MX2007011344A - Composiciones de polimero rellenas preparadas a partir de interpolimeros de etileno/a-olefinas y sus usos. - Google Patents
Composiciones de polimero rellenas preparadas a partir de interpolimeros de etileno/a-olefinas y sus usos.Info
- Publication number
- MX2007011344A MX2007011344A MX2007011344A MX2007011344A MX2007011344A MX 2007011344 A MX2007011344 A MX 2007011344A MX 2007011344 A MX2007011344 A MX 2007011344A MX 2007011344 A MX2007011344 A MX 2007011344A MX 2007011344 A MX2007011344 A MX 2007011344A
- Authority
- MX
- Mexico
- Prior art keywords
- ethylene
- polymer
- percent
- filled polymer
- filled
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 452
- 239000000203 mixture Substances 0.000 title claims abstract description 322
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 201
- 239000005977 Ethylene Substances 0.000 title claims abstract description 201
- 239000000945 filler Substances 0.000 claims abstract description 65
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 239000004711 α-olefin Substances 0.000 claims description 123
- -1 titanates Substances 0.000 claims description 74
- 229920001577 copolymer Polymers 0.000 claims description 62
- 239000003921 oil Substances 0.000 claims description 50
- 238000002844 melting Methods 0.000 claims description 49
- 230000008018 melting Effects 0.000 claims description 49
- 230000004927 fusion Effects 0.000 claims description 46
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 45
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- 238000007906 compression Methods 0.000 claims description 36
- 230000006835 compression Effects 0.000 claims description 36
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 33
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 32
- 229920000570 polyether Polymers 0.000 claims description 28
- 238000009826 distribution Methods 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 25
- 238000003860 storage Methods 0.000 claims description 23
- 150000001993 dienes Chemical class 0.000 claims description 21
- 238000012545 processing Methods 0.000 claims description 20
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- 239000000155 melt Substances 0.000 claims description 19
- 238000011084 recovery Methods 0.000 claims description 19
- 229920000728 polyester Polymers 0.000 claims description 17
- 229920000098 polyolefin Polymers 0.000 claims description 16
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 14
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 14
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 229920000573 polyethylene Polymers 0.000 claims description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 13
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 12
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 235000021355 Stearic acid Nutrition 0.000 claims description 9
- 230000001186 cumulative effect Effects 0.000 claims description 9
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000008117 stearic acid Substances 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229940117958 vinyl acetate Drugs 0.000 claims description 6
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 5
- 229910052775 Thulium Inorganic materials 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 229910052702 rhenium Inorganic materials 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000002174 Styrene-butadiene Substances 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 4
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- 239000000395 magnesium oxide Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000378 calcium silicate Substances 0.000 claims description 3
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 3
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 3
- 239000010433 feldspar Substances 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000004005 microsphere Substances 0.000 claims description 3
- 239000010434 nepheline Substances 0.000 claims description 3
- 229910052664 nepheline Inorganic materials 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 229920001400 block copolymer Polymers 0.000 abstract description 27
- 238000009408 flooring Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 62
- 239000003054 catalyst Substances 0.000 description 50
- 235000019198 oils Nutrition 0.000 description 47
- 238000000113 differential scanning calorimetry Methods 0.000 description 42
- 239000000178 monomer Substances 0.000 description 41
- 239000000654 additive Substances 0.000 description 39
- 230000000052 comparative effect Effects 0.000 description 38
- 239000000523 sample Substances 0.000 description 35
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
- 238000006116 polymerization reaction Methods 0.000 description 28
- 239000000243 solution Substances 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 26
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- 238000001938 differential scanning calorimetry curve Methods 0.000 description 24
- 235000010216 calcium carbonate Nutrition 0.000 description 20
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000000049 pigment Substances 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- 238000004519 manufacturing process Methods 0.000 description 16
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 16
- 230000035515 penetration Effects 0.000 description 16
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 150000001336 alkenes Chemical class 0.000 description 15
- 238000010828 elution Methods 0.000 description 15
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 14
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 14
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- 238000004458 analytical method Methods 0.000 description 13
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
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- 238000005481 NMR spectroscopy Methods 0.000 description 11
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 10
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- 239000011701 zinc Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 230000007423 decrease Effects 0.000 description 9
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
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- 239000010959 steel Substances 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 150000003440 styrenes Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- HSVFKFNNMLUVEY-UHFFFAOYSA-N sulfuryl diazide Chemical class [N-]=[N+]=NS(=O)(=O)N=[N+]=[N-] HSVFKFNNMLUVEY-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229910002029 synthetic silica gel Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical group CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- QEPDENOFSCCDEA-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)alumane;2-undecyl-1h-imidazole Chemical compound CCCCCCCCCCCC1=NC=CN1.FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F.FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F QEPDENOFSCCDEA-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
- C08F297/086—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene the block polymer contains at least three blocks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/005—Modified block copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2005/008917 WO2005090427A2 (en) | 2004-03-17 | 2005-03-17 | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US71758705P | 2005-09-16 | 2005-09-16 | |
| PCT/US2006/009411 WO2006101932A2 (en) | 2005-03-17 | 2006-03-15 | FILLED POLYMER COMPOSITIONS MADE FROM INTERPOLYMERS OF ETHYLENE/α-OLEFINS AND USES THEREOF |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2007011344A true MX2007011344A (es) | 2007-10-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2007011344A MX2007011344A (es) | 2005-03-17 | 2006-03-15 | Composiciones de polimero rellenas preparadas a partir de interpolimeros de etileno/a-olefinas y sus usos. |
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| Country | Link |
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| EP (1) | EP1858962B1 (enExample) |
| JP (2) | JP5214434B2 (enExample) |
| CN (1) | CN101365742B (enExample) |
| AR (1) | AR055045A1 (enExample) |
| AU (1) | AU2006227671A1 (enExample) |
| BR (1) | BRPI0609843B1 (enExample) |
| CA (1) | CA2601275A1 (enExample) |
| MX (1) | MX2007011344A (enExample) |
| RU (1) | RU2007134346A (enExample) |
| TW (1) | TWI374150B (enExample) |
| WO (1) | WO2006101932A2 (enExample) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CA2601292A1 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Ethylene/alpha-olefins block interpolymers |
| US7786216B2 (en) * | 2005-03-17 | 2010-08-31 | Dow Global Technologies Inc. | Oil based blends of interpolymers of ethylene/α-olefins |
| EP2121813B2 (en) | 2007-02-15 | 2019-09-25 | Trinseo Europe GmbH | Thermoplastic fiber concentrate methods and articles |
| EP2170604B1 (en) * | 2007-07-13 | 2019-05-15 | Dow Global Technologies LLC | Ethylene/alpha-olefin interpolymers having low crystallinity hard blocks |
| US8569422B2 (en) * | 2007-07-13 | 2013-10-29 | Dow Global Technologies, Llc | Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block |
| JP5357169B2 (ja) * | 2007-10-22 | 2013-12-04 | ダウ グローバル テクノロジーズ エルエルシー | 物品を成形するためのポリマー組成物及び方法 |
| CN105001584A (zh) * | 2008-01-30 | 2015-10-28 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃嵌段互聚物 |
| US8529821B2 (en) | 2009-01-30 | 2013-09-10 | Dow Global Technologies Llc | Polymeric compositions and filled TPO articles having improved aesthetics |
| KR101311230B1 (ko) * | 2009-03-24 | 2013-09-24 | 에스케이종합화학 주식회사 | 전력케이블용 비 가교 폴리에틸렌 조성물 |
| CN102725345B (zh) * | 2009-09-18 | 2014-12-10 | 陶氏环球技术有限责任公司 | 用于凝塑成形工艺的粉末热塑性聚烯烃弹性体组合物 |
| WO2011066177A1 (en) * | 2009-11-30 | 2011-06-03 | Dow Global Technologies Inc. | Thermoformable sound-deadening filled thermoplastic polyolefin composition |
| KR101668146B1 (ko) * | 2010-02-22 | 2016-10-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 도장된 폴리올레핀 물품 |
| EP2580286B1 (en) * | 2010-06-14 | 2015-05-06 | Dow Global Technologies LLC | Olefin block copolymer composition with low tack |
| KR101818792B1 (ko) | 2010-06-18 | 2018-01-15 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 전기 전도성 올레핀 멀티블록 공중합체 조성물 |
| RU2620414C2 (ru) * | 2011-12-29 | 2017-05-25 | Фаэрстоун Билдинг Продактс Ко., Ллк | Кровельные мембраны, содержащие терморасширяющийся графит в качестве антипирена |
| WO2013134083A1 (en) | 2012-03-07 | 2013-09-12 | Dow Global Technologies Llc | Polyolefin based formulations for membranes and fabrics |
| JP6179243B2 (ja) * | 2012-07-31 | 2017-08-16 | 大日本印刷株式会社 | 太陽電池モジュール及びこれに用いられる太陽電池用封止材 |
| MX348309B (es) * | 2012-09-25 | 2017-06-06 | Dow Global Technologies Llc | Composiciones de polímero modificado a base de etileno y métodos para su producción. |
| US10066102B2 (en) | 2013-11-22 | 2018-09-04 | Trinseo Europe Gmbh | Polycarbonate containing compositions |
| CN105814138B (zh) | 2013-11-22 | 2018-06-01 | 盛禧奥欧洲有限责任公司 | 含聚碳酸酯的组合物 |
| EP3105053B1 (en) | 2014-01-31 | 2021-09-22 | Kimberly-Clark Worldwide, Inc. | Thin nanocomposite film for use in an absorbent article |
| RU2612931C1 (ru) | 2014-01-31 | 2017-03-13 | Кимберли-Кларк Ворлдвайд, Инк. | Жесткая нанокомпозитная пленка для применения во впитывающем изделии |
| RU2647314C2 (ru) * | 2014-01-31 | 2018-03-15 | Кимберли-Кларк Ворлдвайд, Инк. | Нанокомпозитная упаковочная пленка |
| EP2918635A1 (en) * | 2014-03-12 | 2015-09-16 | Autoneum Management AG | Thermoplastic compostition comprising Polyethylene, manufacture and use thereof |
| KR102387086B1 (ko) * | 2014-06-16 | 2022-04-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 블록 코폴리머를 갖는 아크릴 조성물 |
| JP6057955B2 (ja) * | 2014-08-14 | 2017-01-11 | ダウ グローバル テクノロジーズ エルエルシー | 低結晶化度ハードブロックを含むエチレン／α−オレフィンインターポリマー |
| JP6165192B2 (ja) * | 2015-05-22 | 2017-07-19 | ダウ グローバル テクノロジーズ エルエルシー | 低温および湿潤用途用の熱可塑性エラストマー |
| CN107614594B (zh) * | 2015-05-22 | 2021-06-01 | 陶氏环球技术有限责任公司 | 用于制造具有交联绝缘层的电缆的方法以及用此方法制造的电缆 |
| RU2678051C2 (ru) * | 2016-04-07 | 2019-01-22 | Общество с ограниченной ответственностью "Рекстром-М" | Способ получения материала для изготовления панелей звукопоглощающих экранов методом экструзии |
| KR101905958B1 (ko) * | 2016-06-30 | 2018-10-18 | 현대자동차주식회사 | 차음재의 제조방법, 이 제조방법으로 제조된 차음재 및 이를 이용한 차량용 카페트 |
| JP6725112B6 (ja) * | 2016-07-29 | 2020-08-19 | 国立研究開発法人産業技術総合研究所 | 多成分系溶液の性状推定方法、装置、及びプログラム |
| CN109996920B (zh) * | 2016-09-28 | 2022-06-17 | 陶氏环球技术有限责任公司 | 经涂布的聚酯织物 |
| TWI619754B (zh) * | 2016-11-01 | 2018-04-01 | Chen Jin Fu | 環保材料及使用該環保材料所製成之窗簾葉片 |
| JP6456905B2 (ja) * | 2016-12-14 | 2019-01-23 | ダウ グローバル テクノロジーズ エルエルシー | 低結晶化度ハードブロックを含むエチレン／α−オレフィンインターポリマー |
| US11732071B2 (en) | 2018-05-04 | 2023-08-22 | Lg Chem, Ltd. | Olefin-based copolymer and method for preparing the same |
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| JP7482794B2 (ja) * | 2019-02-05 | 2024-05-14 | 株式会社ブリヂストン | 樹脂組成物及び樹脂製品 |
| CN110372953A (zh) * | 2019-07-24 | 2019-10-25 | 江苏银辉生态科技有限公司 | 一种聚丙烯纳米隔声板及其制备方法 |
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| JPS6088016A (ja) * | 1983-10-21 | 1985-05-17 | Mitsui Petrochem Ind Ltd | エチレン共重合体 |
| JPS6166741A (ja) * | 1984-09-07 | 1986-04-05 | Mitsubishi Petrochem Co Ltd | オレフイン系ブロツク共重合体組成物 |
| KR100197327B1 (ko) * | 1988-07-15 | 1999-06-15 | 치어즈 엠. 노우드 | 신디오택틱 폴리프로필렌 |
| WO1998003521A1 (en) * | 1996-07-23 | 1998-01-29 | Symyx Technologies | Combinatorial synthesis and analysis of organometallic compounds and catalysts |
| JP2000095903A (ja) * | 1998-07-21 | 2000-04-04 | Mitsui Chemicals Inc | シンジオタクティックポリプロピレン組成物およびその成形体 |
| US6306658B1 (en) * | 1998-08-13 | 2001-10-23 | Symyx Technologies | Parallel reactor with internal sensing |
| US6316663B1 (en) * | 1998-09-02 | 2001-11-13 | Symyx Technologies, Inc. | Catalyst ligands, catalytic metal complexes and processes using and methods of making the same |
| AU4186500A (en) * | 1999-04-01 | 2000-10-23 | Symyx Technologies, Inc. | Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and methods of making same |
| MXPA01011557A (es) * | 1999-05-14 | 2002-07-30 | Dupont Dow Elastomers Llc | Interpolimeros de etileno/alfa-olefina/polieno altamente cristalinos. |
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| JP3404368B2 (ja) * | 1999-11-04 | 2003-05-06 | 日東電工株式会社 | 粘着テープ |
| US6653385B2 (en) * | 2001-10-18 | 2003-11-25 | Bostik Findley, Inc. | Hot melt adhesive composition based on a blend of amorphous poly-α-olefin and syndiotactic polypropylene |
| EP1444276A1 (en) * | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| JP3948937B2 (ja) * | 2001-11-09 | 2007-07-25 | 日本ポリプロ株式会社 | プロピレン系樹脂組成物 |
| JP2004168876A (ja) * | 2002-11-19 | 2004-06-17 | Inoac Corp | マスターバッチ |
| JP4068953B2 (ja) * | 2002-12-25 | 2008-03-26 | 三井化学株式会社 | プロピレン系樹脂組成物 |
| JP2004204058A (ja) * | 2002-12-25 | 2004-07-22 | Mitsui Chemicals Inc | オレフィン系ブロック共重合体 |
| JP4907062B2 (ja) * | 2004-04-20 | 2012-03-28 | 日本ポリプロ株式会社 | ポリプロピレン系二軸延伸複層フィルム |
| JP5133050B2 (ja) * | 2004-03-17 | 2013-01-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| JP4879882B2 (ja) * | 2004-03-17 | 2012-02-22 | ダウ グローバル テクノロジーズ エルエルシー | より高次のオレフィンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| KR101277095B1 (ko) * | 2004-03-17 | 2013-06-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 셔틀링제를 포함하는, 에틸렌 공중합체 형성용 촉매 조성물 |
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| AR055045A1 (es) | 2007-08-01 |
| JP5425290B2 (ja) | 2014-02-26 |
| JP2013064138A (ja) | 2013-04-11 |
| WO2006101932A3 (en) | 2007-10-04 |
| JP2008540697A (ja) | 2008-11-20 |
| JP5214434B2 (ja) | 2013-06-19 |
| AU2006227671A1 (en) | 2006-09-28 |
| BRPI0609843A2 (pt) | 2010-05-04 |
| EP1858962A2 (en) | 2007-11-28 |
| TW200640960A (en) | 2006-12-01 |
| CN101365742B (zh) | 2012-02-08 |
| CA2601275A1 (en) | 2006-09-28 |
| BRPI0609843B1 (pt) | 2023-01-10 |
| EP1858962B1 (en) | 2018-11-14 |
| CN101365742A (zh) | 2009-02-11 |
| TWI374150B (en) | 2012-10-11 |
| WO2006101932A2 (en) | 2006-09-28 |
| RU2007134346A (ru) | 2009-03-20 |
| WO2006101932B1 (en) | 2007-11-15 |
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