TWI555265B - 供硫－鋰離子電池用之電極組及含彼之硫－鋰離子電池 - Google Patents
供硫－鋰離子電池用之電極組及含彼之硫－鋰離子電池 Download PDFInfo
- Publication number
- TWI555265B TWI555265B TW103119209A TW103119209A TWI555265B TW I555265 B TWI555265 B TW I555265B TW 103119209 A TW103119209 A TW 103119209A TW 103119209 A TW103119209 A TW 103119209A TW I555265 B TWI555265 B TW I555265B
- Authority
- TW
- Taiwan
- Prior art keywords
- sulfur
- lithium
- anode
- ion battery
- cathode
- Prior art date
Links
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 title claims description 31
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 31
- 229910052744 lithium Inorganic materials 0.000 claims description 42
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 31
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 30
- 229910052717 sulfur Inorganic materials 0.000 claims description 30
- 239000011593 sulfur Substances 0.000 claims description 30
- -1 lithium transition metal Chemical class 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 19
- 239000011230 binding agent Substances 0.000 claims description 18
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000003792 electrolyte Substances 0.000 claims description 11
- 229920001021 polysulfide Polymers 0.000 claims description 11
- 239000005077 polysulfide Substances 0.000 claims description 11
- 150000008117 polysulfides Polymers 0.000 claims description 11
- 239000004020 conductor Substances 0.000 claims description 10
- 239000007784 solid electrolyte Substances 0.000 claims description 10
- 239000002033 PVDF binder Substances 0.000 claims description 9
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 9
- 239000006183 anode active material Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 8
- 239000006182 cathode active material Substances 0.000 claims description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 4
- 229910003480 inorganic solid Inorganic materials 0.000 claims description 4
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 4
- 229910003002 lithium salt Inorganic materials 0.000 claims description 4
- 159000000002 lithium salts Chemical class 0.000 claims description 4
- 230000014759 maintenance of location Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 4
- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- 229910018091 Li 2 S Inorganic materials 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- KDXKERNSBIXSRK-UHFFFAOYSA-N lysine Polymers NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229910000319 transition metal phosphate Inorganic materials 0.000 claims description 3
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 claims description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 claims description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 claims description 2
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 claims description 2
- CFYJDRYLYZCRPZ-UHFFFAOYSA-N 1-cyclobutyl-1-methylhydrazine Chemical compound C1(CCC1)N(N)C CFYJDRYLYZCRPZ-UHFFFAOYSA-N 0.000 claims description 2
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 claims description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- 229910012722 Li3N-LiI-LiOH Inorganic materials 0.000 claims description 2
- 229910012716 Li3N-LiI—LiOH Inorganic materials 0.000 claims description 2
- 229910012734 Li3N—LiI—LiOH Inorganic materials 0.000 claims description 2
- 229910013043 Li3PO4-Li2S-SiS2 Inorganic materials 0.000 claims description 2
- 229910013035 Li3PO4-Li2S—SiS2 Inorganic materials 0.000 claims description 2
- 229910012810 Li3PO4—Li2S-SiS2 Inorganic materials 0.000 claims description 2
- 229910012797 Li3PO4—Li2S—SiS2 Inorganic materials 0.000 claims description 2
- 229910012047 Li4SiO4-LiI-LiOH Inorganic materials 0.000 claims description 2
- 229910012075 Li4SiO4-LiI—LiOH Inorganic materials 0.000 claims description 2
- 229910012057 Li4SiO4—LiI—LiOH Inorganic materials 0.000 claims description 2
- 229910010238 LiAlCl 4 Inorganic materials 0.000 claims description 2
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 2
- 229910015044 LiB Inorganic materials 0.000 claims description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 2
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 2
- 229910012513 LiSbF 6 Inorganic materials 0.000 claims description 2
- 229910012573 LiSiO Inorganic materials 0.000 claims description 2
- 229910012346 LiSiO4-LiI-LiOH Inorganic materials 0.000 claims description 2
- 229910012345 LiSiO4-LiI—LiOH Inorganic materials 0.000 claims description 2
- 229910012348 LiSiO4—LiI—LiOH Inorganic materials 0.000 claims description 2
- 239000004472 Lysine Substances 0.000 claims description 2
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- GJEAMHAFPYZYDE-UHFFFAOYSA-N [C].[S] Chemical class [C].[S] GJEAMHAFPYZYDE-UHFFFAOYSA-N 0.000 claims description 2
- BEKPOUATRPPTLV-UHFFFAOYSA-N [Li].BCl Chemical compound [Li].BCl BEKPOUATRPPTLV-UHFFFAOYSA-N 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- HQFQTTNMBUPQAY-UHFFFAOYSA-N cyclobutylhydrazine Chemical compound NNC1CCC1 HQFQTTNMBUPQAY-UHFFFAOYSA-N 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 2
- 238000010494 dissociation reaction Methods 0.000 claims description 2
- 230000005593 dissociations Effects 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 235000015110 jellies Nutrition 0.000 claims description 2
- 239000008274 jelly Substances 0.000 claims description 2
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 2
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 claims description 2
- LRMHVVPPGGOAJQ-UHFFFAOYSA-N methyl nitrate Chemical compound CO[N+]([O-])=O LRMHVVPPGGOAJQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940017219 methyl propionate Drugs 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920001523 phosphate polymer Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 150000004060 quinone imines Chemical class 0.000 claims description 2
- 150000003464 sulfur compounds Chemical class 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Polymers NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 claims 2
- 239000003463 adsorbent Substances 0.000 claims 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims 1
- 125000003588 lysine group Polymers [H]N([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 claims 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 11
- 239000011267 electrode slurry Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000006257 cathode slurry Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- YQCIWBXEVYWRCW-UHFFFAOYSA-N methane;sulfane Chemical compound C.S YQCIWBXEVYWRCW-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 4
- 239000006245 Carbon black Super-P Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 2
- 229910015645 LiMn Inorganic materials 0.000 description 2
- 229910014689 LiMnO Inorganic materials 0.000 description 2
- 241000237536 Mytilus edulis Species 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000006256 anode slurry Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 235000020638 mussel Nutrition 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical compound FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- LECKFEZRJJNBNI-UHFFFAOYSA-N 4-fluoro-5-methyl-1,3-dioxolan-2-one Chemical compound CC1OC(=O)OC1F LECKFEZRJJNBNI-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910000925 Cd alloy Inorganic materials 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910013716 LiNi Inorganic materials 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- PRMUYRHOSNIRPW-UHFFFAOYSA-N P(=O)([O-])([O-])[O-].P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.[NH4+].[NH4+].[NH4+] Chemical compound P(=O)([O-])([O-])[O-].P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.[NH4+].[NH4+].[NH4+] PRMUYRHOSNIRPW-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920006373 Solef Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- QDDVNKWVBSLTMB-UHFFFAOYSA-N [Cu]=O.[Li] Chemical compound [Cu]=O.[Li] QDDVNKWVBSLTMB-UHFFFAOYSA-N 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- XAQHXGSHRMHVMU-UHFFFAOYSA-N [S].[S] Chemical compound [S].[S] XAQHXGSHRMHVMU-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 150000004693 imidazolium salts Chemical class 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000010220 ion permeability Effects 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical group [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- HYIMSNHJOBLJNT-UHFFFAOYSA-N nifedipine Chemical compound COC(=O)C1=C(C)NC(C)=C(C(=O)OC)C1C1=CC=CC=C1[N+]([O-])=O HYIMSNHJOBLJNT-UHFFFAOYSA-N 0.000 description 1
- 229960001597 nifedipine Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000001008 quinone-imine dye Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000014233 sulfur utilization Effects 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
- H01M4/5815—Sulfides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130063522A KR101497330B1 (ko) | 2013-06-03 | 2013-06-03 | 황-리튬 이온 전지용 전극 조립체 및 이를 포함하는 황-리튬 이온 전지 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201523991A TW201523991A (zh) | 2015-06-16 |
| TWI555265B true TWI555265B (zh) | 2016-10-21 |
Family
ID=52008361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103119209A TWI555265B (zh) | 2013-06-03 | 2014-06-03 | 供硫－鋰離子電池用之電極組及含彼之硫－鋰離子電池 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10243212B2 (ja) |
| EP (1) | EP2892104B1 (ja) |
| JP (1) | JP6313296B2 (ja) |
| KR (1) | KR101497330B1 (ja) |
| CN (1) | CN104380520B (ja) |
| RU (1) | RU2646217C2 (ja) |
| TW (1) | TWI555265B (ja) |
| WO (1) | WO2014196777A1 (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3367490B1 (en) * | 2015-09-16 | 2019-07-31 | Kabushiki Kaisha Toshiba | Secondary battery, battery pack, and vehicle |
| CN106169561B (zh) * | 2016-09-30 | 2019-06-25 | 上海空间电源研究所 | 一种硫系复合正极极片、包含其的电池及其制备方法 |
| EP3327830B1 (en) * | 2016-11-25 | 2019-11-06 | Sumitomo Rubber Industries, Ltd. | Metal-ion secondary battery |
| KR102183662B1 (ko) | 2017-05-26 | 2020-11-26 | 주식회사 엘지화학 | 리튬-황 전지용 전해액 및 이를 포함하는 리튬-황 전지 |
| JP6589940B2 (ja) * | 2017-06-06 | 2019-10-16 | トヨタ自動車株式会社 | 硫化物固体電解質材料の製造方法 |
| KR102244905B1 (ko) | 2017-07-28 | 2021-04-26 | 주식회사 엘지화학 | 리튬-황 전지용 양극 및 이를 포함하는 리튬-황 전지 |
| KR20190021504A (ko) * | 2017-08-22 | 2019-03-06 | 전자부품연구원 | 리튬-황 이차전지용 전해액 및 그를 포함하는 리튬-황 이차전지 |
| WO2019176618A1 (ja) * | 2018-03-13 | 2019-09-19 | 株式会社Adeka | 非水電解質二次電池 |
| JP7017123B2 (ja) * | 2018-06-01 | 2022-02-08 | トヨタ自動車株式会社 | 正極合材、全固体電池および正極合材の製造方法 |
| KR101923861B1 (ko) | 2018-06-20 | 2018-11-29 | 고려대학교 산학협력단 | 촉매를 포함하는 리튬이차전지용 양극용 슬러리 및 이를 포함하는 리튬이차전지 |
| CN109687016B (zh) * | 2018-12-24 | 2020-07-28 | 郑州新世纪材料基因组工程研究院有限公司 | 一种锂离子固体电解质及其制备方法 |
| CN116779344B (zh) * | 2023-07-18 | 2024-06-18 | 四川创仕鼎电子有限公司 | 一种用于新能源汽车放电装置的电容 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1285086A (zh) * | 1997-12-19 | 2001-02-21 | 摩尔科技公司 | 含有电活性硫材料的阴极以及使用该阴极的二次电池 |
| CN1336696A (zh) * | 2000-08-02 | 2002-02-20 | 三星Sdi株式会社 | 锂硫电池 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4794056A (en) * | 1987-09-11 | 1988-12-27 | Eveready Battery Company | Coiled electrode assembly cell construction with telescopic terminal tab |
| JPH0927317A (ja) | 1994-06-24 | 1997-01-28 | Matsushita Electric Ind Co Ltd | 非水電解質二次電池およびその負極の製造方法 |
| CA2186099A1 (en) * | 1996-09-20 | 1996-11-18 | David Stanley Wainwright | Aqueous rechargeable battery |
| JP4253051B2 (ja) | 1997-12-26 | 2009-04-08 | 株式会社クレハ | 非水系電池用電極合剤および非水系電池 |
| WO2001035474A1 (en) | 1999-11-05 | 2001-05-17 | Conoco Inc. | Composite carbon electrode for rechargeable lithium-based batteries |
| JP2003532976A (ja) | 1999-11-05 | 2003-11-05 | コノコフィリップス カンパニー | リチウム系蓄電池用の複合炭素電極 |
| KR100338032B1 (ko) * | 2000-06-13 | 2002-05-24 | 김순택 | 리튬-황 전지 |
| KR100553776B1 (ko) | 2003-09-05 | 2006-02-20 | 삼성에스디아이 주식회사 | 유기 전해액 및 이를 포함한 리튬 설퍼 전지 |
| KR100590096B1 (ko) * | 2004-04-29 | 2006-06-14 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
| DE102005011940A1 (de) * | 2005-03-14 | 2006-09-21 | Degussa Ag | Verfahren zur Herstellung von beschichteten Kohlenstoffpartikel und deren Verwendung in Anodenmaterialien für Lithium-Ionenbatterien |
| EP1867000B1 (en) | 2005-03-22 | 2011-10-05 | Oxis Energy Limited | Lithium sulphide battery and method of producing the same |
| KR100781051B1 (ko) * | 2005-10-26 | 2007-12-03 | 주식회사 엘지화학 | 접착력이 향상된 음극 합제 및 이를 포함하는 리튬이차전지 |
| KR100801637B1 (ko) | 2006-05-29 | 2008-02-11 | 주식회사 엘지화학 | 양극 활물질 및 그것을 포함하고 있는 리튬 이차전지 |
| CN101675553B (zh) * | 2007-05-11 | 2012-10-10 | 奈米克斯股份有限公司 | 锂离子二次电池及其制造方法 |
| US20080305395A1 (en) * | 2007-06-05 | 2008-12-11 | Sony Corporation | Anode and secondary battery |
| KR100982003B1 (ko) | 2008-04-17 | 2010-09-13 | 주식회사 엘지화학 | 절연특성이 향상된 전지 |
| JP5259268B2 (ja) * | 2008-06-25 | 2013-08-07 | 三星エスディアイ株式会社 | 非水電解質二次電池 |
| JP2012519366A (ja) | 2009-03-02 | 2012-08-23 | エルジー ケム． エルティーディ． | パウチおよびこれを含む二次電池 |
| WO2011156925A2 (en) * | 2010-06-17 | 2011-12-22 | Linda Faye Nazar | Multicomponent electrodes for rechargeable batteries |
| EP2595221A4 (en) | 2010-07-16 | 2014-03-26 | Mitsubishi Chem Corp | CATHODE FOR LITHIUM SECONDARY BATTERY AND LITHIUM SECONDARY BATTERY USING THE SAME |
| KR101182428B1 (ko) * | 2010-07-20 | 2012-09-12 | 삼성에스디아이 주식회사 | 양극 및 이를 포함한 리튬 전지 |
| US9112212B1 (en) * | 2010-10-26 | 2015-08-18 | Amprius, Inc. | Forming multilayered solid electrolyte interphase structures on high capacity electrodes |
| KR101310430B1 (ko) | 2010-11-15 | 2013-09-24 | 삼성전기주식회사 | 음극 활물질 및 그를 구비하는 리튬 이차전지, 그리고 상기 리튬 이차전지의 제조 방법 |
| JP2012142101A (ja) | 2010-12-28 | 2012-07-26 | Toyota Central R&D Labs Inc | リチウム硫黄電池およびリチウム硫黄電池の製造方法 |
| JP5002824B1 (ja) * | 2011-03-02 | 2012-08-15 | 独立行政法人産業技術総合研究所 | リチウム二次電池用負極材料及びその製造方法、並びにリチウム二次電池用負極及びリチウム二次電池 |
| CN102790212B (zh) * | 2011-05-18 | 2014-09-24 | 国家纳米科学中心 | 锂离子电池负极活性物质及其制备方法和负极材料及负极 |
| KR20130008883A (ko) * | 2011-07-13 | 2013-01-23 | 주식회사 엘지화학 | 우수한 제조 공정성의 전극조립체 및 이를 포함하는 이차전지 |
| JP5811700B2 (ja) * | 2011-08-31 | 2015-11-11 | ユーハ味覚糖株式会社 | 発泡性食品及びその製造方法 |
| JP6004274B2 (ja) | 2012-03-19 | 2016-10-05 | 国立大学法人横浜国立大学 | アルカリ金属−硫黄系二次電池 |
| US9324995B2 (en) * | 2012-04-04 | 2016-04-26 | Nokia Technologies Oy | Apparatus and associated methods |
| CN103390767B (zh) * | 2012-05-11 | 2016-01-20 | 清华大学 | 锂离子电池 |
| KR101920714B1 (ko) * | 2012-05-16 | 2018-11-21 | 삼성전자주식회사 | 리튬 전지용 음극 및 이를 포함하는 리튬 전지 |
-
2013
- 2013-06-03 KR KR1020130063522A patent/KR101497330B1/ko active IP Right Grant
-
2014
- 2014-06-03 US US14/409,861 patent/US10243212B2/en active Active
- 2014-06-03 TW TW103119209A patent/TWI555265B/zh active
- 2014-06-03 WO PCT/KR2014/004905 patent/WO2014196777A1/ko active Application Filing
- 2014-06-03 RU RU2014151558A patent/RU2646217C2/ru active
- 2014-06-03 JP JP2015521566A patent/JP6313296B2/ja active Active
- 2014-06-03 EP EP14796650.1A patent/EP2892104B1/en active Active
- 2014-06-03 CN CN201480001576.8A patent/CN104380520B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1285086A (zh) * | 1997-12-19 | 2001-02-21 | 摩尔科技公司 | 含有电活性硫材料的阴极以及使用该阴极的二次电池 |
| CN1336696A (zh) * | 2000-08-02 | 2002-02-20 | 三星Sdi株式会社 | 锂硫电池 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014196777A1 (ko) | 2014-12-11 |
| KR20140142009A (ko) | 2014-12-11 |
| CN104380520B (zh) | 2017-11-28 |
| CN104380520A (zh) | 2015-02-25 |
| TW201523991A (zh) | 2015-06-16 |
| RU2646217C2 (ru) | 2018-03-02 |
| EP2892104A4 (en) | 2016-03-30 |
| RU2014151558A (ru) | 2017-07-14 |
| KR101497330B1 (ko) | 2015-03-02 |
| JP2015523693A (ja) | 2015-08-13 |
| EP2892104B1 (en) | 2017-10-18 |
| EP2892104A1 (en) | 2015-07-08 |
| JP6313296B2 (ja) | 2018-04-18 |
| US20160093887A1 (en) | 2016-03-31 |
| US10243212B2 (en) | 2019-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI555265B (zh) | 供硫－鋰離子電池用之電極組及含彼之硫－鋰離子電池 | |
| KR101653299B1 (ko) | 고전압용 양극 활물질 및 이를 포함하는 리튬 이차전지 | |
| US9985287B2 (en) | Electrode including different electrode material layers and lithium secondary battery | |
| KR101481993B1 (ko) | 시안기를 포함하는 화합물을 포함하는 전극 및 이를 포함하는 리튬이차전지 | |
| JP6749692B2 (ja) | リチウム二次電池、電池モジュール、電池パック、及び電池パックを含むデバイス | |
| KR20150014800A (ko) | 균일한 공극률의 전극재층을 포함하는 전극 | |
| KR20130116028A (ko) | 전극의 제조방법 및 이를 사용하여 제조되는 전극 | |
| KR101588624B1 (ko) | 전극 전도도가 향상된 전극 및 이의 제조방법 | |
| KR101772420B1 (ko) | 비표면적이 큰 음극 활물질층을 포함하는 음극 및 이의 제조방법 | |
| KR20160126840A (ko) | 하나 이상의 코팅층을 포함하는 양극 활물질 입자 및 이의 제조 방법 | |
| KR101511022B1 (ko) | 수분 제한 전극 활물질, 수분 제한 전극 및 이를 포함하는 리튬 이차전지 | |
| KR101572074B1 (ko) | 용량이 향상된 음극 활물질 및 이를 포함하는 리튬 이차전지 | |
| KR20130117688A (ko) | 낮은 함습성의 전극 활물질 및 이를 포함하는 리튬 이차전지 | |
| KR101610924B1 (ko) | 상이한 전극재 층들을 포함하는 전극 및 리튬 이차전지 | |
| KR20150055890A (ko) | 표면개질된 음극 활물질 및 이의 제조방법 | |
| KR20130116027A (ko) | 전극의 제조방법 및 이를 사용하여 제조되는 전극 | |
| KR101580486B1 (ko) | 젖음성이 향상된 이차전지용 음극 및 이를 포함하는 리튬 이차전지 | |
| KR101613079B1 (ko) | 분리된 두 개의 수납부를 포함하는 전지 케이스 및 리튬 이차전지 | |
| KR20130118247A (ko) | 전극의 제조방법 및 이를 사용하여 제조되는 전극 | |
| KR20130117716A (ko) | 고율 특성의 전극 활물질 및 이를 포함하는 리튬 이차전지 | |
| KR20140008956A (ko) | 리튬 이차전지용 음극의 제조 방법 및 이러한 방법에 의해 제조된 음극을 포함하는 리튬 이차전지 | |
| KR101521082B1 (ko) | 음극 활물질 및 이를 포함하는 리튬 이차전지 | |
| KR101606429B1 (ko) | 다공성 전자 전도 층을 포함하는 전극 및 리튬 이차전지 | |
| KR20140142038A (ko) | 리튬-유황 전지용 양극 활물질 및 이를 포함하는 리튬-유황 전지 | |
| KR20150015421A (ko) | 요철 구조의 라미네이트 시트 |