TWI225046B - Phthalamide derivatives, or salt thereof agrohorticultural insecticide, and method for using the same - Google Patents

Phthalamide derivatives, or salt thereof agrohorticultural insecticide, and method for using the same Download PDF

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Publication number
TWI225046B
TWI225046B TW088120428A TW88120428A TWI225046B TW I225046 B TWI225046 B TW I225046B TW 088120428 A TW088120428 A TW 088120428A TW 88120428 A TW88120428 A TW 88120428A TW I225046 B TWI225046 B TW I225046B
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Taiwan
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alkyl
halo
group
halogen
alkoxy
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TW088120428A
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English (en)
Inventor
Masanori Tonishi
Hayami Nakao
Eiji Kohno
Tatsuki Nishida
Takashi Furuya
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Nihon Nohyaku Co Ltd
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    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C317/28—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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    • C07C317/34—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring
    • C07C317/38—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atom of at least one amino group being part of any of the groups, X being a hetero atom, Y being any atom, e.g. N-acylaminosulfones
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    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
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Description

u〇U46
CH2SCH3 , CH2SOCH3 ,或
Q 七，. ),2： CH2S02CH3 及R可相同或相異，表示氫原子，（V c6院基； 插入〜或 子· 5 可結合A1或R1形成5-至7-員環，其可 個相同或相異的氧原子、硫原子或氮原 可相同或相異表示鹵原子，硝基，_ c6烷基、 1¾ Q n _ 1 6 $兀基，C2-C6烯基，鹵c2-c6烯基，c2-c6炔 基 5 r^i # 國C^c6炔基，c3-C6環烷基，鹵c3-c6環烷基， 广ό院氧基，鹵（：】-(：6烷氧基，CVC6烷硫基，鹵Cr C6j:完硫基，C!-C6烷基亞磺醯基，鹵CrC6烷基亞磺醯 基’ C1-C6烷基磺醯基，鹵CrC6烷基磺醯基，或經取 代之苯氧基，其具有至少一個相同或相異之取代基 選自鹵（Vc6烷基，及1表示整數0至4;以及 或者，X可與苯基環之毗鄰碳原子共同形成一個 稠合環，且該稠合環含有至少一個相同或相異的取 代基選自鹵原子；以及 Y可相同或相異且表示鹵原子，c! -c6烷基，鹵 1225046 /、、申睛專利範圍 C】-C6烷基，羥C]_C6烷基，羥鹵Ci_c6烷基，（^乂烷 氧基鹵κ6烷基，（:^匕烷硫基鹵CVC6烷基，c3-c6 .嫌基，鹵cvc6烯基，c3-c6炔基，鹵c3-c6炔基，CV c6烷氧基，鹵（^匕烷氧基，CVC6烷氧基鹵CVC6烷 氧基’〔^(：6烷硫基鹵（VC6烷氧基，鹵CVC6烷氧基 _ G-C6烷氧基，鹵〇3-(：6烯氧基，cvc6烷硫基，鹵 C〗-C6烷硫基，鹵c]_c6烷氧基鹵Ci_C6烷硫基，鹵 C1 -C6烯硫基，c! -C6烷基亞磺醯基，鹵q -C6烷基亞 石黃醒基，（Vc6烷基磺醯基，鹵cvc6烷基磺醯基，單 q-C6烷基胺基、二（:厂匕烷基胺基（其中Cl-c6烷基可 相同或相異）、Cl_C6烷氧羰基，C3_C6環烷基，鹵c3-匸6環院基，二焼胺基擴醯基（其中CrG院基可 相同或相異），鹵C]-C6烷基磺醯氧基，二Cl-C6院胺 基羰基（其中Cl_C6烷基可相同或相異），三C^C6院基 砂烷基，鹵C^C：6烷基磺醯基胺基，苯基，經取代之 苯基，其含有至少一個相同或相異取代基選自下列 組群包含鹵原子、CrC6烷基、鹵C^c6烷基、CrC6 院氧基、鹵^-匕烷氧基、（VC6烷硫_、鹵 硫基、齒（VC6院基亞擴醯基及鹵（^〇6烷基磺醯 基’苯氧基’經取代之本氧基’其具有至少一個相 同或相異取代基選自下列組群包含鹵原子、Ci _C6火完 基、鹵C]-C6烷基、Ci-C6烷氧基、鹵c]‘c6^氧基、 &lt;^-〇6;1:兀硫基'鹵（：1-(：6：1：元硫基、鹵（：】、(^烷基亞磺醯 1225046 t、申請專利範圍 基及鹵CfC6院基磺醒基；苯基硫基，經取代之苯其 硫基，其具有至少一個相同或相異的取代基係 下列組群包含鹵原子 ' &lt;:丨-c6烷基、_ Γ W ^丨 L6 ί元基、 C】-C6烷氧基、鹵CVC6烷氧基、烷硫基、鹵c】· 烷硫基、鹵（V C6烷基亞磺醯基及鹵Γ w C L 6 /兀基石貝 醯基；經取代之苯基Cl-C6烷基，其具有至少一個相 同或相異之取代基選自鹵原子或羥基；經取代之苯鑛 基，其有至少一個相同或相異之取代基選自鹵原子或 C厂C6院基；經取代之苯基胺羰基，於其環上帶有至少 個相同或相異之取代基選自鹵原子；經取代之苯基_ N-G-C6烷基胺羰基，於其環上帶有至少一個取代基選 自鹵原子，吡啶基氧基；經取代之吡啶基氧基，其含 有至少一個相同或相異的取代基選自下列組群包含 鹵原子、cvc6烷基、鹵cvc6烷基、Cl_C6烷氧基、 m表示1至5之整數；及 鹵〔厂匕烷氧基、Ci_c6烷硫基、鹵烷硫基、鹵 C]-C6；(:完基亞磺醯基及鹵Ci_C6烷基磺醯基；吡啶基硫 基’經取代之吡啶基硫基，其含有至少一個相同或 相異的取代基選自下列組群包含鹵原子、C! - C6烷 基、齒1-(：6烷基、CrC6烷氧基、鹵（^-(：6烷氧基、 C】-C6院硫基、鹵c】_c6烷硫基、鹵烷基亞磺醯 基及鹵CrC6烷基磺醯基；或c(N = 〇- cvc6烷基）經 取代之苯基’其具有至少一個相同或相異之取代基 選自鹵原子；及 1225046 六、申請專利範圍 γ可與苯基環上毗鄰碳原子共同接合形成〜_ _ 合環，及該稠合環可含有至少一個相同或相異的取 代基選自鹵原子；以及 η表示0至2之整數。 2 ·如申請專利範圍第1項之酞醯胺衍生物或其鹽，其 中Α1表示CVh伸烷基； R1表示氫原子，（VC6烷基，鹵（VC6烷基，c r π6 烯基，C3-C6炔基，CVCJl烷基，c】-c6烷硫基， c6烷氧基cvc6烷基，CVG烷硫基（VC6烷基，c Γ 1 - 烷基羰基，單（VC6烷基胺基羰基，二院基 胺基羰基（其中h - C6烷基可相同或相異），單c _ Γ 1 16 烷基胺基硫羰基，二（^-(:6烷基胺基硫羰基（其中C1_ C6烷基可相同或相異），C】_C6烷基羰基Ci—c6烷基， C】-C6烷氧亞胺基（：丨&lt;6烷基，Cl-C6烷氧羰基（Vc6j^ 基’單c】-C6《兀基te：基叛基c】-C6院基或二c^-c^院基 胺基羰基G-C6烷基（其中c]_c6烷基可相同或相 異）·， R2及R3可相同或相異表示氫原子或C]_C6烷基； X可相同或相異表示鹵原子，硝基，Ci_C6烷基， 鹵CVC6院基，Crh烷氧基，鹵（：]-(：6烷氧基， 院硫基、鹵CVC6烷硫基、c]_c6烷基亞磺醯基，鹵 C^C：6烷基亞磺醯基、（^―匕烷基磺醯基或鹵 基feiS®基，及1表示〇至4之整數；且 1225046
六、申請專利範圍 或者，X可與苯基環之毗鄰碳原子共同接合形成 一個稠合環，且該稠合環可含有至少一個相同或相 異取代基選自鹵原子； Y可相同或相異及表示鹵原子，C】-C6烷基，鹵 C^c6烷基，（^-匕烷氧基鹵（VC6烷基，cvc6烷氧 基，鹵cvc6烷氧基，鹵（^&lt;6烷氧基鹵（VC6烷氧 基，CrC6烷硫基，鹵（^-(：6烷硫基，（^-(^烷基亞磺 醯基、鹵C^C：6烷基亞磺醯基，烷基磺醯基、齒 q-C6烷基磺醯基；經取代之苯基，其含有至少—個 相同或相異的取代基選自下列組群包含鹵原子、 c6烷基、鹵c]-c6烷基、c]-c6烷氧基、鹵〇^(：6院氧 基、院硫基、鹵院硫基、鹵C]-C6焼基亞 磺醯基及鹵C^C：6烷基磺醯基；經取代之苯氧.基，其 含有至少一個相同或相異取代基選自下列組群包含 鹵原子、C! - C6院基、鹵C! - C6院基、C】-c6院氧基、 鹵（：】-(：6烷氧基、cvc6烷硫基、鹵CVC6烷硫基、齒 h-C6烷基亞磺醯基及鹵C^C：6烷基磺醯基；或經取代 之吡啶基氧基，其含有至少一個相同或相異的取α 基選自下列組群包含鹵原子、C! - C6院基、鹵c】-c6 j:完 基、CVC6院氧基、鹵C】-C6院氧基、CVCe院硫基、 鹵C ] - C6院硫基、鹵C】-C6院基亞磺醯基及鹵c j - c 6 j:完 基磺醯基；及m表示1至5之整數；以及 γ可與苯環上毗鄰碳原子共同形成一個稠合環， 1225046 六、申請專利範圍 且該稠合環含有至少一個相同或相異的取代基選自 鹵原子；以及 η表示〇至2之整數。 3 . —種農園藝殺蟲劑，其特徵在於含有作爲其活性成 VC-N-R2 (Υ)η II ο 其中Α1表示0丨-(：6伸烷基；經取代之（:丨-匕伸烷 基，其含有至少一個相同或相異的取代基係選自下 列組群包含鹵原子，鹵烷基，烷氧基， 鹵C^-C^院氧基’ CVC^院硫基，鹵院硫基， Κ6烷基亞磺醯基，鹵（VC6烷基亞磺醯基，（VG 烷基磺醯基，鹵烷基磺醯基，羥（^-(：6烷基， 苯基，及CVC6烷硫基（VC6烷基，以及 R1表示氫原子，毓基，（VC6烷基，鹵Ci-C6烷 基，c3-c6烯基，鹵c3-c6烯基，c3-c6炔基，鹵c3-c6 炔基，C3-C6環烷基，鹵C3-C6環烷基，CVC6烷硫 基，鹵Ci-G烷硫基，羥CVC6烷基，（^(：6烷氧基 (VC6烷基，Κ6烷硫基cvc6烷基，單（VC6烷胺 基（VC6烷基，二G-C6烷胺基（VC6烷基（其中cvc6 烷基可相同或相異）’ C1 _c6烷基羰基’鹵q -C6烷基 分之一種如下通式（I)表示之酞醯胺衍生物或其鹽， (0)。 001 0 Α1- “1
1225046 六、申請專利範圍
羰基，（Vc6烷硫基羰基，Cl_c6烷氧羰基，單^ c 烷基胺基羰基，二C】-C：6烷基胺基羰基（其中c丨-c6院 基可相同或相異），單c丨-c6烷基胺基硫羰基，二c] _ C6烷基胺基硫羰基（其中c! -C6烷基可相同或相異）， 丨元基鑛基Ci-C6院基，院氧亞胺基 烷基，CVC：6烷氧羰基CVC6烷基，鹵〇]&lt;6烷羰氧基 c]-c6烷基，單（VC6烷基胺基羰基（VC6烷基，二 C]-C6烷基胺基羰基c】-C6烷基（其中（：^(：6烷基可相 同或相異），苯基，經取代之苯基，其具有至少一個 相同或相異取代基係選自下列組群包含鹵原子，氰 基’硝基’ C ] - C6院基，鹵C】-C6院基，C丨-C 6院氧 基’鹵C!-C6院氧基，院硫基，鹵完硫 基’ c!-C6烷基亞磺醯基，鹵G - c6烷基亞磺醯基， (VC6烷基磺醯基，鹵cvc6烷基磺醯基，單 烷胺基，二（VC6烷胺基（其中cvc6烷基可相同或 相異）’及C ] - C 6院氧羰基；苯基C! - C 6院基，經取代 之苯基C】-C 6院基，於其環上有至少一個相同或相異 取代基選自下列組群包含鹵原子、氰基、硝基、C i、 c6烷基、鹵CVC6烷基、CVC6烷氧基、鹵（：^(：6烷氧 基、C! -C6烷硫基、鹵c! -C6烷硫基、c, -C6烷基亞_ 醯基、鹵c^c6烷基亞磺醯基、Cl-C6烷基磺醯基、 鹵Cr C6烷基磺醯基 '單c】-C6烷基胺基、二c!-c6 烷基胺基（其中C i - C6烷基可相同或相異）、及C, - C -10-
1225046 t、申請專利範圍 院氧線基；苯基羰基，經取代之苯基鑛基，其具有 至少一個相同或相異的取代基選自下列組群包含鹵 原子、氰基、硝基、C! -c6烷基、鹵C! -C6烷基、（V C6焼氧基、鹵C】-C6院氧基、c】-C6焼硫基、鹵CVC6 院硫基、C! - C6烷基亞磺醯基、鹵c] - c6烷基亞磺醯 基、cvc6烷基磺醯基 '鹵Cl_c6烷基磺醯基、單Cl-C6烷基胺基、二C】-C6烷基胺基（其中c]_c6烷基可相 同或相異）、及CrG烷氧羰基；苯基硫基；經取代 之苯基硫基，其具有至少一個相同或相異取代基選 自下列組群包含鹵原子，氰基，硝基，C^c6烷基， 鹵CVC6烷基’ CVC6烷氧基，鹵Cl_c6烷氧基，（VC6 院硫基’鹵C!-C6院硫基，院基亞擴醯基，齒 cvc6烷基亞磺醯基，cvc6烷基磺醯基，鹵cvc6烷 基磺醯基，單（:厂匕烷基胺基，二。-(^烷基胺基（其 中CrQ烷基可相同或相異），及Cl-C6烷氧羰基；吡 啶基，噻唑基，噻二唑基，苯并噻唑基，經取代之 嘧啶基，具有至少一個相同或相異之取代基選自C】-c6烷基；或 或者，R 1可結合A1形成
to
&gt; 1 1 &gt; 1225046 申睛專利範圍
CH2SCH3 , CH2SOCH3 , Q-： _ ιΟ CH2S02CH3 ； R及R3可相同或相異，表示氫原子，Ci_C6烷基； 或 或者’ R2可結合A1或R]形成5-至7-員環，其可插 入一或一個相同或相異的氧原子、硫原子或氮原子； 、X可相同或相異表示鹵原子，硝基，烷基、 鹵Cl C6蜣基，CVc6烯基，鹵c2-c6烯基，C2-C6炔 基 ® C2_C6炔基，c3-c6環烷基，鹵c3-c6環烷基， 氧基，鹵（^匕烷氧基，烷硫基，鹵c]_ C6烷硫基，Cl-C6烷基亞磺醯基，鹵CrC6烷基亞磺醯 基，C广C6烷基磺醯基，鹵c】-C6烷基磺醯基，或經取 代之本氧基’其有至少一個相同或相異之取代基選 自鹵c^c：6烷基，及丨表示整數〇至4 ;以及 或者’ X可與苯基環之毗鄰碳原子共同形成一個 稠口 ，且s亥稠合環含有至少一個相同或相異的取 代基選自鹵原子；以及 Y可相同或相異且表示鹵原子，Ci_C6院基，齒 c,-c6烷基，羥Ci-c6烷基，羥鹵C「C6烷基’ 烷 1 1225046 申請專利範圍 氧基鹵cvc6院基，（^-(：6烷硫基鹵烷基，c3-c6 烯基，鹵C3-C6烯基，CVC6炔基，鹵C3_C6炔基， C6院氧基’鹵（^-匕烷氧基，Cl-C6烷氧基鹵CrCdt 與基’（^-(1!6丨兀硫基鹵C】-C6院氧基，鹵焼氧基 齒Ci-Ce院氧基’鹵C3-C6烯氧基，（^-(：6烷硫基，鹵 C1-C6 fet硫基’鹵c! -C6烷氧基鹵c! -c6烷硫基，鹵 Ci-C6^硫基’ c】-C6丨元基亞礦釀基，鹵C j - C 6院某亞 石貝醯基’ G-C：6烷基磺醯基，鹵CrC6烷基磺醯基，單 C〗-C6烷基胺基、二CVC6烷基胺基（其中c】-c6院基可 相同或相異）、c】-C6燒氧羯基，C3-C6環燒基，鹵c3_ G環烷基’二c]-C6烷胺基磺醯基（其中Ci_c6烷基可 相同或相異），鹵cvc6烷基磺醯氧基，二c]_c6院胺 基羰基（其中C! -C6烷基可相同或相異），三c; -C6烷基 砂烷基，幽C, -c6烷基磺醯基胺基，苯基，經取代之 本基，其含有至少一個相同或相異取代基選自下列 組群包含鹵原子、（VC6烷基、鹵（VC6烷基、cvc6 院氧基、鹵（^(：6烷氧基、CVC6烷硫基、鹵（^-“烷 硫基、鹵烷基亞磺醯基及鹵烷基磺醯 基；苯氧基，經取代之苯氧基，其有至少一個相同 或相異取代基選自下列組群包含鹵原子、C! - C6烷 基、鹵c^c6烷基、CVC6烷氧基、鹵1-(：6烷氧基、 C^c6烷硫基、鹵Cl-C6烷硫基、鹵（VC6烷基亞磺醯 基及鹵C! -c6烷基磺醯基；苯基硫基，經取代之苯基 1225046 ^、申請專利範圍 硫基，其含有至少一個相同或相異的取代基係選自 下列組群包含鹵原子、eve,烷基、鹵Ci-C6院基、 cvc6烷氧基、鹵（VC6烷氧基、Ci_c6烷硫基、鹵c]_ 匸6丨兀硫基、齒c】-C6院基亞磺if基及鹵院基石黃 醯基’經取代之本基C ] - C6院基，其有至少一個相同 或相異之取代基選自鹵原子或經基，經取代之苯鑛 基，其有至少一個相同或相異之取代基選自鹵原子或 C】-C6烷基，經取代之苯基胺羰基，其於環上帶有至少 個相同或相異之取代基選自鹵原子，經取代之苯基_ N - Cl - C6院基胺羰基，其於環上帶有至少一個取代基選 自鹵原子，吡啶基氧基，經取代之吡啶基氧基，其含 有至少一個相同或相異的取代基選自下列組群包含 鹵原子、（VC6烷基、鹵CVC6烷基、（：】-(：6烷氧基、 _ ^&lt;6烷氧基、c^C6烷硫基、鹵（VC6烷硫基、鹵 CrC6院基亞磺醯基及鹵Cl_c6烷基磺醯基；吡啶基硫 基’經取代之吡啶基硫基，其含有至少一個相同或 #異的取代基選自下列組群包含鹵原子、Cl _C6烷 基 '鹵烷基、Ci-C6烷氧基、鹵1-(：6烷氧基、 C】-G燒硫基、鹵烷硫基 '鹵cvc6烷基亞磺醯 基及齒C「C6烷基磺醯基；或C(N = 0- (VC6烷基）經 取代苯基，其有至少一個相同或相異之取代基選 白鹵原子；及m表不1至5之整數，及 Y可與苯基環上毗鄰碳原子共同接合形成一個稠 1225046 六、申請專利範圍 合環’及該稠合環可含有至少一個相同或相異的取 代基選自鹵原子；以及 η表示〇至2之整數。 4 .如申請專利範圍第3項之農園藝殺蟲劑，其中Al表 示C6伸烷基； R1表示氫原子，CVC6烷基，鹵C】-C6烷基，c3-c6 燒基’ C3-C6炔基，（：346環烷基，C]-C6烷硫基， C6燒氧基（VC6烷基，cvc6烷硫基cvc6烷基，Cl_c6 院基鑛基，單c]_c6烷胺基羰基，二^-(^烷胺基羰 基（其中C^C：6烷基可相同或相異），單c】-c6烷胺基 硫缓基’二（：厂(：6烷基胺基硫羰基（其中（Vc6院基可 相同或相異），（^(：6烷基羰基Ci-C6烷基，Crh烷氧 亞月女基C]-C6；t兀基’（^-(^6火元氧羯基Ci_C6院基，單 CI-C6院基胺基羰基Cl-c6烷基或二Ci_c6烷基胺基羰 基C^C：6烷基（其中CrG烷基可相同或相異）； R2及R3可相同或相異表示氫原子或Cl-C6烷基； X可相同或相異表示鹵原子，硝基，c] - c6院基， 齒C^C6院基，Ci_C6烷氧基，鹵c】-c6烷氧基，Cl-C6 丈元硫基、鹵。-(：6烷硫基、c^c6烷基亞磺醯基，鹵 h-C6院基亞磺醯基、。—(^烷基磺醯基或鹵1-(：6烷 基擴醯基；及丨表示0至4之整數；以及 或者’ X可與苯基環之毗鄰碳原子共同接合形成 〜個稠合環’且該稠合環可含有至少一個相同或相 1225046
、申請專利範圍 異取代基選自鹵原子； Y可相同或相異及表示鹵原子，G - c6烷基，鹵 c!-c6烷基，（^(：6烷氧基鹵（VC6烷基，CVC6烷氧 基’鹵C!-C6烷氧基，鹵cvc6烷氧基鹵（^-(^烷氧 基’ 烷硫基，鹵（^_〇6烷硫基，（^匕烷基亞磺 廳基、鹵烷基亞磺醯基，烷基磺醯基、鹵 C ! - C6烷基磺醯基，經取代之苯基，其含有至少一個 相同或相異的取代基選自下列組群包含鹵原子、C1 _ c6烷基、鹵（vc6烷基、cvg烷氧基、鹵&lt;vc6烷氧 基、cvc6烷硫基、鹵cvg烷硫基、鹵cvc6烷基亞 磺醯基及鹵烷基磺醯基；經取代之苯氧基，其 含有至少一個相同或相異取代基選自下列組群包含 鹵原子、cvc6烷基、鹵cvc6烷基、（^-(：6烷氧基、 國C ! - C 6院氧基、C ! - C 6焼硫基、鹵C i - C 6院硫基、鹵
Cj-C6烷基亞磺醯基及鹵CrC6烷基磺醯基；或經取代 之吡啶基氧基，其含有至少一個相同或相異的取代 基選自下列組群包含鹵原子、CrC6烷基、鹵Cl-C6；^ 基、（VC6烷氧基、鹵（：】-(：6烷氧基、（vc6烷硫基、 鹵CVC6烷硫基、鹵CVC6烷基亞磺醯基及鹵 基磺醯基；及m表示1至5之整數；以及 γ可與苯環上毗鄰碳原子共同形成一個稠合環， 且該稠合環含有至少一個相同或相異的取代基選自 鹵原子；以及 η表示0至2之整數。
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Families Citing this family (116)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUP0201555A3 (en) * 1999-06-24 2002-12-28 Nihon Nohyaku Co Ltd Heterocyclic dicarboxylic acid diamide derivatives and insecticide compositions containing these compounds
AR030154A1 (es) 1999-07-05 2003-08-13 Nihon Nohyaku Co Ltd Derivado de ftalamida, derivado de amina heterociclico util como intermediario para la produccion del mismo, insecticida agrohorticola y metodo para utilizar dicho insecticida
JP2002105046A (ja) * 2000-09-25 2002-04-10 Nippon Nohyaku Co Ltd チオアルキルアミン−ｓ−酸化体及びその塩類
DE10115406A1 (de) * 2001-02-06 2002-08-08 Bayer Ag Phthalsäurediamide
EP1360190B1 (de) * 2001-02-06 2005-09-07 Bayer CropScience AG Phthalsäurediamide, ein verfahren zu ihrer herstellung und ihre verwendung als schädlingsbekämpfungsmittel
US7361653B2 (en) * 2001-04-17 2008-04-22 Nihon Nohyaku Co., Ltd Pest control agent composition and method of using the same
KR20040032096A (ko) * 2001-04-26 2004-04-14 니혼노야쿠가부시키가이샤 농업 및 원예 용도를 위한 프탈아미드 유도체, 살충제, 및이들의 적용 방법
EP1389613A4 (en) * 2001-04-26 2004-06-02 Nihon Nohyaku Co Ltd PHTHALAMIDE DERIVATIVES, AN INSECTICIDE FOR AGRICULTURAL AND HORTICULTURAL USE AND THEIR APPLICATION METHOD
AR035884A1 (es) 2001-05-18 2004-07-21 Nihon Nohyaku Co Ltd Derivado de amida aromatico sustituido, derivado de amina aromatico sustituido con un grupo fluoroalquilo util como intermediario para obtener el mismo, insecticida para agrohorticultura que lo contiene y metodo para usar este ultimo
WO2003011028A1 (en) * 2001-08-01 2003-02-13 Nissan Chemical Industries, Ltd. Substituted amides and pest controllers
DE10157545A1 (de) * 2001-11-23 2003-06-12 Bayer Cropscience Gmbh Herbizide Mittel enthaltend Benzoylpyrazole und Safener
US7151195B2 (en) 2002-05-02 2006-12-19 Bayer Cropscience Lp Phthalamide derivative, agricultural or horticultural insecticide, and method of use thereof
JP2004018506A (ja) * 2002-06-20 2004-01-22 Bayer Ag 殺虫性フタラミド誘導体
EP1538138A4 (en) * 2002-08-26 2007-07-25 Nissan Chemical Ind Ltd SUBSTITUTED BENZANILIDE COMPOUND AND PROTECTIVE AGENTS
JP4411582B2 (ja) * 2002-08-26 2010-02-10 日本農薬株式会社 スルホンアミド誘導体及び農園芸用殺虫剤並びにその使用方法
DE10248257A1 (de) * 2002-10-16 2004-04-29 Bayer Cropscience Ag Wirkstoffkombinationen im insektiziden und akariziden Eigenschaften
DE10310906A1 (de) * 2003-03-13 2004-09-23 Bayer Cropscience Ag Synergistische Wirkstoffkombinationen
JP2004277333A (ja) 2003-03-14 2004-10-07 Bayer Cropscience Ag 殺虫性フタラミド誘導体
DE10330724A1 (de) 2003-07-08 2005-01-27 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10330723A1 (de) * 2003-07-08 2005-02-03 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
US7790377B2 (en) * 2003-08-29 2010-09-07 The University Of North Carolina At Greensboro Compounds that act to modulate insect growth and methods and systems for identifying such compounds
US8637237B2 (en) * 2003-08-29 2014-01-28 The University Of North Carolina At Greensboro Methods, compositions, and systems for the identification of species-specific or developmental stage-specific insecticides
US20100240056A1 (en) * 2003-08-29 2010-09-23 Henrich Iii Vincent C Methods And Systems For Screening Species-Specific Insecticidal Candidates
CA2772017C (en) * 2003-08-29 2016-05-31 Mitsui Chemicals, Inc. Agricultural/horticultural insecticide and method for using the same
JP2005114718A (ja) * 2003-10-10 2005-04-28 Bayer Cropscience Ag 殺虫剤活性化合物を特定するための方法
JP2006076990A (ja) * 2004-03-12 2006-03-23 Bayer Cropscience Ag 殺虫性ベンゼンジカルボキサミド類
US7459562B2 (en) * 2004-04-23 2008-12-02 Bristol-Myers Squibb Company Monocyclic heterocycles as kinase inhibitors
TW200538453A (en) * 2004-04-26 2005-12-01 Bristol Myers Squibb Co Bicyclic heterocycles as kinase inhibitors
US7432373B2 (en) * 2004-06-28 2008-10-07 Bristol-Meyers Squibb Company Processes and intermediates useful for preparing fused heterocyclic kinase inhibitors
US7173031B2 (en) 2004-06-28 2007-02-06 Bristol-Myers Squibb Company Pyrrolotriazine kinase inhibitors
US7439246B2 (en) * 2004-06-28 2008-10-21 Bristol-Myers Squibb Company Fused heterocyclic kinase inhibitors
DE102004035134A1 (de) 2004-07-20 2006-02-16 Bayer Cropscience Ag Selektive Insektizide auf Basis von Halogenalkylnicotinsäurederivaten, Anthranilsäureamiden oder Phthalsäurediamiden und Safenern
GB0418047D0 (en) 2004-08-12 2004-09-15 Syngenta Participations Ag Fungicidal compositions
CN101006049A (zh) * 2004-08-23 2007-07-25 日本农药株式会社 旋光邻苯二酰胺衍生物、农业或园艺杀虫剂及其使用方法
WO2006024402A1 (de) * 2004-08-31 2006-03-09 Bayer Cropscience Ag Chirale 3-halophthalsäure-derivate
JP4977607B2 (ja) * 2004-08-31 2012-07-18 バイエル・クロップサイエンス・アーゲー 光学活性フタルアミド
GB0419420D0 (en) * 2004-09-01 2004-10-06 Syngenta Participations Ag Novel insecticides
TW200626532A (en) 2004-09-21 2006-08-01 Syngenta Participations Ag Novel insecticides
GB0422401D0 (en) 2004-10-08 2004-11-10 Syngenta Participations Ag Fungicidal compositions
DE102004055582A1 (de) 2004-11-18 2006-05-24 Bayer Cropscience Ag N-Heterocyclyl-phthalsäurediamide
EP1688039A3 (en) * 2005-02-08 2006-10-11 Nihon Nohyaku Co., Ltd. Agricultural and horticultural poison bait preparation
JP2006347936A (ja) 2005-06-15 2006-12-28 Bayer Cropscience Ag 殺虫性ベンズアニリド類
DE102005059466A1 (de) * 2005-12-13 2007-06-14 Bayer Cropscience Ag Insektizide Zusammensetzungen mit verbesserter Wirkung
DE102005059467A1 (de) * 2005-12-13 2007-06-14 Bayer Cropscience Ag Insektizide Zusammensetzungen mit verbesserter Wirkung
ES2381864T3 (es) 2005-12-15 2012-06-01 Nihon Nohyaku Co., Ltd. Derivado de ftalamida, pesticida agrícola u hortícola y utilización del pesticida
TW200803740A (en) 2005-12-16 2008-01-16 Du Pont 5-aryl isoxazolines for controlling invertebrate pests
TWI324908B (en) * 2006-01-05 2010-05-21 Du Pont Liquid formulations of carboxamide arthropodicides
ZA200804771B (en) * 2006-01-05 2009-10-28 Du Pont Liquid formulations of carboxamide arthropodicides
CN101410016B (zh) 2006-02-09 2013-07-31 先正达参股股份有限公司 杀真菌组合物
DE102006015197A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden Eigenschaften
DE102006010206A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006010208A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006010204A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006010211A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006037120A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Synergistische Wirkstoffkombinationen
DE102006010209A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102006010201A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Synergistische Zusammensetzungen
DE102006010205A1 (de) * 2006-03-06 2007-09-13 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
KR101385068B1 (ko) * 2006-03-27 2014-04-25 신젠타 파티서페이션즈 아게 과립 제형
WO2007112844A1 (de) * 2006-03-29 2007-10-11 Bayer Cropscience Ag Neue kristalline modifikationen von 3-chlor-n2-[(1s)-1-methyl-2-(methyl-sulfonyl)ethyl]-n1- {2-methyl-4-[1,2,2,2-tetrafluor-1-(trifluormethyl)- ethyl]phenyl}phthalamid
JP2009532347A (ja) * 2006-03-31 2009-09-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 節足動物の生殖能を撹乱する方法
BRPI0710751A2 (pt) * 2006-04-28 2011-06-14 Syngenta Participations Ag composto, mÉtodo de combater e controlar insetos, acarinos, nematàdeos ou moluscos, e, composiÇço inseticida, acaridica ou nematicida
DE102006027732A1 (de) * 2006-06-16 2008-01-10 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006027731A1 (de) 2006-06-16 2007-12-20 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
CL2007002306A1 (es) * 2006-08-09 2009-08-28 Du Pont Metodo para incrementar el rendimiento de un cultivo o el vigor de un cultivo y detener la transmision de enfermedades infecciosas por artropodos plaga que comprende tratar plantas de un cultivo con una carboxamida artropodicida,su n-oxido, o una sal de esta.
WO2008037378A2 (de) * 2006-09-30 2008-04-03 Bayer Cropscience Aktiengesellschaft Suspensionskonzentrate zur verbesserung der wurzelaufnahme von agrochemischen wirkstoffen
KR20090060446A (ko) * 2006-09-30 2009-06-12 바이엘 크롭사이언스 아게 재배 기재에 적용시 농약 조성물의 생물학적 작용 개선, 적합한 제제 및 그의 용도
WO2008037376A2 (de) * 2006-09-30 2008-04-03 Bayer Cropscience Aktiengesellschaft Verbesserung der biologischen wirkung von agrochemischen zusammensetzungen bei applikation in das kultursubstrat, geeignete formulierungen und ihre anwendung
TWI484910B (zh) * 2006-12-01 2015-05-21 Du Pont 甲醯胺殺節肢動物劑之液體調配物
CL2007003748A1 (es) 2006-12-22 2008-07-18 Bayer Cropscience Ag Composicion pesticida que comprende fosetil-al, propamocarb-hcl y una sustancia insecticida activa; y metodo para controlar hongos fitopatogenos o insecticidas daninos de las plantas, cultivos o semillas que comprende aplicar dicha composicion.
TWI430995B (zh) 2007-06-26 2014-03-21 Du Pont 萘異唑啉無脊椎有害動物控制劑
MX2009013750A (es) * 2007-06-27 2010-01-25 Du Pont Formulaciones solidas de artropodicidas de carboxamida.
KR20100039859A (ko) * 2007-06-27 2010-04-16 이 아이 듀폰 디 네모아 앤드 캄파니 카르복스아미드 살절지동물제의 고체 제형
JP5345617B2 (ja) * 2007-07-27 2013-11-20 バイエル・クロップサイエンス・アーゲー 三元活性化合物組合せ
EP2033516A1 (de) 2007-09-05 2009-03-11 Bayer CropScience AG Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
EP2070414A1 (en) * 2007-12-11 2009-06-17 Bayer CropScience AG Active compound combinations
TWI401023B (zh) 2008-02-06 2013-07-11 Du Pont 中離子農藥
EP2127522A1 (de) 2008-05-29 2009-12-02 Bayer CropScience AG Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
WO2010013684A1 (ja) 2008-07-29 2010-02-04 イハラニッケイ化学工業株式会社 フタル酸ジクロリド化合物の製造方法、これに用いられる触媒及びその調製方法
EP2227951A1 (de) 2009-01-23 2010-09-15 Bayer CropScience AG Verwendung von Enaminocarbonylverbindungen zur Bekämpfung von durch Insekten übertragenen Viren
JP2011042643A (ja) * 2009-07-24 2011-03-03 Bayer Cropscience Ag 殺虫性カルボキサミド類
MX2012001646A (es) 2009-08-05 2012-03-21 Du Pont Pesticidas mesoionicos.
JP2013501059A (ja) 2009-08-05 2013-01-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー メソイオン性殺虫剤
WO2011095462A1 (en) * 2010-02-03 2011-08-11 Syngenta Participations Ag Insecticidal compounds
EP2382865A1 (de) 2010-04-28 2011-11-02 Bayer CropScience AG Synergistische Wirkstoffkombinationen
CN101803598B (zh) * 2010-04-30 2013-05-29 江苏龙灯化学有限公司 低浓度氟虫双酰胺悬浮剂
CA2799963C (en) 2010-05-27 2018-01-23 E. I. Du Pont De Nemours And Company Crystalline form of 4- [5 - [3 -chloro-5 - (trifluoromethyl) phenyl] -4,5 -dihydro-5 - (trifluoromethyl) -3 - isoxazolyl] -n- [2-0x0-2- [(2,2,2-trifluoroethyl)amino]ethyl] -1-naphthalenecarboxamide
CN101836643B (zh) * 2010-06-01 2012-12-12 扬州大学 防治小菜蛾等蔬菜害虫的农药制剂
CN101948413B (zh) * 2010-08-31 2013-03-27 上海赫腾精细化工有限公司 氟虫酰胺的制备方法
MY165916A (en) * 2011-06-06 2018-05-18 Nihon Nohyaku Co Ltd Plant growth regulator and method for using the same
CN102503876A (zh) * 2011-09-28 2012-06-20 南开大学 双酰胺衍生物及其制备和应用
JP2015027951A (ja) * 2011-11-02 2015-02-12 日本農薬株式会社 フタルアミド誘導体及び該誘導体を含有する農園芸用殺虫剤並びにその使用方法
CN102396477A (zh) * 2011-12-14 2012-04-04 湖南化工研究院 仲丁威与氟虫双酰胺的杀虫组合物
CN102578117A (zh) * 2012-01-19 2012-07-18 华南理工大学 氟虫双酰胺与鱼藤酮复配悬浮剂及其制备方法
CN103300000B (zh) * 2012-03-12 2016-04-06 陕西韦尔奇作物保护有限公司 一种含环虫酰肼与酰胺类的杀虫组合物
CN105025707A (zh) 2012-08-30 2015-11-04 先锋良种国际有限公司 使用包含利阿诺定受体激动剂的组合物的种子包衣方法
CN103503896A (zh) * 2012-12-05 2014-01-15 江苏辉丰农化股份有限公司 具有增效作用的杀虫组合物
US9549551B2 (en) 2013-04-19 2017-01-24 Bayer Cropscience Aktiengesellschaft Active compound combinations having insecticidal properties
CN104106592A (zh) * 2013-04-22 2014-10-22 陕西美邦农药有限公司 一种含氟苯虫酰胺与拟除虫菊酯类的杀虫组合物
CN103420884B (zh) * 2013-05-17 2015-12-02 南开大学 具有光学活性和几何异构的双酰胺衍生物与制备及应用
CN103392705A (zh) * 2013-07-22 2013-11-20 浙江威尔达化工有限公司 一种含氟苯虫酰胺和烯啶虫胺的杀虫组合物及其应用
CN103461376B (zh) * 2013-09-05 2015-08-12 江苏龙灯化学有限公司 一种含氟虫双酰胺和哒嗪硫磷的农药杀虫组合物
CN104855399B (zh) * 2015-05-02 2018-06-19 广东中迅农科股份有限公司 一种含有丁烯氟虫腈和氟苯虫酰胺的杀虫组合物
JP6464428B2 (ja) * 2015-08-31 2019-02-06 株式会社ダイセル 増粘安定剤、及びそれを用いた増粘安定化組成物
AU2017247937A1 (en) 2016-04-06 2018-10-04 Bayer Cropscience Aktiengesellschaft Combination of nuclear polyhedrosis virus and diamides
MX2019006738A (es) 2016-12-08 2019-08-22 Bayer Cropscience Ag Uso de insecticidas para el control de gusanos.
CN109574892B (zh) * 2018-11-29 2020-11-17 常州沃腾化工科技有限公司 微通道反应制备3-碘-n-(1,1-二甲基-2-甲硫基乙基)邻氨甲酰苯甲酸的方法
CN109485588A (zh) * 2018-12-25 2019-03-19 成都蓝蜻蜓生物技术有限公司 一种氟虫双酰胺的合成方法
CN110272361B (zh) * 2019-07-11 2021-06-11 华东理工大学 含烷氧基六氟异丙基的邻苯二甲酰胺类化合物及其应用
WO2022200364A1 (en) 2021-03-25 2022-09-29 Syngenta Crop Protection Ag Insect, acarina and nematode pest control
EP4337015A1 (en) 2021-05-14 2024-03-20 Syngenta Crop Protection AG Insect, acarina and nematode pest control
AR126212A1 (es) 2021-06-24 2023-09-27 Pi Industries Ltd Una combinación de flubendiamida y extracto de algas
WO2022268815A1 (en) 2021-06-24 2022-12-29 Syngenta Crop Protection Ag Insect, acarina and nematode pest control
WO2022268813A1 (en) 2021-06-24 2022-12-29 Syngenta Crop Protection Ag Insect, acarina and nematode pest control
WO2023105065A1 (en) 2021-12-10 2023-06-15 Syngenta Crop Protection Ag Insect, acarina and nematode pest control
WO2023105064A1 (en) 2021-12-10 2023-06-15 Syngenta Crop Protection Ag Insect, acarina and nematode pest control

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE119428C (zh)
DE3305569A1 (de) 1983-02-18 1984-08-23 Bayer Ag, 5090 Leverkusen Biscarboxamide zur bekaempfung von erkrankungen sowie verfahren zu ihrer herstellung
JPS61180753A (ja) * 1985-02-06 1986-08-13 Nippon Kayaku Co Ltd フタラミン酸誘導体およびそれを有効成分とする除草剤又は植物生長調節剤
US4937253A (en) 1985-04-19 1990-06-26 Smithkline Beecham Corporation Ester prodrugs
JPH07107601B2 (ja) 1985-07-26 1995-11-15 富士写真フイルム株式会社 ハロゲン化銀カラー写真感光材料
DE3802175A1 (de) 1988-01-26 1989-08-03 Hoechst Ag N-phenylbenzamide und n-phenylbenzamidoxime, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung als schaedlingsbekaempfungsmittel
FR2655339B2 (fr) 1989-04-19 1992-04-10 Medgenix Group Sa Composes et complexes utiles notamment en imagerie medicale.
IL95157A (en) 1989-07-28 1996-05-14 Rohm & Haas S-Melted Beta-Thioacrylamides, their preparation and use as bactericides

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