TW201031743A

TW201031743A - Surfactant mixture comprising branched short-chain and branched long-chain components

Surfactant mixture comprising branched short-chain and branched long-chain components Download PDF

Info

Publication number: TW201031743A
Authority: TW; Taiwan
Prior art keywords: mixture; alkanol; surfactant; group; weight
Prior art date: 2008-12-18

Application number

TW098142090A

Other languages

English (en)

Chinese (zh)

Inventor

Frank Rittig

Ulrich Steinbrenner

Wolfgang Spiegler

Michael Stoesser

Inge Langbein

Richard Baur

Original Assignee

Basf Se

Priority date

2008-12-18

Filing date

2009-12-09

Publication date

2010-09-01

2009-12-09 Application filed by Basf Se filed Critical Basf Se

2010-09-01 Publication of TW201031743A publication Critical patent/TW201031743A/zh

Links

239000000203 mixture Substances 0.000 title claims abstract description 248
239000004094 surface-active agent Substances 0.000 title claims abstract description 124
125000003545 alkoxy group Chemical group 0.000 claims abstract description 65
-1 ether carboxylates Chemical class 0.000 claims abstract description 65
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 46
238000009472 formulation Methods 0.000 claims abstract description 38
238000000034 method Methods 0.000 claims abstract description 28
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 13
150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 62
150000004703 alkoxides Chemical group 0.000 claims description 25
239000003599 detergent Substances 0.000 claims description 22
238000007254 oxidation reaction Methods 0.000 claims description 15
239000004753 textile Substances 0.000 claims description 14
239000003795 chemical substances by application Substances 0.000 claims description 13
229910052751 metal Inorganic materials 0.000 claims description 13
239000002184 metal Substances 0.000 claims description 13
230000003647 oxidation Effects 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
150000001335 aliphatic alkanes Chemical class 0.000 claims description 11
238000002156 mixing Methods 0.000 claims description 11
238000004519 manufacturing process Methods 0.000 claims description 9
238000012545 processing Methods 0.000 claims description 9
238000005187 foaming Methods 0.000 claims description 7
239000000126 substance Substances 0.000 claims description 5
239000013543 active substance Substances 0.000 claims description 4
238000005238 degreasing Methods 0.000 claims description 4
239000010985 leather Substances 0.000 claims description 4
125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 4
229910019142 PO4 Inorganic materials 0.000 claims description 3
239000000853 adhesive Substances 0.000 claims description 3
230000001070 adhesive effect Effects 0.000 claims description 3
239000002537 cosmetic Substances 0.000 claims description 3
239000000835 fiber Substances 0.000 claims description 3
239000003973 paint Substances 0.000 claims description 3
235000021317 phosphate Nutrition 0.000 claims description 3
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 claims description 3
239000004909 Moisturizer Substances 0.000 claims description 2
239000008199 coating composition Substances 0.000 claims description 2
238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
238000000855 fermentation Methods 0.000 claims description 2
230000004151 fermentation Effects 0.000 claims description 2
235000013305 food Nutrition 0.000 claims description 2
239000003906 humectant Substances 0.000 claims description 2
229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
239000011707 mineral Substances 0.000 claims description 2
230000001333 moisturizer Effects 0.000 claims description 2
125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
208000027418 Wounds and injury Diseases 0.000 claims 1
125000002355 alkine group Chemical group 0.000 claims 1
230000006378 damage Effects 0.000 claims 1
208000014674 injury Diseases 0.000 claims 1
150000003014 phosphoric acid esters Chemical class 0.000 abstract 1
239000003054 catalyst Substances 0.000 description 64
150000001336 alkenes Chemical class 0.000 description 59
239000000047 product Substances 0.000 description 53
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 47
238000006243 chemical reaction Methods 0.000 description 43
229930195733 hydrocarbon Natural products 0.000 description 30
150000002430 hydrocarbons Chemical class 0.000 description 30
239000004215 Carbon black (E152) Substances 0.000 description 26
239000002253 acid Substances 0.000 description 26
239000007844 bleaching agent Substances 0.000 description 23
150000001875 compounds Chemical class 0.000 description 23
150000003839 salts Chemical class 0.000 description 19
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 18
238000005984 hydrogenation reaction Methods 0.000 description 17
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 16
238000006116 polymerization reaction Methods 0.000 description 16
125000002947 alkylene group Chemical group 0.000 description 15
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 14
238000007037 hydroformylation reaction Methods 0.000 description 14
108090000790 Enzymes Proteins 0.000 description 13
102000004190 Enzymes Human genes 0.000 description 13
238000006555 catalytic reaction Methods 0.000 description 13
229910017052 cobalt Inorganic materials 0.000 description 13
239000010941 cobalt Substances 0.000 description 13
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 13
229940088598 enzyme Drugs 0.000 description 13
239000003112 inhibitor Substances 0.000 description 13
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 13
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 12
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 12
239000011976 maleic acid Substances 0.000 description 12
239000002736 nonionic surfactant Substances 0.000 description 12
238000004140 cleaning Methods 0.000 description 11
238000004821 distillation Methods 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 11
238000005406 washing Methods 0.000 description 11
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 10
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 10
239000003945 anionic surfactant Substances 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 10
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 10
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 10
229920000642 polymer Polymers 0.000 description 10
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
238000009826 distribution Methods 0.000 description 9
238000007046 ethoxylation reaction Methods 0.000 description 9
239000001257 hydrogen Substances 0.000 description 9
229910052739 hydrogen Inorganic materials 0.000 description 9
238000006384 oligomerization reaction Methods 0.000 description 9
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 8
229920001577 copolymer Polymers 0.000 description 8
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
229920000742 Cotton Polymers 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
239000012190 activator Substances 0.000 description 7
229910052783 alkali metal Inorganic materials 0.000 description 7
150000001412 amines Chemical class 0.000 description 7
230000000694 effects Effects 0.000 description 7
239000004744 fabric Substances 0.000 description 7
239000007789 gas Substances 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
239000000178 monomer Substances 0.000 description 7
YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 description 7
239000010457 zeolite Substances 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
239000002202 Polyethylene glycol Substances 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 6
PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 6
125000003158 alcohol group Chemical group 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 6
239000002585 base Substances 0.000 description 6
229910002091 carbon monoxide Inorganic materials 0.000 description 6
150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
239000000463 material Substances 0.000 description 6
239000003921 oil Substances 0.000 description 6
235000019198 oils Nutrition 0.000 description 6
229920001223 polyethylene glycol Polymers 0.000 description 6
239000000843 powder Substances 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
238000002310 reflectometry Methods 0.000 description 6
229910052707 ruthenium Inorganic materials 0.000 description 6
239000011734 sodium Substances 0.000 description 6
229910021653 sulphate ion Inorganic materials 0.000 description 6
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 6
229920001567 vinyl ester resin Polymers 0.000 description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
229910021536 Zeolite Inorganic materials 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 5
239000000654 additive Substances 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
230000036571 hydration Effects 0.000 description 5
238000006703 hydration reaction Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
230000008569 process Effects 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
229920006395 saturated elastomer Polymers 0.000 description 5
238000000926 separation method Methods 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000002689 soil Substances 0.000 description 5
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
238000003786 synthesis reaction Methods 0.000 description 5
229940117972 triolein Drugs 0.000 description 5
239000000052 vinegar Substances 0.000 description 5
235000021419 vinegar Nutrition 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 4
239000004606 Fillers/Extenders Substances 0.000 description 4
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
239000004721 Polyphenylene oxide Substances 0.000 description 4
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
229910000323 aluminium silicate Inorganic materials 0.000 description 4
238000004380 ashing Methods 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
238000007796 conventional method Methods 0.000 description 4
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
239000008187 granular material Substances 0.000 description 4
239000002638 heterogeneous catalyst Substances 0.000 description 4
239000003915 liquefied petroleum gas Substances 0.000 description 4
235000008390 olive oil Nutrition 0.000 description 4
239000004006 olive oil Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
239000012188 paraffin wax Substances 0.000 description 4
239000002304 perfume Substances 0.000 description 4
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
229920001515 polyalkylene glycol Polymers 0.000 description 4
229920000570 polyether Polymers 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
238000007639 printing Methods 0.000 description 4
229910052938 sodium sulfate Inorganic materials 0.000 description 4
235000011152 sodium sulphate Nutrition 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
238000009736 wetting Methods 0.000 description 4
UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 3
229910052784 alkaline earth metal Inorganic materials 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
150000003863 ammonium salts Chemical class 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
229910052797 bismuth Inorganic materials 0.000 description 3
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
238000004061 bleaching Methods 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
239000004927 clay Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical class [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000008139 complexing agent Substances 0.000 description 3
DDRJAANPRJIHGJ-UHFFFAOYSA-N creatinine Chemical compound CN1CC(=O)NC1=N DDRJAANPRJIHGJ-UHFFFAOYSA-N 0.000 description 3
238000006356 dehydrogenation reaction Methods 0.000 description 3
150000004985 diamines Chemical class 0.000 description 3
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 3
239000000975 dye Substances 0.000 description 3
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
150000002191 fatty alcohols Chemical class 0.000 description 3
238000004231 fluid catalytic cracking Methods 0.000 description 3
235000011187 glycerol Nutrition 0.000 description 3
229920000578 graft copolymer Polymers 0.000 description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
239000003949 liquefied natural gas Substances 0.000 description 3
229910052744 lithium Inorganic materials 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
150000005673 monoalkenes Chemical class 0.000 description 3
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
230000003287 optical effect Effects 0.000 description 3
239000000049 pigment Substances 0.000 description 3
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230000002829 reductive effect Effects 0.000 description 3
230000002441 reversible effect Effects 0.000 description 3
229930195734 saturated hydrocarbon Natural products 0.000 description 3
239000000344 soap Substances 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000004575 stone Substances 0.000 description 3
239000001384 succinic acid Substances 0.000 description 3
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229910052723 transition metal Inorganic materials 0.000 description 3
150000003624 transition metals Chemical class 0.000 description 3
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
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KVGOXGQSTGQXDD-UHFFFAOYSA-N 1-decane-sulfonic-acid Chemical compound CCCCCCCCCCS(O)(=O)=O KVGOXGQSTGQXDD-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 2
JSUXZEJWGVYJJG-UHFFFAOYSA-N 2-propylhexan-1-ol Chemical compound CCCCC(CO)CCC JSUXZEJWGVYJJG-UHFFFAOYSA-N 0.000 description 2
HSJKGGMUJITCBW-UHFFFAOYSA-N 3-hydroxybutanal Chemical compound CC(O)CC=O HSJKGGMUJITCBW-UHFFFAOYSA-N 0.000 description 2
UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
239000007848 Bronsted acid Substances 0.000 description 2
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
YLQAHJZLBGVPHU-UHFFFAOYSA-N CCCC(CCC(C)S)CO Chemical compound CCCC(CCC(C)S)CO YLQAHJZLBGVPHU-UHFFFAOYSA-N 0.000 description 2
229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
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