KR970027091A - 유기 규소 변성된 전하 수송성 화합물 및 이 화합물을 함유하고 전하 수송능을 갖는 경화성 조성물 - Google Patents

유기 규소 변성된 전하 수송성 화합물 및 이 화합물을 함유하고 전하 수송능을 갖는 경화성 조성물 Download PDF

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KR970027091A
KR970027091A KR1019960052270A KR19960052270A KR970027091A KR 970027091 A KR970027091 A KR 970027091A KR 1019960052270 A KR1019960052270 A KR 1019960052270A KR 19960052270 A KR19960052270 A KR 19960052270A KR 970027091 A KR970027091 A KR 970027091A
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organosilicon
charge transport
curable composition
represented
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노부오 구시비끼
기꾸꼬 다께우찌
히데끼 고바야시
도루 마사또미
가즈오 요시나가
유이찌 하시모또
슌이찌로 니시다
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마쯔무라 다다시
다우 코닝 아시아 가부시끼가이샤
아이즈까 고지
도레이 다우 코닝 실리콘 가부끼가이샤
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Abstract

본 발명은 구조가 하기 화학식 (I)로 표시되는 유기 규소 변성된 전하 수송성 화합물, 및 이 유기 규소 변성된 전하 수송성 화합물과 유기 규소계 고분자를 주성분으로 하는 경화형 수지를 함유하는 경화성 조성물에 관한 것이다.
상기 식 중, A는 전하 수송기를 나타내고, Q는 가수 분해성기 또는 히드록실기를 나타내고, R2는 탄소 원자수 1 내지 15의 1가 탄화수소기 또는 할로겐 치환된 1가 탄화수소기를 나타내고, n은 1 내지 18이고, m은 1 내지 3이고, 1은 1 내지 5이다.

Description

유기 규소 변성된 전하 수송성 화합물 및 이 화합물을 함유하고 전하 수송능을 갖는 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 1의 4-[2-(트리에톡시실릴)에틸]트리페닐아민의 H-NMR 스펙트럼, 제2도는 실시예 4의 4-[N, N-비스(3,4-디메틸페닐)아미노]-[2-(트리에톡시실릴)에틸]벤젠의 H-NMR 스펙트럼, 제3도는 실시예 4의 4-[N,N-비스(3,4-디메틸페닐)아미노]-[2-(트리에톡시실릴)에틸]벤젠의 C-NMR 스펙트럼.

Claims (10)

  1. 구조가 하기 화학식 (I)로 표시되는 유기 규소 변성된 전하 수송성 화합물.
    상기 식 중, A는 전하 수송기를 나타내고, Q는 가수 분해성기 또는 히드록실기를 나타내고, R2는 탄소 원자수 1 내지 15의 1가 탄화수소기 또는 할로겐 치환된 1가 탄화수소기를 나타내고, n은 1 내지 18이고, m은 1내지 3이고, 1은 1내지 5이다.
  2. 제1항에 있어서, 상기 가수 분해성기가 -OR1(여기서, R1은 탄소 원자수 1 내지 6의 알킬기 또는 알콕시 알킬기를 나타냄)로 표시되는 기인 유기 규소 변성된 전하 수송성 화합물.
  3. 제1항에 있어서, 이온화 포텐셜이 4.5eV 내지 6.2eV인 유기 규소 변성된 전하 수송성 화합물.
  4. 제1항에 있어서, 상기 전하 수송기의 구조가 하기 화학식 (II)로 표시되는 것인 유기 규소 변성된 전하 수송성 화합물.
    상기 식 중, R3, R4및 R5는 각각 유기기를 나타내고, 이들 중 적어도 하나는 방향족 탄화수소 고리기 또는 헤테로시클릭기를 나타내고, R3, R4및 R5는 동일하거나 또는 상이할 수 있다.
  5. 규소 원자에 결합된 1가 탄화수소기 및 규소 원자의 비가 0.5 내지 1.5인 유기 규소계 고분자를 주성분으로 하는 경화형 수지 및 구조가 하기 화학식 (I)로 표시되는 유기 규소 변성된 전하 수송성 화합물을 포함하는, 전하 수송능을 갖는 경화성 조성물.
    상기 식 중, A는 전하 수송기를 나타내고, Q는 가수 분해성기 또는 히드록실기를 나타내고, R2는 탄소 원자수 1 내지 15의 1가 탄화수소기 또는 할로겐 치환된 1가 탄화수소기를 나타내고, n은 1 내지 18이고, m은 1 내지 3이고, 1은 1 내지 5이다.
  6. 제5항에 있어서, 상기 가수 분해성기가 -OR1(여기서, R1은 탄소 원자수 1 내지 6의 알킬기 또는 알콕시 알킬기를 나타냄)로 표시되는 기인 경화성 조성물.
  7. 제5항에 있어서, 상기 유기 규소계 고분자가 하기 일반식(Ⅲ)으로 표시되는 구조 단위를 갖는 오르가노폴리실록산인 경화성 조성물.
    R6 nSiO(4-n-m)/2(OR7)m(Ⅲ)
    상기 식 중, R6은 탄소 원자수 1 내지 18의 직쇄 또는 분지쇄 알킬기 또는 알케닐기, 또는 아릴기를 나타내고, R7은 탄소 원자수 1 내지 4의 알킬기를 나타내고, n은 평균 0.5 내지 1.5이고, m은 평균 0.001 내지 1.5이다.
  8. 제5항에 있어서, 상기 유기 규소 변성된 전하 수송성 화합물이 경화성 수지의 유기 규소계 고분자 100 중량부에 대하여 20 중량부 내지 200 중량부의 양으로 함유되는 것인 경화성 조성물.
  9. 제5항에 있어서, 상기 전하 수송기의 구조가 하기 화학식(Ⅱ)로 표시되는 것인 경화성 조성물.
    상기 식중, R3, R4및 R5는 각각 유기기를 나타내고, 이들 중 적어도 하나는 방향족 탄화수소 고리기 또는 헤테로시클릭기를 나타내고, R3, R4및 R5는 동일하거나 또는 상이할 수 있다.
  10. 제5항에 있어서, 상기 경화성 수지가 하기 화학식(Ⅳ)로 표시되는 실란 화합물을 함유하는 것인 경화성 조성물.
    R8 aSiX4-a(Ⅳ)
    상기 식 중, R8은 탄소 원자수 1 내지 18의 직쇄 또는 분지쇄 또는 알케닐기, 또는 페닐기를 나타내고, X는 가수 분해성기를 나타내고, a는 몰비를 나타낸다.
    ※ 참고사항 : 최초출원 의하여 공개하는 것임.
KR1019960052270A 1995-11-06 1996-11-06 유기 규소 변성된 전하 수송성 화합물 및 이 화합물을 함유하고 전하 수송능을 갖는 경화성 조성물 KR100195429B1 (ko)

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