MXPA06010485A - Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de etileno. - Google Patents
Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de etileno.Info
- Publication number
- MXPA06010485A MXPA06010485A MXPA06010485A MXPA06010485A MXPA06010485A MX PA06010485 A MXPA06010485 A MX PA06010485A MX PA06010485 A MXPA06010485 A MX PA06010485A MX PA06010485 A MXPA06010485 A MX PA06010485A MX PA06010485 A MXPA06010485 A MX PA06010485A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- polymer
- chain
- group
- polymerization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 245
- 239000000203 mixture Substances 0.000 title claims abstract description 169
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 75
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- 229920001038 ethylene copolymer Polymers 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims abstract description 279
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 96
- 229920001400 block copolymer Polymers 0.000 claims abstract description 81
- 239000000178 monomer Substances 0.000 claims abstract description 54
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- 229920001577 copolymer Polymers 0.000 claims abstract description 39
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 33
- 239000000126 substance Substances 0.000 claims abstract description 23
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 21
- 230000000704 physical effect Effects 0.000 claims abstract description 16
- 238000011065 in-situ storage Methods 0.000 claims abstract description 15
- -1 cycloheteroalkyl Chemical group 0.000 claims description 219
- 238000000034 method Methods 0.000 claims description 130
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 118
- 229910052751 metal Inorganic materials 0.000 claims description 84
- 239000002184 metal Substances 0.000 claims description 82
- 125000004432 carbon atom Chemical group C* 0.000 claims description 80
- 229910052739 hydrogen Inorganic materials 0.000 claims description 76
- 239000001257 hydrogen Substances 0.000 claims description 76
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- 125000000217 alkyl group Chemical group 0.000 claims description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 37
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- 239000011574 phosphorus Substances 0.000 claims description 13
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- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 9
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- 239000004711 α-olefin Substances 0.000 claims description 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical group CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 16
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 16
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- 238000012360 testing method Methods 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
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- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 11
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 11
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 10
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- 238000004458 analytical method Methods 0.000 description 10
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- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 10
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- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 8
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- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical class [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 3
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- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 3
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- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 3
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- MDYARPNTSPYOED-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)borane;2-undecyl-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCC1=NCCN1.FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F.FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F MDYARPNTSPYOED-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55390604P | 2004-03-17 | 2004-03-17 | |
| PCT/US2005/008916 WO2005090425A1 (en) | 2004-03-17 | 2005-03-17 | Catalyst composition comprising shuttling agent for ethylene copolymer formation |
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- 2005-03-17 JP JP2007504110A patent/JP5159302B2/ja not_active Expired - Lifetime
- 2005-03-17 BR BRPI0508161A patent/BRPI0508161B1/pt active IP Right Grant
- 2005-03-17 WO PCT/US2005/008916 patent/WO2005090425A1/en not_active Ceased
- 2005-03-17 AR ARP050101042A patent/AR048273A1/es unknown
- 2005-03-17 US US10/589,378 patent/US7915192B2/en active Active
- 2005-03-17 KR KR1020067019077A patent/KR101277095B1/ko not_active Expired - Lifetime
- 2005-03-17 CA CA002558251A patent/CA2558251A1/en not_active Abandoned
- 2005-03-17 AR ARP050101043A patent/AR048817A1/es active IP Right Grant
- 2005-03-17 AU AU2005224258A patent/AU2005224258B2/en not_active Ceased
- 2005-03-17 MX MXPA06010485A patent/MXPA06010485A/es unknown
- 2005-03-17 CN CNA2005800085352A patent/CN1934150A/zh active Pending
- 2005-03-17 EP EP05725817.0A patent/EP1735360B1/en not_active Expired - Lifetime
- 2005-03-17 EP EP10185503.9A patent/EP2327727B1/en not_active Expired - Lifetime
- 2005-03-17 RU RU2006136410/04A patent/RU2359979C2/ru not_active IP Right Cessation
-
2006
- 2006-09-15 NO NO20064198A patent/NO20064198L/no not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864338A (zh) * | 2017-05-12 | 2018-11-23 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组合物及烯烃聚合的方法 |
| CN108864338B (zh) * | 2017-05-12 | 2020-11-10 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组合物及烯烃聚合的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2359979C2 (ru) | 2009-06-27 |
| KR20070004729A (ko) | 2007-01-09 |
| EP1735360A1 (en) | 2006-12-27 |
| NO20064198L (no) | 2006-10-16 |
| RU2006136410A (ru) | 2008-04-27 |
| EP2327727A1 (en) | 2011-06-01 |
| AU2005224258B2 (en) | 2010-09-02 |
| JP5159302B2 (ja) | 2013-03-06 |
| US7915192B2 (en) | 2011-03-29 |
| CN1934150A (zh) | 2007-03-21 |
| KR101277095B1 (ko) | 2013-06-20 |
| AU2005224258A1 (en) | 2005-09-29 |
| EP2327727B1 (en) | 2015-07-22 |
| BRPI0508161B1 (pt) | 2015-11-17 |
| SG151310A1 (en) | 2009-04-30 |
| AR048273A1 (es) | 2006-04-12 |
| EP1735360B1 (en) | 2013-09-11 |
| CA2558251A1 (en) | 2005-09-29 |
| WO2005090425A1 (en) | 2005-09-29 |
| AR048817A1 (es) | 2006-05-31 |
| BRPI0508161A (pt) | 2007-08-07 |
| JP2007529616A (ja) | 2007-10-25 |
| US20070167315A1 (en) | 2007-07-19 |
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