blue light emitted by the LED or laser diode can efficiently excite the green- emitting phosphors.
  • one or more of the following phosphors are used: Ba 2 MgSi 2 O 7 :Eu 2+ ; Ba 2 SiO 4 :Eu 2+ ; and (Sr,Ca,Ba)(Al,Ga) 2 S 4 :Eu 2+ .
  • x, y, and z are all nonzero.
  • x and y are both nonzero.
  • the green emitting phosphors preferably have peak emissions between about 500 nm and about 555 nm.
  • Figures 5, 6, and 7 show the emission spectra for the three green phosphors disclosed herein. As shown in the Figures, the emission spectra of the green phosphors coincide to a large extent with the most sensitive region of the spectral luminous efficacy curve of Figure 1.
  • Ba 2 MgSi 2 O 7 :Eu 2+ has a peak emission at about 495-505 nm, typically about 500 nm
  • Ba 2 SiO 4 :Eu 2+ has a peak emission at about 500-510 nm, typically about 505 nm
  • (Sr,Ca,Ba)(Al,Ga) 2 S 4 :Eu 2+ has a peak emission at about 535-545 nm, typically about 540 ran.
  • the resulting spectral luminous efficacy of the lamp using one or more of these phosphors, assuming substantially all of the blue light is absorbed by the phosphor, is typically greater than 550 lumens per watt of radiant power.
  • the device -luminous efficacy defined as the luminous flux output by the lamp divided by the electric power input to the lamp.
  • the device luminous efficacy of the lamp takes into account the spectral luminous efficacy of the output spectrum as well as three additional factors.
  • the device efficiency represents the radiant power output by the LED divided by the electric power input to the LED. For a typical blue LED, the device efficiency is about 10%.
  • the quantum efficiency of the phosphor represents a loss associated with the transfer of energy from the absorbed photons to the emitted photons. The quantum efficiency is defined as the number of photons emitted by the phosphor divided by the number of photons absorbed by the phosphor.
  • the quantum efficiency is typically about 80%.
  • Third, there is an energy loss associated with the decrease in frequency of the emitted light affected by the phosphor equal to h ⁇ v, where h is Plank's constant and ⁇ v is the change in frequency of the light. For light absorbed at 450 nm and emitted at 555 nm, the emitted energy is 450/555 81% of the absorbed energy.
  • the device luminous efficacy (DLE) for a typical lamp is:
  • This range of device luminous efficacy represents a significant increase over known LED lamps.
  • conventional green-emitting LEDs typically produce no more than 30 lumens per watt (lpw) of input electric power.
  • the device luminous efficacy can be increased still further by utilizing a laser diode, which may have a device efficiency of 40%, for example. Assuming the other variables remain substantially the same, the device luminous efficacy is increased to about 143-177 lumens per watt of input electric power.
  • the output light has a spectrum which is concentrated around the most sensitive region of the spectral luminous efficiency curve of Figure 1, producing a high spectral luminous efficacy, e.g. at least 550 lpw.
  • the invention thus provides the advantage of a significantly increased luminous flux output without any increase in the electric power input to the LED or laser diode.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Luminescent Compositions (AREA)
  • Semiconductor Lasers (AREA)
  • Led Device Packages (AREA)
PCT/US1999/028279 1998-11-30 1999-11-30 Light emitting device with phosphor having high luminous efficacy Ceased WO2000033389A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP99964012.1A EP1051758B1 (en) 1998-11-30 1999-11-30 Light emitting device with phosphor having high luminous efficacy
JP2000585941A JP5085815B2 (ja) 1998-11-30 1999-11-30 視感度の高い蛍光体による発光デバイス
AU20338/00A AU2033800A (en) 1998-11-30 1999-11-30 Light emitting device with phosphor having high luminous efficacy

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/203,206 US6429583B1 (en) 1998-11-30 1998-11-30 Light emitting device with ba2mgsi2o7:eu2+, ba2sio4:eu2+, or (srxcay ba1-x-y)(a1zga1-z)2sr:eu2+phosphors
US09/203,206 1998-11-30

Publications (1)

Publication Number Publication Date
WO2000033389A1 true WO2000033389A1 (en) 2000-06-08

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Country Status (6)

Country Link
US (2) US6429583B1 (enExample)
EP (1) EP1051758B1 (enExample)
JP (1) JP5085815B2 (enExample)
CN (1) CN100385688C (enExample)
AU (1) AU2033800A (enExample)
WO (1) WO2000033389A1 (enExample)

Cited By (47)

* Cited by examiner, † Cited by third party
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US6417019B1 (en) 2001-04-04 2002-07-09 Lumileds Lighting, U.S., Llc Phosphor converted light emitting diode
WO2002054502A1 (de) * 2000-12-28 2002-07-11 Tridonic Optoelectronics Gmbh Lichtquelle mit einem lichtemittlierenden element
US6501102B2 (en) 1999-09-27 2002-12-31 Lumileds Lighting, U.S., Llc Light emitting diode (LED) device that produces white light by performing phosphor conversion on all of the primary radiation emitted by the light emitting structure of the LED device
JP2003045206A (ja) * 2001-05-24 2003-02-14 Matsushita Electric Ind Co Ltd 照明光源
US6603258B1 (en) 2000-04-24 2003-08-05 Lumileds Lighting, U.S. Llc Light emitting diode device that emits white light
WO2003071610A1 (en) * 2002-02-25 2003-08-28 Mitsubishi Cable Industries, Ltd. Light emitting device and lighting fixture using it
US6642618B2 (en) 2000-12-21 2003-11-04 Lumileds Lighting U.S., Llc Light-emitting device and production thereof
US6680569B2 (en) 1999-02-18 2004-01-20 Lumileds Lighting U.S. Llc Red-deficiency compensating phosphor light emitting device
US6686691B1 (en) 1999-09-27 2004-02-03 Lumileds Lighting, U.S., Llc Tri-color, white light LED lamps
JP2004056045A (ja) * 2002-07-24 2004-02-19 Mitsubishi Chemicals Corp 発光装置及びそれを用いた照明装置
US6696703B2 (en) 1999-09-27 2004-02-24 Lumileds Lighting U.S., Llc Thin film phosphor-converted light emitting diode device
US6765237B1 (en) 2003-01-15 2004-07-20 Gelcore, Llc White light emitting device based on UV LED and phosphor blend
US6791259B1 (en) 1998-11-30 2004-09-14 General Electric Company Solid state illumination system containing a light emitting diode, a light scattering material and a luminescent material
WO2004085570A1 (en) * 2003-03-28 2004-10-07 Korea Research Institute Of Chemical Technology Strontium silicate-based phosphor, fabrication method thereof, and led using the phosphor
US6936857B2 (en) 2003-02-18 2005-08-30 Gelcore, Llc White light LED device
WO2005098972A1 (en) * 2004-04-07 2005-10-20 Lg Innotek Co., Ltd Light emitting device and phosphor for the same
WO2005098973A1 (en) * 2004-04-07 2005-10-20 Lg Innotek Co., Ltd Light emitting device and phosphor for the same
US7064480B2 (en) 2000-07-28 2006-06-20 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Illumination device with at least one led as the light source
US7088038B2 (en) 2003-07-02 2006-08-08 Gelcore Llc Green phosphor for general illumination applications
JP2006261702A (ja) * 2001-05-24 2006-09-28 Matsushita Electric Ind Co Ltd 照明光源
US7125501B2 (en) 2003-04-21 2006-10-24 Sarnoff Corporation High efficiency alkaline earth metal thiogallate-based phosphors
JP2007123927A (ja) * 2006-12-18 2007-05-17 Mitsubishi Cable Ind Ltd 発光装置およびそれを用いた照明装置
US7248310B2 (en) 2001-04-04 2007-07-24 Philips Lumileds Lighting Company, Llc Flat panel energized by blue LED for generating white light
US7274045B2 (en) 2005-03-17 2007-09-25 Lumination Llc Borate phosphor materials for use in lighting applications
JP2007329511A (ja) * 2001-09-03 2007-12-20 Matsushita Electric Ind Co Ltd 半導体発光装置
US7358542B2 (en) 2005-02-02 2008-04-15 Lumination Llc Red emitting phosphor materials for use in LED and LCD applications
US7368179B2 (en) 2003-04-21 2008-05-06 Sarnoff Corporation Methods and devices using high efficiency alkaline earth metal thiogallate-based phosphors
US7422504B2 (en) 2001-09-03 2008-09-09 Matsushita Electric Industrial Co., Ltd. Light-emitting semiconductor device, light-emitting system and method for fabricating light-emitting semiconductor device
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