KR880701254A - 자기도우프성 중합체 - Google Patents

자기도우프성 중합체

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Publication number
KR880701254A
KR880701254A KR1019870701093A KR870701093A KR880701254A KR 880701254 A KR880701254 A KR 880701254A KR 1019870701093 A KR1019870701093 A KR 1019870701093A KR 870701093 A KR870701093 A KR 870701093A KR 880701254 A KR880701254 A KR 880701254A
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polymer
group
bronsted acid
carbon atoms
chain alkyl
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KR1019870701093A
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English (en)
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KR960009685B1 (ko
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우우들 프레드
헤에거 알란
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로져 지. 디트젤
유니버시티 오브 켈리포니아 평의원
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Publication of KR960009685B1 publication Critical patent/KR960009685B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

내용 없음

Description

자기도우프성 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 폴리(티오펜-3-아세트산)의 적의 스펙트럼이다.

Claims (22)

  1. 그(단량체 단위)의 약 0.01 내지 100몰%가 거기에 공유결합된 적어도 하나의 브론스테드 산기를 갖고 있는 복수개의 단량체 단위로 되어있는, 그의 골격를 따라 π-전자 공액체계를 갖는 것을 특징으로 하는 도전성 자기 도우프성 중합체.
  2. 제1항에 있어서, 공유 결합된 브론스테드산기를 갖고 있는 상기 단량체 단위가 다음 구조식(Ⅰ) 또는 (Ⅱ)로부터 선택되는 것을 특징으로 하는 중합체.
    상기식에서, Ht는 복소기이고, Y1,Y2,Y3및 Y4는 수소와 -R-X-M로 구성된 군에서 독립적으로 선택되고, R는 탄소원자수 1내지 약 10의 직쇄 또는 측쇄을 알킬, 에테르, 에스테르 또는 아미드 부분이고, M은 브론스테드산 음이온이고, 또한 은 산화될 때 양의 1가 카운터이온을 생성할 수 있는 원자이다.
  3. 제2항에 있어서, Ht는 NH, S, O, Se 및 Te으로 구성된 군에서 선택되고, Y1,Y2및 Y4는 수소이고, R은 탄소원자수 약 1 내지 10인 직쇄의 알킬 또는 에테르기고, X는 CO2또는 SO3이고, 또한 M은 H, Li, Na 및 K로 구성된 군에서 선택되는 것을 특징으로 하는 중합체.
  4. 제3항에 있어서, Ht는 NH또는 S이고, R은 탄소원자수 2 내지 약 4의 직쇄알킬이고, M은 H, Li및 Na로된 군에서 선택되는 것을 특징으로 하는 중합체.
  5. 제3항에 있어서, 공유 결합된 브론스테드산기를 갖고 있는 상기 단량체 단위가 화학식(Ⅰ)의 구조에 의해 주어지는 것을 특징으로 하는 중합체.
  6. 제4항에 있어서, 공유 결합된 브론스테드산 기를 갖고 있는 상기 단량체 단위가 화학식(Ⅰ)의 구조에의해 주어지는 것을 특징으로 하는 중합체.
  7. 제3항에 있어서, 공유 결합된 브론스테드산기를 갖고 있는 상기단량체 단위가 화학식(Ⅱ)에 의해 주어지는 것을 특징으로 하는 중합체.
  8. 제4항에 있어서, 공유 결합된 브론스테드산기를 갖고 있는 상기 단량체 단위가 화학식(Ⅱ)의 구조에 의해 주어지는 것을 특징으로 하는 중합체.
  9. 제1항에 있어서, 단일 중합체인 것을 특징으로 하는 중합체.
  10. 제1항에 있어서, 공중합체인 것을 특징으로 하는 중합체.
  11. 제1항에 있어서, 쯔비터 이온성 중합체인 것을 특징으로 하는 중합체.
  12. 제1항에 있어서, 상기 단량체 단위가, Ht는 복소기이고, R은 탄소원자수 1내지 약 10의 직쇄 또는 측쇄의 알킬, 에테르, 에스테르 또는 아미드 부분이고 X는 브론스테드산 음이온인 다음의 구조들로부터 선택되는 것을 특징으로 하는 쯔비터 이온성 중합체.
  13. 제12항에 있어서, Ht는 NH, S, O, Se 및 Te로 구성된 군으로부터 선택되고, R은 탄소원자수 약 1내지 10의 직쇄알킬 또는 에테르기이고 X는 CO2또는 SO2인 것을 특징으로 하는 쯔비터 이온성 중합체.
  14. 제13항에 있어서, Ht는 NH 또는 S이고 R은 탄소원자수 2내지 약 4인 직쇄 알킬인 것을 특징으로 하는 쯔비터이온성 중합체.
  15. 제1항에 의한 중합체로피복된 도전성 기판으로 되어 있는 것을 특징으로 하는 전기 화학적 전지용 전극.
  16. 제11항에 의한 중합체로 피복된 도전성 기판으로 되어 있는 것을 특징으로 하는 하는 전기 화학적 전지용전극.
  17. 다음 구조
    (상기식에서 Ht는 복소기이고, M은 산화시 양의 1가 카운터 이온을 생성하는 원자이고, X는 브론스테드 산기이고, R은 탄소원자수 1내지 약 10의 직쇄 또는 측쇄의 알킬, 에테르, 에스테르 또는 아미드 임)를 가진 단량체를 포함하는 전해질 용액을 만드는 단계와; 상기 전해질 용액 내에 작업전극과 대향 전극을 침지하는 단계와; 작업전극에서 상기 단량체의 중합이 일어나 다음 화학식
    의 반복구조를 가진 중합체가 생성되도록, 상기 작업전극과 상기 대향 전극사이에 전압을 인가하는 단계; 로 되어 있는 것을 특징으로 하는 자기 도우프된 쯔비터 이온성 중합체의 제조방법.
  18. 제17항에 있어서, 상기 중합이 약 -30℃와 약 25℃사이의 온도에서 행해지는 것을 특징으로 하는 방법.
  19. 제17항에 있어서, 상기 단량체가 티오펜-3-아세트산, 메틸 티오펜-3-(2-에탄 술포네이트), 및 메틸티오펜-3-(4-부탄술포네이트)로된 군에서 선택되는 것을 특징으로 하는 방법.
  20. 메틸 티오펜-3-(2-에탄술포네이트)로 되어 있는 도전성 중합체의 제조에 유용한 것을 특징으로 하는 화합물.
  21. 메틸 티오펜-3-(4-부탄술포네이트)로 되어 있는 도전성 중합체의 제조에 유용한 것을 특징으로 하는 화합물.
  22. 폴리아닐린 디에스테르를 제공하는 단계와; 상기 디에스테르를 해당하는 디카르복실산으로 변환시키기 위해 상기 디 에스테르를 수산화 물로 처리하는 단계로 되어 있는 것을 특징으로 하는 자기 도우프성 폴리아닐린의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870701093A 1986-03-24 1986-09-29 자기 도우프된 중합체의 제조방법 KR960009685B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP86-64271 1986-03-24
JP6427286 1986-03-24
JP64271/86 1986-03-24
PCT/US1986/002042 WO1987005914A1 (en) 1986-03-24 1986-09-29 Self-doped polymers

Publications (2)

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KR880701254A true KR880701254A (ko) 1988-07-26
KR960009685B1 KR960009685B1 (ko) 1996-07-23

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KR1019870701093A KR960009685B1 (ko) 1986-03-24 1986-09-29 자기 도우프된 중합체의 제조방법
KR1019950704733A KR100206730B1 (en) 1986-03-24 1995-10-27 Self-doped polymers
KR95704731A KR960012361B1 (en) 1986-03-24 1995-10-27 Electrode made of self-doped polymers

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Application Number Title Priority Date Filing Date
KR1019950704733A KR100206730B1 (en) 1986-03-24 1995-10-27 Self-doped polymers
KR95704731A KR960012361B1 (en) 1986-03-24 1995-10-27 Electrode made of self-doped polymers

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EP (1) EP0262147B1 (ko)
JP (2) JP2668060B2 (ko)
KR (3) KR960009685B1 (ko)
CN (2) CN1059914A (ko)
AT (1) ATE90948T1 (ko)
CA (1) CA1277989C (ko)
DE (1) DE3688615T2 (ko)
WO (1) WO1987005914A1 (ko)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0813873B2 (ja) * 1986-09-29 1996-02-14 昭和電工株式会社 水溶性自己ドープ型導電性ポリマー及びその製造方法
JPS6451434A (en) * 1987-08-21 1989-02-27 Tosoh Corp Aniline polymer and its production
JP2512523B2 (ja) * 1988-05-02 1996-07-03 株式会社トクヤマ 電 池
US5164465A (en) * 1988-05-13 1992-11-17 Ohio State University Research Foundation Sulfonated polyaniline salt compositions, processes for their preparation and uses thereof
JPH01315951A (ja) * 1988-06-16 1989-12-20 Tokuyama Soda Co Ltd 電気化学セル
JP2699500B2 (ja) * 1988-12-21 1998-01-19 東ソー株式会社 導電性高分子複合体
JP2763903B2 (ja) * 1989-01-18 1998-06-11 昭和電工株式会社 自己ドーピング機能を有する導電体の製造方法
EP0385523A1 (fr) * 1989-02-20 1990-09-05 SOLVAY (Société Anonyme) Procédé pour la préparation de polymères électroconducteurs dérivés de 3-alkylthiophènes et dispositifs électroconducteurs les contenant
JP2804285B2 (ja) * 1989-03-20 1998-09-24 昭和電工株式会社 導電性重合体組成物
FR2650909B1 (fr) * 1989-08-14 1994-07-29 Solvay Dispositifs electrochimiques de stockage d'energie comprenant un polymere conducteur d'electricite et leurs utilisations
US5284723A (en) * 1989-07-14 1994-02-08 Solvay & Cie (Societe Anonyme) Electrochemical energy storage devices comprising electricaly conductive polymer and their uses
FR2650833B1 (fr) * 1989-08-14 1991-11-08 Solvay Compositions de polymeres conducteurs d'electricite derives de pyrrole substitue ou non et procede pour leur obtention
JPH03205422A (ja) * 1990-01-08 1991-09-06 Nippon Oil Co Ltd ポリ［（３―ピロリル）酢酸］
JP2902727B2 (ja) * 1990-05-30 1999-06-07 株式会社日立製作所 荷電粒子線照射方法及び観察方法
JP2767721B2 (ja) * 1991-03-19 1998-06-18 富士写真フイルム株式会社 導電性高分子及びその製造方法
JPH05226238A (ja) * 1991-10-31 1993-09-03 Internatl Business Mach Corp <Ibm> Ｅ−ビームレジスト用の塩基現像可能な放電トップ層
US5648453A (en) * 1991-12-04 1997-07-15 Showa Denko K.K. Electroconductive polymer and process for producing the polymer
US5688873A (en) * 1991-12-04 1997-11-18 Showa Denko K.K. Electroconductive polymer and process for producing the polymer
US5589108A (en) * 1993-12-29 1996-12-31 Nitto Chemical Industry Co., Ltd. Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers
JP2942710B2 (ja) * 1994-11-14 1999-08-30 昭和電工株式会社 水溶性自己ドープ型導電性ポリマー複合体及びその製造方法
JP2960859B2 (ja) * 1994-11-14 1999-10-12 昭和電工株式会社 自己ドープ型導電性ポリマー水溶液及びその製造方法
JP2785116B2 (ja) * 1995-07-17 1998-08-13 昭和電工株式会社 水溶性自己ドープ型高分子導電体
US6024895A (en) * 1995-08-11 2000-02-15 Mitsubishi Rayon Co., Ltd. Cross-linkable, electrically conductive composition, electric conductor and process for forming the same
TW464661B (en) * 1996-06-10 2001-11-21 Nippon Catalytic Chem Ind Water-soluble electrically-conductive polyaniline and method for production thereof and antistatic agent using water-soluble electrically-conductive polymer
CN1056165C (zh) * 1996-12-25 2000-09-06 中国科学院长春应用化学研究所 掺杂态聚苯胺水溶液和水系分散液的制备
CN101319045B (zh) * 1999-04-06 2012-04-18 剑桥显示技术有限公司 掺杂聚合物的方法
US7217295B2 (en) 2002-01-31 2007-05-15 L'oreal S.A. Use of soluble conductive polymers for treating human keratin fibers
CN100398582C (zh) * 2002-06-26 2008-07-02 中国人民解放军63971部队 一种氯代聚苯胺的制备方法
KR100720628B1 (ko) 2002-11-01 2007-05-21 미츠비시 레이온 가부시키가이샤 탄소 나노튜브 함유 조성물, 이를 포함하는 도막을 갖는복합체, 및 이들의 제조 방법
FR2858222A1 (fr) * 2003-07-16 2005-02-04 Oreal Composition comprenant un polymere conducteur et un agent oxydant,procede de deformation permanente la mettant en oeuvre
CA2548510C (en) 2003-12-04 2012-10-16 University Of Manitoba A switchable self-doped polyaniline
TW200531587A (en) * 2003-12-09 2005-09-16 Showa Denko Kk Polymer for anode buffer layer, coating solution for anode buffer layer, and organic light emitting device
JP4760056B2 (ja) * 2005-03-01 2011-08-31 日産自動車株式会社 繊維アクチュエータ
WO2011069554A1 (en) * 2009-12-11 2011-06-16 Imec Polymers comprising 3 -substituted thiophene moieties as active layers for solar cells
BR112013002602A2 (pt) 2010-08-02 2016-06-07 Univ Florida método de processamento para materiais poliméricos solúveis em água
WO2013024532A1 (ja) 2011-08-17 2013-02-21 三菱レイヨン株式会社 固体電解コンデンサ、およびその製造方法
US10096395B2 (en) 2012-07-24 2018-10-09 Mitsubishi Chemical Corporation Conductor, conductive composition and laminate
JP2014139927A (ja) * 2012-12-20 2014-07-31 Nitto Denko Corp 蓄電デバイス、およびそれに用いる電極並びに多孔質シート
KR101775141B1 (ko) * 2015-04-27 2017-09-05 연세대학교 산학협력단 암 진단 및 치료용 나노 프로브
CN106653135A (zh) * 2017-02-04 2017-05-10 陈柏瑞 π电子轨域半导体型量子电池
CN115197583B (zh) 2017-02-10 2024-03-15 三菱化学株式会社 导电性组合物、导电性组合物的制造方法和导电体的制造方法
JP7094137B2 (ja) * 2017-05-08 2022-07-01 東ソー株式会社 ３，４－エチレンジオキシチオフェン構造を有するスルホン酸エステル、およびそれから誘導されるポリ（３，４－エチレンジオキシチオフェン）誘導体の合成法
JP6464245B1 (ja) 2017-09-20 2019-02-06 ▲緑▼能奈米科技有限公司 遠赤外線繊維の男性性機能を増強するための下着
WO2019146715A1 (ja) 2018-01-26 2019-08-01 三菱ケミカル株式会社 導電性組成物とその製造方法及び水溶性ポリマーとその製造方法
TW202344565A (zh) 2018-03-15 2023-11-16 日商三菱化學股份有限公司 導電膜及其製造方法、導電體、抗蝕劑圖案的形成方法及積層體
TWI802677B (zh) 2018-04-10 2023-05-21 日商三菱化學股份有限公司 導電性組成物、導電膜及積層體
EP3882314A4 (en) 2018-11-15 2022-03-16 Mitsubishi Chemical Corporation CONDUCTIVE COMPOSITION AND METHOD OF PRODUCTION, CONDUCTORS AND METHOD OF PRODUCTION
CN110628018A (zh) * 2019-09-10 2019-12-31 华南理工大学 一种聚苯胺类化合物的制备方法
KR20220114591A (ko) 2020-01-29 2022-08-17 미쯔비시 케미컬 주식회사 도전성 조성물, 레지스트 피복 재료, 레지스트, 및 레지스트 패턴의 형성 방법

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3557068A (en) * 1968-02-01 1971-01-19 Pennsalt Corp Thiophene polymers and method of preparation
US4001150A (en) * 1970-11-25 1977-01-04 Kansai Paint Company, Ltd. Composition for preparing electroconductive resin comprising an unsaturated polyester and phosphoric or sulfonic unsaturated ester
JPS5939447B2 (ja) * 1982-02-26 1984-09-22 東京工業大学長 線状ポリ（３−アルキル２、５−チエニレン）重合体およびその製造方法
US4501686A (en) * 1982-04-26 1985-02-26 Matsushita Electric Industrial Co., Ltd. Anion-doped polymers of five-membered oxygen family heterocyclic compounds and method for producing same
JPS58222151A (ja) * 1982-06-17 1983-12-23 Matsushita Electric Ind Co Ltd 複素五員環式化合物重合体
DE3223544A1 (de) * 1982-06-24 1983-12-29 Basf Ag, 6700 Ludwigshafen Copolymere von pyrrolen, verfahren zu ihrer herstellung sowie ihre verwendung
US4582595A (en) * 1982-07-27 1986-04-15 Mobil Oil Corporation Process for hydroprocessing heavy oils utilizing sepiolite-based catalysts
US4543402A (en) * 1983-04-18 1985-09-24 The B. F. Goodrich Company Electrically conductive pyrrole polymers
JPS59202226A (ja) * 1983-05-04 1984-11-16 Matsushita Electric Ind Co Ltd 複素五員環式化合物重合体
DE3325892A1 (de) * 1983-07-19 1985-01-31 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von feinteiligen elektrisch leitfaehigen pyrrol-polymerisaten
DE3325893A1 (de) * 1983-07-19 1985-01-31 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von feinteiligen elektrisch leitfaehigen pyrrol-polymerisaten
DE3327012A1 (de) * 1983-07-27 1985-02-07 Basf Ag, 6700 Ludwigshafen Verfahren zur elektrochemischen polymerisation von pyrrolen, anode zur durchfuehrung dieses verfahrens sowie nach diesem verfahren erhaltene produkte
JPS6065061A (ja) * 1983-09-19 1985-04-13 Matsushita Electric Ind Co Ltd ポリチェニレンもしくはその誘導体フィルム
DE3346934A1 (de) * 1983-12-24 1985-07-04 Basf Ag, 6700 Ludwigshafen Verfahren zur verbesserung der langzeitstabilitaet der elektrischen leitfaehigkeit von pyrrol-polymerisaten
JPS60229917A (ja) * 1984-04-28 1985-11-15 Agency Of Ind Science & Technol 有機半導体材料の製造方法
DE3425511A1 (de) * 1984-07-11 1986-01-16 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von p-gedopten polyheterocyclen
US4582575A (en) * 1984-09-04 1986-04-15 Rockwell International Corporation Electrically conductive composites and method of preparation
EP0203438A1 (en) * 1985-05-31 1986-12-03 Corporation Allied Solution processible forms of neutral and electrically conductive poly(substituted heterocycles)

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DE3688615T2 (de) 1993-10-07
EP0262147A4 (en) 1988-07-27
KR960012361B1 (en) 1996-09-18
CA1277989C (en) 1990-12-18
JPS6339916A (ja) 1988-02-20
JP2668060B2 (ja) 1997-10-27
CN86107279A (zh) 1987-10-07
WO1987005914A1 (en) 1987-10-08
CN1059914A (zh) 1992-04-01
KR100206730B1 (en) 1999-07-01
CN1019809B (zh) 1992-12-30
DE3688615D1 (de) 1993-07-29
EP0262147B1 (en) 1993-06-23
ATE90948T1 (de) 1993-07-15
KR960009685B1 (ko) 1996-07-23
JPH09120709A (ja) 1997-05-06
JP2858648B2 (ja) 1999-02-17
EP0262147A1 (en) 1988-04-06

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