MX358426B - Metodo para la preparacion de nitrosil nitrato de rutenio solido mediante el uso de un catalizador residual que contiene rutenio. - Google Patents
Metodo para la preparacion de nitrosil nitrato de rutenio solido mediante el uso de un catalizador residual que contiene rutenio.Info
- Publication number
- MX358426B MX358426B MX2014010569A MX2014010569A MX358426B MX 358426 B MX358426 B MX 358426B MX 2014010569 A MX2014010569 A MX 2014010569A MX 2014010569 A MX2014010569 A MX 2014010569A MX 358426 B MX358426 B MX 358426B
- Authority
- MX
- Mexico
- Prior art keywords
- ruthenium
- nitrate
- nitrosyl
- solid
- gas
- Prior art date
Links
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 12
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 12
- 239000007787 solid Substances 0.000 title abstract 7
- NSNVGCNCRLAWOJ-UHFFFAOYSA-N [N+](=O)([O-])[O-].N(=O)[Ru+2].[N+](=O)([O-])[O-] Chemical compound [N+](=O)([O-])[O-].N(=O)[Ru+2].[N+](=O)([O-])[O-] NSNVGCNCRLAWOJ-UHFFFAOYSA-N 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 239000002699 waste material Substances 0.000 title abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- 239000007789 gas Substances 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 235000010288 sodium nitrite Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/048—Recovery of noble metals from waste materials from spent catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/005—Preliminary treatment of scrap
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/36—Detoxification by using acid or alkaline reagents
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/40—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Se describe un método para la preparación de nitrosil nitrato de rutenio sólido mediante el uso de un catalizador residual que contiene rutenio. Los pasos del método son: secar y calcinar un catalizador residual que contiene rutenio para obtener un sólido negro que contiene rutenio, moler el sólido que contiene negro de rutenio a un polvo, alimentar hidrógeno para efectuar una reducción para formar rutenio metálico, oxidar el rutenio metálico mediante el uso de una mezcla gaseosa de ozono y aire para producir un gas de tetraóxido de rutenio, colectar el gas, alimentar el gas en una solución de ácido nítrico, adicionar nitrito de sodio sólido para preparar una solución que contiene nitrosil nitrato de rutenio, y finalmente emplear dietil éter para la extracción, y evaporar el éter dietílico para adquirir nitrosil nitrato de rutenio sólido. El método puede recuperar efectivamente el metal noble rutenio de varios residuos de catalizadores del tipo de carga que contienen rutenio, a fin de lograr el reciclaje eficaz de los recursos de rutenio, y tiene pasos de operación simple y no implica la intervención de compuestos intermedios de rutenio, lo que asegura un alto rendimiento de producto. El sólido nitrosil nitrato de rutenio obtenido está libre de halógeno, tiene una alta pureza, y es capaz de ser aplicado directamente a la preparación de catalizadores.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210055796.1A CN102616868B (zh) | 2012-03-05 | 2012-03-05 | 利用含钌废催化剂制备固体亚硝酰硝酸钌的方法 |
| PCT/CN2013/072105 WO2013131451A1 (zh) | 2012-03-05 | 2013-03-04 | 利用含钌废催化剂制备固体亚硝酰硝酸钌的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014010569A MX2014010569A (es) | 2015-06-02 |
| MX358426B true MX358426B (es) | 2018-08-17 |
Family
ID=46557154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014010569A MX358426B (es) | 2012-03-05 | 2013-03-04 | Metodo para la preparacion de nitrosil nitrato de rutenio solido mediante el uso de un catalizador residual que contiene rutenio. |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US9005555B2 (es) |
| EP (1) | EP2823900B1 (es) |
| JP (1) | JP5902324B2 (es) |
| KR (1) | KR101567592B1 (es) |
| CN (1) | CN102616868B (es) |
| AP (1) | AP2014007986A0 (es) |
| AU (1) | AU2013230403B2 (es) |
| BR (1) | BR112014021848A2 (es) |
| CA (1) | CA2866207C (es) |
| DK (1) | DK2823900T3 (es) |
| ES (1) | ES2637517T3 (es) |
| IN (1) | IN2014MN01924A (es) |
| MX (1) | MX358426B (es) |
| MY (1) | MY166186A (es) |
| PL (1) | PL2823900T3 (es) |
| RU (1) | RU2580414C1 (es) |
| SG (1) | SG11201405382UA (es) |
| WO (1) | WO2013131451A1 (es) |
| ZA (1) | ZA201407147B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556250B (zh) * | 2014-12-19 | 2016-06-01 | 昆明珀玺金属材料有限公司 | 一种制备亚硝酰硝酸钌溶液或纯净晶体的新方法 |
| JP6562351B2 (ja) * | 2015-09-10 | 2019-08-21 | 学校法人上智学院 | ポリマーの製造方法およびニトロシルルテニウム錯体の使用 |
| CN106698529B (zh) * | 2017-01-12 | 2017-12-26 | 郴州高鑫材料有限公司 | 两步合成亚硝酰硝酸钌的方法 |
| CN106927514B (zh) * | 2017-03-20 | 2018-10-02 | 昆明理工大学 | 一种制备亚硝酰硝酸钌的方法 |
| WO2020256007A1 (ja) * | 2019-06-21 | 2020-12-24 | 株式会社トクヤマ | 酸化ルテニウムガスの吸収液、酸化ルテニウムの分析方法およびトラップ装置、定量分析装置 |
| CN112538573B (zh) * | 2020-11-18 | 2022-04-15 | 铜陵欣诺科新材料有限公司 | 从含钌废液中回收钌的方法 |
| CN113582259B (zh) * | 2021-08-25 | 2023-09-08 | 合创(无锡)环保科技有限公司 | 一种液体硝酸钌合成工艺方法 |
| CN115650322B (zh) * | 2022-11-02 | 2024-03-01 | 金川集团股份有限公司 | 一种亚硝酰基硝酸钌的方法 |
| CN115536520A (zh) * | 2022-11-02 | 2022-12-30 | 金川集团股份有限公司 | 一种醋酸钌的制备方法 |
| CN115874060A (zh) * | 2022-12-19 | 2023-03-31 | 本源精化环保科技有限公司 | 一种从废弃负载型复合催化剂中提取贵金属的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4132569A (en) * | 1977-10-25 | 1979-01-02 | Diamond Shamrock Corporation | Ruthenium recovery process |
| US20010024700A1 (en) * | 1997-05-01 | 2001-09-27 | Asbish Shah | Ruthenium-containing ultrasonically coated substrate for use in a capacitor and method of manufacture |
| RU2195431C2 (ru) * | 2000-12-25 | 2002-12-27 | ОАО "Красноярский завод цветных металлов им. В.Н.Гулидова" | Способ реэкстракции рутения из тбф |
| JP4756530B2 (ja) * | 2004-07-02 | 2011-08-24 | 住化エンビロサイエンス株式会社 | 有機酸ルテニウムの製造方法 |
| DE102005061954A1 (de) * | 2005-12-23 | 2007-07-05 | Basf Ag | Verfahren zur Wiedergewinnung von Ruthenium aus gebrauchten Rutheniumoxid-haltigen Katalysatoren |
| CN100387344C (zh) * | 2006-06-21 | 2008-05-14 | 浙江工业大学 | 一种活性炭负载的钌催化剂的回收方法 |
| DE102007020142A1 (de) * | 2007-04-26 | 2008-10-30 | Bayer Materialscience Ag | Verfahren zur Rückgewinnung von Ruthenium aus einem rutheniumhaltigen geträgerten Katalysatormaterial |
| CN101638727B (zh) | 2008-07-31 | 2011-04-20 | 中国石油天然气股份有限公司 | 一种活性炭负载钌催化剂中钌的回收方法 |
| CN102167405B (zh) * | 2011-01-24 | 2013-06-12 | 昆明贵金属研究所 | 一种制备固体亚硝酰硝酸钌的方法 |
| CN102108444B (zh) * | 2011-04-01 | 2013-04-17 | 开滦能源化工股份有限公司 | 从负载型钌金属或氧化钌催化剂中回收钌的方法 |
-
2012
- 2012-03-05 CN CN201210055796.1A patent/CN102616868B/zh active Active
-
2013
- 2013-03-04 PL PL13758228T patent/PL2823900T3/pl unknown
- 2013-03-04 EP EP13758228.4A patent/EP2823900B1/en not_active Not-in-force
- 2013-03-04 MY MYPI2014002571A patent/MY166186A/en unknown
- 2013-03-04 ES ES13758228.4T patent/ES2637517T3/es active Active
- 2013-03-04 IN IN1924MUN2014 patent/IN2014MN01924A/en unknown
- 2013-03-04 AP AP2014007986A patent/AP2014007986A0/xx unknown
- 2013-03-04 AU AU2013230403A patent/AU2013230403B2/en not_active Ceased
- 2013-03-04 DK DK13758228.4T patent/DK2823900T3/en active
- 2013-03-04 BR BR112014021848-0A patent/BR112014021848A2/pt not_active IP Right Cessation
- 2013-03-04 MX MX2014010569A patent/MX358426B/es active IP Right Grant
- 2013-03-04 KR KR1020147027911A patent/KR101567592B1/ko active IP Right Grant
- 2013-03-04 RU RU2014140158/13A patent/RU2580414C1/ru not_active IP Right Cessation
- 2013-03-04 JP JP2014560228A patent/JP5902324B2/ja not_active Expired - Fee Related
- 2013-03-04 SG SG11201405382UA patent/SG11201405382UA/en unknown
- 2013-03-04 CA CA2866207A patent/CA2866207C/en not_active Expired - Fee Related
- 2013-03-04 WO PCT/CN2013/072105 patent/WO2013131451A1/zh active Application Filing
-
2014
- 2014-09-02 US US14/475,547 patent/US9005555B2/en not_active Expired - Fee Related
- 2014-10-02 ZA ZA2014/07147A patent/ZA201407147B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140130747A (ko) | 2014-11-11 |
| EP2823900A1 (en) | 2015-01-14 |
| RU2580414C1 (ru) | 2016-04-10 |
| EP2823900B1 (en) | 2017-05-17 |
| CA2866207C (en) | 2017-04-18 |
| CA2866207A1 (en) | 2013-09-12 |
| ZA201407147B (en) | 2016-01-27 |
| ES2637517T3 (es) | 2017-10-13 |
| DK2823900T3 (en) | 2017-09-04 |
| JP2015514563A (ja) | 2015-05-21 |
| SG11201405382UA (en) | 2014-10-30 |
| CN102616868B (zh) | 2014-04-30 |
| CN102616868A (zh) | 2012-08-01 |
| AU2013230403B2 (en) | 2015-10-08 |
| AP2014007986A0 (en) | 2014-10-31 |
| US9005555B2 (en) | 2015-04-14 |
| MX2014010569A (es) | 2015-06-02 |
| MY166186A (en) | 2018-06-07 |
| EP2823900A4 (en) | 2015-11-25 |
| US20140369905A1 (en) | 2014-12-18 |
| KR101567592B1 (ko) | 2015-11-20 |
| JP5902324B2 (ja) | 2016-04-13 |
| PL2823900T3 (pl) | 2018-01-31 |
| IN2014MN01924A (es) | 2015-07-10 |
| AU2013230403A1 (en) | 2014-10-16 |
| BR112014021848A2 (pt) | 2021-05-18 |
| WO2013131451A1 (zh) | 2013-09-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MX358426B (es) | Metodo para la preparacion de nitrosil nitrato de rutenio solido mediante el uso de un catalizador residual que contiene rutenio. | |
| CN105669464A (zh) | 一种无金属加氢催化剂在催化硝基苯及其衍生物加氢反应中的应用 | |
| CN105344357A (zh) | 一种用于甘油氢解制备1,3-丙二醇的催化剂 | |
| CN102125851B (zh) | 一种废铜基催化剂制备甲醇制氢催化剂的应用方法 | |
| CN103626240A (zh) | 低浓度复杂含钌废液制备三氯化钌的方法 | |
| AU2013409375A1 (en) | Method for preparing polyoxymethylene dimethyl ether carbonyl compound and methyl methoxyacetate | |
| CN103285856A (zh) | 一种用于制备卤代苯胺的防脱卤钌基催化剂及其制备方法 | |
| CN104556250B (zh) | 一种制备亚硝酰硝酸钌溶液或纯净晶体的新方法 | |
| CN103570498B (zh) | 一种甘油氯化制备二氯丙醇的方法 | |
| CN103755717B (zh) | 一种纤维素/生物质催化热解制备lac的方法 | |
| CN105753717B (zh) | 一种无金属加氢催化剂在催化1-硝基萘加氢反应中的应用 | |
| CN103394371A (zh) | 乙炔法生产4-羟丁基乙烯基醚的方法及其催化剂 | |
| CN106319230A (zh) | 一种干法回收废scr催化剂中金属钛钒钨的方法 | |
| CN105664949A (zh) | 一种铜锌催化剂的制备方法 | |
| CN102786487A (zh) | 石墨烯作为催化剂在制备四氮唑类化合物中的应用 | |
| CN102502777B (zh) | 以各种含银离子废水为原料制备硝酸银的方法 | |
| CN106179412B (zh) | 一种制备片状SmS-CrS2层间不匹配化合物的方法 | |
| CN103028411B (zh) | 一种无铬气相法合成n-甲基苯胺催化剂 | |
| CN103265399A (zh) | 基于催化剂的氯代特戊烷制备工艺 | |
| CN103570551A (zh) | 一种合成草酸酯用亚硝酸酯的装置和方法 | |
| CN105289718B (zh) | 一种合成3,3,3‑三氟丙酸乙酯的催化剂及其制备方法 | |
| CN102659626B (zh) | 还原溴代沙坦联苯废渣的方法 | |
| TH155615A (th) | วิธีเตรียมไนโตรซิลรูเทเนียมไนเตรทในรูปของแข็งโดยใช้สารเร่งปฏิกิริยาของเสียที่มีรูเทเนียม | |
| UA104858C2 (uk) | Спосіб знешкодження радіоактивних відходів у силікатному склі (варіанти) | |
| CN103755536A (zh) | 一种苯偶姻简便氧化制备苯偶酰的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |