KR950008463A - 초산의 제조방법 - Google Patents

초산의 제조방법 Download PDF

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Publication number
KR950008463A
KR950008463A KR1019940022862A KR19940022862A KR950008463A KR 950008463 A KR950008463 A KR 950008463A KR 1019940022862 A KR1019940022862 A KR 1019940022862A KR 19940022862 A KR19940022862 A KR 19940022862A KR 950008463 A KR950008463 A KR 950008463A
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South Korea
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promoter
iridium
liquid reaction
reaction composition
ruthenium
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KR1019940022862A
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English (en)
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KR100337066B1 (ko
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셔만 갈랜드 칼
프란시스 길레스 마틴
글렌 선레이 존
Original Assignee
제이쓰 와아윅 덴바이
비피 케미칼즈 리미티드
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Priority claimed from GB939318809A external-priority patent/GB9318809D0/en
Priority claimed from GB9408966A external-priority patent/GB9408966D0/en
Application filed by 제이쓰 와아윅 덴바이, 비피 케미칼즈 리미티드 filed Critical 제이쓰 와아윅 덴바이
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

(a) 초산, (b) 이리듐 촉매, (c) 요오도화 메틸, (d) 일정 농도이상의 물 및 (e) 메틸 아세테이트를 함유하는 액체 반응 조성물중에 메탄올 또는 그의 반응성 유도체를 일산화탄소와 접촉시킴으로써 메탄올 또는 그의 반응성 유도체를 카르보닐화시켜 초산을 제조하는 방법이 촉진제로서 루테늄과 오스뮴중 하나 이상의 것을 사용함으로써 개선되었다.

Description

초산의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 카르보닐화 반응기내에서 액체 반응 조성물중에 메탄올 또는 그의 반응성 유도체를 일산화탄소와 접촉시키는 것으로 구성된 메탄올 또는 그의 반응성 유도체의 카르보닐화에 의한 초산의 제조방법에 있어서, 상기 액체 반응 조성물이 (a) 초산, (b) 이리듐 촉매, (c) 요오도화 메틸, (d) 일정 농도이상의 물, (e) 메틸 아세테이트 및 (f) 촉진제로서 루테늄과 오스뮴중 하나 이상의 것을 함유함을 특징으로 하는 초산의 제조방법.
  2. 제1항에 있어서, 상기 반응기의 일산화탄소 부분압이 15bar 미만인 방법.
  3. 제1 또는 2항에 있어서, 촉진제 대 이리듐의 몰비가 0.1:1 내지 15:1인 방법.
  4. 제3항에 있어서, 촉진제가 루테늄인 방법.
  5. 제1 또는 2항에 있어서, 액체 반응 조성물이 100 내지 6000중량ppm의 이리듐을 함유하는 방법.
  6. 제5항에 있어서, 촉진제 대 이리듐의 몰비가 0.1:1 내지 15:1인 방법.
  7. 제6항에 있어서, 촉진제가 루테늄인 방법.
  8. 제1 또는 2항에 있어서, 액체 반응 조성물이 0.1 내지 15중량%의 물을 함유하는 방법.
  9. 제1 또는 2항에 있어서, 액체 반응 조성물이 1 내지 20중량%의 요오드화 메틸을 함유하는 방법.
  10. 제1 또는 2항에 있어서, 액체 반응 조성물이 1 내지 70중량%의 메틸 아세테이트를 함유하는 방법.
  11. 제1 또는 2항에 있어서, 액체 반응 조성물이 100 내지 6000ppm의 이리둠, 0.1 내지 15중량%의 물, 1 내지 20중량%의 요오드화 메틸 및 1 내지 70중량%의 메틸 아세테이트를 함유하는 방법.
  12. 제11항에 있어서, 촉진제 대 이리듐의 몰비가 0.1:1 내지 15:1인 방법.
  13. 제12항에 있어서, 촉진제가 루테늄인 방법.
  14. 일정농도이상의 물의 존재하에 메탄올 또는 그의 반응성 유도체를 카르보닐화시킴으로써 초산을 제조할 수 있는 (a) 이리듐 촉매, (b) 요오드화 메틸 및 (c) 루테늄과 오스뮴중 하나 이상의 촉진제를 함유하는 촉매계.
  15. 제14항에 있어서, 촉진제 대 이리듐의 몰비가 0.1:1 내지 15:1인 촉매계.
  16. 제15항에 있어서, 촉진제가 루테늄인 촉매계.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940022862A 1993-09-10 1994-09-10 초산의제조방법 KR100337066B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB9318809.2 1993-09-10
GB939318809A GB9318809D0 (en) 1993-09-10 1993-09-10 Process
GB93418809.2 1993-09-10
GB9408966.1 1994-05-05
GB9408966A GB9408966D0 (en) 1994-05-05 1994-05-05 Process

Publications (2)

Publication Number Publication Date
KR950008463A true KR950008463A (ko) 1995-04-17
KR100337066B1 KR100337066B1 (ko) 2002-11-30

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US (2) US5672743A (ko)
EP (1) EP0643034B1 (ko)
JP (2) JP4195103B2 (ko)
KR (1) KR100337066B1 (ko)
CN (2) CN1041915C (ko)
BR (1) BR9403499A (ko)
CA (1) CA2117569C (ko)
DE (1) DE69410557T2 (ko)
ES (1) ES2116539T3 (ko)
FI (1) FI944164A (ko)
IN (1) IN187227B (ko)
MY (1) MY121194A (ko)
NO (1) NO301708B1 (ko)
NZ (1) NZ264419A (ko)
RU (1) RU2132840C1 (ko)
SG (1) SG43676A1 (ko)
TW (1) TW252105B (ko)
UA (1) UA26345C2 (ko)
YU (1) YU49260B (ko)

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NZ264419A (en) 1995-03-28
TW252105B (ko) 1995-07-21
CN1041915C (zh) 1999-02-03
DE69410557T2 (de) 1998-09-17
US5672743A (en) 1997-09-30
CA2117569A1 (en) 1995-03-11
IN187227B (ko) 2002-03-02
JP2008110990A (ja) 2008-05-15
BR9403499A (pt) 1995-05-16
CA2117569C (en) 2003-12-30
KR100337066B1 (ko) 2002-11-30
NO943318L (no) 1995-03-13
DE69410557D1 (de) 1998-07-02
NO301708B1 (no) 1997-12-01
MY121194A (en) 2006-01-28
US5942460A (en) 1999-08-24
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FI944164A (fi) 1995-03-11
CN1210760A (zh) 1999-03-17
FI944164A0 (fi) 1994-09-09
EP0643034A1 (en) 1995-03-15
JP4195103B2 (ja) 2008-12-10
CN1107460A (zh) 1995-08-30
RU2132840C1 (ru) 1999-07-10
SG43676A1 (en) 1997-11-14
EP0643034B1 (en) 1998-05-27
RU94033107A (ru) 1996-07-20
UA26345C2 (uk) 1999-08-30
ES2116539T3 (es) 1998-07-16
NO943318D0 (no) 1994-09-08
YU53394A (sh) 1996-10-18
CN1092541C (zh) 2002-10-16

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