WO1995010774A1 - Detecteur d'oxyde d'azote - Google Patents

Detecteur d'oxyde d'azote Download PDF

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Publication number
WO1995010774A1
WO1995010774A1 PCT/DE1994/001051 DE9401051W WO9510774A1 WO 1995010774 A1 WO1995010774 A1 WO 1995010774A1 DE 9401051 W DE9401051 W DE 9401051W WO 9510774 A1 WO9510774 A1 WO 9510774A1
Authority
WO
WIPO (PCT)
Prior art keywords
oxide
layer
sensor according
metal oxide
sensor
Prior art date
Application number
PCT/DE1994/001051
Other languages
German (de)
English (en)
Inventor
Heidrun Potthast
Bernd Schumann
Original Assignee
Robert Bosch Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch Gmbh filed Critical Robert Bosch Gmbh
Priority to US08/628,664 priority Critical patent/US5624640A/en
Priority to JP51115295A priority patent/JP3606874B2/ja
Priority to KR1019960701947A priority patent/KR100337102B1/ko
Priority to EP94926095A priority patent/EP0723662B1/fr
Priority to DE59408526T priority patent/DE59408526D1/de
Publication of WO1995010774A1 publication Critical patent/WO1995010774A1/fr

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/0037—NOx
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/005—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods investigating the presence of an element by oxidation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/17—Nitrogen containing
    • Y10T436/177692—Oxides of nitrogen

Definitions

  • the invention relates to a sensor for the detection of nitrogen oxides (NO, NO, NO) according to the preamble of claim 1. It is known to use sensors for determining specific components of a test gas, the sensitive element of which is a semiconductor material whose electrical resistance changes on contact with the specific gas component. Sensors of this type are used in particular for determining the oxygen content in exhaust gases, for example from internal combustion engines, but also for determining methane, carbon monoxide or alcohol. Semiconducting metal oxides, such as tin oxide (SnO), zinc oxide (ZnO), titanium oxide (TiO), or tungsten oxide (WO) are used in particular as semiconductor materials, depending on the purpose.
  • tin oxide SnO
  • ZnO zinc oxide
  • TiO titanium oxide
  • WO tungsten oxide
  • Such a sensor is known, for example, from EP-OS 313 390.
  • the heating device and sensor arrangement are located on one side of a substrate made of aluminum oxide (MO).
  • MO aluminum oxide
  • Tin oxide (SnO) for methane gas, wofram oxide (WO) for carbon monoxide or lanthanum nickel oxide (LaNiO_) for the detection of alcohol is proposed as the semiconducting material.
  • a sensor in which the heating device is integrated in the substrate is known from DE-OS 36 24 217.
  • Aluminum oxide (M O) is again proposed as the material for the substrate, in this case the gas-sensitive semiconductor layer consists of a porous titanium dioxide (TiO), which is enriched with a further metal oxide.
  • TiO porous titanium dioxide
  • the sensor described is intended in particular for regulating the air / fuel ratio in an exhaust gas by measuring the oxygen content.
  • the detection of diesel exhaust gases can be used, for example, to interrupt the supply of outside air, in which diesel exhaust gases were detected, to rooms or vehicles in ventilation or air conditioning systems by means of a control flap.
  • NO, NO nitrogen oxides
  • the object of the present invention is to provide a sensor and a method for its production, which is of simple construction and allows a sufficiently good determination of the proportion of nitrogen oxides in a test gas.
  • the sensor according to the invention can be produced using fundamentally known techniques and is therefore inexpensive. When used, it shows gases containing nitrogen oxide quickly and with good sensitivity, without being influenced by CO, H or CH components present at the same time. It is therefore particularly suitable for use in motor vehicles to control the interior ventilation, which it may interrupt if diesel exhaust gases enter the interior.
  • Advantageous further developments and expedient refinements of the sensor according to the invention and of the method for its production result from the subclaims.
  • the nitrogen dioxide (NO) sensitivity can be adjusted with regard to the specified use.
  • a second coating of the sensor with platinum (Pt) and / or rhodium (Rh) is expediently used to support the desorption of the nitrogen dioxide (NO) formed and the rate of increase and differentiation of the signal with different nitrogen dioxide (NO) concentrations trations to improve.
  • the sensor can detect low NO / NO concentrations common in road traffic with a stable basic resistance without there being a constant increase in resistance and drift.
  • the proposed sensor can be heated up to temperatures of 700 ° C. in order to periodically clean it and to stabilize the surface.
  • the proposed sensor is also well suited for the summary of combustion plants depending on their oxygen content.
  • FIG. 1 to 3 show top views of a sensor according to the invention
  • FIG. 4 shows a side view of the same sensor
  • FIG. 5 shows a view of the same sensor from the underside
  • FIG. 6 shows another embodiment of the sensor in side view
  • FIG. 7 shows another embodiment of the sensor with over side view of the sensitive semiconductor layer arranged intermediate layer.
  • Figure 1 shows a plan view of a proposed sensor, which was designed rod-shaped. It consists of a substrate made of an electrically insulating and heat-resistant material, preferably aluminum oxide (O), to which the further components forming the sensor are applied using thick-film technology. On one surface of the substrate, referred to here as the upper side, two conductor tracks 2 are applied, which are toothed in a comb-like manner at their head ends.
  • O aluminum oxide
  • a semiconducting metal oxide layer 3 is expediently applied in a thickness of 10 to 500 ⁇ m to the conductor tracks 2. It consists of indium oxide (In 0) or tin oxide (SnO), to which a doping element which increases the conductivity is added in concentrations of 0.005 to 0.05 mol /%. Tantalum (Ta), niobium (Nb), antimony (Sb) or tungsten (W), and with indium oxide (In O also tin (Sn), titanium (Ti) or cerium (Ce) can be used as doping element.
  • a divalent element in particular magnesium (Mg), barium (Ba), calcium (Ca), strontium (Sr), zinc (Zn ) or a trivalent element such as aluminum oxide (O) in concentrations of 0.01 to 30% in the metal oxide
  • the metal oxide of layer 3 is further impregnated with a precious metal additive, which consists in particular of palladium (Pd) with additives of platinum (Pt) and / or rhodium (Rh) in a concentration of 0.001 to 0.5 mol%.
  • the palladium (Pd) is used to adjust the sensitivity to nitrogen dioxide (NO).
  • the addition of platinum or rhodium facilitates the desorption of the formed nitrogen dioxide (NO) it improves the rate of rise and the differentiation of the signal with different nitrogen dioxide (NO) concentrations.
  • the sensor can detect low, customary nitrogen oxide / nitrogen dioxide concentrations with a stable basic resistance without there being a constant increase in resistance and drift.
  • a converter layer 4 is advantageously applied over the metal oxide layer 3 in a thickness of 10 to 100 / A. It preferably consists of aluminum oxide (Al 0), titanium oxide (TiO), zirconium oxide (ZrO) or silicon oxide (SiO) with a platinum content of 0.01 to 20%. Their production is based on powdered starting material, which is impregnated with the platinum or the precious metal used or mixed with the platinum-containing metal powder.
  • a heating arrangement 5 which is shown in FIG. 5 as a top view. It essentially consists of a conductor track meandering in the area below the metal oxide layer 3.
  • the principle of operation of the sensor according to the invention is to first convert the nitrogen oxide contained in the test gas into nitrogen dioxide (NO) and then to feed it to the sensitive metal oxide layer 3.
  • the conversion takes place in the converter layer 4 by oxidation of the nitrogen oxide (NO) with the atmospheric oxygen to nitrogen dioxide (N0 ") or nitrous oxide (N" 0).
  • the converter layer 2 2 4 simultaneously fulfills the function of keeping the as yet unconverted nitrogen monoxide (NO) away from the semiconducting metal oxide layer 3.
  • Their thickness should be chosen accordingly so that no nitrogen monoxide (NO) reaches the metal oxide layer.
  • the converter layer 4 serves to combustible components such as carbon monoxide (CO), hydrogen (H) or hydrocarbons contained in the test gas with those contained in the test gas Oxidize oxygen.
  • CO carbon monoxide
  • H hydrogen
  • hydrocarbons contained in the test gas with those contained in the test gas Oxidize oxygen.
  • the converter layer 4 fulfills a further function by storing the nitrogen oxide (NO) or nitrogen dioxide (NO) up to an amount determined by the residence time of the gas molecules above the semiconducting metal oxide layer 3. At low nitrogen oxide (NO) concentrations, this increases the sensitivity of the sensor by converting more NO to NO.
  • the nitrogen dioxide (NO) reaching the - n-conducting - metal oxide layer 3 binds electrons on contact with the surface due to its dipole properties and thus causes an increase in the electrical resistance of the metal oxide layer 3, which is measured in a known manner.
  • a constant current is applied, for example, via the conductor tracks 2; the changes in the voltage required to maintain the constant current after changing the resistance of the metal oxide layer 3 are measured.
  • the sensor 1 to 4 In order to increase the sensitivity of the sensor 1 to 4, it is heated from the underside of the substrate 1 to a temperature of approximately 180 ° to 400 ° C. by means of the heating arrangement 5.
  • the heating increases the conductivity in the metal oxide layer 3. Furthermore, the heating supports the maintenance of the dynamic equilibrium of absorption and desorption. It also accelerates the oxidation of the combustible components contained in the test gas.
  • FIG. 6 Another embodiment of the sensor according to the invention is shown in FIG. 6. It differs from the variant shown in FIGS. 1 to 5 in that an intermediate converter layer 6 is also introduced between the metal oxide layer 3 and the converter layer 4 has been.
  • the first converter layer 4 consists, for example, of aluminum oxide (MO), titanium oxide (TiO), zirconium oxide (ZrO) or silicon oxide (SiO), but preferably has a reduced noble metal content, for example of platinum, of 0.001 to 2%.
  • Their thickness is expediently 10 to 500 / m.
  • mixtures of the oxides mentioned with tin oxide (SnO) or indium oxide (In 0.) can also be used.
  • the intermediate converter layer 6 additionally ensures that all nitrogen oxides (NO) are converted into nitrogen oxide (NO) or nitrous oxide (NO) and that no nitrogen oxides (NO) reach the metal oxide layer 3.
  • the residence time of the nitrogen oxide (NO) or nitrogen dioxide (NO) molecules above the metal oxide layer 3 is increased.
  • the introduction of the intermediate converter layer 6 leads to a functional separation such that the combustible components of the test gas essentially oxidize in the converter layer 4, while the conversion of the nitrogen monoxide (NO) takes place in the intermediate converter layer 6.
  • a structure with two converter layers 4 and 6 is therefore particularly recommended in the case of high concentrations of combustible components in the test gas.
  • Both the intermediate converter layer 6 and the converter layer 4 can also contain components for accelerating the oxidation processes, such as cerium oxide (CeO).
  • CeO cerium oxide
  • the exemplary embodiment according to FIG. 5 shows another possibility for arranging the heating arrangement 5.
  • the heating arrangement 5 is placed, which thus heats the sensor arrangement 1 to 4 from the top.
  • a pore former is expediently admixed to at least one converter layer 4 or 6, so that the temperature of the metal oxide layer 3 can be kept lower than the temperature of the converter layers 4 or 6.
  • An arrangement according to FIG. 5 allows the sensor to be operated at temperatures up to 450 ° C.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Molecular Biology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)

Abstract

Est décrit un détecteur d'oxydes d'azote (NO, NO2, N2O4) dans un gaz d'essai comportant une couche d'oxyde métallique semi-conductrice (3) sur un substrat (10), dont la résistance électrique renseigne sur la concentration en oxyde d'azote (NO, NO2, N2O4) dans le gaz d'essai. Les principaux constituants de ce détecteur sont une couche de conversion (4) appliquée sur la couche d'oxyde métallique (3) et composée d'un matériau provoquant l'oxydation des constituants combustibles du gaz d'essai, laquelle couche de conversion (4) convertit l'oxyde nitrique (NO) du gaz d'essai en dioxyde d'azote (NO2) ou en tétroxyde d'azote (N2O4), lesquels parviennent ensuite à la couche d'oxyde métallique (3). Est également décrit un dispositif de chauffage (5) qui chauffe la couche d'oxyde métallique (3) et la couche de conversion (4). Cette dernière est de préférence formée d'oxyde de titane (TiO2) et/ou d'oxyde de zirconium (ZrO2) et/ou d'oxyde de silicium (SiO2) et/ou d'oxyde d'aluminium (Al2O3) et présente une teneur en platine de 0,01 à 20 % en poids.
PCT/DE1994/001051 1993-10-12 1994-09-14 Detecteur d'oxyde d'azote WO1995010774A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US08/628,664 US5624640A (en) 1993-10-12 1994-09-14 Sensor for detecting nitrogen oxide
JP51115295A JP3606874B2 (ja) 1993-10-12 1994-09-14 窒素酸化物を検出するためのセンサー
KR1019960701947A KR100337102B1 (ko) 1993-10-12 1994-09-14 질소산화물을검출하기위한센서
EP94926095A EP0723662B1 (fr) 1993-10-12 1994-09-14 Detecteur d'oxyde d'azote
DE59408526T DE59408526D1 (de) 1993-10-12 1994-09-14 Sensor zum nachweis von stickoxid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4334672.3 1993-10-12
DE4334672A DE4334672C2 (de) 1993-10-12 1993-10-12 Sensor zum Nachweis von Stickoxid

Publications (1)

Publication Number Publication Date
WO1995010774A1 true WO1995010774A1 (fr) 1995-04-20

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Application Number Title Priority Date Filing Date
PCT/DE1994/001051 WO1995010774A1 (fr) 1993-10-12 1994-09-14 Detecteur d'oxyde d'azote

Country Status (6)

Country Link
US (1) US5624640A (fr)
EP (1) EP0723662B1 (fr)
JP (1) JP3606874B2 (fr)
KR (1) KR100337102B1 (fr)
DE (2) DE4334672C2 (fr)
WO (1) WO1995010774A1 (fr)

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KR100898268B1 (ko) * 2007-10-24 2009-05-18 한국에너지기술연구원 친수성 젖음벽을 구비한 기액 흡수평형 측정 장치
CN104459041A (zh) * 2014-11-28 2015-03-25 苏州东辰林达检测技术有限公司 一种氮氧化物检测试剂及其制备方法

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* Cited by examiner, † Cited by third party
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US6113859A (en) * 1998-02-04 2000-09-05 Korea Institute Of Science And Technology Bar-type NOx gas sensor having WO3 sensing film
KR100898268B1 (ko) * 2007-10-24 2009-05-18 한국에너지기술연구원 친수성 젖음벽을 구비한 기액 흡수평형 측정 장치
CN104459041A (zh) * 2014-11-28 2015-03-25 苏州东辰林达检测技术有限公司 一种氮氧化物检测试剂及其制备方法

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EP0723662A1 (fr) 1996-07-31
KR960705207A (ko) 1996-10-09
EP0723662B1 (fr) 1999-07-21
JP3606874B2 (ja) 2005-01-05
KR100337102B1 (ko) 2002-11-23
US5624640A (en) 1997-04-29
DE4334672C2 (de) 1996-01-11
JPH09503587A (ja) 1997-04-08
DE4334672A1 (de) 1995-04-13
DE59408526D1 (de) 1999-08-26

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