DE60238829D1 - Unter verwendung eines thermisch aktivierten n-heterocyclischen carbenvorläufers gebildete hochaktive metallcarbenmetathesekatalysatoren - Google Patents

Unter verwendung eines thermisch aktivierten n-heterocyclischen carbenvorläufers gebildete hochaktive metallcarbenmetathesekatalysatoren

Info

Publication number
DE60238829D1
DE60238829D1 DE60238829T DE60238829T DE60238829D1 DE 60238829 D1 DE60238829 D1 DE 60238829D1 DE 60238829 T DE60238829 T DE 60238829T DE 60238829 T DE60238829 T DE 60238829T DE 60238829 D1 DE60238829 D1 DE 60238829D1
Authority
DE
Germany
Prior art keywords
metethesis
carbent
heterocyclic
catalysts
processor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60238829T
Other languages
English (en)
Inventor
Andrew Bell
Robert H Grubbs
John P Morgan
Jason L Moore
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
California Institute of Technology CalTech
Materia Inc
Original Assignee
California Institute of Technology CalTech
Materia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by California Institute of Technology CalTech, Materia Inc filed Critical California Institute of Technology CalTech
Application granted granted Critical
Publication of DE60238829D1 publication Critical patent/DE60238829D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/466—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE60238829T 2001-03-23 2002-03-25 Unter verwendung eines thermisch aktivierten n-heterocyclischen carbenvorläufers gebildete hochaktive metallcarbenmetathesekatalysatoren Expired - Lifetime DE60238829D1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US27831101P 2001-03-23 2001-03-23
US28868001P 2001-05-03 2001-05-03
US36077502P 2002-03-01 2002-03-01
PCT/US2002/009273 WO2002076613A1 (en) 2001-03-23 2002-03-25 High activity metal carbene metathesis catalysts generated using a thermally activated n-heterocyclic carbene precursor

Publications (1)

Publication Number Publication Date
DE60238829D1 true DE60238829D1 (de) 2011-02-17

Family

ID=30003738

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60238829T Expired - Lifetime DE60238829D1 (de) 2001-03-23 2002-03-25 Unter verwendung eines thermisch aktivierten n-heterocyclischen carbenvorläufers gebildete hochaktive metallcarbenmetathesekatalysatoren

Country Status (9)

Country Link
EP (1) EP1372844B1 (de)
JP (1) JP4402354B2 (de)
CN (1) CN1265881C (de)
AT (1) ATE494065T1 (de)
CA (1) CA2441500C (de)
DE (1) DE60238829D1 (de)
DK (1) DK1372844T3 (de)
MX (1) MXPA03008644A (de)
WO (1) WO2002076613A1 (de)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10137051A1 (de) * 2001-07-31 2003-02-20 Bayer Ag Neue Übergangsmetall-Komplexe und deren Einsatz in Übergangsmetall-katalysierten Reaktionen
JP4922558B2 (ja) * 2002-08-01 2012-04-25 カリフォルニア インスティテュート オブ テクノロジー 環状オレフィンモノマーの環挿入重合による大環状ポリマーの合成
US7390579B2 (en) 2003-11-25 2008-06-24 Magnequench, Inc. Coating formulation and application of organic passivation layer onto iron-based rare earth powders
DE102007039526A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
CN102083798B (zh) * 2008-04-09 2016-10-26 马特里亚公司 带有具有取代骨架的n-杂环卡宾配体的钌烯烃易位催化剂
JP5493628B2 (ja) * 2008-10-08 2014-05-14 住友化学株式会社 α−ヒドロキシケトン化合物の製造方法
WO2011083146A1 (fr) * 2010-01-08 2011-07-14 Bluestar Silicones France Sas Procede de preparation de carbene en solution, nouvelle forme stable de carbene obtenu notamment par ce procede et applications de celle-ci en catalyse.
CN102153557B (zh) * 2011-01-21 2013-03-20 中国科学院上海有机化学研究所 具有乙二胺骨架的多手性中心氮杂环卡宾前体盐、合成方法及用途
EP2644636A1 (de) * 2012-03-26 2013-10-02 Basf Se Verfahren zur herstellung von polyetherpolyolen
EP2644635A1 (de) * 2012-03-26 2013-10-02 Basf Se Verfahren zur organokatalytischen ringöffnenden Polymerisation
JP6271595B2 (ja) * 2013-02-27 2018-01-31 マテリア， インコーポレイテッド 金属カルベンオレフィンメタセシス２種の触媒組成物
EP2933274A1 (de) * 2014-04-16 2015-10-21 Evonik Degussa GmbH Verfahren zur Herstellung von Polymeren mittels ringöffnender Polymerisation
CN103965402B (zh) * 2014-05-21 2016-06-01 中国科学院长春应用化学研究所 一种环烯烃共聚物及其制备方法
WO2016022965A1 (en) 2014-08-08 2016-02-11 Massachusetts Institute Of Technology Persistent carbene adducts and related methods
KR20180059489A (ko) 2015-09-24 2018-06-04 우미코레 아게 운트 코 카게 금속 카르벤 올레핀 복분해 촉매
TW202134296A (zh) * 2020-01-02 2021-09-16 美商普羅梅勒斯有限公司 作為光學材料之保存期限延長的本體聚合型多環烯烴組成物
WO2022098537A1 (en) * 2020-11-03 2022-05-12 Cesaroni Aerospace Incorporated Ammunition cartridge cases
CN112547126B (zh) * 2020-12-21 2023-03-21 上海中化科技有限公司 钌卡宾化合物、其组合物、制备方法及应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4447066A1 (de) * 1994-12-29 1996-07-04 Hoechst Ag Heterocyclische Carbene enthaltende Metallkomplexverbindungen
DE19610908A1 (de) * 1996-03-20 1997-09-25 Hoechst Ag Verfahren zur Herstellung heterocyclischer Carbene
US6107420A (en) * 1998-07-31 2000-08-22 California Institute Of Technology Thermally initiated polymerization of olefins using Ruthenium or osmium vinylidene complexes
MXPA01012033A (es) * 1999-05-24 2002-11-04 California Inst Of Techn Catalizador de metatesis de metal-carbeno basado en inidazolidina.
AU2002307089A1 (en) * 2001-04-02 2002-10-15 California Institute Of Technology One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts

Also Published As

Publication number Publication date
CN1265881C (zh) 2006-07-26
DK1372844T3 (da) 2011-04-18
CA2441500A1 (en) 2002-10-03
EP1372844B1 (de) 2011-01-05
JP4402354B2 (ja) 2010-01-20
JP2004530540A (ja) 2004-10-07
EP1372844A1 (de) 2004-01-02
WO2002076613A1 (en) 2002-10-03
ATE494065T1 (de) 2011-01-15
MXPA03008644A (es) 2006-03-09
CA2441500C (en) 2016-05-17
CN1511064A (zh) 2004-07-07
EP1372844A4 (de) 2005-10-12

Similar Documents

Publication Publication Date Title
DE60238829D1 (de) Unter verwendung eines thermisch aktivierten n-heterocyclischen carbenvorläufers gebildete hochaktive metallcarbenmetathesekatalysatoren
TR970073A2 (tr) Alfa adrenerjik resentör antagonistleri olarak pirimidindion pirimidintrion,triazindion, tetrahidrokinazolindion türevleri.
WO2003087167A3 (en) Cross-metathesis of olefins directly substituted with an electron-withdrawing group using transition metal carbene catalysts
BR0016197A (pt) Sistema catalisador múltiplo
HK1071323A1 (en) Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
EA200401474A1 (ru) Способ получения катализатора полимеризации олефинов
MXPA03007873A (es) Materiales de estructura organometalicos y metodo para producir los mismos.
DE69941219D1 (de) Katalysatorkomplex mit phenylindenyliden-ligand
DE60238939D1 (de) Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen
PT1140956E (pt) Ligantes e complexos para a hidrogenacao enantiosselectiva
ATE424422T1 (de) Dual-site- olefinpolymerisationskatalysatorzusammensetzung
AU2003280428A1 (en) Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization
DK1495072T3 (da) Syntaktisk polyolefinsammensætning til rörbelægning
DE59308118D1 (de) Koordinations-katalysatorsysteme
DE69806634T2 (de) Ruthenium- und osmiumkatalysatoren mit hetercyclischem liganden
BR0313087B1 (pt) derivados de indenila tricÍclico substituÍdo com 4-arila contendo complexos de metais do grupo 4 e seu uso.
DE50107565D1 (de) Metallische Zylinderkopfdichtung
MY130628A (en) Phosphorus containing ligands for metathesis catalysts
FR2793435B1 (fr) Tete de rasoir comportant un element anti-friction solidaire d'une semelle
DE59904113D1 (de) Kolbenpumpe zur kraftstoffhochdruckversorgung
ATE380817T1 (de) Verfahren zur katalytischen herstellung von hydrocodon und hydromorphon
ATE404521T1 (de) Carbonylierunsprozess unter verwendung von metallkatalysatoren mit mehrzähnigen liganden
DE60317092D1 (de) Katalytisches verfahren zur herstellung von hydromorphone und hydrocodone
TWI256948B (en) Process for preparing adrenaline
DE602005013949D1 (de) Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren