LT4864B - Sapropelio trąšos ir jų gavimo būdas - Google Patents
Sapropelio trąšos ir jų gavimo būdas Download PDFInfo
- Publication number
- LT4864B LT4864B LT2001004A LT2001004A LT4864B LT 4864 B LT4864 B LT 4864B LT 2001004 A LT2001004 A LT 2001004A LT 2001004 A LT2001004 A LT 2001004A LT 4864 B LT4864 B LT 4864B
- Authority
- LT
- Lithuania
- Prior art keywords
- sapropel
- peat
- fertilizer
- mixture
- fertilizers
- Prior art date
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- 239000003337 fertilizer Substances 0.000 title claims description 45
- 238000004519 manufacturing process Methods 0.000 title description 3
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000003415 peat Substances 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003892 spreading Methods 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- SBXDENYROQKXBE-UHFFFAOYSA-N 2-phenylbenzenesulfonamide Chemical class NS(=O)(=O)C1=CC=CC=C1C1=CC=CC=C1 SBXDENYROQKXBE-UHFFFAOYSA-N 0.000 abstract 1
- 229940118365 Endothelin receptor antagonist Drugs 0.000 abstract 1
- 206010020772 Hypertension Diseases 0.000 abstract 1
- 229940127282 angiotensin receptor antagonist Drugs 0.000 abstract 1
- 201000010099 disease Diseases 0.000 abstract 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract 1
- 239000002308 endothelin receptor antagonist Substances 0.000 abstract 1
- 239000008194 pharmaceutical composition Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 8
- 239000011707 mineral Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 230000035784 germination Effects 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- 239000006259 organic additive Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000004720 fertilization Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 244000299906 Cucumis sativus var. sativus Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
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- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
- C07D261/10—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D261/14—Nitrogen atoms
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- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
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Description
Išradimas priklauso trąšų gamybos sričiai, būtent organinių trąšų mišiniams, į kurių sudėtį įeina sapropelis ir jų gavimo būdui. Šiuo būdu gautos trąšos naudojamos efektyviam dirvų tręšimui.
Sapropelis - tai ežerų dugne, esant deguonies trūkumui, iš tirpių ir kietų nuosėdų, veikiant biologiniamš procesams, per kelis tūkstantmečius susiformavusi organinė medžiaga. Seniai yra žinomas organinio sapropelio panaudojimas žemės ūkyje (L. Katkevičius, A. Ciūnys, E. Bakšienė Ežerų sapropelis žemės ūkiui”, Vilnius, 1998).
Žinomas organmineralinių sapropelio trąšų gavimo būdas, kai sapropelio pulpą sutirština nusodintuve, pašalina pagrindinę nuskaidrinto vandens masę ir į sutirštintą sapropelio pulpą deda mineralinius priedus, būtent skalūnų pelenus (buv. TSRS a.l. Nr. 1724657).
Aprašyto sapropelio trąšų gavimo būdo trūkumas yra ilgai trunkantis šių trąšų paruošimas, o šiuo būdu gautos trąšos lėtai mineralizuojasi ir maisto medžiagas atiduoda palaipsniui, be to, šiose trąšose yra mažai hidrolizuojamų medžiagų.
Žinomos sapropelio trąšos, susidedančios iš sapropelio ir organinių ir/arba mineralinių priedų, kaip organiniai priedai gali būti durpės ir/arba skiedros, ir/arba pjuvenos, ir u.oa mėšlas, o kaip mineraliniai priedai gali būti ceolitas ir/arba mineralinės trąšos, ir/arba šlakas, ir/arba karbonatinis sapropelis. Sapropelio trąšose priedai sudaro nurodytus masės % : durpės su drėgminiu imlumu 1000% 30;Fosforo trąšos 0,4
Kalio trąšos 0,2
Azoto trąšos 0,25
Likusi dalis: Karbonatinis sapropelis (Rusijos patentas Nr. 2041866, 1994 01 20, C05F 7/00).
Žinomas sapropelio trąšų gavimo būdas, kai išimtą iš ežero sapropelį aikštelėje paskleidžia sluoksniu ir periodiškai maišant džiovina pridedant priedų. Žiemą sapropelį šaldo ir sudeda į m aukščio krūvas, kad pavasarį po šalčių sapropelio masės drėgnis būtų apie 40 %
Maišymo metu į sapropelį įveda mineralinius ir/arba organinius priedus, tokius kaip durpes, 2 LT 4864 B ir/arba skiedras, ir/arba pjuvenas, ir/arba ceolitą, ir/arba mineralines trąšas, ir/arba šlaką, ir/arba karbonatinį sapropelį. Po to sapropelį valo nuo pašalinių priemaišų, mala, džiovina iki jo drėgnis siekia 10-40% bei granuliuoja (Rusijos patentas Nr. 2041866, 1994 01 20, C05F 7/00).
Žinomose sapropelio trąšose dedama 30 masės % durpių su drėgminiu imlumu 1000%, tai atitinka sausosios medžiagos durpių 9 masės %. Žinomo sapropelio trąšų gavimo būdas ilgas ir brangus, nes šiuo būdu gautų trąšų kompozicijoje esantis mineralinių ir organinių medžiagų masių santykis neužtikrina greito sapropelio trąšų džiovinimo proceso, be to, reikalinga įranga trąšų malimui, granuliavimui bei jų pergabenimui nuo vienos apdorojimo operacijos prie kitos. Gautos šiuo būdu trąšos nepakankamai efektyvios, nes granulėse esančios maisto medžiagos lėtai atiduodamos dėl mažo granulių vandens imlumo.
Išradimu siekiama supaprastinti sapropelio trąšų gavimo būdą bei pagerinti sapropelio trąšų efektyvumą.
Uždavinio sprendimo esmė yra ta, kad sapropelio trąšose, susidedančiose iš sapropelio ir durpių mišinio, nauja yra tai, kad sapropelio ir durpių sausųjų medžiagų masių santykis mišinyje yra ribose nuo 1 : 1 iki 1 : 0,5.
Sapropelio gavimo būde, apimančiame sapropelio išėmimą iš ežero, jo paskleidimą sluoksniu aikštelėje, džiovinimą ir džiovinimo metu periodiškai maišant organinių priedų, pavyzdžiui, durpių į sapropelį įvedimą, nauja yra tai, kad sapropelio ir durpių sausųjų medžiagų masių santykį mišinyje palaiko ribose nuo 1 : 1 iki 1 : 0,5.
Sapropelio džiovinimo metu jo sumaišymas su durpėmis užtikrinant sausųjų medžiagų masių santykį nuo 1 : 1 iki 1 : 0,5 pagreitina sapropelio džiovinimą, tuo pačiu ir sapropelio trąšų gavimą bei pagerina gautų trąšų efektyvumą. Gauta mišinio masė puri, biri, struktūringa, pasižymi geromis absorbcinėmis sąvybėmis. Šis trąšų gamybos būdas yra pigus, jo realizavimas nereikalauja sudėtingos įrangos. Gautose trąšose esanti durpių dalis pagreitina sapropelio mineralizaciją, padidina lengvai hidrolizuojamų medžiagų bei humusinių rūgščių kiekį, o esanti sapropelio dalis sulėtina durpių mineralizaciją, neleidžia išgaruoti išsiskiriančioms augalų maisto medžiagoms
Trąšų optimalus džiovinimo laikas ir trąšų efektyvumas buvo nustatytas įvertinus žemiau aprašytus bandymus.
Bandymais buvo nustatyti sapropelio, durpių bei šių medžiagų mišinių džiovinimo duomenys, kurie pateikti 1 lentelėje.
lentelė
| Bandymų variantai | Būklė | Džiovinimo laikas paromis' ir medžiagos drėgnis % | |||||
| Šviežias | 5 paros | 10 parų | 20 parų | 30 parų | 40 | ||
| parų | |||||||
| 1. Sapropelis (S) | Tešlos | 92 | 91 | 86 | 79 | 72 | 64 |
| Konsist. | |||||||
| 2. Durpės (D) | Puri | 73 | 69 | 47 | 34 | 27 | 28 |
| 3. S+D 1:1 | Tirštos | 89 | 87 | 81 | 69 | 56 | 51 |
| tesi. kons. | |||||||
| 4. S+D 1:2 | Biri | 87 | 84 | 70 | 62 | 54 | 48 |
| 5. S+D 1:3 | Puri | 82 | 79 | 63 | 55 | 49 | 36 |
| 6. S+D 1:0,5 | Tirštos | 90 | 89 | 84 | 73 | 66 | 58 |
| Tešlos | |||||||
| konsist. |
lentelės duomenys rodo, kad sumaišytas sapropelis su durpėmis greičiau džiūsta ir jo struktūra pasidaro puri. Greičiausiai džiūsta durpės ir tas mišinys, kur durpių daugiausiai, t.y. S+D 1:3. Tačiau šis sapropelio ir durpių santykis nėra efektyviausias augalams. Siekiant įvertinti sapropelio ir durpių bei jų mišinio kaip trąšų vertingumą, buvo atlikti bandymai, nustatant šių medžiagų toksiškumą. Kuo mažesnis trąšų toksiškumas, tuo didesni augalų dygimo energija, daigumas ir augimas. Pagal Valstybinį standartąNr.5055-56 buvo nustatyta agurkų veislės “Alfa” sėklų dygimo energija ir daigumas. Escherichia coli bakterinė kultūra buvo įvesta į vandeninę tiriamosios medžiagos ištrauką santykiu (1 : 1). Bandymo rezultatai pateikti 2 lentelėje.
lentelė. Sapropelio - durpių trąšų vertingumo nustatymas
| Bandymų variantai | Dygimo energija % | Daigumas % | Augimas pagal E.c. |
| 1. Sapropelis (S) | +9 | +12 | +2 |
| 2. Durpės (D) | +3 1 | -2 | -2 |
| 3. S + D 1:1 | +6 | +5 | +4 |
| 4. S + D 1:2 | +3 | +3 | +3 |
| 5. S + D 1:3 | +2 | +1 | +1 |
| 6. S + D 1:0,5 | +8 | +7 | +5 |
lentelės duomenys rodo, kad efektyviausia trąša yra sapropelio ir durpių mišinys 1 : 0,5, tačiau šios trąšos lėtokai džiūsta. Įvertinus abiejų lentelių duomenis buvo nustatyta, kad geriausias trąšų efektyvumas ir palygint neilgas džiovinimo laikas pasiekiam·- Yiant sapropelį su durpėmis sausųjų medžiagų masės santykiu apie 1:1. Toks mišinys gerai išdžiūsta ir gaunama efektyvi trąša.
Pasiūlytos sapropelio trąšos susideda iš sapropelio ir durpių mišinio, kuriame sapropelio ir durpių sausųjų medžiagų masių santykis mišinyje yra nuo 1 : 1 iki 1 : 0,5.
Trąšų gavimo būdas. Nustatomas pradinių medžiagų t.y. sapropelio ir durpių, iš kurių bus gaminamos trąšos, drėgnis. Žinomais literatūroje aprašytais būdais (payzdžiui, sapropelio sausųjų medžiagų kiekis, esant skirtingam žaliavos drėgniui, yra pateiktas grafiko pavidale knygoje L. Katkevičius, A. Ciūnys, E. Bakšienė “Ežerų sapropelis žemės ūkiui”, Vilnius, 1998, 50 psl.) nustatomas santykis tarp atitinkamo drėgnio žaliavos ir sausųjų medžiagų kiekio. Sis santykis pateikiamas 3 lentelėje.
lentelė.
| Žaliavos drėgnis, %. | Sausųjų medžiagų kiekis, kg/mJ |
| 90% | 100 kg/m3 |
| 80% | 220 kg/m3 |
| 70% | 360 kg/m3 |
| 65% | 590 kg/m3 |
| 50% | 670 kg/m3 |
| 40% | 820 kg/ m3 |
| 30% | . 960 kg/m3 |
Pagal pateiktą lentelę, esant sapropelio drėgniui 70%, sausųjų medžiagų kiekis yra 360 kg/m3, o durpių drėgniui esant apie 40%, sausųjų medžiagų kiekis yra 820 kg/m3, todėl, norint pasiekti minėtų sausųjų medžiagų santykį 1:1, sapropelio kiekį reikia padidinti ne mažiau kaip dvigubai. Esant nurodytam pradinių medžiagų drėgmiui dedama 1 m3 durpių ir 2 m3 sapropelio, po to nurodytu santykiu sudėtos medžiagos mechaniškai sumaišomos. Vėliau mišinys džiovinamas apie 15 parų, kol mišinio drėgnis pasiekia apie 50%.
Pasiūlytų sapropelio trąšų gavimo būdas detaliau paiškintas pateiktuoses pavyzdžiuose.
pavyzdys. Valant užpelkėjusius ežerus iškasamos durpės, kurios būna susiformavusios ežerų pakraščiuose. Durpės vienkaušiu ekskavatoriumi supilamos ant kranto į 2 - 3 m aukščio krūvas. Durpės krūvose greitai išdžiūsta (po 20 dienų jų drėgnis siekia 30 — 4u ir gali būti naudojamos trąšoms gaminti.
Sapropelis kuopiamas atskirai, dažniausiai pulpos pavidale siurbiamas žemsiurbe .> ir plastmasiniais vamzdžiais arba polietileninėmis rankovėmis (žarnomis) transportuojamas į sėsdintuvus, kur supilamas 0,5 m storio sluoksniu. Nuleidus iš sėsdintuvo vandenį sapropelio drėgnis siekia 80 - 85%.
Išdžiūvusios durpės vežamos prie sėsdintuvų, pilamos 0,3 - 0,4 m storio sluoksniu ant sapropelio sluoksnio ir ekskavatoriumi su juo sumaišomos. Po to mišinys dar džiovinamas apie 15 parų. Kai jo drėgnis siekia apie 50%, trąšų mišinys gali būti fasuojamas arba išvežamas autotransportu laukams tręšti.
pavyzdys. Sapropelio ir durpių gavyba vykdoma analogiškai aprašytam pirmajame pavyzdyje. Sapropelis sėsdintuve paliekamas džiūti 15-18 parų, kol jo paviršius sutrūkinėja (jo drėgnis siekia apie 70%). Prie sėsdintuvo atvežamos sausos durpės. Sapropelio ir durpių 6 LT 4864 B maišymas vykdomas betono (ar panašia) maišykle (apie 2/3 tūrio sudaro sapropelis, 1/3 durpės, kad sausųjų medžiagos santykis išliktų 1:1). Mišinio drėgnis siekia 50 - 45%. Po kelių (5-8) parų drėgmė dar sumažėja, mišinys pasidaro purus, birus, jo granulių dydis 0,3 0,8 cm. Mišinys fasuojamas į maišelius.
pavyzdys. Užpelkėjusioje ežero pakrantėje pradžioje vienkaušiu ekskavatoriumi kasamos durpės ir supilamos į 2 - 3 m aukščio krūvas. Po to iš gilesnių sluoksnių kasamos žemiau esantis sapropelis, kraunamas į traktorines priekabas ir išvežamas į sandėliavimo aikštelę, kur paskleidžiamas 0,5 m storio sluoksniu. Po 10 parų sapropelio paviršius sutrūkinėja, jo drėgnis siekia apie 70 %. Tuomet atvežamos išdžiūvusios durpės ir maišomos su sapropeliu pirmajame arba antrajame pavyzdžiuose aprašytu būdu.
Claims (2)
- IŠRADIMO APIBRĖŽTIS1. Sapropelio trąšos, susidedančios iš sapropelio ir durpių mišinio, besiskiriančios tuo, kad sapropelio ir durpių sausųjų medžiagų masių santykis mišinyje yra nuo 1 : 1 iki1 : 0,5.
- 2. Sapropelio trąšų pagal 1 punktą gavimo būdas, apimantis sapropelio išėmimą iš ežero, jo paskleidimą sluoksniu aikštelėje, džiovinimą ir džiovinimo metu, periodiškai maišant, durpių įvedimą į sapropelį, besiskiriantis tuo, kad sapropelio ir durpių sausųjų medžiagų masių santykį mišinyje palaiko nuo 1 : 1 iki 1 : 0,5.
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