TWI395360B - 全固體電池 - Google Patents

全固體電池 Download PDF

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Publication number
TWI395360B
TWI395360B TW098140999A TW98140999A TWI395360B TW I395360 B TWI395360 B TW I395360B TW 098140999 A TW098140999 A TW 098140999A TW 98140999 A TW98140999 A TW 98140999A TW I395360 B TWI395360 B TW I395360B
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TW
Taiwan
Prior art keywords
active material
electrode active
positive electrode
solid electrolyte
solid
Prior art date
Application number
TW098140999A
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English (en)
Chinese (zh)
Other versions
TW201037875A (en
Inventor
Yasushi Tsuchida
Yukiyoshi Ueno
Shigenori Hama
Hirofumi Nakamoto
Hiroshi Nagase
Masato Kamiya
Kazunori Takada
Original Assignee
Toyota Motor Co Ltd
Nat Inst For Materials Science
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Application filed by Toyota Motor Co Ltd, Nat Inst For Materials Science filed Critical Toyota Motor Co Ltd
Publication of TW201037875A publication Critical patent/TW201037875A/zh
Application granted granted Critical
Publication of TWI395360B publication Critical patent/TWI395360B/zh

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/185—Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/002—Inorganic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0091—Composites in the form of mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Primary Cells (AREA)
TW098140999A 2008-12-02 2009-12-01 全固體電池 TWI395360B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008307276A JP4948510B2 (ja) 2008-12-02 2008-12-02 全固体電池

Publications (2)

Publication Number Publication Date
TW201037875A TW201037875A (en) 2010-10-16
TWI395360B true TWI395360B (zh) 2013-05-01

Family

ID=41606698

Family Applications (1)

Application Number Title Priority Date Filing Date
TW098140999A TWI395360B (zh) 2008-12-02 2009-12-01 全固體電池

Country Status (11)

Country Link
US (1) US20120052396A1 (fr)
EP (1) EP2353198A1 (fr)
JP (1) JP4948510B2 (fr)
KR (1) KR101314031B1 (fr)
CN (1) CN102239589A (fr)
AU (1) AU2009323792B2 (fr)
BR (1) BRPI0922356A2 (fr)
CA (1) CA2745379C (fr)
RU (1) RU2485635C2 (fr)
TW (1) TWI395360B (fr)
WO (1) WO2010064127A1 (fr)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
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JP5287739B2 (ja) 2009-05-01 2013-09-11 トヨタ自動車株式会社 固体電解質材料
JP5455766B2 (ja) 2010-04-23 2014-03-26 トヨタ自動車株式会社 複合正極活物質、全固体電池、および、それらの製造方法
JP5349427B2 (ja) 2010-08-26 2013-11-20 トヨタ自動車株式会社 硫化物固体電解質材料、正極体およびリチウム固体電池
JP5601157B2 (ja) * 2010-11-01 2014-10-08 トヨタ自動車株式会社 正極活物質材料、正極活物質層、全固体電池および正極活物質材料の製造方法
US20130260258A1 (en) * 2010-12-10 2013-10-03 Toyota Jidosha Kabushiki Kaisha Electrode body and all solid state battery
JP5556797B2 (ja) * 2010-12-17 2014-07-23 トヨタ自動車株式会社 二次電池
JP5423725B2 (ja) * 2011-05-17 2014-02-19 トヨタ自動車株式会社 正極活物質粒子及びその製造方法
WO2012157119A1 (fr) * 2011-05-19 2012-11-22 トヨタ自動車株式会社 Batterie au lithium solide
EP2717364B1 (fr) * 2011-05-23 2023-05-03 Toyota Jidosha Kabushiki Kaisha Utilisation d'un matériau d'électrode positive pour une batterie à électrolyte solide à base de sulfure et batterie à électrolyte solide à base de sulfure avec un tel matériau d'électrode positive
JP5578280B2 (ja) 2011-05-26 2014-08-27 トヨタ自動車株式会社 被覆活物質およびリチウム固体電池
JP5195975B2 (ja) * 2011-07-20 2013-05-15 トヨタ自動車株式会社 全固体電池およびその製造方法
CN103814472B (zh) * 2011-09-30 2016-05-04 丰田自动车株式会社 全固体电池及其制造方法
WO2013084352A1 (fr) * 2011-12-09 2013-06-13 トヨタ自動車株式会社 Matière active d'électrode positive, couche de matière active d'électrode positive, batterie entièrement solide et procédé de production de matière active d'électrode positive
JP5817657B2 (ja) * 2012-06-20 2015-11-18 トヨタ自動車株式会社 電池システム、電池システムの製造方法、電池の制御装置
KR102133786B1 (ko) 2012-08-28 2020-07-14 어플라이드 머티어리얼스, 인코포레이티드 고체 상태 배터리 제조
KR20140053451A (ko) * 2012-10-25 2014-05-08 삼성에스디아이 주식회사 복합양극활물질, 그 제조방법 및 이를 채용한 양극과 리튬전지
JP2014102911A (ja) * 2012-11-16 2014-06-05 Toyota Motor Corp 全固体電池用電極材及びその製造方法並びにそれを使用した全固体電池
JP6329745B2 (ja) * 2013-10-02 2018-05-23 三星電子株式会社Ｓａｍｓｕｎｇ Ｅｌｅｃｔｒｏｎｉｃｓ Ｃｏ．，Ｌｔｄ． リチウムイオン二次電池およびリチウムイオン二次電池用正極活物質の製造方法
JP6102859B2 (ja) 2014-08-08 2017-03-29 トヨタ自動車株式会社 リチウム電池用正極活物質、リチウム電池およびリチウム電池用正極活物質の製造方法
JP6067645B2 (ja) * 2014-10-21 2017-01-25 トヨタ自動車株式会社 硫化物全固体電池用の正極複合材の製造方法
JP6252524B2 (ja) 2015-03-12 2017-12-27 トヨタ自動車株式会社 固体電池用正極活物質の製造方法
DE102015210402A1 (de) * 2015-06-05 2016-12-08 Robert Bosch Gmbh Kathodenmaterial für Lithium-Schwefel-Zelle
JP2017027867A (ja) * 2015-07-24 2017-02-02 トヨタ自動車株式会社 リチウムイオン伝導性固体電解質
JP6699473B2 (ja) * 2015-09-14 2020-05-27 トヨタ自動車株式会社 全固体電池システム及びその製造方法
EP3513447A4 (fr) * 2016-09-16 2020-07-01 Robert Bosch GmbH Matériau actif de cathode revêtu destiné à des interfaces de batterie à l'état solide modifiées
JP6916815B2 (ja) * 2016-12-16 2021-08-11 株式会社日立製作所 二次電池用電極、二次電池、それらの製造方法
KR20180071438A (ko) 2016-12-19 2018-06-28 현대자동차주식회사 양극 활물질 및 이의 제조방법과 이를 이용한 전고체 전지
KR102496180B1 (ko) * 2016-12-28 2023-02-06 현대자동차주식회사 에너지 밀도가 향상된 전고체 전지 및 이의 제조방법
WO2018123322A1 (fr) * 2016-12-29 2018-07-05 株式会社 村田製作所 Matériau actif d'électrode négative, électrode négative, batterie, bloc-batterie, dispositif électronique, véhicule électrique, dispositif d'accumulation d'énergie et système d'alimentation
JP7050898B2 (ja) * 2017-04-10 2022-04-08 アルトゥーロ・ソリス・エルレラ 固体メラニン電池
KR102529616B1 (ko) * 2017-06-26 2023-05-04 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질의 제작 방법 및 이차 전지
JP6838521B2 (ja) * 2017-08-10 2021-03-03 トヨタ自動車株式会社 全固体電池および負極
WO2019063431A1 (fr) * 2017-09-29 2019-04-04 Robert Bosch Gmbh Électrode composite à l'état solide dotée de matériaux revêtus
US10930927B2 (en) 2017-11-08 2021-02-23 Samsung Electronics Co., Ltd. Positive electrode active material, methods for the manufacture thereof, and electrochemical cell comprising the positive electrode active material
KR102575407B1 (ko) 2017-12-07 2023-09-05 현대자동차주식회사 전고체 이차 전지용 양극활물질 및 그 제조 방법
WO2019135322A1 (fr) * 2018-01-05 2019-07-11 パナソニックＩｐマネジメント株式会社 Matériau d'électrode positive et batterie
CN111566851B (zh) * 2018-01-26 2024-05-24 松下知识产权经营株式会社 正极材料和电池
JP6512332B2 (ja) * 2018-03-27 2019-05-15 Tdk株式会社 リチウムイオン二次電池
KR20200028165A (ko) 2018-09-06 2020-03-16 삼성전자주식회사 고체 전해질, 그 제조방법 및 이를 포함하는 이차전지
CN109449492B (zh) * 2018-11-01 2022-03-29 中南大学 一种陶瓷基全固态电池及其制备方法
TWI676316B (zh) * 2018-11-06 2019-11-01 輝能科技股份有限公司 極層複合材料改良結構
KR102650658B1 (ko) 2018-11-15 2024-03-25 삼성전자주식회사 헤테로고리 방향족 구조의 음이온을 포함하는 금속염 및 그 제조방법, 그리고 상기 금속염을 포함하는 전해질 및 전기화학소자
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JP7366663B2 (ja) * 2019-09-18 2023-10-23 太平洋セメント株式会社 全固体二次電池用正極活物質複合体及びその製造方法
JP2024098726A (ja) 2023-01-11 2024-07-24 トヨタ自動車株式会社 複合粒子、正極、および全固体電池

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WO2007004590A1 (fr) * 2005-07-01 2007-01-11 National Institute For Materials Science Batterie au lithium entierement a l'etat solide

Also Published As

Publication number Publication date
EP2353198A1 (fr) 2011-08-10
JP4948510B2 (ja) 2012-06-06
KR101314031B1 (ko) 2013-10-01
RU2485635C2 (ru) 2013-06-20
CN102239589A (zh) 2011-11-09
AU2009323792A1 (en) 2011-06-23
JP2010135090A (ja) 2010-06-17
BRPI0922356A2 (pt) 2017-10-24
KR20110091735A (ko) 2011-08-12
CA2745379C (fr) 2016-01-12
CA2745379A1 (fr) 2010-06-10
WO2010064127A1 (fr) 2010-06-10
RU2011122217A (ru) 2013-01-10
US20120052396A1 (en) 2012-03-01
TW201037875A (en) 2010-10-16
AU2009323792B2 (en) 2013-08-15

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