LT2771307T - Akrilatų gamybos būdas iš epoksidų - Google Patents
Akrilatų gamybos būdas iš epoksidųInfo
- Publication number
- LT2771307T LT2771307T LTEP12842768.9T LT12842768T LT2771307T LT 2771307 T LT2771307 T LT 2771307T LT 12842768 T LT12842768 T LT 12842768T LT 2771307 T LT2771307 T LT 2771307T
- Authority
- LT
- Lithuania
- Prior art keywords
- epoxides
- acrylates
- production
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
- C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
- C07D305/12—Beta-lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/81—Preparation processes using solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161551496P | 2011-10-26 | 2011-10-26 | |
PCT/US2012/061791 WO2013063191A1 (fr) | 2011-10-26 | 2012-10-25 | Procédé pour la production d'acrylates à partir d'époxydes |
Publications (1)
Publication Number | Publication Date |
---|---|
LT2771307T true LT2771307T (lt) | 2018-09-25 |
Family
ID=48168463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
LTEP12842768.9T LT2771307T (lt) | 2011-10-26 | 2012-10-25 | Akrilatų gamybos būdas iš epoksidų |
Country Status (16)
Country | Link |
---|---|
US (3) | US9096510B2 (fr) |
EP (2) | EP2771307B1 (fr) |
JP (3) | JP6219834B2 (fr) |
KR (1) | KR101894709B1 (fr) |
CN (2) | CN107382699B (fr) |
CY (1) | CY1120779T1 (fr) |
DK (1) | DK2771307T3 (fr) |
ES (1) | ES2684970T3 (fr) |
HK (1) | HK1245240B (fr) |
HR (1) | HRP20181284T1 (fr) |
HU (1) | HUE039449T2 (fr) |
LT (1) | LT2771307T (fr) |
PL (1) | PL2771307T3 (fr) |
PT (1) | PT2771307T (fr) |
SI (1) | SI2771307T1 (fr) |
WO (1) | WO2013063191A1 (fr) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8445703B2 (en) | 2009-04-08 | 2013-05-21 | Novomer, Inc. | Process for beta-lactone production |
EP2707353B1 (fr) | 2011-05-13 | 2021-03-31 | Novomer, Inc. | Catalyseurs de carbonylation et procédé |
EP2771307B1 (fr) | 2011-10-26 | 2018-05-30 | Novomer, Inc. | Procédé pour la production d'acrylates à partir d'époxydes |
JP2015511947A (ja) | 2012-02-13 | 2015-04-23 | ノボマー, インコーポレイテッド | エポキシドから酸無水物を生成するためのプロセス |
WO2015085295A2 (fr) | 2013-12-07 | 2015-06-11 | Novomer, Inc. | Membranes de nanofiltration et procédés d'utilisation |
CN106232607A (zh) | 2014-03-14 | 2016-12-14 | 诺沃梅尔公司 | 环氧化物羰基化催化剂 |
WO2015171372A1 (fr) | 2014-05-05 | 2015-11-12 | Novomer, Inc. | Procédés de recyclage de catalyseurs |
WO2015184289A1 (fr) | 2014-05-30 | 2015-12-03 | Novomer Inc. | Procédés intégrés pour la synthèse de produits chimiques |
CN104014227B (zh) * | 2014-06-05 | 2016-03-09 | 万华化学集团股份有限公司 | 一种含环氧丙烷或环氧乙烷有机废气的净化方法 |
JP6670011B2 (ja) * | 2014-07-25 | 2020-03-18 | ノボマー, インコーポレイテッド | 金属錯体の合成およびその使用 |
MA41507A (fr) * | 2015-02-13 | 2017-12-19 | Novomer Inc | Systèmes et procédés de production de polymères |
MA41513A (fr) * | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de distillation pour la production d'acide acrylique |
WO2016130998A1 (fr) | 2015-02-13 | 2016-08-18 | Novomer, Inc. | Procédés de carbonylation continue |
MA41508A (fr) * | 2015-02-13 | 2017-12-19 | Novomer Inc | Systèmes et procédés de production d'acide polyacrylique |
US10662283B2 (en) * | 2015-02-13 | 2020-05-26 | Novomer, Inc. | Process and system for production of polypropiolactone |
MA41510A (fr) * | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de production d'acide acrylique |
EP3757088A1 (fr) * | 2015-02-13 | 2020-12-30 | Novomer, Inc. | Plate-forme de production chimique souple |
MA41514A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédés intégrés de synthèse chimique |
WO2017004441A2 (fr) | 2015-07-01 | 2017-01-05 | Novomer, Inc | Procédés pour la coproduction d'acide téréphtalique et de styrène à partir d'oxyde d'éthylène |
CA2991207A1 (fr) | 2015-07-01 | 2017-01-05 | Novomer, Inc. | Procedes de production d'acide terephtalique a partir d'oxyde d'ethylene |
MX2018001404A (es) | 2015-07-31 | 2018-08-15 | Novomer Inc | Sistema de produccion/proceso de producción para acido acrilico y sus precursores. |
US20180282251A1 (en) | 2017-03-21 | 2018-10-04 | Novomer, Inc. | Systems and processes for producing organic acids direct from beta-lactones |
JP6997459B2 (ja) * | 2016-03-21 | 2022-02-04 | ノボマー, インコーポレイテッド | 改良されたアクリル酸製造プロセス |
JP2019512585A (ja) * | 2016-03-21 | 2019-05-16 | ノボマー, インコーポレイテッド | 高吸収性ポリマーを生成するためのシステムおよび方法 |
US20180305286A1 (en) * | 2016-03-21 | 2018-10-25 | Novomer, Inc. | Systems and Processes for Producing Organic Acids Direct from Beta-Lactones |
KR20190025574A (ko) * | 2016-06-30 | 2019-03-11 | 제이엔씨 주식회사 | 에틸렌성 불포화기 함유 γ-부티로락톤 유도체의 제조 방법 |
CN109890785A (zh) * | 2016-11-02 | 2019-06-14 | 诺沃梅尔公司 | 吸收性聚合物和其制造方法与系统及其用途 |
US10144802B2 (en) | 2016-12-05 | 2018-12-04 | Novomer, Inc. | Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof |
US10500104B2 (en) | 2016-12-06 | 2019-12-10 | Novomer, Inc. | Biodegradable sanitary articles with higher biobased content |
EP3596156A4 (fr) | 2017-03-17 | 2020-12-30 | Novomer, Inc. | Polyamides et procédés de production de ces polyamides |
US10065914B1 (en) | 2017-04-24 | 2018-09-04 | Novomer, Inc. | Thermolysis of polypropiolactone to produce acrylic acid |
US10676426B2 (en) | 2017-06-30 | 2020-06-09 | Novomer, Inc. | Acrylonitrile derivatives from epoxide and carbon monoxide reagents |
US10899622B2 (en) * | 2017-06-30 | 2021-01-26 | Novomer, Inc. | Biobased carbon fibers and carbon black and methods of making the same |
US10781156B2 (en) | 2017-06-30 | 2020-09-22 | Novomer, Inc. | Compositions for improved production of acrylic acid |
US10961209B2 (en) | 2017-08-10 | 2021-03-30 | Novomer, Inc. | Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts |
US10590099B1 (en) | 2017-08-10 | 2020-03-17 | Novomer, Inc. | Processes for producing beta-lactone with heterogenous catalysts |
WO2019051184A1 (fr) * | 2017-09-09 | 2019-03-14 | Novomer, Inc. | Composés amide et nitrile et procédés de production et d'utilisation de ceux-ci |
US11814360B2 (en) | 2017-10-05 | 2023-11-14 | Novomer, Inc. | Isocyanates, derivatives, and processes for producing the same |
JP2021528478A (ja) | 2018-06-29 | 2021-10-21 | ノボマー, インコーポレイテッド | ベータ−ラクトンから有機酸を直接に生成するためのシステム及びプロセス |
WO2020014466A1 (fr) | 2018-07-13 | 2020-01-16 | Novomer, Inc. | Mousses de polylactone et leurs procédés de production |
WO2020033248A1 (fr) * | 2018-08-07 | 2020-02-13 | Novomer, Inc. | Processus de production de dérivés de bêta-lactone et de bêta-lactone avec des catalyseurs hétérogènes |
KR20210137037A (ko) | 2019-03-08 | 2021-11-17 | 노보머, 인코포레이티드 | 아미드 및 니트릴 화합물을 생산하기 위한 통합 방법 및 시스템 |
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US20220380330A1 (en) * | 2019-11-01 | 2022-12-01 | Exxonmobil Research And Engineering Company | Process for Producing Substituted Lactones |
EP4015077A1 (fr) * | 2020-12-15 | 2022-06-22 | Covestro Deutschland AG | Procédé de carbonylation des époxydés |
CN116964128A (zh) | 2021-02-26 | 2023-10-27 | 诺沃梅尔公司 | 用于生产可生物降解聚酯的方法 |
KR20230170697A (ko) | 2021-04-16 | 2023-12-19 | 노보머, 인코포레이티드 | 폴리프로피오락톤 및 제조 방법 |
WO2023003890A1 (fr) | 2021-07-21 | 2023-01-26 | Novomer, Inc. | Procédés de copolymérisation de bêta-lactone |
CN113786864A (zh) * | 2021-09-07 | 2021-12-14 | 安徽建筑大学 | 一种催化剂及其催化乙酰丙酸加氢制γ-戊内酯的方法 |
CN115850065A (zh) * | 2022-10-14 | 2023-03-28 | 东莞理工学院 | 一种以硫酸氢钠为催化剂催化聚3-羟基丁酸酯降解制备r-3-羟基丁酸酯的方法 |
CN116273120A (zh) * | 2023-03-07 | 2023-06-23 | 淮安禾之盛新材料技术开发服务有限公司 | 一种碳氮掺杂负载型钴基催化剂及其制备方法与应用 |
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EP2771307B1 (fr) * | 2011-10-26 | 2018-05-30 | Novomer, Inc. | Procédé pour la production d'acrylates à partir d'époxydes |
JP2015511947A (ja) | 2012-02-13 | 2015-04-23 | ノボマー, インコーポレイテッド | エポキシドから酸無水物を生成するためのプロセス |
SG11201405138SA (en) | 2012-02-22 | 2014-11-27 | Novomer Inc | Acrylic acid production methods |
JP5843659B2 (ja) | 2012-02-24 | 2016-01-13 | 株式会社日本触媒 | エポキシドのラクトン化用触媒及びそれを用いたラクトン化方法 |
CA2877903A1 (fr) | 2012-06-27 | 2014-01-03 | Novomer, Inc. | Catalyseurs et procedes de fabrication de polyester |
JP2015523363A (ja) | 2012-07-02 | 2015-08-13 | ノボマー, インコーポレイテッド | アクリレート生成のための過程 |
WO2015085295A2 (fr) | 2013-12-07 | 2015-06-11 | Novomer, Inc. | Membranes de nanofiltration et procédés d'utilisation |
CN106232607A (zh) | 2014-03-14 | 2016-12-14 | 诺沃梅尔公司 | 环氧化物羰基化催化剂 |
WO2015171372A1 (fr) | 2014-05-05 | 2015-11-12 | Novomer, Inc. | Procédés de recyclage de catalyseurs |
WO2015184289A1 (fr) | 2014-05-30 | 2015-12-03 | Novomer Inc. | Procédés intégrés pour la synthèse de produits chimiques |
JP6670011B2 (ja) | 2014-07-25 | 2020-03-18 | ノボマー, インコーポレイテッド | 金属錯体の合成およびその使用 |
MA41510A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de production d'acide acrylique |
US10662283B2 (en) | 2015-02-13 | 2020-05-26 | Novomer, Inc. | Process and system for production of polypropiolactone |
EP3757088A1 (fr) | 2015-02-13 | 2020-12-30 | Novomer, Inc. | Plate-forme de production chimique souple |
MA41507A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Systèmes et procédés de production de polymères |
MA41514A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédés intégrés de synthèse chimique |
MA41508A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Systèmes et procédés de production d'acide polyacrylique |
WO2016130998A1 (fr) | 2015-02-13 | 2016-08-18 | Novomer, Inc. | Procédés de carbonylation continue |
MA41513A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de distillation pour la production d'acide acrylique |
-
2012
- 2012-10-25 EP EP12842768.9A patent/EP2771307B1/fr active Active
- 2012-10-25 PT PT12842768T patent/PT2771307T/pt unknown
- 2012-10-25 SI SI201231370T patent/SI2771307T1/sl unknown
- 2012-10-25 KR KR1020147013829A patent/KR101894709B1/ko active IP Right Grant
- 2012-10-25 WO PCT/US2012/061791 patent/WO2013063191A1/fr active Application Filing
- 2012-10-25 EP EP18168238.6A patent/EP3375769B1/fr active Active
- 2012-10-25 HU HUE12842768A patent/HUE039449T2/hu unknown
- 2012-10-25 LT LTEP12842768.9T patent/LT2771307T/lt unknown
- 2012-10-25 US US14/353,532 patent/US9096510B2/en active Active
- 2012-10-25 PL PL12842768T patent/PL2771307T3/pl unknown
- 2012-10-25 ES ES12842768.9T patent/ES2684970T3/es active Active
- 2012-10-25 CN CN201710361942.6A patent/CN107382699B/zh active Active
- 2012-10-25 DK DK12842768.9T patent/DK2771307T3/en active
- 2012-10-25 JP JP2014538976A patent/JP6219834B2/ja active Active
- 2012-10-25 CN CN201280061231.2A patent/CN103987682B/zh active Active
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2015
- 2015-06-29 US US14/753,457 patent/US20150299083A1/en not_active Abandoned
-
2016
- 2016-10-11 US US15/291,011 patent/US9914689B2/en active Active
-
2017
- 2017-06-22 JP JP2017122352A patent/JP6486992B2/ja active Active
-
2018
- 2018-04-11 HK HK18104751.1A patent/HK1245240B/zh not_active IP Right Cessation
- 2018-05-01 JP JP2018088351A patent/JP2018119010A/ja active Pending
- 2018-08-03 HR HRP20181284TT patent/HRP20181284T1/hr unknown
- 2018-08-28 CY CY181100899T patent/CY1120779T1/el unknown
Also Published As
Publication number | Publication date |
---|---|
EP3375769A1 (fr) | 2018-09-19 |
JP2018119010A (ja) | 2018-08-02 |
EP3375769B1 (fr) | 2022-03-09 |
CN107382699B (zh) | 2019-02-22 |
KR101894709B1 (ko) | 2018-09-05 |
JP2014532650A (ja) | 2014-12-08 |
WO2013063191A1 (fr) | 2013-05-02 |
CY1120779T1 (el) | 2019-12-11 |
ES2684970T3 (es) | 2018-10-05 |
HRP20181284T1 (hr) | 2018-10-05 |
JP2017171681A (ja) | 2017-09-28 |
DK2771307T3 (en) | 2018-08-13 |
JP6486992B2 (ja) | 2019-03-20 |
PL2771307T3 (pl) | 2019-06-28 |
EP2771307B1 (fr) | 2018-05-30 |
JP6219834B2 (ja) | 2017-10-25 |
CN103987682A (zh) | 2014-08-13 |
CN103987682B (zh) | 2017-06-16 |
US20150299083A1 (en) | 2015-10-22 |
EP2771307A4 (fr) | 2015-06-24 |
EP2771307A1 (fr) | 2014-09-03 |
US9096510B2 (en) | 2015-08-04 |
PT2771307T (pt) | 2018-10-09 |
HK1245240B (zh) | 2020-04-09 |
CN107382699A (zh) | 2017-11-24 |
SI2771307T1 (sl) | 2018-10-30 |
KR20140084257A (ko) | 2014-07-04 |
US9914689B2 (en) | 2018-03-13 |
US20140309399A1 (en) | 2014-10-16 |
US20170247309A1 (en) | 2017-08-31 |
HUE039449T2 (hu) | 2018-12-28 |
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