TW523490B - Procedure for preparing molecular sieve films - Google Patents
Procedure for preparing molecular sieve films Download PDFInfo
- Publication number
- TW523490B TW523490B TW086111957A TW86111957A TW523490B TW 523490 B TW523490 B TW 523490B TW 086111957 A TW086111957 A TW 086111957A TW 86111957 A TW86111957 A TW 86111957A TW 523490 B TW523490 B TW 523490B
- Authority
- TW
- Taiwan
- Prior art keywords
- molecular sieve
- carrier
- microcrystals
- membrane
- zsm
- Prior art date
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 166
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 165
- 238000000034 method Methods 0.000 title claims abstract description 103
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Classifications
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- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D67/0039—Inorganic membrane manufacture
- B01D67/0051—Inorganic membrane manufacture by controlled crystallisation, e,.g. hydrothermal growth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0083—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/105—Support pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2323/35—Use of magnetic or electrical fields
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electrochemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9600970A SE9600970D0 (sv) | 1996-03-14 | 1996-03-14 | Förfarande för framställning av mycket tunna filmer av molekylsiktar |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW523490B true TW523490B (en) | 2003-03-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086111957A TW523490B (en) | 1996-03-14 | 1997-08-15 | Procedure for preparing molecular sieve films |
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| ZA (1) | ZA972251B (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI477449B (zh) * | 2008-11-13 | 2015-03-21 | Univ Ishou | Method for producing zeolite film |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR9406483A (pt) * | 1993-04-23 | 1996-01-09 | Exxon Chemical Patents Inc | Camada e processos para preparar a mesma para separar uma mistura fluida e para catalisar uma reaç o quimica |
| WO2000023378A1 (en) * | 1998-10-20 | 2000-04-27 | Ngk Insulators, Ltd. | Zeolite composite film and process for producing the same |
| US6440885B1 (en) * | 1998-12-30 | 2002-08-27 | Corning Incorporated | Zeolite membrane and a process for the production thereof |
| GB9905560D0 (en) | 1999-03-11 | 1999-05-05 | Exxon Chemical Patents Inc | Process for the manufacture of supported materials |
| GB9905561D0 (en) | 1999-03-11 | 1999-05-05 | Exxon Chemical Patents Inc | Molecular sieve layers and process for their manufacture |
| WO2000071254A1 (en) * | 1999-05-20 | 2000-11-30 | Exxon Chemical Patents Inc. | Hydrocarbon conversion process and catalyst useful therein |
| JP2001232156A (ja) * | 2000-02-23 | 2001-08-28 | Kanebo Ltd | 分子ふるい炭素膜を用いた浸透気化分離方法または蒸気分離方法 |
| JP4527229B2 (ja) * | 2000-02-28 | 2010-08-18 | 日本碍子株式会社 | モルデナイトゼオライト膜およびその製造方法 |
| JP2001305368A (ja) * | 2000-04-21 | 2001-10-31 | Shin Etsu Chem Co Ltd | 光導波路基板の製造方法 |
| DE10027685B4 (de) * | 2000-05-26 | 2005-11-10 | INSTITUT FüR ANGEWANDTE CHEMIE BERLIN-ADLERSHOF E.V. | Verfahren zur Herstellung von Molekularsieb-Membranen auf porösen Trägern |
| DE10052075A1 (de) * | 2000-10-19 | 2002-05-02 | Thomas Bein | Poröse Schichten und ein Verfahren zu deren Herstellung mittels Spin-Coating |
| KR100395902B1 (ko) | 2000-11-01 | 2003-08-25 | 학교법인 서강대학교 | 제올라이트 또는 유사분자체의 패턴화된 단층 또는 다층복합체의 제조 방법 및 이에 의해 제조된 복합체 |
| US20020114958A1 (en) * | 2000-11-27 | 2002-08-22 | Toray Industries, Inc. | Method of coating zeolite crystals, substrate containing zeolite crystals, method of manufacturing zeolite membrane, method of processing zeolite membrane, zeolite membrane, aluminum electrolytic capacitor, degassing membrane and separation method |
| AU2002251946A1 (en) | 2001-02-14 | 2002-08-28 | Science And Technology Corporation @ Unm | Nanostructured devices for separation and analysis |
| US6913697B2 (en) | 2001-02-14 | 2005-07-05 | Science & Technology Corporation @ Unm | Nanostructured separation and analysis devices for biological membranes |
| FR2827856B1 (fr) * | 2001-07-25 | 2004-06-04 | Saint Gobain Quartz | Fibre minerale munie d'un revetement microporeux ou mesoporeux |
| JP4860851B2 (ja) * | 2001-09-19 | 2012-01-25 | 日本碍子株式会社 | ゼオライト積層複合体及びそれを用いたゼオライトメンブレンリアクタ |
| US20050011409A1 (en) * | 2001-12-25 | 2005-01-20 | Yasuhide Isobe | Inorganic oxide |
| US7625840B2 (en) * | 2003-09-17 | 2009-12-01 | Uchicago Argonne, Llc. | Catalytic nanoporous membranes |
| DE60333099D1 (de) * | 2003-10-17 | 2010-08-05 | Univ Delft Tech | Verfahren zur Abtrennung von Wasser aus einem Reaktionsgemisch unter Verwendung einer Hydroxy-Sodalit-Membran |
| DE102004001975A1 (de) * | 2004-01-13 | 2005-10-06 | Basf Ag | Verfahren zur Herstellung von Membranen |
| DE102004001974A1 (de) * | 2004-01-13 | 2005-08-04 | Basf Ag | Komposit-Membran |
| US7465381B2 (en) * | 2004-01-22 | 2008-12-16 | Stc.Unm | Electrokinetic molecular separation in nanoscale fluidic channels |
| US20060065528A1 (en) * | 2004-02-03 | 2006-03-30 | Gabriel Lopez | Nanostructured devices for separation and analysis |
| US20050221087A1 (en) * | 2004-02-13 | 2005-10-06 | James Economy | Nanoporous chelating fibers |
| US20050202241A1 (en) * | 2004-03-10 | 2005-09-15 | Jian-Ku Shang | High surface area ceramic coated fibers |
| US8105471B1 (en) | 2004-07-19 | 2012-01-31 | Han Sang M | Nanofluidics for bioseparation and analysis |
| CN1993167A (zh) * | 2004-08-03 | 2007-07-04 | 科罗拉多州立大学董事会 | 用于高选择性分离的膜 |
| ITMI20042169A1 (it) * | 2004-11-12 | 2005-02-12 | Polimeri Europa Spa | Processo continuo per la preparazione di fenolo da benzene in reattore a letto fisso |
| WO2006059394A1 (en) * | 2004-12-01 | 2006-06-08 | Bussan Nanotech Research Institute Inc. | Method for manufacturing zeolite membrane |
| DE102005012659A1 (de) * | 2005-03-18 | 2006-09-21 | Herding Gmbh Filtertechnik | Filterelement mit Beschichtung zur Oberflächenfiltration |
| DE102005016397A1 (de) * | 2005-04-08 | 2006-10-12 | Forschungszentrum Jülich GmbH | Membran für Gasphasenseparation sowie dafür geeignetes Herstellungsverfahren |
| JP2007070128A (ja) * | 2005-09-02 | 2007-03-22 | Denso Corp | 吸着素子の製造方法、吸着素子、水熱合成装置 |
| WO2007058388A1 (ja) * | 2005-11-17 | 2007-05-24 | Ngk Insulators, Ltd. | ゼオライト配向膜配設体 |
| FR2894844B1 (fr) * | 2005-12-21 | 2008-07-18 | Inst Francais Du Petrole | Membranes zeolithiques supportees, leur procede de fabrication et leurs applications |
| FR2895275B1 (fr) * | 2005-12-22 | 2008-07-25 | Framatome Sa | Membranes de separation de gaz contenant une couche de silice microporeuse a base de silice dopee par un element trivalent |
| EP1847311A1 (en) * | 2006-04-19 | 2007-10-24 | Universität Hannover | Composite Membrane |
| CN101443298A (zh) | 2006-05-15 | 2009-05-27 | 科罗拉多州立大学董事会 | 用于co2/ch4分离的高通量和高选择性的sapo-34膜 |
| EP2032239B1 (de) * | 2006-06-13 | 2014-03-19 | Basf Se | Verfahren zur herstellung einer komposit-membran sowie verwendungen |
| US20080007838A1 (en) * | 2006-07-07 | 2008-01-10 | Omnitech Partners, Inc. | Field-of-view indicator, and optical system and associated method employing the same |
| BRPI0719873A2 (pt) * | 2006-12-07 | 2014-04-15 | Grace W R & Co | Composições catalisadoras de craqueamento catalítico tendo conversão de bases. |
| WO2008112520A1 (en) * | 2007-03-09 | 2008-09-18 | The Regents Of The University Of Colorado, A Body Corporate | Synthesis of zeolites and zeolite membranes using multiple structure directing agents |
| JP2008247654A (ja) * | 2007-03-29 | 2008-10-16 | Hiroshima Univ | アンモニアの分離方法、製造方法、及び気体分離膜 |
| FR2917645B1 (fr) * | 2007-06-20 | 2011-04-08 | Centre Nat Etd Spatiales | Utilisation de zeolithes modifiees pour la decontamination moleculaire. |
| US8431508B2 (en) * | 2007-10-30 | 2013-04-30 | Cerahelix, Inc. | Inorganic structure for molecular separations |
| US8431509B2 (en) | 2007-10-30 | 2013-04-30 | Cerahelix, Inc. | Structure for molecular separations |
| JP5164542B2 (ja) * | 2007-12-04 | 2013-03-21 | ニチハ株式会社 | 建材の塗装方法 |
| BRPI0912586A8 (pt) * | 2008-05-15 | 2017-10-03 | Shell Oil Co | Método para fazer um suporte de membrana de peneira molecular de separação de gás de alto desempenho usando um tempo de cristalização encurtado |
| CN101279210B (zh) * | 2008-05-20 | 2010-12-08 | 吉林大学 | Zsm-5分子筛膜及在处理砷方面的应用 |
| JP5495531B2 (ja) * | 2008-10-09 | 2014-05-21 | Jx日鉱日石エネルギー株式会社 | パラキシレン製造用合成ゼオライト触媒の製造方法、並びに該方法で製造したパラキシレン製造用触媒を用いた高純度パラキシレンの製造方法 |
| JP5481075B2 (ja) * | 2009-02-04 | 2014-04-23 | 日本碍子株式会社 | ゼオライト膜の製造方法 |
| CN102427870B (zh) | 2009-05-19 | 2014-01-29 | 国际壳牌研究有限公司 | 组合应用蒸馏和膜分离从轻烃气体物流中分离酸性污染物的方法 |
| US10265660B2 (en) | 2009-05-21 | 2019-04-23 | Battelle Memorial Institute | Thin-sheet zeolite membrane and methods for making the same |
| EA021262B1 (ru) | 2009-05-29 | 2015-05-29 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения молекулярно-ситовой мембраны для разделения газов |
| BRPI1011334A2 (pt) | 2009-05-29 | 2016-03-08 | Shell Int Research | método para preparar uma membrana de separação de gás sustentada, membrana de separação de gás sustentada, e, processo para separar um primeiro componente de gás a partir de uma mistura gasosa |
| CN101712478B (zh) * | 2009-11-19 | 2012-02-29 | 上海第二工业大学 | 一种制备低介电常数纳米氧化硅分子筛薄膜的方法 |
| RU2417837C1 (ru) * | 2009-11-23 | 2011-05-10 | Государственное образовательное учреждение высшего профессионального образования Нижегородский государственный технический университет им. Р.Е. Алексеева (НГТУ) | Способ приготовления формованного силикалита титана |
| CN102210985B (zh) * | 2010-04-06 | 2013-05-01 | 中国科学院过程工程研究所 | 一种有机-无机杂化荷正电分离膜 |
| US8679227B2 (en) | 2010-04-29 | 2014-03-25 | The Regents Of The University Of Colorado | High flux SAPO-34 membranes for CO2/CH4 separation and template removal method |
| JP2011251951A (ja) * | 2010-06-03 | 2011-12-15 | Mitsubishi Chemicals Corp | 水素化芳香族化合物の製造方法及び有機化合物の製造方法 |
| CN101920170B (zh) * | 2010-08-10 | 2012-10-10 | 南京工业大学 | 一种高通量的分子筛透醇膜及其制备方法 |
| US8791040B2 (en) * | 2010-11-03 | 2014-07-29 | Fina Technology, Inc. | Catalysts containing nano-materials and methods of making and using same |
| CN102336414B (zh) * | 2011-06-29 | 2012-12-05 | 同济大学 | 一种使用清澈溶胶法制备高质量sapo-34分子筛膜的方法 |
| US9180413B2 (en) | 2011-09-06 | 2015-11-10 | Regents Of The University Of Minnesota | One-step synthesis of mesoporous pentasil zeolite with single-unit-cell lamellar structural features |
| JP6056310B2 (ja) * | 2012-09-19 | 2017-01-11 | 三菱化学株式会社 | アンモニアの分離方法 |
| FR2999193B1 (fr) | 2012-12-07 | 2017-07-28 | Saint-Gobain Centre De Rech Et D'Etudes Europeen | Produit a fonction orientee. |
| US10682626B2 (en) | 2013-03-14 | 2020-06-16 | Zeomem Sweden Ab | Method for producing a crystalline film of zeolite and/or zeolite like crystals on a porous substrate |
| CN105073687B (zh) * | 2013-03-29 | 2017-04-12 | 日本碍子株式会社 | 磷酸铝‑金属氧化物接合体及其制造方法 |
| CN105531020A (zh) * | 2013-05-07 | 2016-04-27 | 陶氏环球技术有限责任公司 | 用于制备离子交换沸石膜的真空辅助法 |
| CN103372379B (zh) * | 2013-07-14 | 2015-01-28 | 浙江大学 | 一种以金属氧化物为载体的分子筛复合膜制备方法 |
| WO2015128824A1 (en) * | 2014-02-28 | 2015-09-03 | Reliance Industries Limited | A naphtha reforming process |
| JP6523342B2 (ja) | 2014-06-11 | 2019-05-29 | サン−ゴバン サントル ド レシェルシュ エ デテュド ユーロペアン | 配向した粒子を有するセラミック物体およびその製造法 |
| CN105582997B (zh) * | 2014-10-21 | 2018-05-18 | 中国石油化工股份有限公司 | 石脑油催化裂解产丙烯的催化剂及其制备方法和石脑油催化裂解产丙烯的方法 |
| CN104276635B (zh) * | 2014-10-29 | 2016-04-27 | 扬州大学 | 光电催化氧化用负载型y型分子筛膜阳极材料的制备方法 |
| JP6670825B2 (ja) * | 2015-03-31 | 2020-03-25 | 日本碍子株式会社 | ゼオライト膜構造体及びその製造方法 |
| CN106466633A (zh) * | 2015-08-20 | 2017-03-01 | 中国石油化工股份有限公司 | Zsm-22/sapo-34复合分子筛及其合成方法 |
| DE112016005301T5 (de) * | 2015-11-18 | 2018-08-02 | Ngk Insulators, Ltd. | Reparatur-Verfahren für eine Trennmembran und ein Verfahren zum Herstellen einer Trennmembranstruktur |
| JP6757606B2 (ja) * | 2016-06-21 | 2020-09-23 | 日立造船株式会社 | Mfi型ゼオライト(シリカライト)を用いた分離膜の製造方法 |
| US11498062B2 (en) | 2016-09-30 | 2022-11-15 | Regents Of The University Of Minnesota | Phosphorus-containing solid catalysts and reactions catalyzed thereby, including synthesis of p-xylene |
| WO2018116172A1 (en) * | 2016-12-19 | 2018-06-28 | Khalifa University of Science and Technology | Fibrous zeolite catalyst for hydrocracking |
| CN106957062B (zh) * | 2017-05-05 | 2019-11-01 | 南京膜材料产业技术研究院有限公司 | 一种取向sapo-34分子筛膜的制备方法 |
| JP7056658B2 (ja) | 2017-06-15 | 2022-04-19 | 三菱ケミカル株式会社 | アンモニアの分離方法およびゼオライト |
| GB201714269D0 (en) * | 2017-09-05 | 2017-10-18 | Hedlund Jonas | Methods for preparing supported zeolite films |
| JP6500161B1 (ja) * | 2018-03-20 | 2019-04-10 | レンゴー株式会社 | ゼオライト膜を有する積層体の製造方法 |
| CN111087279A (zh) * | 2019-11-27 | 2020-05-01 | 南京工业大学 | 一种基于分子筛膜反应器的甲烷无氧芳构化方法 |
| RU2744166C1 (ru) * | 2019-12-09 | 2021-03-03 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Цеолит типа mor и способ его получения |
| CN111180645B (zh) * | 2020-02-18 | 2021-07-13 | 江苏厚生新能源科技有限公司 | 一种聚烯烃多孔膜及其制备方法 |
| CN111892064B (zh) * | 2020-07-16 | 2022-02-18 | 万华化学集团股份有限公司 | 一种分子筛膜、膜反应器及在制备对叔丁基苯酚中的应用 |
| CN112657462A (zh) * | 2020-12-09 | 2021-04-16 | 江西茂盛环境有限公司 | 一种废气吸附材料及其制备方法 |
| CN116059844B (zh) * | 2021-10-31 | 2024-09-03 | 中国石油化工股份有限公司 | 一种全硅沸石分子筛膜的修饰方法及制备的膜和应用 |
| CN117180989B (zh) * | 2023-09-19 | 2024-04-05 | 广东诚刻新材料有限公司 | 一种有机无机杂化超滤膜及其制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8334626D0 (en) * | 1983-12-30 | 1984-02-08 | Exxon Research Engineering Co | Zeolite coated substrates |
| US4801476A (en) * | 1986-09-24 | 1989-01-31 | Exxon Research And Engineering Company | Method for production of large area 2-dimensional arrays of close packed colloidal particles |
| JPS63171671A (ja) * | 1986-09-24 | 1988-07-15 | エクソン リサーチ アンド エンヂニアリング コムパニー | 密にパックされたコロイド粒子の大面積・2次元配置物の製造法 |
| NL9100217A (nl) * | 1991-02-07 | 1992-09-01 | Univ Delft Tech | Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. |
| DE4216846A1 (de) * | 1992-05-21 | 1993-11-25 | Basf Ag | Verfahren zur Fixierung großer zeolithischer und zeolithanaloger Molekularsieb-Kristalle auf Formkörper |
| US5310714A (en) * | 1992-07-08 | 1994-05-10 | Mobil Oil Corp. | Synthesis of zeolite films bonded to substrates, structures and uses thereof |
| JPH0632610A (ja) * | 1992-07-17 | 1994-02-08 | Kobe Steel Ltd | A型またはフォージャサイト型ゼオライト膜の製造方法 |
| SE9202518L (sv) * | 1992-09-02 | 1994-03-03 | Jan Erik Otterstedt | Mikropartiklar |
| JPH0789714A (ja) * | 1993-09-22 | 1995-04-04 | Ngk Insulators Ltd | ゼオライト膜の製造方法 |
| JP3272119B2 (ja) * | 1993-10-12 | 2002-04-08 | 中部電力株式会社 | ゼオライト結晶膜の製造方法 |
| JPH07330326A (ja) * | 1994-06-10 | 1995-12-19 | Sumitomo Electric Ind Ltd | ゼオライト膜及びその合成方法 |
| ATE276038T1 (de) * | 1994-07-08 | 2004-10-15 | Exxonmobil Res & Eng Co | Zeolith enthaltende zusammensetzung mit einer selektivität erhhöhenden beschichtung |
| EP0775015B1 (en) * | 1994-07-08 | 2004-09-15 | ExxonMobil Research and Engineering Company | Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer |
| GB9413863D0 (en) * | 1994-07-08 | 1994-08-24 | Exxon Chemical Patents Inc | Molecular sieves and processes for their manufacture |
| US5573121A (en) * | 1994-11-03 | 1996-11-12 | Durand-Raute Industries Ltd. | Veneer sorting apparatus |
-
1996
- 1996-03-14 SE SE9600970A patent/SE9600970D0/xx unknown
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- 1997-03-13 US US09/142,838 patent/US6177373B1/en not_active Expired - Lifetime
- 1997-03-13 CA CA002249360A patent/CA2249360A1/en not_active Abandoned
- 1997-03-13 RU RU98118686/12A patent/RU2183499C2/ru not_active IP Right Cessation
- 1997-03-13 BR BR9707991A patent/BR9707991A/pt active Search and Examination
- 1997-03-13 MX MX9807509A patent/MX206953B/es not_active IP Right Cessation
- 1997-03-13 KR KR1019980707270A patent/KR19990087788A/ko not_active Ceased
- 1997-03-13 EP EP97914234A patent/EP0888173A1/en not_active Withdrawn
- 1997-03-13 WO PCT/EP1997/001267 patent/WO1997033684A1/en not_active Ceased
- 1997-03-13 AU AU21559/97A patent/AU723976B2/en not_active Ceased
- 1997-03-13 JP JP53229297A patent/JP4511637B2/ja not_active Expired - Fee Related
- 1997-03-13 CN CN97193836A patent/CN1216480A/zh active Pending
- 1997-03-14 ZA ZA972251A patent/ZA972251B/xx unknown
- 1997-08-15 TW TW086111957A patent/TW523490B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI477449B (zh) * | 2008-11-13 | 2015-03-21 | Univ Ishou | Method for producing zeolite film |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4511637B2 (ja) | 2010-07-28 |
| MX206953B (cg-RX-API-DMAC7.html) | 2002-02-28 |
| ZA972251B (en) | 1999-01-19 |
| CN1216480A (zh) | 1999-05-12 |
| JP2000507909A (ja) | 2000-06-27 |
| SE9600970D0 (sv) | 1996-03-14 |
| AU2155997A (en) | 1997-10-01 |
| MX9807509A (cg-RX-API-DMAC7.html) | 1999-05-31 |
| BR9707991A (pt) | 1999-07-27 |
| CA2249360A1 (en) | 1997-09-18 |
| WO1997033684A1 (en) | 1997-09-18 |
| EP0888173A1 (en) | 1999-01-07 |
| US6177373B1 (en) | 2001-01-23 |
| AU723976B2 (en) | 2000-09-07 |
| RU2183499C2 (ru) | 2002-06-20 |
| KR19990087788A (ko) | 1999-12-27 |
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