US20030172840A1 - Aqueous printing inks for use in the ink-jet printing method the production and the use on textile fibre materials therof - Google Patents
Aqueous printing inks for use in the ink-jet printing method the production and the use on textile fibre materials therof Download PDFInfo
- Publication number
- US20030172840A1 US20030172840A1 US10/182,937 US18293702A US2003172840A1 US 20030172840 A1 US20030172840 A1 US 20030172840A1 US 18293702 A US18293702 A US 18293702A US 2003172840 A1 US2003172840 A1 US 2003172840A1
- Authority
- US
- United States
- Prior art keywords
- dried
- reactive
- rinsed warm
- sulfolane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
Definitions
- the inkjet printing process is usually carried out using aqueous inks, which are sprayed as small droplets directly onto the substrate.
- aqueous inks which are sprayed as small droplets directly onto the substrate.
- There is a continuous form of the process in which the ink is pressed piezoelectrically through a nozzle at a uniform rate and deflected onto the substrate by an electric field, depending on the pattern to be produced, and there is an uninterrupted inkjet or drop-on-demand process, in which the ink is expelled only where a colored dot is to appear.
- the latter form of the process employs either a piezoelectric crystal or a heated cannula (bubble or thermal jet process) to exert pressure on the ink system and so eject an ink droplet.
- EP-A 0 886 000 and EP-A 0 885 998, EP 0 620 116, EP-A 0 606 777, DE-A 4417718, DE-A 4417719 describe dye inks containing fiber-reactive dyes. These dye inks have some application weaknesses, for example unsatisfactory dye ink stability or low dye yield owing to insufficient interaction of the dyes from the ink with the fiber.
- the European patent specification EP-A 0 602 885 describes sulfolane-containing dye inks for the nontextile area which are not suitable for textile application. Consequently, there is a demand for novel printing inks for the inkjet process with fiber-reactive dyes that have improved properties, especially application properties.
- aqueous printing inks containing sulfolane which does not impair the reactivity of reactive dyes and at the same time substantially prevents nozzle cloggage, one or more reactive dyes and a buffer system ensuring the functionality of the reactive groups provide excellent results.
- the present invention accordingly provides aqueous textile inkjet printing inks including one or more reactive dyes, sulfolane and a buffer system and having a pH of not more than 7.0 when one or more of said reactive dyes have reactive systems of the vinyl sulfone series.
- Useful dyes include all reactive dyes recited for example in European patent specifications EP-B 590397, EP-A 886000 and EP-A 613975.
- C. I. Reactive Yellow 85 C. I. Reactive Yellow 95, C. I. Yellow 181, C. I. Reactive Orange 12, C. I. Reactive Orange 13, C. I. Reactive Orange 35, C. I. Reactive Red 3:1, C. I. Reactive Red 24, C. I. Reactive Red 31,C. I. Reactive Red 45, C. I. Reactive Red 187, C. I. Reactive Red 218, C. I. Reactive Red 245, C. I. Reactive Violet 1, C. I. Reactive Blue 13, C. I. Reactive Blue 49, C. I. Reactive Blue 71, C. I. Reactive Blue 72, C. I. Reactive Blue 162, C. I. Reactive Blue 234, C. I. Reactive Brown 11, C. I. Reactive Brown 17, C. I. Reactive Brown 38, C. I. Reactive Black 8, C. I. Reactive Black 39.
- Double and mixed reactive products are for example C. I. Reactive Red 198, C. I. Reactive Red 239, C. I. Reactive Black 5, C. I. Reactive Blue 21.
- the reactive dyes used are known and are obtainable by customary diazotization, coupling and condensation reactions.
- the printing inks of the invention include one or more reactive dyes for example in amounts of 0.1% by weight to 50% by weight, preferably in amounts of 1% by weight to 30% by weight, particularly preferably in amounts of 5% by weight to 25% by weight based on the total weight of the ink.
- the pH of the printing inks is preferably adjusted to 7.0 to 9.0 by use of a suitable buffer system. They are used in amounts of 0.1-3% by weight, preferably in 0.5-1.5% by weight, based on the total weight of the ink.
- Useful buffer systems for printing inks including dyes of the monochlorotriazine series include for example borax, disodium hydrogenphosphate, modified phosphonates, DEAS.
- the pH of the printing inks is preferably adjusted to 3.0 to 7.0 by use of a suitable buffer system. They are used in amounts of 0.1-3% by weight, preferably in 0.5 to 2.5% by weight, based on the total weight of the ink.
- Useful buffer systems for printing inks including dyes of the vinyl sulfone series include for example monosodium phosphate, sodium citrate, modified phosphonates.
- the dyes used in the inks have in particular a salt content of less than 0.1% by weight, for example 0.01 to 0.099, based on the weight of the dyes. If necessary, the dyes have to be desalted, for example by membrane separation processes, before use in the inks of the invention.
- a conductivity of 0.5 to 25 mS/m can be set by adding an electrolyte.
- Useful electrolytes include for example lithium nitrate and potassium nitrate.
- the inks of the invention include for example 1-30% by weight of sulfolane, preferably 5-25% by weight, particularly preferably 10-20% by weight, of sulfolane.
- the dye inks of the invention may include further organic solvents to a total content of 5-20%, preferably 5-15% by weight.
- Useful organic solvents include for example alcohols, eg. methanol, ethanol, 1-propanol, isopropanol, 1-butanol, tert-butanol, pentyl alcohol, polyhydric alcohols eg.: 1,2-ethanediol, 1,2,3-propanetriol, butanediol, 1,3-butanediol, 1,4-butanediol, 1,2-propanediol, 2,3-propanediol, pentanediol, 1,4-pentanediol, 1,5-pentanediol, hexanediol, D,L-1,2-hexanediol, 1,6-hexanediol, 1,2,6-hexanediol, 1,2-octanediol, polyalkylene glycols, eg.: polyethylene glycol, polypropylene glycol
- the printing inks of the invention may further include customary additives, for example viscosity moderators to set viscosities in the range from 1.5 to 40.0 mpa*s in a temperature range from 20 to 50° C.
- Preferred inks have a viscosity of 1.5 to 20 mPa*s and particularly preferred inks have a viscosity of 1.5 to 15 mPa*s.
- Useful viscosity moderators include rheological additives, for example: polyvinylcaprolactam, polyvinylpyrrolidone and their copolymers polyetherpolyol, associative thickeners, polyurea, polyurethane, sodium alginates, modified galactomannans, polyetherurea, polyurethane, nonionic cellulose ethers.
- rheological additives for example: polyvinylcaprolactam, polyvinylpyrrolidone and their copolymers polyetherpolyol, associative thickeners, polyurea, polyurethane, sodium alginates, modified galactomannans, polyetherurea, polyurethane, nonionic cellulose ethers.
- the inks of the invention may include surface-active substances to set surface tensions of 20 to 65 mN/m, which are adapted if necessary as a function of the process used (thermal or piezotechnology).
- Useful surface-active substances include for example:
- nonionic surfactants butyidiglycol, 1,2-hexanediol.
- the inks may further include customary additives, for example substances to inhibit fungal and bacterial growth in amounts of 0.01 to 1% by weight based on the total weight of the ink.
- the inks may be prepared in a conventional manner by mixing the components in water.
- the dye inks of the invention are useful in inkjet printing processes for printing a wide variety of pretreated materials, such as silk, leather, wool, polyamide fibers and polyurethanes, and especially cellulosic fiber materials of any kind.
- pretreated materials such as silk, leather, wool, polyamide fibers and polyurethanes, and especially cellulosic fiber materials of any kind.
- fiber materials are for example in the natural fiber cellulose fibers, such as cotton, linen and hemp, and also pulp and regenerated cellulose.
- the printing inks of the invention are also useful for printing pretreated hydroxyl- or amino-containing fibers present in blend fabrics, for example blends of cotton, silk, wool with polyester fibers or polyamide fibers.
- the pretreatment of the textile substrate is effected with an aqueous alkaline liquor prior to printing.
- alkali for example sodium carbonate, sodium bicarbonate, sodium acetate, trisodium phosphate, sodium silicate, sodium hydroxide, alkali donors such as, for example, sodium trichloroacetate, sodium formate, hydrotropic substances such as, for example, urea, reduction inhibitors, for example sodium nitrobenzenesulfonates, and also thickeners to prevent flowing of the motives when the printing ink is applied, for example sodium alginates, modified polyacrylates or highly etherified galactomannans.
- pretreatment reagents are uniformly applied to the textile substrate in a defined amount using suitable applicators, for example using a 2- or 3-roll pad, contactless spraying technologies, by means of foam application or using appropriately adapted inkjet technologies, and subsequently dried.
- the textile fiber material is dried at 120 to 150° C. and subsequently fixed.
- the fixing of the inkjet prints prepared with reactive dyes may be effected at room temperature or with saturated steam, with superheated steam, with hot air, with microwaves, with infrared radiation, with laser or electron beams or with other suitable energy transfer techniques.
- the necessary fixing chemicals are already on the textile substrate.
- the prints prepared with the dye inks of the invention, especially on cellulose fiber materials, have high color strength and a high fiber-dye bond stability not only in the acidic but also in the alkaline range, good lighffastness and very good weffastness properties, such as wash, water, seawater, cross-dyeing and perspiration fastnesses, and also good fastness to heat setting and plating and crockfastness.
- Parts and percentages are by weight, unless otherwise stated. Parts by weight relate to parts by volume as the kilogram relates to the liter.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a brilliant yellow print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 30 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a turquoise print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a golden yellow print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a brownish orange print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a blue print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a navy print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 40 g/l of sodium bicarbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a navy print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 40 g/l of sodium bicarbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a green print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a black print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of sodium bicarbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 30 g/l of sodium bicarbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a green print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a brilliant yellow print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a golden yellow print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a brownish orange print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a blue print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 40 g/l of sodium bicarbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a navy print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 40 g/l of sodium bicarbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a green print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a black print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of sodium bicarbonate, 120 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of sodium bicarbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of sodium bicarbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a blue print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 30 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a yellow print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a yellow print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a golden yellow print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a blue print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a navy print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the thus pretreated textile is printed with an aqueous ink containing
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a yellow print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of degummed silk is padded with a liquor containing 50 g/l of sodium acetate, 100 g/l of urea and 150 g/l of a highly etherified galactomannan (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a yellow print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a golden yellow print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a blue print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a gray print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a yellow print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- the result is a yellow print having excellent use fastnesses.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of chlorinated wool is padded with a liquor containing 50 g/l of sodium acetate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (5%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm in the presence of 1-2 ml of 25% ammonia, subjected to a fastness wash with hot water at 70 to 80° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 50 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a golden yellow print having excellent use fastnesses.
- a textile fabric of causticized viscose is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 200 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a red print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 150 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- the result is a blue print having excellent use fastnesses.
- a textile fabric of mercerized cotton is padded with liquor containing 35 g/l of anhydrous sodium carbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
- the print is then rinsed warm, subjected to a fastness wash with hot water at 95° C., rinsed warm and then dried.
- a textile fabric of mercerized cotton is padded with liquor containing 40 g/l of sodium bicarbonate, 100 g/l of urea and 150 g/l of a low viscosity sodium alginate solution (6%) and then dried.
- the wet pickup is 70%.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10004954A DE10004954A1 (de) | 2000-02-04 | 2000-02-04 | Wässrige Drucktinten für den Einsatz nach dem Tintenstrahldruck-Verfahren, ihre Herstellung und ihre Verwendung auf textilen Fasermaterialien |
DE10004954.0 | 2000-02-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
US20030172840A1 true US20030172840A1 (en) | 2003-09-18 |
Family
ID=7629835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/182,937 Pending US20030172840A1 (en) | 2000-02-04 | 2001-01-27 | Aqueous printing inks for use in the ink-jet printing method the production and the use on textile fibre materials therof |
Country Status (17)
Country | Link |
---|---|
US (1) | US20030172840A1 (de) |
EP (1) | EP1268922B1 (de) |
JP (1) | JP2003521572A (de) |
KR (1) | KR100707575B1 (de) |
CN (1) | CN1292122C (de) |
AT (1) | ATE340893T1 (de) |
BR (1) | BR0108097A (de) |
CA (1) | CA2399119A1 (de) |
CZ (1) | CZ20022661A3 (de) |
DE (2) | DE10004954A1 (de) |
ES (1) | ES2270983T3 (de) |
HU (1) | HUP0204369A2 (de) |
MX (1) | MXPA02007555A (de) |
PT (1) | PT1268922E (de) |
TW (1) | TWI278553B (de) |
WO (1) | WO2001057308A2 (de) |
ZA (1) | ZA200205628B (de) |
Cited By (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030199611A1 (en) * | 2002-03-08 | 2003-10-23 | Chandrasekaran Casey K. | Inkjet ink for textiles |
US6866378B2 (en) * | 2002-10-28 | 2005-03-15 | Hewlett-Packard Development Company, L.P. | Conductive additives for use in printing processes employing radiational drying |
US20060109327A1 (en) * | 2004-11-01 | 2006-05-25 | Diamond Arthur S | Radiofrequency activated inkjet inks and apparatus for inkjet printing |
US20060173096A1 (en) * | 2005-01-24 | 2006-08-03 | Seiko Epson Corporation | Aqueous ink composition, and ink jet recording method and recorded matter using the same |
US20070103529A1 (en) * | 2003-06-16 | 2007-05-10 | Kornit Digital Ltd. | Process and system for printing images on absorptive surfaces |
US20090211488A1 (en) * | 2008-02-25 | 2009-08-27 | Everlight Usa, Inc. | Inc composition |
US20090294300A1 (en) * | 2006-11-13 | 2009-12-03 | Kc Energy, Llc | Rf systems and methods for processing salt water |
US20110032304A1 (en) * | 2009-08-10 | 2011-02-10 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
US20110041265A1 (en) * | 2009-08-21 | 2011-02-24 | Everlight Usa, Inc. | Reactive printing dye and its aqueous composition application |
EP2311917A1 (de) * | 2008-07-31 | 2011-04-20 | Nippon Kayaku Kabushiki Kaisha | Tintensatz für tintenstrahldruck und verfahren zum bedrucken von fasern damit |
EP2333150A1 (de) * | 2008-10-01 | 2011-06-15 | Mimaki Engineering Co., Ltd. | Tintenzusammensetzung zur tintenstrahlbedruckung von textilien und verfahren zur tintenstrahlbedruckung von textilien |
US20130152315A1 (en) * | 2011-03-18 | 2013-06-20 | Ashwini Kumar Agrawal | Apparatus and methods for dyeing of fibers |
US20140157530A1 (en) * | 2012-12-10 | 2014-06-12 | Seiko Epson Corporation | Ink composition for ink jet textile printing and ink jet textile printing method |
US8926080B2 (en) | 2010-08-10 | 2015-01-06 | Kornit Digital Ltd. | Formaldehyde-free inkjet compositions and processes |
US20150118419A1 (en) * | 2012-06-04 | 2015-04-30 | Hewlett-Packard Development Company, L.P. | Fabric print media |
EP2743318A4 (de) * | 2011-08-09 | 2015-05-20 | Nippon Kayaku Kk | Graue tintenzusammensetzung für tintenstrahldruck und verfahren zum bedrucken von fasern damit |
US20150166807A1 (en) * | 2013-12-17 | 2015-06-18 | Seiko Epson Corporation | Ink composition for ink jet textile printing and textile printing method |
US9550374B1 (en) | 2007-06-27 | 2017-01-24 | Cafepress Inc. | System and method for improved digital printing on textiles |
EP3342926A1 (de) * | 2016-12-28 | 2018-07-04 | Seiko Epson Corporation | Tintenstrahltintenzusammensetzung für textildruck, tintensatz und aufzeichnungsverfahren |
US10259961B2 (en) * | 2016-03-24 | 2019-04-16 | Seiko Epson Corporation | Ink jet textile printing ink composition, ink set, and printing method |
US10544318B2 (en) * | 2016-03-16 | 2020-01-28 | Fujifilm Corporation | Inks |
US11098214B2 (en) | 2016-10-31 | 2021-08-24 | Kornit Digital Ltd. | Dye-sublimation inkjet printing for textile |
US11186738B2 (en) | 2017-09-29 | 2021-11-30 | Seiko Epson Corporation | Ink jet printing ink, ink jet printing ink set, and printing method |
US11248135B2 (en) | 2016-12-28 | 2022-02-15 | Seiko Epson Corporation | Ink jet ink composition for textile printing, ink set, and recording method |
US11255044B2 (en) * | 2017-09-27 | 2022-02-22 | Seiko Epson Corporation | Recording method |
US11292930B2 (en) | 2018-02-13 | 2022-04-05 | Seiko Epson Corporation | Textile printing ink jet ink composition set and recording method |
US11447648B2 (en) | 2004-05-30 | 2022-09-20 | Kornit Digital Ltd. | Process and system for printing images on absorptive surfaces |
US11629265B2 (en) | 2017-10-22 | 2023-04-18 | Kornit Digital Ltd. | Low-friction images by inkjet printing |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0222695D0 (en) * | 2002-10-01 | 2002-11-06 | Lumenia Technology Ltd | Improvements in and relating to methods of colouring materials |
KR100499312B1 (ko) * | 2002-11-22 | 2005-07-04 | 세기유화주식회사 | 수용성 날염 잉크의 제조방법 및 그 방법에 의해 제조된잉크 |
US7351277B2 (en) * | 2004-09-08 | 2008-04-01 | E. I. Du Pont De Nemours And Company | IR transparent cyan inkjet ink |
JP2010084058A (ja) * | 2008-10-01 | 2010-04-15 | Mimaki Engineering Co Ltd | インクジェット捺染用インク組成物 |
JP2010084289A (ja) * | 2008-10-01 | 2010-04-15 | Mimaki Engineering Co Ltd | インクジェット捺染方法 |
IT1393671B1 (it) * | 2009-02-05 | 2012-05-08 | Everlight Usa Inc | Composizione di inchiostro |
WO2014017082A1 (ja) * | 2012-07-23 | 2014-01-30 | コニカミノルタ株式会社 | インクジェット捺染インクセット |
JP6198341B2 (ja) * | 2013-09-12 | 2017-09-20 | 日本化薬株式会社 | インク組成物及び繊維の捺染方法 |
JP6402980B2 (ja) * | 2014-08-01 | 2018-10-10 | セイコーエプソン株式会社 | インクジェット捺染用インク組成物及び捺染方法 |
KR101694726B1 (ko) * | 2015-05-29 | 2017-01-10 | 주식회사 디지아이 | 디지털 날염 전처리용 조성물 |
JP6801305B2 (ja) * | 2016-03-24 | 2020-12-16 | セイコーエプソン株式会社 | インクジェット捺染用インク組成物、インクセット及び記録方法 |
CN106320015B (zh) * | 2016-08-17 | 2019-01-11 | 上海贝通色彩科技有限公司 | 一种数码印花活性红色墨水及其制备方法 |
WO2018097061A1 (ja) * | 2016-11-25 | 2018-05-31 | 日本化薬株式会社 | インク、インクセット、及び繊維の捺染方法 |
JP6954053B2 (ja) * | 2016-12-28 | 2021-10-27 | セイコーエプソン株式会社 | 捺染用インクジェットインク組成物、インクセット及び記録方法 |
JP6972741B2 (ja) * | 2016-12-28 | 2021-11-24 | セイコーエプソン株式会社 | 捺染用インクジェットインク組成物、インクセット及び記録方法 |
EP3924431B1 (de) | 2019-03-18 | 2022-07-06 | Nike Innovate C.V. | Färbemittel-lösungsmittel-system, verwendungsverfahren und artikel |
JP2022103952A (ja) * | 2020-12-28 | 2022-07-08 | セイコーエプソン株式会社 | 水系インクジェットインク組成物および記録方法 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5250121A (en) * | 1991-09-26 | 1993-10-05 | Canon Kabushiki Kaisha | Ink-jet textile printing ink and ink-jet textile printing process |
US5348557A (en) * | 1992-09-26 | 1994-09-20 | Hoechst Aktiengesellschaft | Production of dyeings by the inkjet printing technique on modified fiber materials using anionic textile dyes |
US5364462A (en) * | 1991-08-14 | 1994-11-15 | Graphic Utilities, Incorporated | Waterfast inks |
US5443630A (en) * | 1993-03-02 | 1995-08-22 | Hoechst Aktiengesellschaft | Inkjet single-phase reactive printing |
US5500023A (en) * | 1993-04-21 | 1996-03-19 | Canon Kabushiki Kaisha | Ink-jet printing process, ink set for use in such process, and processed article obtained thereby |
US5542972A (en) * | 1994-05-20 | 1996-08-06 | Hoechst Ag | Reactive dyes for inkjet printing |
US5847740A (en) * | 1992-12-17 | 1998-12-08 | Canon Kabushiki Kaisha | Ink-jet printing cloth and ink-jet printing process |
US5902387A (en) * | 1993-03-23 | 1999-05-11 | Canon Kabushiki Kaisha | Ink-jet textile printing ink, and ink-jet printing process and instrument making use of the same |
US5958120A (en) * | 1998-02-02 | 1999-09-28 | Xerox Corporation | Ink compositions with improved waterfastness |
US5972084A (en) * | 1997-06-17 | 1999-10-26 | Ciba Specialty Chemicals Corporation | Process for printing textile fiber materials in accordance with the ink-jet printing process |
US6015454A (en) * | 1997-06-17 | 2000-01-18 | Ciba Specialty Chemicals Corporation | Process for printing textile fibre materials in accordance with the ink-jet printing process |
US6284348B1 (en) * | 1993-11-08 | 2001-09-04 | Canon Kabushiki Kaisha | Ink-jet printing cloth, textile printing process and print |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56161479A (en) * | 1980-04-10 | 1981-12-11 | Canon Inc | Recording liquid and recording method |
JP3323549B2 (ja) * | 1991-09-26 | 2002-09-09 | キヤノン株式会社 | インクジェット捺染用インク及びインクジェット捺染方法 |
US5258064A (en) * | 1992-12-17 | 1993-11-02 | Xerox Corporation | Ink compositions and preparation processes thereof |
JP3666895B2 (ja) * | 1993-01-13 | 2005-06-29 | キヤノン株式会社 | インクジェット捺染インク、かかるインクを用いた捺染方法、機器および得られる捺染物 |
JP2959691B2 (ja) * | 1993-04-21 | 1999-10-06 | キヤノン株式会社 | インクジェット捺染方法 |
JP2959692B2 (ja) * | 1993-04-21 | 1999-10-06 | キヤノン株式会社 | インクジェット捺染方法 |
US6054505A (en) * | 1998-03-24 | 2000-04-25 | Xerox Corporation | Ink compositions with improved shelf stability |
-
2000
- 2000-02-04 DE DE10004954A patent/DE10004954A1/de not_active Ceased
-
2001
- 2001-01-27 DE DE50111094T patent/DE50111094D1/de not_active Expired - Lifetime
- 2001-01-27 MX MXPA02007555A patent/MXPA02007555A/es active IP Right Grant
- 2001-01-27 KR KR1020027010042A patent/KR100707575B1/ko not_active IP Right Cessation
- 2001-01-27 EP EP01909699A patent/EP1268922B1/de not_active Expired - Lifetime
- 2001-01-27 PT PT01909699T patent/PT1268922E/pt unknown
- 2001-01-27 CN CNB01804493XA patent/CN1292122C/zh not_active Expired - Fee Related
- 2001-01-27 ES ES01909699T patent/ES2270983T3/es not_active Expired - Lifetime
- 2001-01-27 US US10/182,937 patent/US20030172840A1/en active Pending
- 2001-01-27 CA CA002399119A patent/CA2399119A1/en not_active Abandoned
- 2001-01-27 JP JP2001555930A patent/JP2003521572A/ja active Pending
- 2001-01-27 BR BR0108097-0A patent/BR0108097A/pt active Search and Examination
- 2001-01-27 HU HU0204369A patent/HUP0204369A2/hu unknown
- 2001-01-27 CZ CZ20022661A patent/CZ20022661A3/cs unknown
- 2001-01-27 WO PCT/EP2001/000882 patent/WO2001057308A2/de active IP Right Grant
- 2001-01-27 AT AT01909699T patent/ATE340893T1/de not_active IP Right Cessation
- 2001-02-01 TW TW090102072A patent/TWI278553B/zh not_active IP Right Cessation
-
2002
- 2002-07-15 ZA ZA200205628A patent/ZA200205628B/xx unknown
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5364462A (en) * | 1991-08-14 | 1994-11-15 | Graphic Utilities, Incorporated | Waterfast inks |
US5358558A (en) * | 1991-09-26 | 1994-10-25 | Canon Kabushiki Kaisha | Ink-jet textile printing ink and ink-jet textile printing process |
US5250121A (en) * | 1991-09-26 | 1993-10-05 | Canon Kabushiki Kaisha | Ink-jet textile printing ink and ink-jet textile printing process |
US5348557A (en) * | 1992-09-26 | 1994-09-20 | Hoechst Aktiengesellschaft | Production of dyeings by the inkjet printing technique on modified fiber materials using anionic textile dyes |
US5847740A (en) * | 1992-12-17 | 1998-12-08 | Canon Kabushiki Kaisha | Ink-jet printing cloth and ink-jet printing process |
US5443630A (en) * | 1993-03-02 | 1995-08-22 | Hoechst Aktiengesellschaft | Inkjet single-phase reactive printing |
US6254231B1 (en) * | 1993-03-23 | 2001-07-03 | Canon Kabushiki Kaisha | Ink-jet textile printing ink and ink-jet printing process and instrument making use of the same |
US5902387A (en) * | 1993-03-23 | 1999-05-11 | Canon Kabushiki Kaisha | Ink-jet textile printing ink, and ink-jet printing process and instrument making use of the same |
US5500023A (en) * | 1993-04-21 | 1996-03-19 | Canon Kabushiki Kaisha | Ink-jet printing process, ink set for use in such process, and processed article obtained thereby |
US6284348B1 (en) * | 1993-11-08 | 2001-09-04 | Canon Kabushiki Kaisha | Ink-jet printing cloth, textile printing process and print |
US5542972A (en) * | 1994-05-20 | 1996-08-06 | Hoechst Ag | Reactive dyes for inkjet printing |
US6015454A (en) * | 1997-06-17 | 2000-01-18 | Ciba Specialty Chemicals Corporation | Process for printing textile fibre materials in accordance with the ink-jet printing process |
US5972084A (en) * | 1997-06-17 | 1999-10-26 | Ciba Specialty Chemicals Corporation | Process for printing textile fiber materials in accordance with the ink-jet printing process |
US5958120A (en) * | 1998-02-02 | 1999-09-28 | Xerox Corporation | Ink compositions with improved waterfastness |
Cited By (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030199611A1 (en) * | 2002-03-08 | 2003-10-23 | Chandrasekaran Casey K. | Inkjet ink for textiles |
US6866378B2 (en) * | 2002-10-28 | 2005-03-15 | Hewlett-Packard Development Company, L.P. | Conductive additives for use in printing processes employing radiational drying |
US20070103529A1 (en) * | 2003-06-16 | 2007-05-10 | Kornit Digital Ltd. | Process and system for printing images on absorptive surfaces |
US11447648B2 (en) | 2004-05-30 | 2022-09-20 | Kornit Digital Ltd. | Process and system for printing images on absorptive surfaces |
US20060109328A1 (en) * | 2004-11-01 | 2006-05-25 | Gorbold Jonathan M | Fast-drying, radiofrequency-activatable inkjet inks and methods and systems for their use |
US7520600B2 (en) | 2004-11-01 | 2009-04-21 | Basf Corporation | Fast-drying, radiofrequency-activatable inkjet inks and methods and systems for their use |
US20060109327A1 (en) * | 2004-11-01 | 2006-05-25 | Diamond Arthur S | Radiofrequency activated inkjet inks and apparatus for inkjet printing |
US8061832B2 (en) | 2004-11-01 | 2011-11-22 | Basf Corporation | Fast-drying, radiofrequency-activatable inkjet inks and methods and systems for their use |
US20060173096A1 (en) * | 2005-01-24 | 2006-08-03 | Seiko Epson Corporation | Aqueous ink composition, and ink jet recording method and recorded matter using the same |
US20090294300A1 (en) * | 2006-11-13 | 2009-12-03 | Kc Energy, Llc | Rf systems and methods for processing salt water |
US9550374B1 (en) | 2007-06-27 | 2017-01-24 | Cafepress Inc. | System and method for improved digital printing on textiles |
US20090211488A1 (en) * | 2008-02-25 | 2009-08-27 | Everlight Usa, Inc. | Inc composition |
US7967903B2 (en) * | 2008-02-25 | 2011-06-28 | Everlight Usa, Inc. | Ink composition |
EP2311917A1 (de) * | 2008-07-31 | 2011-04-20 | Nippon Kayaku Kabushiki Kaisha | Tintensatz für tintenstrahldruck und verfahren zum bedrucken von fasern damit |
EP2311917A4 (de) * | 2008-07-31 | 2012-07-25 | Nippon Kayaku Kk | Tintensatz für tintenstrahldruck und verfahren zum bedrucken von fasern damit |
EP2333150A1 (de) * | 2008-10-01 | 2011-06-15 | Mimaki Engineering Co., Ltd. | Tintenzusammensetzung zur tintenstrahlbedruckung von textilien und verfahren zur tintenstrahlbedruckung von textilien |
EP2333150A4 (de) * | 2008-10-01 | 2014-05-14 | Mimaki Eng Kk | Tintenzusammensetzung zur tintenstrahlbedruckung von textilien und verfahren zur tintenstrahlbedruckung von textilien |
US11898048B2 (en) | 2009-08-10 | 2024-02-13 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
US8540358B2 (en) | 2009-08-10 | 2013-09-24 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
US20110032304A1 (en) * | 2009-08-10 | 2011-02-10 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
US11021627B2 (en) | 2009-08-10 | 2021-06-01 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
US10472533B2 (en) | 2009-08-10 | 2019-11-12 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
US9611401B2 (en) | 2009-08-10 | 2017-04-04 | Kornit Digital Ltd. | Inkjet compositions and processes for stretchable substrates |
EP2290016A1 (de) | 2009-08-21 | 2011-03-02 | Everlight USA, Inc. | Reaktiver Druckfarbstoff und seine wässrige Zusammensetzungsanwendung |
US8349028B2 (en) * | 2009-08-21 | 2013-01-08 | Everlight Usa, Inc. | Reactive printing dye and its aqueous composition application |
US20110041265A1 (en) * | 2009-08-21 | 2011-02-24 | Everlight Usa, Inc. | Reactive printing dye and its aqueous composition application |
US8926080B2 (en) | 2010-08-10 | 2015-01-06 | Kornit Digital Ltd. | Formaldehyde-free inkjet compositions and processes |
US9616683B2 (en) | 2010-08-10 | 2017-04-11 | Kornit Digital Ltd. | Formaldehyde-free inkjet compositions and processes |
US20130152315A1 (en) * | 2011-03-18 | 2013-06-20 | Ashwini Kumar Agrawal | Apparatus and methods for dyeing of fibers |
EP2743318A4 (de) * | 2011-08-09 | 2015-05-20 | Nippon Kayaku Kk | Graue tintenzusammensetzung für tintenstrahldruck und verfahren zum bedrucken von fasern damit |
US20150118419A1 (en) * | 2012-06-04 | 2015-04-30 | Hewlett-Packard Development Company, L.P. | Fabric print media |
US9682587B2 (en) * | 2012-06-04 | 2017-06-20 | Hewlett-Packard Development Company, L.P. | Fabric print media |
US20140157530A1 (en) * | 2012-12-10 | 2014-06-12 | Seiko Epson Corporation | Ink composition for ink jet textile printing and ink jet textile printing method |
US9340923B2 (en) * | 2012-12-10 | 2016-05-17 | Seiko Epson Corporation | Ink composition for ink jet textile printing and ink jet textile printing method |
US20150166807A1 (en) * | 2013-12-17 | 2015-06-18 | Seiko Epson Corporation | Ink composition for ink jet textile printing and textile printing method |
US9909024B2 (en) * | 2013-12-17 | 2018-03-06 | Seiko Epson Corporation | Ink composition for ink jet textile printing and textile printing method |
US10544318B2 (en) * | 2016-03-16 | 2020-01-28 | Fujifilm Corporation | Inks |
US10259961B2 (en) * | 2016-03-24 | 2019-04-16 | Seiko Epson Corporation | Ink jet textile printing ink composition, ink set, and printing method |
US11098214B2 (en) | 2016-10-31 | 2021-08-24 | Kornit Digital Ltd. | Dye-sublimation inkjet printing for textile |
US10894896B2 (en) | 2016-12-28 | 2021-01-19 | Seiko Epson Corporation | Ink jet ink composition for textile printing, ink set, and recording method |
US11248135B2 (en) | 2016-12-28 | 2022-02-15 | Seiko Epson Corporation | Ink jet ink composition for textile printing, ink set, and recording method |
EP3342926A1 (de) * | 2016-12-28 | 2018-07-04 | Seiko Epson Corporation | Tintenstrahltintenzusammensetzung für textildruck, tintensatz und aufzeichnungsverfahren |
US11255044B2 (en) * | 2017-09-27 | 2022-02-22 | Seiko Epson Corporation | Recording method |
US11186738B2 (en) | 2017-09-29 | 2021-11-30 | Seiko Epson Corporation | Ink jet printing ink, ink jet printing ink set, and printing method |
US11629265B2 (en) | 2017-10-22 | 2023-04-18 | Kornit Digital Ltd. | Low-friction images by inkjet printing |
US11292930B2 (en) | 2018-02-13 | 2022-04-05 | Seiko Epson Corporation | Textile printing ink jet ink composition set and recording method |
Also Published As
Publication number | Publication date |
---|---|
ES2270983T3 (es) | 2007-04-16 |
JP2003521572A (ja) | 2003-07-15 |
DE50111094D1 (de) | 2006-11-09 |
WO2001057308A2 (de) | 2001-08-09 |
EP1268922A2 (de) | 2003-01-02 |
CN1398311A (zh) | 2003-02-19 |
KR100707575B1 (ko) | 2007-04-13 |
PT1268922E (pt) | 2007-01-31 |
CZ20022661A3 (cs) | 2002-11-13 |
DE10004954A1 (de) | 2001-08-16 |
EP1268922B1 (de) | 2006-09-27 |
ATE340893T1 (de) | 2006-10-15 |
WO2001057308A3 (de) | 2002-03-14 |
TWI278553B (en) | 2007-04-11 |
HUP0204369A2 (en) | 2003-04-28 |
BR0108097A (pt) | 2002-10-29 |
KR20020073199A (ko) | 2002-09-19 |
CA2399119A1 (en) | 2001-08-09 |
CN1292122C (zh) | 2006-12-27 |
MXPA02007555A (es) | 2002-12-13 |
ZA200205628B (en) | 2003-11-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20030172840A1 (en) | Aqueous printing inks for use in the ink-jet printing method the production and the use on textile fibre materials therof | |
KR101217646B1 (ko) | 반응성 염료의 혼합물 및 이의 용도 | |
EP2376578B1 (de) | Faserreaktive azofarbstoffe und farbstoffmischungen, ihre herstellung und verwendung | |
KR20060133015A (ko) | 섬유-반응성 아조 염료의 혼합물, 이의 제조 및 용도 | |
EP1756233B1 (de) | Mischungen von faserreaktiven azofarbstoffen | |
MXPA05012935A (es) | Mezclas de colorantes azoicos reactivos con fibra, produccion y utilizacion de los mismos. | |
JP2004536180A (ja) | インクジェットプリントのための水性インク配合物 | |
EP1817380A2 (de) | Reaktive farbstoffe mit zweiwertigem schwefel in einer nichtreaktiven seitenkette am triazinkern | |
US20080028542A1 (en) | New Reactive Dyes | |
CN110072947B (zh) | 蓝色和海军蓝纤维活性染料混合物 | |
KR101287741B1 (ko) | 반응성 염료, 이의 제조 방법 및 이의 용도 | |
US20080194817A1 (en) | Reactive Dyestuffs, Method for the Production Thereof, and Use of the Same | |
MX2007005993A (en) | Reactive dyes containing divalent sulfur in non-reactive side chain at trizine nucleus |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: DYSTAR TEXTILFARBEN GMBH & CO., GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BLANK, KARL-HANS;MACH, HORST-ROLAND;REEL/FRAME:014114/0581 Effective date: 20020719 |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: FINAL REJECTION MAILED |
|
AS | Assignment |
Owner name: ANKURA TRUST COMPANY, LLC, ILLINOIS Free format text: SECURITY INTEREST;ASSIGNOR:EMBR LABS IP LLC;REEL/FRAME:063210/0582 Effective date: 20230331 |