BR0314566A - ligante bis-quelante e uso do mesmo em processos de carbonilação - Google Patents

ligante bis-quelante e uso do mesmo em processos de carbonilação

Info

Publication number
BR0314566A
BR0314566A BRPI0314566-2A BR0314566A BR0314566A BR 0314566 A BR0314566 A BR 0314566A BR 0314566 A BR0314566 A BR 0314566A BR 0314566 A BR0314566 A BR 0314566A
Authority
BR
Brazil
Prior art keywords
sup
independently selected
arylenes
hydrogen
bis
Prior art date
Application number
BRPI0314566-2A
Other languages
English (en)
Inventor
Wei-Jun Peng
Jonathon E Holladay
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of BR0314566A publication Critical patent/BR0314566A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"LIGANTE BIS-QUELANTE E USO DO MESMO EM PROCESSOS DE CARBONILAçãO". Uma nova composição bis-quelante caracterizada pela fórmula I: onde M é um elemento do Grupo VB; R¬ 1~ e R¬ 2¬ são, cada um, independentemente, selecionados de hidrogênio e radicais hidrocarbila monovalentes; ou R¬ 1¬ e R¬ 2¬ ligam-se entre si para formar um di-radical; ou um dentre R¬ 1¬ ou R¬ 2¬ é hidrogênio ou um radical hidrocarbila monovalente, enquanto que o outro dentre R¬ 1¬ ou R¬ 2¬ é um radical hidrocarbila ligado a um átomo em Ar sendo que Ar é selecionado de 1,2-arilenos; Q é selecionado do grupo consistindo de 1,2-arilenos, 2,2'-bis-arilenos e diradicais alquilas; e W é selecionado do grupo consistindo de fórmulas II, III, IV ou V: onde M está definido anteriormente; cada R é selecionado independentemente de hidrogênio e radicais hidrocarbila monovalentes; X é selecionado de di-radicais alquila e arila; Ar¬ 1¬ e Ar¬ 2¬ são, cada um, independentemente selecionados de 1,2-arilenos; Ar¬ 3¬ e Ar¬ 4¬ são cada um, independentemente selecionados de radicais arila monovalentes; e na fórmula IV, n é 0 ou 1. A composição encontra utilidade como ligante em catalisadores para processos de carbonilação.
BRPI0314566-2A 2002-10-15 2003-09-26 ligante bis-quelante e uso do mesmo em processos de carbonilação BR0314566A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41862002P 2002-10-15 2002-10-15
PCT/US2003/030380 WO2004035595A1 (en) 2002-10-15 2003-09-26 Bis-chelating ligand and use thereof in carbonylation processes

Publications (1)

Publication Number Publication Date
BR0314566A true BR0314566A (pt) 2006-06-27

Family

ID=32107957

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0314566-2A BR0314566A (pt) 2002-10-15 2003-09-26 ligante bis-quelante e uso do mesmo em processos de carbonilação

Country Status (9)

Country Link
US (1) US7294729B2 (pt)
EP (1) EP1554293B1 (pt)
JP (1) JP2006503086A (pt)
CN (1) CN100418974C (pt)
AT (1) ATE388956T1 (pt)
AU (1) AU2003270902A1 (pt)
BR (1) BR0314566A (pt)
DE (1) DE60319725T2 (pt)
WO (1) WO2004035595A1 (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1639177B (zh) 2002-03-11 2010-05-05 陶氏技术投资有限责任公司 用于羰基化过程的双亚磷酸酯
WO2005007602A1 (en) * 2003-07-03 2005-01-27 Union Carbide Chemicals & Plastics Technology Corporation Minimization of ligand degradation products, of reversion of same to useful phosphine ligands
US20080027218A1 (en) * 2004-04-29 2008-01-31 Daugs Edward D Hydroformylation Process for Pharmaceutical Intermediate
DE102004049339A1 (de) * 2004-10-08 2006-04-13 Basf Ag Verfahren zur Reinigung von phosphorhaltigen Chelat-Liganden
KR101381015B1 (ko) * 2006-04-04 2014-04-04 가부시키가이샤 구라레 비스포스파이트 및 제 8 ∼ 10 족 금속 화합물을 사용한 알데히드의 제조 방법, 그리고 그 비스포스파이트
WO2007133379A1 (en) * 2006-05-15 2007-11-22 Dow Global Technologies Inc. Hydroformylation process and product separation with improved recovery of rhodium
DE102006058682A1 (de) * 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
US7906688B2 (en) * 2007-04-05 2011-03-15 Dow Global Technologies Inc. Calixarene bisphosphite ligand for use in hydroformylation processes

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US4947003A (en) * 1988-11-28 1990-08-07 Virginia Tech Intellectual Properties, Inc. Process for the hydroformulation of olefinically unsaturated organic reactants using a supported aqueous phase catalyst
JP2893902B2 (ja) * 1989-10-19 1999-05-24 三菱化学株式会社 オレフィンのヒドロホルミル化法
US5292785A (en) 1992-05-05 1994-03-08 Ciba-Geigy Corporation Bis-phosphite stabilized compositions
DK0730574T3 (da) 1993-11-23 1999-05-25 Du Pont Fremgangsmåder og katalysatorsammensætninger til hydrocyanering af monoolefiner
US5756855A (en) * 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
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CN1639177B (zh) * 2002-03-11 2010-05-05 陶氏技术投资有限责任公司 用于羰基化过程的双亚磷酸酯
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Also Published As

Publication number Publication date
JP2006503086A (ja) 2006-01-26
DE60319725T2 (de) 2009-01-29
DE60319725D1 (de) 2008-04-24
AU2003270902A1 (en) 2004-05-04
EP1554293A1 (en) 2005-07-20
CN100418974C (zh) 2008-09-17
EP1554293B1 (en) 2008-03-12
US7294729B2 (en) 2007-11-13
ATE388956T1 (de) 2008-03-15
WO2004035595A1 (en) 2004-04-29
CN1688593A (zh) 2005-10-26
US20060058557A1 (en) 2006-03-16

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