RU2018130981A - Катализатор окисления для обработки выхлопного газа двигателя с воспламенением от сжатия - Google Patents
Катализатор окисления для обработки выхлопного газа двигателя с воспламенением от сжатия Download PDFInfo
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- RU2018130981A RU2018130981A RU2018130981A RU2018130981A RU2018130981A RU 2018130981 A RU2018130981 A RU 2018130981A RU 2018130981 A RU2018130981 A RU 2018130981A RU 2018130981 A RU2018130981 A RU 2018130981A RU 2018130981 A RU2018130981 A RU 2018130981A
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- Prior art keywords
- component
- platinum
- oxidation catalyst
- layer
- diesel oxidation
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims 20
- 230000003647 oxidation Effects 0.000 title claims 17
- 238000007254 oxidation reaction Methods 0.000 title claims 17
- 230000006835 compression Effects 0.000 title 1
- 238000007906 compression Methods 0.000 title 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 59
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 43
- 229910052697 platinum Inorganic materials 0.000 claims 16
- 229910052763 palladium Inorganic materials 0.000 claims 14
- 229910052751 metal Inorganic materials 0.000 claims 11
- 239000002184 metal Substances 0.000 claims 11
- 229910052788 barium Inorganic materials 0.000 claims 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000011575 calcium Substances 0.000 claims 2
- 239000012876 carrier material Substances 0.000 claims 2
- 238000010531 catalytic reduction reaction Methods 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 229910052712 strontium Inorganic materials 0.000 claims 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 230000001988 toxicity Effects 0.000 claims 2
- 231100000419 toxicity Toxicity 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
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- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
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Claims (25)
1. Дизельный катализатор окисления для обработки выхлопного газа из дизельного двигателя, где катализатор окисления содержит
первый слой, содержащий компонент-металл платиновой группы (МПГ), выбранный из группы, состоящей из компонента-платины (Pt) и комбинации компонента-палладия (Pd) и компонента-платины (Pt);
компонент, представляющий собой щелочной металл;
материал носителя, содержащий содержащий оксид алюминия, легированный диоксидом кремния; и
второй слой, содержащий компонент-металл платиновой группы (МПГ), выбранный из группы, состоящей из компонента-платины (Pt) и комбинации компонента-палладия (Pd) и компонента-платины (Pt); и
подложку, которая представляет собой проточный монолит;
и при этом:
первый слой размещен на подложке, а второй слой размещен на первом слое, и первый слой отличается по составу от второго слоя; и
при этом суммарное количество компонента-щелочно-земельного металла составляет 10-500 г⋅фут-3.
2. Дизельный катализатор окисления по п.1, в котором оксид алюминия легирован диоксидом кремния в количестве 0,5-45% по весу.
3. Дизельный катализатор окисления по любому из предшествующих пунктов, в котором компонент-щелочно-земельный элемент включает в себя магний (Mg), кальций (Ca), стронций (Sr), барий (Ba) или комбинацию двух или более из этого.
4. Дизельный катализатор окисления по п.3, где компонент-щелочно-земельный металл включает в себя стронций (Sr) или барий (Ba), предпочтительно барий (Ba).
5. Дизельный катализатор окисления по любому из предшествующих пунктов, в котором компонент-щелочно-земельный элемент нанесен на материал подложки.
6. Дизельный катализатор окисления по любому из предшествующих пунктов, где компонент, представляющий собой, по меньшей мере, один металл платиновой группы (МПГ), нанесен на материал подложки.
7. Дизельный катализатор окисления по любому из предшествующих пунктов, где
первый слой содержит компонент-металл платиновой группы (МПГ), состоящий из комбинации компонента-платины (Pt) и компонента-палладия (Pd), и второй слой включает в себя компонент-металл платиновой группы (МПГ), состоящий из комбинации компонента-палладия (Pd) и компонента-платины (Pt), и при этом отношение по массе компонента-платины (Pt) к компоненту-палладию (Pd) в первом слое отличается от отношения по массе компонента-платины (Pt) к компоненту-палладию (Pd) во втором слое.
8. Дизельный катализатор окисления по любому из пп. 1-6, где первый слой содержит компонент-металл платиновой группы (МПГ), выбранный из группы, состоящей из компонента Pd и комбинации компонента-палладия (Pd) и компонента-платины (Pt), и где второй слой включает в себя компонент-металл платиновой группы (МПГ), состоящий из компонента Pt.
9. Дизельный катализатор окисления по любому из пп. 1-6, где первый слой содержит компонент-металл платиновой группы (МПГ), выбранный из группы, состоящей из компонента-платины (Pt) и комбинации компонента-палладия (Pd) и компонента-платины (Pt), и где второй слой содержит компонент-металл платиновой группы (МПГ), состоящей из компонента-палладия (Pd).
10. Дизельный катализатор окисления по любому из предшествующих пунктов, где первый слой содержит комбинацию компонента-платины (Pt) и компонента-палладия (Pd), и где первый слой имеет отношение по массе платины (Pt) в компоненте-платине (Pt) к палладию (Pd) в компоненте-палладии (Pd) > 2:3.
11. Дизельный катализатор окисления по любому из пп. 1-6, где первый слой содержит компонент-металл платиновой группы (МПГ), выбранный из группы, состоящей из компонента-платины (Pt) и компонента-палладия (Pd), и второй слой содержит компонент-металл платиновой группы (МПГ), состоящий из комбинации компонента-палладия (Pd) и компонента-платины (Pt).
12. Дизельный катализатор окисления по любому из предшествующих пунктов, где второй слой включает в себя второй материал носителя.
13. Дизельный катализатор окисления по любому из предшествующих пунктов, который не содержит родия.
14. Система выпуска для дизельного двигателя, включающая в себя дизельный катализатор окисления по любому из предшествующих пунктов и по меньшей мере одно устройство для снижения токсичности выхлопа.
15. Система выпуска по п. 14, где устройство для снижения токсичности выхлопа выбрано из дизельного фильтра частиц (DPF), катализатора адсорбера NOx (NAC), катализатора NOx обедненных смесей (LNC), катализатора селективного каталитического восстановления (SCR), дизельного катализатора окисления (DOC), катализируемого сажевого фильтра (CSF), фильтра селективного каталитического восстановления (SCRF), и комбинации двух или более их них.
16. Транспортное средство, включающее в себя дизельный двигатель и систему выпуска по п. 14 или 15.
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US201261728834P | 2012-11-21 | 2012-11-21 | |
GB201220912A GB201220912D0 (en) | 2012-11-21 | 2012-11-21 | Oxidation catalyst for treating the exhaust gas of a compression ignition engine |
GB1220912.8 | 2012-11-21 | ||
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GB201308934A GB201308934D0 (en) | 2012-11-21 | 2013-05-17 | Oxidation catalyst for treating the exhaust gas of a compression ignition engine |
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RU2018130981A RU2755297C2 (ru) | 2012-11-21 | 2013-11-21 | Катализатор окисления для обработки выхлопного газа двигателя с воспламенением от сжатия |
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RU2015124014A RU2668272C2 (ru) | 2012-11-21 | 2013-11-21 | Катализатор окисления для обработки выхлопного газа двигателя с воспламенением от сжатия |
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EP (4) | EP2922631B2 (ru) |
JP (6) | JP6466337B2 (ru) |
KR (3) | KR102396154B1 (ru) |
CN (5) | CN110292926A (ru) |
BR (2) | BR112015011641B1 (ru) |
DE (2) | DE102013223845A1 (ru) |
GB (5) | GB201220912D0 (ru) |
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