KR960022547A - 헤테로사이클릭 카르벤을 갖는 금속 착화합물 - Google Patents
헤테로사이클릭 카르벤을 갖는 금속 착화합물 Download PDFInfo
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- KR960022547A KR960022547A KR1019950054212A KR19950054212A KR960022547A KR 960022547 A KR960022547 A KR 960022547A KR 1019950054212 A KR1019950054212 A KR 1019950054212A KR 19950054212 A KR19950054212 A KR 19950054212A KR 960022547 A KR960022547 A KR 960022547A
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- sulfonated
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- 229910052751 metal Inorganic materials 0.000 title claims 2
- 239000002184 metal Substances 0.000 title claims 2
- 125000000623 heterocyclic group Chemical group 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 7
- 239000003446 ligand Substances 0.000 claims abstract 3
- 230000000737 periodic effect Effects 0.000 claims abstract 2
- -1 unsulfonated alkyl radicals Chemical class 0.000 claims 18
- 125000004432 carbon atom Chemical group C* 0.000 claims 7
- 150000003254 radicals Chemical class 0.000 claims 4
- 125000004429 atom Chemical group 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 2
- 150000001450 anions Chemical class 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 150000002500 ions Chemical class 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 2
- UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000005840 aryl radicals Chemical class 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical group C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 claims 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims 1
- 150000002527 isonitriles Chemical class 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 150000005673 monoalkenes Chemical class 0.000 claims 1
- 125000002950 monocyclic group Chemical group 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 125000002577 pseudohalo group Chemical group 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 125000005023 xylyl group Chemical group 0.000 claims 1
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- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
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- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0086—Platinum compounds
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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- B01J31/2265—Carbenes or carbynes, i.e.(image)
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- B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
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- B01J31/22—Organic complexes
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- C07F15/0033—Iridium compounds
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Abstract
본 발명은, 리간드로서 헤테로사이를릭 카르벤을 갖는, 주기율표의 8족, 9족 및 10족 원소의 신규한 착화합물에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 다음 일반식(I)의 착화합물.상기 식에서, M은 중심원자로서의 주기율표의 8족, 9족 및 10족 금속의 산화상태 1 내지 8의 이온을 나타내며, X는 중심원자에 결합된 하전되거나 하전되지 않은 단좌 또는 다좌 리간드이며, L은 또한 중심원자 M에 결합된 리간드로서 일반식모노카르벤 또는 일반식디카르벤을 포함하며, R1, R2, R3, R4, R5및 R6은 동일하거나 상이하고, 직쇄 또는 측쇄이며, 설폰화되거나 설폰화되지 않은 탄소수 1 내지 7의 알킬 라디칼, 설폰화되거나 설폰화되지 않은 탄소수 5내지 18의 모노사이클릭 또는 폴리사이클릭 라디칼, 설폰화되거나 설폰화되지 않은 탄소수 2내지 5의 알케닐 라디칼, 설폰화되거나 설폰화되지 앓은 탄소수 6 내지 14의 아릴 라디칼 또는 설폰화되거나 설폰화되지 않은 탄소수 7 내지 19의 아릴알킬 라디칼이고, R3, R4, R5및 R6은 또한 수소일 수 있고, R3은 R4와 함께, 또한 R5는 R6과 함께, 각각의 경우, 또한 동일하거나 상이하게 융합되고 설폰화되거나 설폰화되지 않은 탄소수 3 내지 7의 라디칼일 수 있으며, Y는 포화 또는 불포화, 직쇄 또는 측쇄의 탄소수 1 내지 4의 알킬리덴 라디칼, 디알킬실릴렌 라디칼 또는 테트라 알킬디실릴렌 라디칼이며, A는 1가 하전된 음이온 또는 다가 하전된 음이온의 화학적 등가물이고, b는 1 내지 3의 정수이며, a는 (1 내지 5)x b의 정수이고, c는 0 또는 정수 (1 내지 4)x b이며, n은 0 또는 정수 1 내지 6이고, c+n은 0보다 크고, 단, (N,N′-디메틸벤즈이미다졸린-2-일리덴)클로로(1,5-사이클로 옥타디엔) 로듐은 제외된다.
- 제1항에 있어서, 일반식(I)X가 수소, 수소 이온, 할로겐, 할로겐 이온, 슈도할라이드, 카복실레이트 이온, 설포네이트 이온, 아미드 라디칼, 탄소수 1 내지 7의 알킬 라디칼, 알콜레이트 라디칼, 아세틸아세토네이트 라디칼, 일산화탄소, 일산화질소, 니트릴, 이소니트릴, 모노올레핀, 디올레핀, 알킬 및 π-방향족의 착화합물.
- 제1항 또는 제2항에 있어서, 일반식(II), (III), (IV) 및 (V)에서, R1, R2, R3, R4, R5및 R6이 각각 메틸, 이소프로필, 3급-부틸, 벤질, 트리페닐메틸, 페닐, 톨릴, 크실릴 및 메시틸인 착화합물.
- 제1항 내지 제3창 중의 어느 한 항에 있어서, 일반식(II), (III), (IV) 및 (V)에서, R1, R2가 동일하거나 상이하고 각각 메틸, 3급-부틸, 페닐, 벤질 또는 o-톨릴인 착화합물.
- 제1항 내지 제4항 중의 어느 한 항에 있어서, 일반식(II), (III), (IV) 및 (V)에서, R3및 R4는 각각 수소 또는 메틸인 착화합물.
- 제1항 내지 제5항 중의 어느 한 항에 있어서, 일반식(II), (III), (IV) 및 (V)에서, R3은 R4와 함께, R5는 R6과 함께 그룹(CH4), (CH2)4및 (CH2)5을 나타내는 착화합물.
- 제1항 내지 제6항 중의 어느 한 항에 있어서, 일반식(IV) 및 (V)에서, Y가 메틸렌, 디메틸메틸렌, 디페닐메틸렌 또는 에틸리덴인 착화합물.
- 제1항 내지 제6항 중의 어느 한 항에 있어서, 일반식(IV) 및 (V)에서, Y가 디메틸실린렌 또는 테트라메틸디실릴렌인 착화합물.
- 제1항 내지 제8항 중의 어느 한 항에 있어서, 일반식(I)에서, a가 1 또는 2인 착화합물.
- 제1항 내지 제9항 중의 어느 한 항에 있어서, 일반식(I)에서, b가 1인 착화합물.
- 제1항 내지 제10항 중의 어느 한 항에 있어서, 일반식(I)에서, n이 0 내지 3인 착화합물.
- 제1항 내지 제11항 중의 어느 한 항에 있어서, 일반식(I)에서, A가 할라이드 및 슈도할라이드 이온, 테트라페닐보레이트, 테트라플루오로보레이트, 헥사플루오로포스페이트, 아세테이트, 테트라카보닐코발테이트, 헥사플루오로페레이트, 테트라클로로페레이트, 테트라클로로알루미네이트 및 테트라클로로팔라데이트 이온인 착화합물.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4447066.5 | 1994-12-29 | ||
| DE4447066A DE4447066A1 (de) | 1994-12-29 | 1994-12-29 | Heterocyclische Carbene enthaltende Metallkomplexverbindungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960022547A true KR960022547A (ko) | 1996-07-18 |
| KR100377674B1 KR100377674B1 (ko) | 2003-06-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950054212A KR100377674B1 (ko) | 1994-12-29 | 1995-12-22 | 헤테로사이클릭카르벤을갖는금속착화합물 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5728839A (ko) |
| EP (1) | EP0721953B1 (ko) |
| JP (1) | JP2777880B2 (ko) |
| KR (1) | KR100377674B1 (ko) |
| CN (1) | CN1062273C (ko) |
| AT (1) | ATE215545T1 (ko) |
| AU (1) | AU699504B2 (ko) |
| BR (1) | BR9505988A (ko) |
| CA (1) | CA2165925C (ko) |
| DE (2) | DE4447066A1 (ko) |
| DK (1) | DK0721953T3 (ko) |
| ES (1) | ES2174895T3 (ko) |
| FI (1) | FI956232A (ko) |
| PL (1) | PL312030A1 (ko) |
| PT (1) | PT721953E (ko) |
| TW (1) | TW461891B (ko) |
| ZA (1) | ZA9510928B (ko) |
Families Citing this family (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19610908A1 (de) * | 1996-03-20 | 1997-09-25 | Hoechst Ag | Verfahren zur Herstellung heterocyclischer Carbene |
| EP0973786A1 (de) * | 1997-04-11 | 2000-01-26 | Ticona GmbH | Katalysator und verwendung des katalysators für die polymerisation |
| EP0921129A1 (en) * | 1997-12-03 | 1999-06-09 | Studiengesellschaft Kohle mbH | Highly active cationic ruthenium and osmium complexes for olefin metathesis reactions |
| DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| US7285593B1 (en) | 1998-05-19 | 2007-10-23 | Advanced Polymer Technologies, Inc. | Polyolefin compositions optionally having variable toughness and/or hardness |
| FR2778916B1 (fr) * | 1998-05-20 | 2000-06-30 | Rhone Poulenc Fibres | Nouveaux complexes organometalliques comprenant des carbenes heterocycliques cationiques et leur procede de preparation |
| US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| EP1115491B1 (en) * | 1998-09-10 | 2009-08-05 | University Of New Orleans Foundation | Catalyst complex with phenylindenylidene ligand |
| US6403802B1 (en) | 1998-09-10 | 2002-06-11 | University Of New Orleans Research & Technology Foundation | Use of catalyst system comprising nickel, palladium, or platinum and imidazoline-2-ylidene or imidazolidine-2-ylidene in amination reactions |
| US6316380B1 (en) * | 1998-09-10 | 2001-11-13 | University Of New Orleans Research & Technology Foundation | Catalyst system comprising transition metal and imidazoline-2-ylidene or imidazolidine-2-ylidene |
| US20140088260A1 (en) | 1999-02-05 | 2014-03-27 | Materia, Inc. | Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces |
| DE60037810T2 (de) | 1999-02-05 | 2009-01-22 | Materia, Inc., Pasadena | Metathese-aktive adhäsionsagenzien und verfahren zur vergrösserung der adhäsion von polymeren an oberflächen |
| MXPA01007857A (es) | 1999-02-05 | 2003-06-04 | Materia Inc | Composiciones de poliolefina que tienen densidad variable y metodos para su produccion y uso. |
| US6403801B1 (en) | 1999-02-22 | 2002-06-11 | University Of New Orleans Research & Technology Foundation | Use of a catalyst system comprising nickel, palladium, or platinum and imidazoline-2-ylidene of imidazolidine-2-ylidene in suzuki coupling reactions |
| US6362357B1 (en) | 1999-02-22 | 2002-03-26 | University Of New Orleans Research & Technology Foundation | Use a catalyst system comprising nickel palladium or platinum and imidazoline-2-ylidene or imidazolidine-2-ylidene in stille coupling reactions |
| JP2002540213A (ja) | 1999-03-31 | 2002-11-26 | カリフォルニア インスティチュート オブ テクノロジー | 高いオレフィンメタセシス活性を示す、トリアゾールイリデン配位子により配位された新規なルテニウム金属アルキルジエン錯体 |
| US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| US6369265B1 (en) | 1999-09-16 | 2002-04-09 | University Of New Orleans Research & Technology Foundation | Use of a catalyst system comprising nickel, palladium, or platinum and imidazoline-2-ylidene or imidazolidine-2-ylidene in kumada coupling reactions |
| US6586599B1 (en) | 2000-04-20 | 2003-07-01 | University Of New Orleans Research And Technology Foundation | Catalyzed coupling reactions of aryl halides with silanes |
| FR2806644B1 (fr) | 2000-03-23 | 2002-05-10 | Inst Francais Du Petrole | Composition catalytique et procede pour la catalyse de dimerisation, de codimerisation et d'oligomerisation des olefines |
| FR2806645B1 (fr) | 2000-03-23 | 2002-05-10 | Inst Francais Du Petrole | Composition catalytique et procede de dimerisation, de codimerisation et d'oligomerisation des olefines |
| US7220914B2 (en) * | 2003-12-01 | 2007-05-22 | Konarka Technologies, Inc. | Zwitterionic compounds and photovoltaic cells containing same |
| FR2813081B1 (fr) * | 2000-08-17 | 2005-12-23 | Rhodia Chimie Sa | Procede de preparation d'huiles silicones par hydrosilylation de synthons contenant au moins un cycle hydrocarbone dans lequel est inclus un atome d'oxygene en presence d'un complexe metallique catalytique |
| WO2002020535A1 (en) * | 2000-09-05 | 2002-03-14 | California Institute Of Technology | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
| AU2002239569A1 (en) | 2000-12-04 | 2002-06-18 | University Of New Orleans Research And Technology Foundation, Inc.(A Louisiana, Us, Corporation) | "metal complexes for hydrogenation of unsaturated compounds" |
| DE10062577B4 (de) * | 2000-12-15 | 2006-06-29 | Umicore Ag & Co. Kg | Carben-Dien-Komplexe von Nickel,Palladium und Platin |
| DE60238829D1 (de) * | 2001-03-23 | 2011-02-17 | California Inst Of Techn | Unter verwendung eines thermisch aktivierten n-heterocyclischen carbenvorläufers gebildete hochaktive metallcarbenmetathesekatalysatoren |
| EP1395616B1 (en) * | 2001-04-16 | 2019-05-22 | California Institute Of Technology | Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts |
| DE10148722A1 (de) * | 2001-10-02 | 2003-04-10 | Bayer Ag | Neue Übergangsmetall-Komplexe mit Diamino-Carbenliganden und deren Einsatz in Übergangsmetallkatalysierten Reaktionen |
| DE10151660B4 (de) * | 2001-10-19 | 2006-02-09 | Süd-Chemie AG | Katalysator und Verfahren zur partiellen Oxidation von Alkanen |
| DE60322365D1 (de) * | 2002-04-12 | 2008-09-04 | Dow Global Technologies Inc | Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation |
| DE60229443D1 (de) * | 2002-05-23 | 2008-11-27 | Rhodia Chimie Sa | Silikonzusammensetzung, die durch hydrosilylierung in gegenwart eines carben-metall-katalysators vernetzt werden kann und katalysator |
| DE10236079A1 (de) * | 2002-08-07 | 2004-02-26 | Umicore Ag & Co.Kg | Neue Nickel-, Palladium- und Platin-Carbenkomplexe, ihre Herstellung und Verwendung in katalytischen Reaktionen |
| AU2003255395A1 (en) * | 2002-08-07 | 2004-02-25 | Umicore Ag And Co. Kg | Novel nickel-carbene, palladium-carbene and platinum-carbene complexes, their production and use in catalytic reactions |
| US7226661B2 (en) * | 2003-02-03 | 2007-06-05 | Board Of Regents, The University Of Texas System | Synthesis of quinones and phenols on solid support |
| DE602004027473D1 (de) * | 2003-03-21 | 2010-07-15 | Dow Global Technologies Inc | Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie |
| US8519146B2 (en) * | 2004-09-07 | 2013-08-27 | The University Of Akron | Metal complexes of N-heterocyclic carbenes as antibiotics |
| CN1926141A (zh) * | 2003-09-05 | 2007-03-07 | 阿克伦大学 | 用作放射性药物和抗生素的n－杂环卡宾的金属配合物 |
| US7041758B2 (en) * | 2004-03-26 | 2006-05-09 | Rohm And Haas Company | Catalyst complexes for polymerization and co-polymerization of cyclic olefins |
| DE102005036040A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Telomerisation von nicht cyclischen Olefinen |
| WO2006058535A2 (de) * | 2004-11-30 | 2006-06-08 | Technische Universität Dresden | N-heterozyklische carbenkomplexe des platins und des palladiums, deren herstellung und verwendung zur partiellen oxidation von kohlenwasserstoffen |
| DE102005058206B4 (de) * | 2004-11-30 | 2017-09-07 | Technische Universität Dresden | N-heterozyklische Carbenkomplexe des Platins und des Palladiums und deren Verwendung |
| DE102004060247A1 (de) * | 2004-12-15 | 2006-06-29 | Studiengesellschaft Kohle Mbh | Neue N-heterocyclische Carbene und ihre Anwendung in der Katalyse |
| BRPI0517210B1 (pt) | 2004-12-17 | 2017-01-24 | Dow Global Technologies Inc | composição adequada para tubos, composição adequada para películas sopradas, composição adequada para artigos moldados soprados, tubo, película, artigo moldado por sopro e método para melhorar o comportamento de fluxo de fluência de uma resina |
| WO2006080515A1 (ja) * | 2005-01-31 | 2006-08-03 | Ube Industries, Ltd. | 置換エチニル金－含窒素へテロ環カルベン錯体及びそれを用いた有機エレクトロルミネッセンス素子 |
| WO2006106842A1 (ja) * | 2005-03-31 | 2006-10-12 | Idemitsu Kosan Co., Ltd. | 遷移金属錯体化合物及びそれを用いた有機エレクトロルミネッセンス素子 |
| CN101282982B (zh) * | 2005-10-05 | 2013-03-27 | Lg化学株式会社 | 用于聚合环烯烃的催化剂 |
| EP1803747A1 (en) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films |
| RU2008122073A (ru) | 2006-05-02 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. (Us) | Композиции полиэтилена высокой плотности, способ их получения, оболочки проводов и кабелей, изготовленные из них, и способ получения таких оболочек проводов и кабелей |
| US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
| DE102007023515A1 (de) | 2006-07-05 | 2008-01-10 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Dienen durch Hydrodimerisierung |
| CN101528755B (zh) * | 2006-10-24 | 2012-07-04 | 宇部兴产株式会社 | 金络合物及其制法、以及使用该金络合物的有机紫外电致发光元件 |
| BRPI0713185B1 (pt) * | 2007-05-02 | 2018-08-28 | Dow Global Technologies Inc | composição de polietileno de alta densidade, método para produzir uma composição de polietileno de alta densidade, tampa de garrafa, método para produzir uma tampa de garrafa e composição de polietileno de alta densidade |
| US7981517B2 (en) * | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
| FR2928151B1 (fr) * | 2008-03-03 | 2010-12-31 | Sanofi Aventis | Derives platine-carbene n-heterocyclique, leur preparation et leur application en therapeutique |
| CN102137852B (zh) * | 2008-06-18 | 2014-10-01 | 科技研究局 | 羟甲基糠醛的制备 |
| RU2515900C2 (ru) | 2008-12-18 | 2014-05-20 | Юнивейшн Текнолоджиз, Ллк | Способ обработки зародышевого слоя реакции полимеризации |
| WO2010088265A1 (en) | 2009-01-30 | 2010-08-05 | Dow Global Technologies Inc. | High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices |
| CA2760789C (en) | 2009-05-05 | 2016-07-19 | Stepan Company | Sulfonated internal olefin surfactant for enhanced oil recovery |
| DE102009031683A1 (de) * | 2009-07-03 | 2011-03-24 | Siemens Aktiengesellschaft | Phophoreszente Metallkomplexverbindung, Verfahren zur Herstellung dazu und strahlungsemittierendes Bauelement |
| DE102010040822B4 (de) * | 2010-09-15 | 2013-09-12 | Ernst-Moritz-Arndt-Universität | Neue Imidazoliumsalze und darauf basierende Carben-Metallkomplexe zur Verwendung als bioanalytische Marker für Biomoleküle |
| US8227371B2 (en) | 2010-09-24 | 2012-07-24 | Exxonmobil Chemical Patents Inc. | Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof |
| US9181360B2 (en) | 2011-08-12 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Polymers prepared by ring opening / cross metathesis |
| IN2015DN03815A (ko) | 2012-12-28 | 2015-10-02 | Univation Tech Llc | |
| BR112015016824B1 (pt) | 2013-01-14 | 2020-10-06 | Univation Technologies, Llc. | Método para produzir um sistema catalítico e processo de polimerização |
| HUP1300539A2 (hu) * | 2013-09-18 | 2015-04-28 | Debreceni Egyetem | Katalizátor és eljárás hidrogéngáznak formiátból történõ elõállítására és hidrogénkarbonát hidrogénezésére, és az ezeket alkalmazó hidrogéntároló rendszer |
| EP2933274A1 (de) * | 2014-04-16 | 2015-10-21 | Evonik Degussa GmbH | Verfahren zur Herstellung von Polymeren mittels ringöffnender Polymerisation |
| US10000515B2 (en) * | 2014-08-12 | 2018-06-19 | Kyushu University, National University Corporation | Hydrosilylation reaction catalyst |
| JP6386888B2 (ja) * | 2014-11-20 | 2018-09-05 | 国立研究開発法人産業技術総合研究所 | 錯体化合物 |
| BR112017023386B1 (pt) | 2015-05-08 | 2022-04-05 | Exxonmobil Chemical Patents Inc | Processo de polimerização em fase gasosa em modo condensado |
| WO2018063765A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063764A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063767A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2019118073A1 (en) | 2017-12-13 | 2019-06-20 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization process |
| WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
| CN112055719B (zh) | 2018-05-02 | 2022-11-25 | 埃克森美孚化学专利公司 | 从中试装置放大到较大生产设施的方法 |
| US11459408B2 (en) | 2018-05-02 | 2022-10-04 | Exxonmobil Chemical Patents Inc. | Methods for scale-up from a pilot plant to a larger production facility |
| WO2020014138A1 (en) | 2018-07-09 | 2020-01-16 | Exxonmobil Chemical Patents Inc. | Polyethylene cast films and methods for making the same |
| EP3826833A1 (en) | 2018-07-26 | 2021-06-02 | ExxonMobil Chemical Patents Inc. | Multilayer foam films and methods for making the same |
| CN113195603B (zh) | 2018-11-13 | 2023-05-26 | 埃克森美孚化学专利公司 | 聚乙烯膜 |
| WO2020102380A1 (en) | 2018-11-13 | 2020-05-22 | Exxonmobil Chemical Patents Inc. | Polyethylene blends and films |
| WO2020163079A1 (en) | 2019-02-06 | 2020-08-13 | Exxonmobil Chemical Patents Inc. | Films and backsheets for hygiene articles |
| WO2021126458A1 (en) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved sealing performance and mechanical properties |
| US20230097375A1 (en) | 2020-03-12 | 2023-03-30 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved bending stiffness and high md tear resistance |
| CN114644661B (zh) * | 2020-12-18 | 2023-10-13 | 北京服装学院 | 一种咪唑类卡宾铁配合物及其应用 |
| WO2022187311A1 (en) * | 2021-03-02 | 2022-09-09 | Rutgers, The State University Of New Jersey | Sterically hindered n-aliphatic n-heterocyclic carbene catalysts and methods using same |
| US20240209124A1 (en) | 2021-04-30 | 2024-06-27 | Exxonmobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
| CN113355075B (zh) * | 2021-05-27 | 2022-08-30 | 长江大学 | 一种稠油降黏剂及其制备方法和应用 |
-
1994
- 1994-12-29 DE DE4447066A patent/DE4447066A1/de not_active Withdrawn
-
1995
- 1995-12-05 TW TW084112914A patent/TW461891B/zh not_active IP Right Cessation
- 1995-12-21 CA CA002165925A patent/CA2165925C/en not_active Expired - Fee Related
- 1995-12-21 ZA ZA9510928A patent/ZA9510928B/xx unknown
- 1995-12-21 BR BR9505988A patent/BR9505988A/pt active Search and Examination
- 1995-12-22 CN CN95120153A patent/CN1062273C/zh not_active Expired - Lifetime
- 1995-12-22 FI FI956232A patent/FI956232A/fi not_active Application Discontinuation
- 1995-12-22 PL PL95312030A patent/PL312030A1/xx unknown
- 1995-12-22 KR KR1019950054212A patent/KR100377674B1/ko not_active IP Right Cessation
- 1995-12-27 DK DK95120577T patent/DK0721953T3/da active
- 1995-12-27 PT PT95120577T patent/PT721953E/pt unknown
- 1995-12-27 AT AT95120577T patent/ATE215545T1/de not_active IP Right Cessation
- 1995-12-27 EP EP95120577A patent/EP0721953B1/de not_active Expired - Lifetime
- 1995-12-27 ES ES95120577T patent/ES2174895T3/es not_active Expired - Lifetime
- 1995-12-27 DE DE59510140T patent/DE59510140D1/de not_active Expired - Lifetime
- 1995-12-28 JP JP7343125A patent/JP2777880B2/ja not_active Expired - Lifetime
- 1995-12-28 AU AU40703/95A patent/AU699504B2/en not_active Ceased
- 1995-12-29 US US08/581,029 patent/US5728839A/en not_active Expired - Lifetime
Also Published As
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|---|---|
| DK0721953T3 (da) | 2002-06-17 |
| AU699504B2 (en) | 1998-12-03 |
| TW461891B (en) | 2001-11-01 |
| PL312030A1 (en) | 1996-07-08 |
| CA2165925A1 (en) | 1996-06-30 |
| CN1138045A (zh) | 1996-12-18 |
| ZA9510928B (en) | 1996-09-26 |
| EP0721953B1 (de) | 2002-04-03 |
| CA2165925C (en) | 2000-02-22 |
| FI956232A (fi) | 1996-06-30 |
| FI956232A0 (fi) | 1995-12-22 |
| EP0721953A1 (de) | 1996-07-17 |
| KR100377674B1 (ko) | 2003-06-11 |
| ATE215545T1 (de) | 2002-04-15 |
| DE4447066A1 (de) | 1996-07-04 |
| AU4070395A (en) | 1996-07-04 |
| DE59510140D1 (de) | 2002-05-08 |
| BR9505988A (pt) | 1997-12-23 |
| PT721953E (pt) | 2002-09-30 |
| JP2777880B2 (ja) | 1998-07-23 |
| US5728839A (en) | 1998-03-17 |
| CN1062273C (zh) | 2001-02-21 |
| JPH08231571A (ja) | 1996-09-10 |
| ES2174895T3 (es) | 2002-11-16 |
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